(trans-Cinnamaldehyde)tris(2,6-diphenylphenoxy)aluminium

, the First Cyclized Lithium Amide Ladder: Synthesis and Structure of Hexamethyleneimidolithium

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A 1 : 1 Adduct of 2-Aminobenzothiazole and a Urea Derivative, and Its Spatial Arrangement

scholarly article by Matthew G. Davidson et al published December 1992 in Angewandte Chemie International Edition

A K3-containing trigonal-bipyramidal cluster: synthesis of (KSCN)3.5HMPA by reaction of solid NH4SCN with solid K or KH in toluene/HMPA and its crystal structure revealing a triangle of three K+ ions linked by three equatorial .mu.2-HMPA ligands and

A Li8cluster of three edge-connected Li4tetrahedra held by Li–N, Li ⋯ C, and Li ⋯ Li interactions: crystal structure of (o-LiC6H4CH2·NLi·CH2CH2NMe2)4and detection of metal ⋯ metal coupling within it by7Li COSY n.m.r. spectroscopy

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A Solid-State, Solution, and Theoretical Structural Study of Kinetic and Thermodynamic Lithiated Derivatives of a Simple Diazomethane and Their Reactivities Towards Aryl Isothiocyanates

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A solid state and theoretical study of the solvent effects controlling the mono- and di-lithiation of aromatic primary amines

A thiouracil-Ca2+ complex containing two tautomeric forms of the thiouracilyl anion: Synthesis and crystal structure of [(thiouracilyl)2Ca·2DMSO·H2O]2

A unique lithium halide complex, [(LiBr)2·3HMPA·toluene]: synthesis from reaction of solid NH4Br with BunLi in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ2-HMPA ligands, and detection

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Aggregation of Metalated Organics by Hydrogen Bonding: Synthesis and Crystal Structures of 2-Aminophenoxy-Aluminum and Salen-Aluminum Ligand-Separated Ion Pairs

scholarly article by Matthew G. Davidson et al published July 1995 in Inorganic Chemistry

Alkaline Earth Metal Complexes Containing Deprotonated Organic Acids and Water: Preparation, Structures and a New Synthetic Strategy

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An unusual Co2-containing anion: synthesis and structure of [(OxS)Ca·4HMPA]+·[(OxS)Co·µ-(OxS)3·CoCl]–[OxS–= C6H4O·(CS)N–; HMPA = OP(NMe2)3]

Azomethine derivatives. Part 20. Crystal and molecular structures of the lithioketimine [{Li(NCBut2)}6] and lithioguanidine [{Li[NC(NMe2)2]}6]; electron-deficient bridging of Li3triangles by methyleneamino-nitrogen atoms

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Bond enthalpies of borane anions BnHn2−

Bond indices, enthalpies and relative stabilities of real and hypothetical closo-BnHc−n clusters (n = 5–12; c = 0, 2 or 4) as revealed by the molecular-orbital bond index method

Bonding implications of interatomic distances and ligand orientations in the iminolithium hexamers [LiNC(Ph)But]6and [LiNC(Ph)NMe2]6: a stacked-ring approach to these and related oligomeric organolithium systems

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Characterization of the bis(pyridine) complex of the butyllithium-pyridine adduct, 2-Bun(C5H5N)Li·(C5H5N)2; its decomposition to 2-butylpyridine via a dihydropyridine

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Cluster bonding and energetics of the borane anions, BnHn2− (n = 5–12): A comparative study using bond length—bond enthal

Crystal and Solution Structures of [tBu2C?NLi�O?P(NMe2)3]n

scholarly article by Donald Barr et al published April 1985 in Angewandte Chemie International Edition

Crystal structure of sodium iodide·(diglyme): An unprecedented bridging role for diglyme

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Crystal structures of (Ph2CNLi·NC5H5)4and [CILi·OP(NMe2)3]4; discrete tetrameric pseudo-cubane clusters with bridging of Li3triangles by nitrogen and by chlorine atoms

