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List of works by Manuel L. Poveda

.eta.1- And .eta.2-Alkaneimidoyl complexes of nickel: synthesis and properties

scholarly article by Ernesto Carmona Guzmán et al published March 1990 in Organometallics

.eta.2-Acyl and methyl complexes of tungsten. Crystal and molecular structures of W(.eta.2-C(O)CH2SiMe3)Cl(CO)(PMe3)3 and W(CH3)(S2CNMe2)(CO)2(PMe3)2

scholarly article by Ernesto. Carmona et al published January 1991 in Organometallics

.eta.2-Acyl coordination and .beta.-carbon-hydrogen bond interaction in acyl complexes of molybdenum. Crystal and molecular structures of tris(trimethylphosphine)carbonylchloro(.eta.2-trimethylsilylacetyl)molybdenum [Mo(.eta.2-COCH2SiMe3)Cl(CO)(PMe3)

scholarly article by Ernesto Carmona Guzmán et al published May 1984 in Journal of the American Chemical Society

A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition

scientific article published on 23 March 2015

A Measureable Equilibrium between Iridium Hydride Alkylidene and Iridium Hydride Alkene Isomers

scholarly article by Margarita Paneque et al published 12 July 2004 in Angewandte Chemie International Edition

Activation of Aldehydes by the Ir−2,3-Dimethylbutadiene Complex TpMe2Ir(CH2C(Me)C(Me)CH2)

scientific article published in 1999

Activation of Aliphatic Ethers by TpMe2Ir Compounds: Multiple C−H Bond Activation and C−C Bond Formation

Aldehyde-Assisted Hydrogen Transfer during the Formation of Hydride-Iridafurans from Alkynes and Aldehydes

scientific article published on 18 December 2012

Alkyl and acyl derivatives of nickel(II) containing tertiary phosphine ligands

scholarly article by Ernesto Carmona Guzmán et al published 1980 in Dalton transactions RSC

Alkylidenes by .alpha.-hydrogen abstraction from metallacycles. Synthesis and characterization of alkylidene-bridged complexes of nickel

scholarly article by Tomas R. Belderrain et al published November 1993 in Organometallics

Alkyne insertion reactions in nickel acyl complexes. Occurrence of a 1,2-trimethylphosphine shift and the x-ray structures of [cyclic] Ni[C(Ph):C(H)(COCH2SiMe3)]Cl(PMe3)2 and [cyclic] Ni[C(Ph)(PMe3)C(H)(COCH2CMe2Ph)]Cl(PMe3)6

scholarly article by Ernesto Carmona Guzmán et al published September 1984 in Organometallics

An iridium(III) compound that thermally activates two molecules of benzene and forms a stable dinitrogen complex

scholarly article by Enrique Gutierrez et al published January 1994 in Journal of the American Chemical Society

Binuclear complexes of nickel bridged by hydrocarbon ligands. Isocyanide insertion chemistry and amide formation by intramolecular coupling of acyl and imidoyl functionalities

scholarly article by Juan Campora et al published January 1992 in Organometallics

Binuclear complexes of nickel with the bridging o-CH2C6H4 ligand: synthesis and reactions. X-ray crystal structure of [cyclic] trans-(Me3P)2BrNi[C(O)C6H4CH2-o]NiBr(PMe3), a complex containing a bridging .mu.2-.eta.1:.eta.1-aroyl ligand

scholarly article by Juan Campora et al published July 1992 in Organometallics

Binuclear σ- and η3-benzylic derivatives of nickel

scholarly article by Juan Cámpora et al published 1992 in Dalton transactions RSC

Bis(dinitrogen)- and Diethylene-molybdenum(0) Complexes

Building a Parent Iridabenzene Structure from Acetylene and Dichloromethane on an Iridium Center

scientific article published on 09 August 2013

C-H Bond activation and C-C bond formation in the reaction of 2,5-dimethylthiophene with TpMe2Ir compounds

scientific article published on 9 March 2005

C-H bond activation reactions of ethers that generate iridium carbenes.

