List of works - Andrea Meli

1-Hexene Hydroformylation with the Rhodium (I) Triphosphane Complex [Rh(CO){PhP(CH2CH2PPh2)2}]PF6: An In Situ Study Using High-Pressure NMR Spectroscopy

A New Way to both Oligothiophene-Spaced Bimetallic Complexes and Functionalized Oligothiophenes

A comparison between silica-immobilized ruthenium(II) single sites and silica-supported ruthenium nanoparticles in the catalytic hydrogenation of model hetero- and polyaromatics contained in raw oil materials

article

A novel linkage-isomeric pair of dinuclear Pd(II) complexes bearing a bis-bidentate tetraphos ligand

scientific article

A novel oxygen-carrying and activating system of rhodium(III). Oxidation and oxygenation reactions of 3,5-di-tert-butylcatechol catalyzed by a rhodium(III) cathecolate through its (.eta.1-superoxo)(.eta.2-semiquinonato)rhodium(III) complex

scholarly article by Claudio Bianchini et al published September 1990 in Inorganic Chemistry

An .eta.4-benzene species mediates acetylene cyclotrimerization

article

Benzene Hydrogenation by Silica-Supported Catalysts Made of Palladium Nanoparticles and Electrostatically Immobilized Rhodium Single Sites

C-S Bond Scission of Substituted Thiophenes at Rhodium. Factors Influencing the Regioselectivity of the Insertion and the Stability of the Resulting Metalathiacycles

scholarly article by Claudio Bianchini et al published July 1995 in Organometallics

CO-ethylene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups

Chemoselective oxidation of 3,5-di-tert-butylcatechol by molecular oxygen. Catalysis by an iridium(III) catecholate through its dioxygen adduct

scholarly article by Pierluigi Barbaro et al published April 1992 in Inorganic Chemistry

Copolymerization of Carbon Monoxide with Ethene Catalyzed by Palladium(II) Complexes of 1,3-Bis(diphenylphosphino)propane Ligands Bearing Different Substituents on the Carbon Backbone

Copolymerization of carbon monoxide with ethene catalyzed by bis-chelated palladium(II) complexes containing diphosphine and dinitrogen ligands

C−S Bond Cleavage of Benzo[b]thiophene at Ruthenium

CH bond activation of thiophenes at iridium: a lower energy process than CS bond scission

scholarly article by Claudio Bianchini et al published November 1995 in Journal of Organometallic Chemistry

Dioxygen uptake and transfer by Co(III), Rh(III) and Ir(III) catecholate complexes

Efficient rhodium catalysts for the hydrogenolysis of thiophenic molecules in homogeneous phase

Electronic Influence of the Thienyl Sulfur Atom on the Oligomerization of Ethylene by Cobalt(II) 6-(Thienyl)-2-(imino)pyridine Catalysis

scholarly article by Claudio Bianchini et al published January 2007 in Organometallics

First example of opening and hydrogenation of 2,3-dihydrobenzo[b]thiophene to 2-ethylthiophenol assisted by a soluble metal complex

HDS Model Systems. Coordination, Opening, and Hydrogenation of Benzo[b]thiophene at Iridium

scholarly article by Claudio Bianchini et al published May 1994 in Journal of the American Chemical Society

HDS model systems. 2,3-Dihydrothiophene as an intermediate in the homogeneous hydrogenation of thiophene to tetrahydrothiophene at iridium

scholarly article by Claudio Bianchini et al published February 1994 in Organometallics

Homogeneous Reactions of Thiophenes with Transition Metals: A Modeling Approach for Elucidation of the Hydrodesulfurization Mechanism and an Effective Method for the Synthesis of Unusual Organosulfur Compounds

scientific article published in 1995

Hydrodesulfurization (HDS) Model Systems. Opening, Hydrogenation, and Hydrodesulfurization of Dibenzothiophene (DBT) at Iridium. First Case of Catalytic HDS of DBT in Homogeneous Phase

scholarly article by Claudio Bianchini et al published May 1995 in Organometallics

Hydrodesulfurization model systems. Homogeneous and heterogeneous (solid-gas) hydrogenation of benzothiophene at iridium

scholarly article by Claudio Bianchini et al published August 1993 in Journal of the American Chemical Society