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Die Reaktion von PtCl2 mit einemN,S,O-koordinierten Calciumkomplex: Synthese und Struktur eines Ca-Pt-Komplexanions

Dilithiated salen complexes: chiral [(salen)Li2·hmpa]2and deliberate partial hydrolysis to give [(salen)Li2]3·Li2O·2tmen·H2O [H2salen =N,N′-ethylenebis(salicylideneimine); hmpa = hexamethylphosphoramide; tmen = tetramethylethylenediamine]

Dilithiation of N,N′-diphenylthiourea, PhNHC(S)NHPh, in HMPA: the unexpected structure of the product, [PhNPh)SLi·2HMPA]2, and supporting ab initio MO calculations on model systems

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Dilithiation of Two Diphenyl Ethers Each Containing Two NHCH2CH2Y (Y = OMe, NMe2) Side Arms inortho Positions: Assembly of ?Adamantanoid? Li4O2N4 Cores

scholarly article by Ian Cragg-Hine et al published August 1993 in Angewandte Chemie International Edition

Dilithiation of a Primary Amine: Synthesis and Structure of[(α-Naphthyl-NLi2)10(Et2O)6]· Et2O, a Paramagnetic Li20 Aggregate

scholarly article by David R. Armstrong et al published December 1991 in Angewandte Chemie International Edition

Dilithiierung eines primären Amins: Synthese und Struktur von [(α-Naphthyl-NLi2)10(Et2O)6] · Et2O, einem paramagnetischen N10Li20-Aggregat

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Dynamic processes in organolithium chemistry: tetrameric and ‘open’ tetrameric chiral α-amino lithium alkoxides

Ein 1:1-Addukt aus 2-Aminobenzothiazol und einem Harnstoffderivat sowie seine Anordnung im Raum

Evidence for CH ? Li interactions in the solid state structure of dibenzylamido-lithium, and in solutions of it and its complexes: coloured species due to benzyl ? lithium charge transfer

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Evidence for a radical-forming process during the reaction of solid NH4SCN with n-butyl-lithium and hexamethylphosphosphoramide (HMPA) in toluene: crystal structure of the product, (LiNCS·2HMPA)2

General equations for determining species involved in solution equilibria and equilibrium constants from solution molecular mass measurements

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Hexameric chiral α-amino lithium alkoxides: a solid-state and theoretical structural investigation

High-field lithium-7 nuclear magnetic resonance spectroscopic and cryoscopic relative molecular mass studies on solutions of amido- and imido-lithium compounds

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Hydride Encapsulation by a Molecular Main-Group-Metal Cluster: Single-Crystal Neutron Diffraction Structure of [{Ph(2-C5H4N)N}6HLi8]+

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Isolation and solution structures of {PhCH2NLiCH2CH2NMe2}n and of the totally rigid dilithium compound, {o-LiC6H4CH2NLiCH2CH2NMe2}n; evidence for Li…o-HC interactions

Isolation, characterisation, and solution structures of the bis(pyridine) complex of the n-butyllithium-pyridine adduct, Bun(C5H5N)Li·2C5H5N, its mode of decomposition, and ab initio calculations on model systems

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Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO c

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Ligand and metal effects on the formation of main-group polyhedral clusters

scientific article published on 01 November 2003

Lithiated amidines: syntheses and structural characterisations

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Lithiated organophosphorus enamines: a new synthetic approach and the first crystal structures

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Lithiation and dethiacarbonylation of a heterocyclic thioamide C6H4O·C(S)NH by reaction with solid Li2S in the presence of hexamethylphosphoramide: synthesis and crystal structure of [C6H4O·C(S)NLi·HMPA]2·C6H4(OH)NH2

Lithiations of mercaptoamines containing NC(S)NH–,–NHC(S)S– and –NHC(S)NH– units: syntheses, crystal structures and model molecular-orbital calculations

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Lithium Intermediates during theα-Lithiation and Subsequentα-Substitution of Heterocyclic Amines in the Presence of CO2

Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: synthesis and crystal structure of [naphthylN·NN·NC(S)]2Ba·3HMPA