scientific article

Carbon dioxide chemistry. The synthesis and properties of trans-bis(carbon dioxide)tetrakis(trimethylphosphine)molybdenum (trans-[Mo(CO2)2(PMe3)4]): the first stable bis(carbon dioxide) adduct of a transition metal

scientific article published in 1984

Consecutive Insertion Reactions of Unsaturated Molecules into the Ni-C Bonds of the Nickelacycle [cyclic] (Me3P)2Ni(CH2CHMe2-o-C6H4). Formation of Heterocycles Derived from Seven-Membered Cyclic Acid Anhydrides

Coupling of Aromatic Aldehydes with CO2Me-Substituted TpMe2Ir(III) Metallacyclopentadienes

Coupling of internal alkynes in tp(me2)ir derivatives: selective oxidation of a noncoordinated double bond of the resulting iridacycloheptatrienes

scientific article

C−H Bond Activation of Benzene and Cyclic Ethers by TpIrIII Species

article

C−H Bond Activation of Thiophenes by Ir Complexes of the Hydrotris(3,5-dimethylpyrazolyl)borate Ligand, TpMe2

CC Bond-Forming Reactions of IrIII-Alkenyls and Nitriles or Aldehydes: Generation of Reactive Hydride- and Alkyl-Alkylidene Compounds and Observation of a Reversible 1,2-H Shift in Stable Hydride–IrIII Alkylidene Complexes

scientific article published on 01 November 2002

CN Bond Formation by O2-Mediated Dehydrogenative Coupling of Phenyl and NH-pyridylidene Ligands on Tp Me 2IrIII Complexes

Decarbonylation of Aliphatic Aldehydes by a TpMe2Ir(III) Metallacyclopentadiene

Deuteration Studies of Tp*IrH4 (Tp* = HB(3,5-Me2pz)3): Observation of Very Unusual 1H NMR Chemical Shift Effects

scientific article published in 1994

Dihydrogen-Catalyzed Reversible Carbon-Hydrogen and Nitrogen-Hydrogen Bond Formation in Organometallic Iridium Complexes

scholarly article by José E. V. Valpuesta et al published 18 June 2012 in Angewandte Chemie International Edition

Does the Facile Inter- and Intramolecular CH Bond Activation by Tp*–Rh Complexes Proceed via RhI or RhIII Intermediates?

Electrophilic Cationic Ethylidene Complexes of Ir(III). Comparative α-Migratory Insertion Processes into Hydride and Ethyl Groups

scientific article published in 1998

Ethoxycarbonyl-, cyano- and methoxy-methyl complexes of nickel(II) and their carbonylation reactions

scholarly article by Tomás R Belderraín et al published 1992 in Dalton transactions RSC

Ethylene Coordination and Acetylene Dimerization at Tp′IrIIICenters

article published in 2009

Ethylene dimerization: an alternative route involving vinyl hydride intermediates

Experimental and Theoretical Studies on Arene-Bridged Metal-Metal-Bonded Dimolybdenum Complexes

Experimental and computational studies on the iridium activation of aliphatic and aromatic C-H bonds of alkyl aryl ethers and related molecules

scientific article published in September 2009

Experimental evidences in favour of the hydroxylamine→nitrene-water tautomerization on the coordination sphere of Ir(III) centres

scientific article

Facile Oxygen Atom Insertion into Unactivated C(sp3)–C(sp2) Single Bonds in Reactions of Iridium(III) Complexes with O2

scholarly article by Crispín Cristóbal et al published 11 January 2013 in Organometallics

Formation and Cleavage of C−H, C−C, and C−O Bonds ofortho-Methyl-Substituted Anisoles by Late Transition Metals

scientific article published in 2006

Formation of 1,2,3-η3-butadienyl derivatives by photochemical C-H activation of Ir(I)-η4-1,3-diene complexes containing tris(pyrazolyl) borate ligands

article published in 1997

Formation of 2-thienyl derivatives during the thermal activation of thiophene by Tp∗Ir(C2H4)2

Formation of Hydrido–η3-Allyl Complexes of IrIII by Sequential Olefinic CH Bond Activation and CC Coupling of Alkenyl and Olefin Ligands

