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List of works by Ademir Neves

2-{[Bis(2-pyridylmethyl)amino]methyl}-6-[(2-hydroxyanilino)methyl]-4-methylphenol: a novel binucleating asymmetric ligand as a precursor to synthetic models for metalloenzymes

scientific article published on 13 January 2007

A Synthetic Pathway for an Unsymmetrical N5O2 Heptadentate Ligand and Its Heterodinuclear Iron(III)Zinc(II) Complex: A Biomimetic Model for the Purple Acid Phosphatases ⬇️

scientific article published on September 1, 2012

A bio-inspired sensor based on surfactant film and Pd nanoparticles

scientific article published on 01 January 2013

A mixed-valence diacetate-bridged Mn(II)-Mn(III) complex incorporating a bridging phenolate ligand.

scientific article published on 14 January 2006

A new heterobinuclear FeIIICuII complex with a single terminal FeIII-O(phenolate) bond. Relevance to purple acid phosphatases and nucleases

article published in 2005

A new heteropentanuclear complex containing the [Fe2IIIZn3II(μ-OH)3] structural motif as a model for purple acid phosphatases

scientific article published in March 2020

A new nitrosyl ruthenium complex: synthesis, chemical characterization, in vitro and in vivo antitumor activities and probable mechanism of action

scientific article published on 19 May 2011

A promiscuous dicopper(II) system promoting the hydrolysis of bis(2,4-dinitrophenyl)phosphate: Gaining mechanistic insight by means of structural and spectroscopic DFT studies

scientific article published in 2009

A synthetic dinuclear copper(II) hydrolase and its potential as antitumoral: cytotoxicity, cellular uptake, and DNA cleavage.

scientific article published on 20 May 2009

Adiabatic intramolecular electron transfer in pyrazine-2,6-dicarboxylato-bridged complexes of cobalt(III)-ruthenium(II) and of cobalt(III)-iron(II): comparison of inner-sphere vs. outer-sphere activated complexes

scholarly article by Ademir Neves et al published October 1984 in Inorganic Chemistry

An unprecedented Fe(III)(mu-OH)Zn(II) complex that mimics the structural and functional properties of purple acid phosphatases

scientific article published on 23 May 2007

Base-Induced Intramolecular Formation of a Mo?Mo Bond in [L2Mo2III?-OH(?-CH3CO2)2]3?(L =N,N?,N?-Trimethyl-1,4,7-triazacyclononane)

scholarly article by Ademir Neves et al published May 1988 in Angewandte Chemie International Edition

Bioinspired FeIIICdII and FeIIIHgII complexes: synthesis, characterization and promiscuous catalytic activity evaluation

scientific article published on 28 August 2011

Biomimetic sensor based on MnIIIMnII complex as manganese peroxidase mimetic for determination of rutin

scientific article published on 14 November 2008

Biomimetic sensor based on a novel copper complex for the determination of hydroquinone in cosmetics

scientific article published in March 2007

Broken symmetry density functional study of a mixed-valence unsymmetrical dinuclear iron complex

scientific article published on 6 July 2009

Broken symmetry density functional study of biomimetic models for Purple Acid Phosphatases of the type Fe(III)–M(II) (M=Fe, Cu, Ni, Co and Mn)

scientific article published in January 2012

Catalytic promiscuity in biomimetic systems: catecholase-like activity, phosphatase-like activity, and hydrolytic DNA cleavage promoted by a new dicopper(II) hydroxo-bridged complex

scientific article published on 01 January 2007

Catalytic promiscuity: catecholase-like activity and hydrolytic DNA cleavage promoted by a mixed-valence FeIII FeII complex

scientific article published in 2010

Catecholase activity of a series of dicopper(II) complexes with variable Cu-OH(phenol) moieties

scientific article

Catecholase and DNase activities of copper(II) complexes containing phenolate-type ligands

scientific article published on 24 August 2010

Chitosan crosslinked with a metal complexing agent: Synthesis, characterization and copper(II) ions adsorption

Correlation between DNA interactions and cytotoxic activity of four new ternary compounds of copper(II) with N-donor heterocyclic ligands.

scientific article published on 5 October 2013

Crystal Structure, Spectroscopy and Magnetic Properties of a Novel FeIIIUnsymmetric Tetranuclear Complex: A Model for met-Hemerythrin