Hydrogen-transfer reactions of the trihydride [(MeC(CH2PPh2)3RhH3]: a simple route to rhodium cis hydride .eta.2-alkene complexes

Hydrogenation of Arenes and Heteroaromatics

Hydrogenation of Arenes over Catalysts that Combine a Metal Phase and a Grafted Metal Complex: Role of the Single-Site Catalyst

scientific article published on 01 June 2003

Hydrogenation of Arenes over Silica-Supported Catalysts That Combine a Grafted Rhodium Complex and Palladium Nanoparticles: Evidence for Substrate Activation on Rhsingle-site−PdmetalMoieties

article

Hydrogenation of Indole by Phosphine-Modified Rhodium and Ruthenium Catalysts

In Situ High-Pressure31P{1H} NMR Studies of the Hydroformylation of 1-Hexene by RhH(CO)(PPh3)3

Insertion of iridium into C-H and C-S bonds of 2,5-dimethylthiophene 2-methylbenzothiophene and 4,6-dimethyldibenzothiophene

scholarly article by Claudio Bianchini et al published August 1997 in Journal of Organometallic Chemistry

Interaction of monohydrido complexes of rhodium(I) with 1-alkynes. Experimental study on deceptively simple reactions

scholarly article by Claudio Bianchini et al published April 1990 in Organometallics

Ligand and Solvent Effects in the Alternating Copolymerization of Carbon Monoxide and Olefins by Palladium−Diphosphine Catalysis

Ligand effects in the non-alternating CO-ethylene copolymerization by palladium(II) catalysis

scientific article published on 17 October 2007

Like on Heterogeneous Hydrodesulfurization(HDS) Catalysts, the Homogeneous HDS of Benzo[b]thiophene Is Achived by the Concomitant Action of a Metal Promoter(Rh) and an Active HDS Component(W)

Liquid-Biphase Hydrogenolysis of Benzo[b]thiophene by Rhodium Catalysis

scholarly article by Claudio Bianchini et al published May 1997 in Journal of the American Chemical Society

Mechanistic Study of Ir(H)2-Assisted Transformations of Ethyne: Cyclotrimerization, Cooligomerization with Ethene, and Reductive Coupling

Metal Activation of Dibenzo[b,d]thiophene. Reactivity of the C-S Insertion Product [MeC(CH2PPh2)3]IrH(.eta.2(C,S)-C12H8S)

Metathesis of CS2-Like Heteroallenes on 1,1-Dithio Complexes of Rhodium(III)

Migration of hydrogen from metal to alkene promoted by dioxygen addition. Oxygen atom transfer from a cis-(alkyl)(η2-dioxygen) complex of rhodium to organic and inorganic substrates

article

Mimicking the HDS Activity of Promoted Tungsten Catalysts. A Homogeneous Modeling Study Using a Two-Component Tungsten/Rhodium System

scholarly article by Claudio Bianchini et al published December 1997 in Organometallics

Mimicking the HDS Activity of Ruthenium-Based Catalysts 2: The Hydrogenation of Benzo[b]thiophene to 2,3-Dihydrobenzo[b]thiophene

scientific article published in 1999

Mimicking the HDS Activity of Ruthenium-Based Catalysts. Homogeneous Hydrogenolysis of Benzo[b]thiophene

Mixed iridium-gold hydrides as model compounds for elucidating the interconversion between classical and nonclassical polyhydrides

scholarly article by Claudio Bianchini et al published September 1992 in Inorganic Chemistry

Molecular Solid-Gas Organometallic Chemistry. Catalytic and Stoichiometric Iridium-Assisted C-C Bond-Forming Reactions Involving Ethyne and Ethene

scholarly article by Claudio Bianchini et al published April 1994 in Organometallics

Molecular solid-gas organometallic chemistry. Catalytic and stoichiometric transformations of ethyne at iridium

scholarly article by Claudio Bianchini et al published August 1993 in Organometallics

New structurally rigid palladium catalysts for the alternating copolymerization of carbon monoxide and ethene