Formation of Iridabenzenes by Coupling of Iridacyclopentadienes and Alkenes

scientific article published on 01 January 2006

Formation of Palladium- and Platinum-Substituted Fulvenes by Activation of a Cyclopentadienyl or Indenyl Ligand

article

Formation of Palladium- and Platinum-Substituted Fulvenes by Cyclopentadienyl Activation in a Formal Insertion Reaction

Formation of Unusual Iridabenzene and Metallanaphthalene Containing Electron-Withdrawing Substituents

scientific article published on 01 August 2003

Formation of acrylic acid derivatives from the reaction of carbon dioxide with ethylene complexes of molybdenum and tungsten

scholarly article by Rafael Alvarez et al published September 1985 in Journal of the American Chemical Society

Formation of alkenyl ketone complexes and of dimeric .alpha.,.beta.-butenolides by sequential insertion of phenylacetylene and carbon monoxide into nickel-acyl bonds. X-ray structures of Ni[C(Ph) = C(H)(COCH2SiMe3)]Cl(PMe3)2 and Ni[C(Ph)(PMe3)C(H)(CO

scholarly article by Ernesto. Carmona et al published April 1989 in Organometallics

Formation of carbonyl-carbonate complexes of molybdenum by reductive disproportionation of carbon dioxide. X-ray structure of Mo4(.mu.4-CO3)(CO)2(O)2(.mu.2-O)2(.mu.2-OH)4(PMe3)6

scholarly article by Rafael. Alvarez et al published April 1991 in Inorganic Chemistry

Formation of carboxylate complexes from the reactions of carbon dioxide with ethylene complexes of molybdenum and tungsten. X-ray and neutron diffraction studies

scholarly article by Rafael. Alvarez et al published October 1989 in Organometallics

Formation of β-Metallanaphthalenes by the Coupling of a Benzo-Iridacyclopentadiene with Olefins

article published in 2014

Formation of η2-Iminoacyls, η3-Azaallyls, and Heterometallacycles during the Rearrangements of Methyl Complexes of Molybdenum and Tungsten Containing Isocyanide Ligands

scholarly article by P. James Daff et al published May 1997 in Organometallics

Functionalization of 3-Iridacyclopentenes

scientific article published on 12 September 2017

Further studies on organonickel compounds: the synthesis of some new alkyl-, acyl- and cyclopentadienyl-derivatives and the crystal structure of trans-[Ni(CH2SiMe3)2(PMe3)2]

Generation and reactivity of sterically hindered iridium carbenes. Competitive α- vs. β-hydrogen elimination in iridium(iii) alkyls

scholarly article by Ernesto Carmona Guzmán et al published 2003 in Dalton Transactions

Generation of Metallacyclic Structures from the Reactions of Vinyl Ethers with a TpMe2IrIIICompound

Investigations on the coupling of ethylene and alkynes in [IrTp Me2] compounds: water as an effective trapping agent

scientific article

Iridafurans by Coupling of Alkynes and Aldehydes on a TpMe2Ir System. Facile Demethoxycarbonylation of a β-CO2Me Substituent

Iridapyrrole Complexes via Formal 3 + 2 Cycloaddition of Iridium Alkenyls to Acetonitrile

scholarly article by Ysaias Alvarado et al published January 1996 in Organometallics

Iridium solutes effect C-H bond activation and C-C bond forming reactions of C6H6-MeOCH2CH2OMe solvent mixtures

scientific article

Iridium(III)-Induced Isomerization of 2-Substituted Pyridines to N-Heterocyclic Carbenes

scholarly article by Eleuterio Álvarez et al published October 2006 in Journal of the American Chemical Society

Iridium(iii) complexes with polypyridine ligands coordinated as N-heterocyclic carbenes. Synthesis, structure and photophysical properties

scientific article published on 02 October 2012

Isocyanide insertion chemistry. Synthesis and structural characterization of bridging imidoyl complexes of nickel and amide formation by intramolecular coupling of acyl and imidoyl functionalities

scholarly article by Juan Campora et al published October 1993 in Organometallics