Crystal structure, spectral and magnetic properties of a new (μ-acetate) (μ-alkoxide) dicopper (II) complex as a model for tyrosinase

DNA photonuclease activity of four new copper(II) complexes under UV and red light: theoretical/experimental correlations with active species generation

scientific article published on 23 December 2009

Design of a Dinuclear Nickel(II) Bioinspired Hydrolase to Bind Covalently to Silica Surfaces: Synthesis, Magnetism, and Reactivity Studies

scientific article published on 15 May 2012

Determination of catechin in green tea using a catechol oxidase biomimetic sensor

article by Suellen C. Fernandes et al published 2008 in Journal of the Brazilian Chemical Society

Determination of chlorogenic acid in coffee using a biomimetic sensor based on a new tetranuclear copper(II) complex

scientific article

Development of a biomimetic chitosan film-coated gold electrode for determination of dopamine in the presence of ascorbic acid and uric acid

article

Development of a new biomimetic sensor based on an FeIIIFeII complex for the determination of phenolic compounds

scientific article published in January 2008

Di-μ-chlorido-bis-[chlorido(1,4,6-trimethyl-6-nitro-1,4-diazepine)copper(II)].

scientific article published on 8 January 2009

Dinuclear copper(II) complexes with derivative triazine ligands as biomimetic models for catechol oxidases and nucleases

scientific article published on 17 September 2020

Dopamine polymerization promoted by a catecholase biomimetic CuII(μ-OH)CuII complex containing a triazine-based ligand.

scientific article published in October 2016

Doubly phenoxo-hydroxo-bridged dicopper(II) complexes: individual contributions of the bridges to antiferromagnetic coupling based on two related biomimetic models for catechol oxidases

scientific article published on 14 May 2012

EPR and semi-empirical studies as tools to assign the geometric structures of FeIII isomer models for transferrins

scientific article published in December 2006

Efficient phosphodiester hydrolysis by luminescent terbium(III) and europium(III) complexes

scientific article published in July 2010

Electronic effects of electron-donating and -withdrawing groups in model complexes for iron-tyrosine-containing metalloenzymes

scientific article published in February 2006

Electronic structure and spectro-structural correlations of Fe(III)Zn(II) biomimetics for purple acid phosphatases: relevance to DNA cleavage and cytotoxic activity.

scientific article published on 16 November 2010

Fe(III)Fe(III) and Fe(II)Fe(III) Complexes as Synthetic Analogues for the Oxidized and Reduced Forms of Purple Acid Phosphatases

scientific article published on 01 April 1996

First-transition-metal complexes containing the ligands 6-amino-6-methylperhydro-1,4-diazepine (AAZ) and a new functionalized derivative: can AAZ act as a mimetic ligand for 1,4,7-triazacyclononane?

scientific article published in October 2005

Guanidine- and purine-functionalized ligands of FeIIIZnII complexes: effects on the hydrolysis of DNA

scientific article published on 02 July 2019

Heterodinuclear Fe(III)Zn(II)-bioinspired complex supported on 3-aminopropyl silica. Efficient hydrolysis of phosphate diester bonds

scientific article published in March 2010

Hydrolytic activity of a dinuclear copper(II,II) complex in phosphate diester and DNA cleavage

Hydrolytic protein cleavage mediated by unusual mononuclear copper(II) complexes: X-ray structures and solution studies

scientific article published in February 2005

In vitro and in vivo activity of a new unsymmetrical dinuclear copper complex containing a derivative ligand of 1,4,7-triazacyclononane: catalytic promiscuity of [Cu2(L)Cl3].

scientific article published in May 2013

Intramolecular electron-transfer reactions in bridged polynuclear ruthenium(II)-cobalt(III) complexes containing a (.mu.-carboxylato)bis(.mu.-hydroxo)bis[(amine)cobalt(III)] and a pentaammineruthenium(II) structural unit

scholarly article by Ademir Neves et al published September 1984 in Journal of the American Chemical Society

Intramolecular, base-induced formation of a metal-metal bond in [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2]3+ (L = 1,4,7-trimethyl-1,4,7-triazacyclononane). Crystal structures of [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2](ClO4)3.cntdot.H2O and [L2MoIII2(.mu.-O)(.mu.-CH