Novel reactions of the [BPh4]- salt of the bifunctional complex [(triphos)Rh(S2CO)]+ (triphos = MeC(CH2PPh2)3): one-electron reduction, cleavage of B-H and B-C bonds, and metathesis of CS2-like heteroallene molecules

Opening and Hydrogenation of Dinaphtho[2,1-b:1‘,2‘-d]thiophene (DNT) by Soluble Rhodium and Iridium Complexes. Homogeneous Hydrogenolysis of DNT to 1,1‘-Binaphthalene-2-thiol by Rhodium Catalysis

scholarly article by Claudio Bianchini et al published January 1996 in Organometallics

Opening, desulfurization, and hydrogenation of thiophene at iridium. An experimental study in a homogeneous phase

scholarly article by Claudio Bianchini et al published April 1993 in Journal of the American Chemical Society

Oxidation of primary alcohols to carboxylic acids made easy at iridium

scholarly article by Claudio Bianchini et al published August 1990 in Journal of the American Chemical Society

Preparation, Characterization, and Performance of Tripodal Polyphosphine Rhodium Catalysts Immobilized on Silica via Hydrogen Bonding

scholarly article by Claudio Bianchini et al published June 1999 in Journal of the American Chemical Society

Preparation, Characterization, and Performance of the Supported Hydrogen-Bonded Ruthenium Catalyst [(sulphos)Ru(NCMe)3](OSO2CF3)/SiO2. Comparisons with Analogous Homogeneous and Aqueous-Biphase Catalytic Systems in the Hydrogenation of Benzylideneace

Redox-Induced Conversion Pathways in Rhodium and Iridium Complexes Containing C-S Bond Cleaved Benzo[b]thiophene

scholarly article by Claudio Bianchini et al published September 1995 in Organometallics

Regioselective propylene dimerization by tetrahedral (imino)pyridine CoII dichloride complexes activated by MAO

Rhodium complexes with the tripodal triphosphine MeC(CH2PPh2)3 as highly reactive systems for hydrogenation and hydroformylation of alkenes

article published in 1988

Rhodium-Assisted Transformations of Substituted Thiophenes into Butadienyl Methyl Sulfides

scholarly article by Claudio Bianchini et al published October 1995 in Organometallics

Role of single-site catalysts in the hydrogenation of thiophenes: from models systems to effective HDS catalysts

Selective hydrogenation of 1,10-phenanthrolines by silica-supported palladium nanoparticles

Stepwise metal-assisted conversion of .eta.2-carbon diselenide to .eta.1-phosphoniodiselenoformate, .eta.2-diselenocarbonate, and .eta.2-diselenium. Crystal structure of the rhodium complexes [(triphos)Rh(Se2CO)]BPh4.cntdot.0.5CH2Cl2.cntdot.0.5C4H9OH

Stepwise metal-assisted reduction of .eta.4-coordinated benzene to cyclohexene

scientific article published in 1992

Synthesis and Characterization of Dirhodium Complexes Containing μ-SO, μ-SH, and μ-S2Groups Stabilized by the Tripodal Ligand CH3C(CH2PPh2)3

Synthesis and characterization of heterobimetallic complexes containing C-S cleaved thiophenes

Synthesis and characterization of palladium(II) complexes with new diphosphonium-diphosphine and diphosphine ligands. Production of low molecular weight alternating polyketones via catalytic CO/ethene copolymerisation.

scientific article

Synthesis of New Polydentate Nitrogen Ligands and Their Use in Ethylene Polymerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides and Methylaluminoxane

scholarly article by Pierluigi Barbaro et al published August 2007 in Organometallics

Synthesis of a New Polydentate Ligand Obtained by Coupling 2,6-Bis(imino)pyridine and (Imino)pyridine Moieties and Its Use in Ethylene Oligomerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides

scientific article

Synthesis of palladium(II) complexes containing a new alpha-D-xylofuranose-modified diphosphine and their application as catalyst precursors in the co- and terpolymerization of CO-ethene and propene.