Isolation of a stable 1-iridabicyclo[3.2.0]hepta-1,3,6-triene and its reversible transformation into an iridacycloheptatriene

scientific article published in February 2004

Mechanism for Hydride-Assisted Rearrangement from Ethylidene to Ethylene in Iridium Cationic Complexes

scholarly article by Maria Besora et al published 10 May 2010 in Organometallics

Metallacyclic Pyridylidene Structures from Reactions of Terminal Pyridylidenes with Alkenes and Acetylene

scientific article published on 01 May 2010

Metallacycloheptatrienes of Iridium(III): Synthesis and Reactivity

scholarly article by Margarita Paneque et al published July 2007 in Organometallics

Methyl-, Ethenyl-, and Ethynyl-Bridged Cationic Digold Complexes Stabilized by Coordination to a Bulky Terphenylphosphine Ligand

scientific article published on 11 November 2015

Monodentate, N-heterocyclic carbene-type coordination of 2,2'-bipyridine and 1,10-phenanthroline to iridium

scientific article published in January 2008

Multiple insertion reactions of CNBut into nickel—alkyl bonds

scholarly article by Ernesto Carmona Guzmán et al published November 1989 in Journal of Organometallic Chemistry

Neutral aminocarbene complexes of nickel from the reaction of [Ni{η2-C(NBut)CH2CMe3}(NC4H2Me2)(PMe3)] with diprotonic acids

scholarly article by Ernesto Carmona Guzmán et al published January 1990 in Polyhedron

New nickel o-methylbenzyl complexes. Crystal and molecular structures of Ni(.eta.3-CH2C6H4-o-Me)Cl(PMe3) and Ni3(.eta.1-CH2C6H4-o-Me)4(PMe3)2(.mu.3-OH)2

scholarly article by Ernesto. Carmona et al published August 1987 in Organometallics

New nickel o-xylyl complexes. Crystal and molecular structure of Ni3(CH2C6H4Me-o)4(PMe3)2(.mu.3-OH)2

scholarly article by Ernesto. Carmona et al published November 1985 in Organometallics

Observation of an unprecedented equilibrium between alkyl-carbonyl, dihapto acyl and agostic acyl isomeric structures

scientific article published in 1991

Oxidative Coupling in the Reaction of TpMe2Ir(2,3-dimethylbutadiene) with Diphenylacetylene

article published in 2007

Preparation and properties of dinitrogen complexes of molybdenum and tungsten with trimethylphosphine as coligand

scholarly article by Ernesto Carmona Guzmán et al published November 1982 in Journal of Organometallic Chemistry

Preparation and properties of dinitrogen trimethylphosphine complexes of molybdenum and tungsten. 4. Synthesis, chemical properties, and x-ray structure of cis-[Mo(N2)2(PMe3)4]. The crystal and molecular structures of trans-[Mo(C2H4)2(PMe3)4] and tra

scholarly article by Ernesto Carmona Guzmán et al published May 1983 in Journal of the American Chemical Society

Preparation and properties of dinitrogen trimethylphosphine complexes of molybdenum and tungsten—II

scholarly article by Ernesto Carmona Guzmán et al published January 1983 in Polyhedron

Pyrrolyl, hydroxo, and carbonate organometallic derivatives of nickel(II). Crystal and molecular structure of [Ni(CH2C6H4-o-Me)(PMe3)(.mu.-OH)]2.cntdot.2,5-HNC4H2Me2

scholarly article by Ernesto Carmona Guzmán et al published May 1989 in Inorganic Chemistry

Reaction of cis-[Mo(N2)2(PMe3)4] with carbon dioxide. Synthesis and characterization of products of disproportionation and the x-ray structure of a tetrametallic mixed-valence Mo(II)-Mo(V) carbonate with a novel mode of carbonate binding

scientific article published in 1983

Reaction of the Iridacyclopentadiene TpMe2Ir(C(R)C(R)C(R)C(R))(H2O) (R = CO2Me) with Alkynes