Metalations of 1-aminonaphthalene with trimethylaluminum and with diethylzinc: syntheses and crystal structures of cyclobutane-like [Me2Al(N(H)naphthyl)]2 and cyclohexane-like [EtZn(N(H)naphthyl).cntdot.THF]3

Mixed-Anion Aggregates of Metalated Organics : Preparation and Structure of the Mixed-Anion Tetramer(PhO⊖Li⊕· HMPA)3(μ3-HMPA· Li⊕)NCS⊖

Molecular Orbital Bond Index (MOBI) calculations on selected organolithium and lithium'ate species: Evidence for Li ⋯ HC three-centre interactions

On enantioselective deprotonation: synthesis and crystal structure of a chiral amidolithium tetrahydrofuran complex

Reaction of solid sodium hydride with solid ammonium thiocyanate in HMPA-toluene: An ESR spectroscopic investigation and crystal structures of the two products of the reaction, [(NaNCS·HMPA)2]∞ and (NaNCS·2HMPA)2

Reactions of ammonium salts with butyllithium and with lithium hydride: new routes to fully anhydrous inorganic lithium complexes

scientific article published in 1987

Role of bifunctional N/S bridging in the association of metals; syntheses and structures of heterobimetallic [Ph3P)2CuL2Li(thf)2]·thf and tetrameric [{CuL(PPh3)}4](L = 1,3-benzoxazoline-2-thionate, thf = tetrahydrofuran)

Self-assembly in the metallation of bis(aminoaryl) ethers

Structure and bonding of the tris(diphenylmethyleneamino)aluminium dimer [Al(NCPh2)3]2: relative strengths of bridging and terminal Al–X bonds in systems X2Al(µ2-X)2AlX2

Structure of the lithium thiocyanate-tetramethylpropylenediamine complex dimer, [LiNCS-Me2N(CH2)3NMe2]2, with asymmetric NCS-bridge bonding: a new bonding mode for the thiocyanate ligand

Syntheses and solid-state structures of trimeric dibenzylamidolithium and its diethyl ether and hexamethylphosphoramide dimeric complexes: an explanation of these structures and evidence for Li ? CH interactions in both solid and solution phases

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Synthesis and Structure of a Sixteen-Membered (AINCO)4 Ring

Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ions linked by bifunctional linear SCN–ligands

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Synthesis and crystal structure of the mixed alkali metal imide Li4 -xNa2 +x[NC(Ph)But]6: three (metal–nitrogen)2ring dimers in a triple-layered stack

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The Ammonium Salt Route to Oligomeric Lanthanum Salt Complexes: Synthesis and X-Ray Crystal Structure of La(NCS)3· 4 HMPA

The First Crystallographic Evidence for the Structures ofortho-Lithiated Aromatic Tertiary Amides

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The First Structure of a Lithiated Cyanamide; Synthesis of(PhNCNLi· HMPA)n by Extrusion of N2 and S from 5-Phenylamino-1,2,3,4-thiatriazole with Li Reagents and HMPA

scholarly article by David R. Armstrong et al published December 1993 in Angewandte Chemie International Edition

The Reaction of PtCl2 with anN,S,O-Coordinated Calcium Complex: Synthesis and Structure of a Complexed CaPt Anion

scholarly article by Matthew G. Davidson et al published December 1991 in Angewandte Chemie International Edition

The first calcium–mercury cocomplex: synthesis and crystal structure

The first lithiated organic compound containing water as a ligand: synthesis and crystal structure of 2-mercaptobenzoxazolyl(tetramethylethylenediamine)lithium monohydrate, C6H4OC(S)NLi(tmeda)H2O, a model acid–base intermediate

The first structurally characterised early main-group metal diazallyl complex; synthesis and crystal structure of LiCPh(NPh)2·NMe[(CH2)2NMe2]2

The first structurally characterised sodium primary amide complex; synthesis and crystal structure of 2-PhOC6H4NHNa·NMe[(CH2)2NMe2]2