scientific article published in May 2008

Synthesis, characterization, and electrochemical properties of a family of dinuclear rhodium complexes containing two terminal hydride ligands and two hydride (or chloride) bridges. Stoichiometric and catalytic hydrogenation reactions of alkynes and

article

The Catalytic Transformation of Benzo[b]thiophene to 2-Ethylthiophenol by a Soluble Rhodium Complex: The Reaction Mechanism Involves Ring Opening Prior to Hydrogenation

scientific article published in 1995

The Mechanism of Acetylene Cyclotrimerization Catalyzed by the fac-IrP3+ Fragment: The Relationship between Fluxionality and Catalysis

Thermal and photochemical carbon-hydrogen bond activation reactions at iridium. .pi.-Coordination vs. C-H cleavage of ethene, styrene, and phenylacetylene

scholarly article by Claudio Bianchini et al published July 1993 in Organometallics

Thiophene C–S bond cleavage by rhodium and iridium. An unprecedented bridging mode of the open C4H4S fragment

scholarly article by Alessia Bacchi et al published 1995 in Journal of the Chemical Society. Chemical communications

Tripodal polyphosphine ligands control selectivity of organometallic reactions

Tripodal polyphosphine ligands in homogeneous catalysis. 1. Hydrogenation and hydroformylation of alkynes and alkenes assisted by organorhodium complexes with MeC(CH2PPh2)3

List of works by Andrea Meli

1-Hexene Hydroformylation with the Rhodium (I) Triphosphane Complex [Rh(CO){PhP(CH2CH2PPh2)2}]PF6: An In Situ Study Using High-Pressure NMR Spectroscopy

A New Way to both Oligothiophene-Spaced Bimetallic Complexes and Functionalized Oligothiophenes

A comparison between silica-immobilized ruthenium(II) single sites and silica-supported ruthenium nanoparticles in the catalytic hydrogenation of model hetero- and polyaromatics contained in raw oil materials

A novel linkage-isomeric pair of dinuclear Pd(II) complexes bearing a bis-bidentate tetraphos ligand

A novel oxygen-carrying and activating system of rhodium(III). Oxidation and oxygenation reactions of 3,5-di-tert-butylcatechol catalyzed by a rhodium(III) cathecolate through its (.eta.1-superoxo)(.eta.2-semiquinonato)rhodium(III) complex

An .eta.4-benzene species mediates acetylene cyclotrimerization

Benzene Hydrogenation by Silica-Supported Catalysts Made of Palladium Nanoparticles and Electrostatically Immobilized Rhodium Single Sites

C-S Bond Scission of Substituted Thiophenes at Rhodium. Factors Influencing the Regioselectivity of the Insertion and the Stability of the Resulting Metalathiacycles

CO-ethylene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups

Chemoselective oxidation of 3,5-di-tert-butylcatechol by molecular oxygen. Catalysis by an iridium(III) catecholate through its dioxygen adduct

Copolymerization of Carbon Monoxide with Ethene Catalyzed by Palladium(II) Complexes of 1,3-Bis(diphenylphosphino)propane Ligands Bearing Different Substituents on the Carbon Backbone

Copolymerization of carbon monoxide with ethene catalyzed by bis-chelated palladium(II) complexes containing diphosphine and dinitrogen ligands

C−S Bond Cleavage of Benzo[b]thiophene at Ruthenium

CH bond activation of thiophenes at iridium: a lower energy process than CS bond scission

Dioxygen uptake and transfer by Co(III), Rh(III) and Ir(III) catecholate complexes

Efficient rhodium catalysts for the hydrogenolysis of thiophenic molecules in homogeneous phase

Electronic Influence of the Thienyl Sulfur Atom on the Oligomerization of Ethylene by Cobalt(II) 6-(Thienyl)-2-(imino)pyridine Catalysis

First example of opening and hydrogenation of 2,3-dihydrobenzo[b]thiophene to 2-ethylthiophenol assisted by a soluble metal complex

HDS Model Systems. Coordination, Opening, and Hydrogenation of Benzo[b]thiophene at Iridium

HDS model systems. 2,3-Dihydrothiophene as an intermediate in the homogeneous hydrogenation of thiophene to tetrahydrothiophene at iridium

Homogeneous Reactions of Thiophenes with Transition Metals: A Modeling Approach for Elucidation of the Hydrodesulfurization Mechanism and an Effective Method for the Synthesis of Unusual Organosulfur Compounds