Reactions of sulfur containing heterocumulenes with low-valent molybdenum and tungsten complexes. Oxidative cleavage of a head-to-tail carbon disulfide dimer in a molybdenum complex

scholarly article by Ernesto Carmona Guzmán et al published December 1990 in Inorganic Chemistry

Reactions of the benzonickelacyclopentene complex [cyclic] (Me3P)2Ni(CH2CMe2-o-C6H4) with alkynes. Synthesis of 1,2-dihydronaphthalenes

Reactivity Studies of Iridium Pyridylidenes [TpMe2Ir(C6H5)2(C(CH)3C(R)NH] (R=H, Me, Ph)

scientific article published on 11 February 2013

Reactivity of TpMe2-Containing Hydride–Iridafurans with Alkenes, Alkynes, and H2

Reactivity of a Cationic (C5Me5)IrIII-Cyclometalated Phosphine Complex with Alkynes

article

Reactivity of a Tp–Iridacyclopentene Complex

Reactivity of the Iridium(I) Alkene/Alkyne Complex TpMe2Ir(C2H4)(MeO2CC⋮CCO2Me)

scholarly article by Margarita Paneque et al published June 2007 in Organometallics

Rearrangement of pyridine to its 2-carbene tautomer mediated by iridium

scientific article published on 31 October 2007

Rotational isomerism and fluxional behavior of bis(carbon dioxide) adducts of molybdenum

scientific article published in 1991

Rotational isomerism in bis(carbon dioxide) complexes of molybdenum generated by conrotatory motion of the CO2 ligands

Selective synthesis of seven-membered cyclic thione analogues of acid anhydrides and other related derivatives via a benzannelated nickelacycle

Seven-coordinate halo and dithiocarbamate trimethylphosphine derivatives of molybdenum(II) and tungsten(II)

scholarly article by Ernesto Carmona Guzmán et al published February 1984 in Inorganic Chemistry

Some trimethyl phosphine and trimethyl phosphite complexes of tungsten(IV)

scholarly article by Ernesto Carmona Guzmán et al published January 1983 in Polyhedron

Stepwise reaction of carbon disulfide with the nickelacyclopentene complexes [cyclic] (R3P)2Ni(CH2CMe2-o-C6H4). Influence of the ancillary phosphine ligands

article published in 1988

Substitution reactions in cyclometallated complexes. Crystal and molecular structure of (C5H5N)(Me3P)6H4)]

article published in 1989

Synthesis and Properties of TpMe2IrH4and TpMe2IrH3(SiEt3): Ir(V) Polyhydride Species withC3vGeometry

scientific article published in 1999

Synthesis and Reactivity of Iridacycles Containing the TpMe2Ir Moiety

Synthesis and Reactivity of [Ir(C2H4)2TpmMe2]PF6(TpmMe2= Tris(3,5-dimethylpyrazolyl)methane): Comparison with the Analogous TpMe2Derivatives (TpMe2= Hydrotris(3,5-dimethylpyrazolyl)borate)

Synthesis and Structural Characterization of Stable Hydride−Alkylidene Complexes of Iridium(III)

scholarly article by Francisco M. Alías et al published September 1998 in Organometallics

Synthesis and X-ray crystal structure of [Mo(CO2)2(PMe3)3(CNPri)]: the first structurally characterized bis(carbon dioxide) adduct of a transition metal

article published in 1984

Synthesis and characterization of some new organometallic complexes of nickel(II) containing trimethylphosphine

scholarly article by Ernesto Carmona Guzmán et al published January 1989 in Polyhedron

Synthesis and properties of cis-bis(dinitrogen)tetrakis(trimethylphosphine)tungsten(0). Crystal and molecular structures of [W(N2)(PMe3)5] and trans-[W(C2H4)2(PMe3)4]

Synthesis and properties of dialkyl complexes of nickel(II). The crystal structure of bis(pyridine)bis(trimethylsilylmethyl)nickel(II)

scholarly article by Ernesto Carmona Guzmán et al published 1981 in Dalton transactions RSC

Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2':6',2''-terpyridine

scientific article published on 18 August 2009

Synthesis and x-ray structure of the nickelabenzocyclopentene complex [cyclic](Me3P)2Ni(CH2CMe2-o-C6H4). Reactivity toward simple, unsaturated molecules and the crystal and molecular structure of the cyclic carboxylate (Me3P)2Ni(CH2CMe2-o-C6H4C(O)O)

scientific article published in 1989

Synthesis of [cyclic]-(Me3P)2Ni(CH2CMe2-o-C6H4) and its reactivity toward carbon dioxide, carbon monoxide and formaldehyde. First observation of a carbonyl-carbonate oxidative conproportionation mediated by a transition-metal complex

article published in 1986

Synthesis of chloro(trimethylphosphine)tris(trimethylsilylmethyl)tungsten(IV); synthesis and molecular structure of di-µ-chloro-bis[dicarbonyl(trimethylphosphine)(1—2-η-trimethylsilylmethylcarbonyl)tungsten(II)]

scholarly article by Ernesto Carmona Guzmán et al published 1983 in Dalton transactions RSC

Synthesis of η2:σ2-Diene Complexes of Iridium(III) by the Reaction of η4:π2-Diene Iridium(I) Species with Lewis Bases

scholarly article by Margarita Paneque et al published August 2000 in Organometallics

Synthetic, mechanistic, and theoretical studies on the generation of iridium hydride alkylidene and iridium hydride alkene isomers

scientific article published in September 2009

Tautomerisation of 2-Substituted Pyridines to N-Heterocyclic Carbene Ligands Induced by the 16 e− Unsaturated [TpMe2IrIII(C6H5)2] Moiety

Tautomerization of Pyridine and 2-Substituted Pyridines to Pyridylidene Ligands by the Iridium(I)–Diene Complex TpMe2Ir(η4-CH2═C(Me)C(Me)═CH2)

scholarly article by Florencia Vattier et al published 2 January 2014 in Organometallics

The Synthesis of Iridabenzenes by the Coupling of Iridacyclopentadienes and Olefins

Transition metal migration upon attempting the Wolff rearrangement of an Ir(III) five-membered metallacycle.

scientific article

Unexpected reactivity of 2,5-dimethylthiophene towards TpMe2Ir(C2H4)2

Unusual alkylidene-bridged complexes of nickel by α-H abstraction from a nickelacycle. Crystal and molecular structure of [{Ni2(CHCMe2-o-C6H4)Cl(PMe3)2}2]

scholarly article by Ernesto Carmona Guzmán et al published 1991 in Journal of the Chemical Society. Chemical communications

Unusual fragmentation of CH2Cl2 by an Ir(III) centre bonded to a doubly metalated Tp(Ms) Ligand (Tp(Ms) = hydrotris(3-mesitylpyrazol-1-yl)borate).

scientific article published on 4 August 2006

Vinylic C−H Bond Activation and Hydrogenation Reactions of Tp‘Ir(C2H4)(L) Complexes

scientific article published on 01 September 1998

Vinylidene Compounds from the Reactions of Me3SiC⋮CSiMe3with TpMe2Ir Precursors. Protonation to Alkylidene and Iridabenzene Structures

Water-Promoted Generation of a Diazairida Homobarrelene by C-C Coupling Between an Iridacyclic Alkylidene and Acetonitrile

scientific article published on 10 June 2015

X-ray crystal structure of [Ni{η2−C(NBut)CH(SiMe3)2}Cl(PMe3)], the first structurally characterized η2-alkaneimidoyl complex of nickel

scholarly article by Tomas R. Belderraín et al published January 1995 in Polyhedron

β-C–H interaction vs. Dihaptoacyl co-ordination in a molybdenum acetyl complex. X-Ray crystal structure of [Mo(Ac)(S2CNMe2)(CO)-(PMe3)2]

η2-Iminoethyl-C,N vs.η3-aminoethylene-C,C′,N formation in the thermally induced rearrangement of isocyanide alkyl complexes of molybdenum

η3-2-Methylallyl phosphine complexes of nickel(II)

scholarly article by Ernesto Carmona Guzmán et al published January 1990 in Polyhedron

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