The isolation and crystal structure of [Ph(2-Pyr)NLi]·(HMPA)·[Ph(2-Pyr)NH]; a model monomeric orgenonitrogen–lithium species containing co-ordination of lithium by both an anchimeric pyridyl N-atom and by a potentially reactive amine ligand

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The isolation and crystal structure of {Li·(H2O)2·[OP(NMe2)3]}22+·2Cl–: a (LiO)2ring compound with bridging neutral oxygen (hexamethylphosphormaide) ligands

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The isolation of a highly arene-soluble alkali metal tetrafluoroborate complex, LiBF4·4HMPA [HMPA = OP(NMe2)3]: evidence for strong Li ⋯ F interactions in solution

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The laddering principle in lithium amide chemistry: the crystal and molecular structure of the pyrrolididolithium adduct [H2C(CH2)3NLi]3·MeN(CH2CH2NMe2)2

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The occurrence of both amide and thiolate forms of the benzoxazole-2-thionate anion (C7H4ONS–) in the same molecule: synthesis and crystal structure of C7H4ONSNa[µ-OP(NMe2)3]3NaC7H4ONS

The ring-stacking principle in organolithium chemistry: its development through the isolation and crystal structures of hexameric iminolithium clusters (RR′CNLi)6(R′= Ph, R = Butor Me2N; R = R′= Me2N or But)

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The stabilisation of water as a ligand in lithiated organic compounds: intra- and inter-molecular hydrogen bonding in the structures of the aquo complexes [Li·HMPA·H2O]2 and [Li·HMPA]2·H2O

The structural isomers of {[ph(2-pyridyl)NLi]·[OP(NMe2)3]}2: dimeric species with alternative central (LiN)2and (LiO)2rings, the latter involving unprecedented neutral bridging oxygen ligands

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The syntheses and crystal structures of two iminolithium adducts: (Ph2CNLi·NC5H5)4, a tetrameric pseudo-cubane formed by stacking two (LiN)2four-membered rings, and [But2CNLi·OP(NMe2)3]2, a dimer prevented sterically from stacking

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The synthesis and X-ray structural characterisation of the first mixed alkali metal organonitrogen molecular cluster LiNa3[OP(NMe2)3]3[NC(NMe2)2]4

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Three model structural types in lithium amide chemistry: the crystal and molecular structures of dimeric [Ph(Me)NLi·TMEDA]2(TMEDA = Me2NCH2CH2NMe2) and monomeric Ph(naphthyl)NLi·PMDETA [PMDETA = MeN(CH2CH2NMe2)2], and of [Ph(naphthyl)NLi·TMEDA]2,

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Trimeric dibenzylamidolithium and its dimeric diethyl ether and hexamethylphosphoramide complexes: structural and theoretical studies of reactive organonitrogen–lithium oligomers

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Two monomeric, octahedral complexes of alkaline earth metal salts: syntheses, physical characteristics, and crystal structures of Srl2·4HMPA and Sr(NCS)2·4HMPA [HMPA = O : P(NMe2)3]

Unusual routes to complexes of binary alkali metal–non-metal compounds: preparations and crystal and solution structures of Li2S6·(tmeda)2(tmeda = etramethylethylenediamine), and synthetic extensions of the routes

Variable-temperature and-concentration1H and7Li NMR studies of solutions of hexameric iminolithium compounds, (R1R2CNLi)6

X-Ray crystal structure of {Li·[OP(NMe2)3]4}+·{Li5[NCPh2]6·[OP·(NMe2)3]}–: a lithium 'ate complex, with a pentanuclear Li5clustered-anion having both µ2edge and µ3face nitrogen to lithium bonding

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X-ray crystallographic and solution studies of the pentamethyldiethylenetriamine and tetramethylethylenediamine adducts of lithium diphenylphosphide

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[PhLiNCH2CH2NLiPh]· 3 HMPA, a Monomeric Dilithiumethylenediamide Complex with N2Li2 Double Bridging: Synthesis, Crystal Structure, and Model MO Calculations

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