Hydrodesulfurization (HDS) Model Systems. Opening, Hydrogenation, and Hydrodesulfurization of Dibenzothiophene (DBT) at Iridium. First Case of Catalytic HDS of DBT in Homogeneous Phase

Hydrodesulfurization model systems. Homogeneous and heterogeneous (solid-gas) hydrogenation of benzothiophene at iridium

Hydrogen-transfer reactions of the trihydride [(MeC(CH2PPh2)3RhH3]: a simple route to rhodium cis hydride .eta.2-alkene complexes

Hydrogenation of Arenes and Heteroaromatics

Hydrogenation of Arenes over Catalysts that Combine a Metal Phase and a Grafted Metal Complex: Role of the Single-Site Catalyst

Hydrogenation of Arenes over Silica-Supported Catalysts That Combine a Grafted Rhodium Complex and Palladium Nanoparticles: Evidence for Substrate Activation on Rhsingle-site−PdmetalMoieties

Hydrogenation of Indole by Phosphine-Modified Rhodium and Ruthenium Catalysts

In Situ High-Pressure31P{1H} NMR Studies of the Hydroformylation of 1-Hexene by RhH(CO)(PPh3)3

Insertion of iridium into C-H and C-S bonds of 2,5-dimethylthiophene 2-methylbenzothiophene and 4,6-dimethyldibenzothiophene

Interaction of monohydrido complexes of rhodium(I) with 1-alkynes. Experimental study on deceptively simple reactions

Ligand and Solvent Effects in the Alternating Copolymerization of Carbon Monoxide and Olefins by Palladium−Diphosphine Catalysis

Ligand effects in the non-alternating CO-ethylene copolymerization by palladium(II) catalysis

Like on Heterogeneous Hydrodesulfurization(HDS) Catalysts, the Homogeneous HDS of Benzo[b]thiophene Is Achived by the Concomitant Action of a Metal Promoter(Rh) and an Active HDS Component(W)

Liquid-Biphase Hydrogenolysis of Benzo[b]thiophene by Rhodium Catalysis

Mechanistic Study of Ir(H)2-Assisted Transformations of Ethyne: Cyclotrimerization, Cooligomerization with Ethene, and Reductive Coupling

Metal Activation of Dibenzo[b,d]thiophene. Reactivity of the C-S Insertion Product [MeC(CH2PPh2)3]IrH(.eta.2(C,S)-C12H8S)

Metathesis of CS2-Like Heteroallenes on 1,1-Dithio Complexes of Rhodium(III)

Migration of hydrogen from metal to alkene promoted by dioxygen addition. Oxygen atom transfer from a cis-(alkyl)(η2-dioxygen) complex of rhodium to organic and inorganic substrates

Mimicking the HDS Activity of Promoted Tungsten Catalysts. A Homogeneous Modeling Study Using a Two-Component Tungsten/Rhodium System

Mimicking the HDS Activity of Ruthenium-Based Catalysts 2: The Hydrogenation of Benzo[b]thiophene to 2,3-Dihydrobenzo[b]thiophene

Mimicking the HDS Activity of Ruthenium-Based Catalysts. Homogeneous Hydrogenolysis of Benzo[b]thiophene

Mixed iridium-gold hydrides as model compounds for elucidating the interconversion between classical and nonclassical polyhydrides

Molecular Solid-Gas Organometallic Chemistry. Catalytic and Stoichiometric Iridium-Assisted C-C Bond-Forming Reactions Involving Ethyne and Ethene

Molecular solid-gas organometallic chemistry. Catalytic and stoichiometric transformations of ethyne at iridium

New structurally rigid palladium catalysts for the alternating copolymerization of carbon monoxide and ethene

Novel reactions of the [BPh4]- salt of the bifunctional complex [(triphos)Rh(S2CO)]+ (triphos = MeC(CH2PPh2)3): one-electron reduction, cleavage of B-H and B-C bonds, and metathesis of CS2-like heteroallene molecules

Opening and Hydrogenation of Dinaphtho[2,1-b:1‘,2‘-d]thiophene (DNT) by Soluble Rhodium and Iridium Complexes. Homogeneous Hydrogenolysis of DNT to 1,1‘-Binaphthalene-2-thiol by Rhodium Catalysis

Opening, desulfurization, and hydrogenation of thiophene at iridium. An experimental study in a homogeneous phase

Oxidation of primary alcohols to carboxylic acids made easy at iridium

Preparation, Characterization, and Performance of Tripodal Polyphosphine Rhodium Catalysts Immobilized on Silica via Hydrogen Bonding

Preparation, Characterization, and Performance of the Supported Hydrogen-Bonded Ruthenium Catalyst [(sulphos)Ru(NCMe)3](OSO2CF3)/SiO2. Comparisons with Analogous Homogeneous and Aqueous-Biphase Catalytic Systems in the Hydrogenation of Benzylideneace

Redox-Induced Conversion Pathways in Rhodium and Iridium Complexes Containing C-S Bond Cleaved Benzo[b]thiophene

Regioselective propylene dimerization by tetrahedral (imino)pyridine CoII dichloride complexes activated by MAO

Rhodium complexes with the tripodal triphosphine MeC(CH2PPh2)3 as highly reactive systems for hydrogenation and hydroformylation of alkenes

Rhodium-Assisted Transformations of Substituted Thiophenes into Butadienyl Methyl Sulfides

Role of single-site catalysts in the hydrogenation of thiophenes: from models systems to effective HDS catalysts

Selective hydrogenation of 1,10-phenanthrolines by silica-supported palladium nanoparticles

Stepwise metal-assisted conversion of .eta.2-carbon diselenide to .eta.1-phosphoniodiselenoformate, .eta.2-diselenocarbonate, and .eta.2-diselenium. Crystal structure of the rhodium complexes [(triphos)Rh(Se2CO)]BPh4.cntdot.0.5CH2Cl2.cntdot.0.5C4H9OH

Stepwise metal-assisted reduction of .eta.4-coordinated benzene to cyclohexene

Synthesis and Characterization of Dirhodium Complexes Containing μ-SO, μ-SH, and μ-S2Groups Stabilized by the Tripodal Ligand CH3C(CH2PPh2)3

Synthesis and characterization of heterobimetallic complexes containing C-S cleaved thiophenes

Synthesis and characterization of palladium(II) complexes with new diphosphonium-diphosphine and diphosphine ligands. Production of low molecular weight alternating polyketones via catalytic CO/ethene copolymerisation.

Synthesis of New Polydentate Nitrogen Ligands and Their Use in Ethylene Polymerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides and Methylaluminoxane

Synthesis of a New Polydentate Ligand Obtained by Coupling 2,6-Bis(imino)pyridine and (Imino)pyridine Moieties and Its Use in Ethylene Oligomerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides

Synthesis of palladium(II) complexes containing a new alpha-D-xylofuranose-modified diphosphine and their application as catalyst precursors in the co- and terpolymerization of CO-ethene and propene.

Synthesis, characterization, and electrochemical properties of a family of dinuclear rhodium complexes containing two terminal hydride ligands and two hydride (or chloride) bridges. Stoichiometric and catalytic hydrogenation reactions of alkynes and

The Catalytic Transformation of Benzo[b]thiophene to 2-Ethylthiophenol by a Soluble Rhodium Complex: The Reaction Mechanism Involves Ring Opening Prior to Hydrogenation

The Mechanism of Acetylene Cyclotrimerization Catalyzed by the fac-IrP3+ Fragment: The Relationship between Fluxionality and Catalysis

Thermal and photochemical carbon-hydrogen bond activation reactions at iridium. .pi.-Coordination vs. C-H cleavage of ethene, styrene, and phenylacetylene

Thiophene C–S bond cleavage by rhodium and iridium. An unprecedented bridging mode of the open C4H4S fragment

Tripodal polyphosphine ligands control selectivity of organometallic reactions

Tripodal polyphosphine ligands in homogeneous catalysis. 1. Hydrogenation and hydroformylation of alkynes and alkenes assisted by organorhodium complexes with MeC(CH2PPh2)3

Unraveling theo-Methoxy Effect in the CO/Ethene Copolymerization Reaction by Diphosphanepalladium(II) Catalysis

Water-Soluble Palladium(II) Catalysts for the Alternating Co- and Terpolymerization of CO and Olefins in Aqueous Phase