Journal of Inorganic Biochemistry. Special section: special issue: containing contributions from the Second Latin American Meeting on Biological Inorganic Chemistry-LABIC 2010. Preface

scientific article published on 06 October 2011

Kinetics and equilibrium adsorption of Cu(II), Cd(II), and Ni(II) ions by chitosan functionalized with 2[-bis-(pyridylmethyl)aminomethyl]-4-methyl-6-formylphenol.

scientific article published on 29 June 2005

Kinetics and mechanism of the outer-sphere electron-transfer-induced formation of cis-dioxovanadium(V) species from vanadyl(IV) complexes. Crystal structures of [VO(TCDA)].cntdot.H2O and [VO2(TCDAH)].cntdot.2H2O (TCDA = 1,4,7-triazacyclononane-N,N'-d

article

Light Response of Three Water-Soluble MnI PhotoCORMs: Spectroscopic Features and CO Release Investigation

scientific article published in 2019

Mononuclear Cu(II)-phenolate bioinspired complex is catalytically promiscuous: phosphodiester and peptide amide bond cleavage

scientific article published on 01 April 2009

New Fe(III)Zn(II) complex containing a single terminal Fe-O(phenolate) bond as a structural and functional model for the active site of red kidney bean purple acid phosphatase

scientific article published in November 2002

New La(III) complex immobilized on 3-aminopropyl-functionalized silica as an efficient and reusable catalyst for hydrolysis of phosphate ester bonds.

scientific article published on 3 March 2014

New dioxidouranium (VI) and mixed-valence oxidovanadium (IV/V) coordination compounds with N,O-pentadentate ligands obtained from pyridoxal and triethylenetetramine

scientific article published in March 2015

New gadolinium complex with efficient hydrolase-like activity: a 100-million-fold rate enhancement in diester hydrolysis.

scientific article

New mononuclear copper(II) complex based on a salen derivative ligand with an unusual coordination and its catecholase activity

scientific article published in November 2013

New unsymmetric dinuclear Cu(II)Cu(II) complexes and their relevance to copper(II) containing metalloenzymes and DNA cleavage.

scientific article

Nitro- and Amino-Porphyrins: Important Intermediates for Novel Porphyrin Derivatives Formation

scientific article published in 2015

Oxygen-independent photonuclease activity of a new iron(II) complex.

scientific article published on 18 March 2010

PEI-coated gold nanoparticles decorated with laccase: a new platform for direct electrochemistry of enzymes and biosensing applications

scientific article

Peroxidase activity of new mixed‐valence cobalt complexes with ligands derived from pyridoxal

scientific article published on 22 April 2019

Phosphate Ester Hydrolysis: Metal Complexes As Purple Acid Phosphatase and Phosphotriesterase Analogues

Phosphate diester hydrolysis and DNA damage promoted by new cis-aqua/hydroxy copper(II) complexes containing tridentate imidazole-rich ligands.

scientific article published in December 2003

Photoactive meso-tetra(4-pyridyl)porphyrin-tetrakis-[chloro(2,2'bipyridine)platinum(ii) derivatives recognize and cleave DNA upon irradiation.

scientific article

Photoinduced DNA cleavage promoted by two copper(II) complexes of tetracyclines and 1,10-phenanthroline

scientific article published on 04 October 2011

Preface for the JIB Special Issue on Latin American Bioinorganic Chemistry

scientific article published on 01 March 2014

Probing the role of the divalent metal ion in uteroferrin using metal ion replacement and a comparison to isostructural biomimetics

scientific article published on 16 October 2007

Pyridoxal derivatized copper(II) complexes: Evaluation of antioxidant, catecholase, and DNA cleavage activity

scientific article published in January 2018

Resonance Raman and crystallographic studies on the complex [Fe2(bbpnol)2]·2DMF (bbpnol=N,N′-bis(2-hydroxybenzyl)-2-ol-1,3-propanediamine)

Rosmarinic acid determination using biomimetic sensor based on purple acid phosphatase mimetic

scientific article published on 29 February 2008

SOD activity of new copper II complexes with ligands derived from pyridoxal and toxicity in Caenorhabditis elegans

scientific article published on 26 November 2019

Searching for Vanadium-Based Prospective Agents againstTrypanosoma cruzi: Oxidovanadium(IV) Compounds with Phenanthroline Derivatives as Ligands

scientific article published on 28 March 2013

Second-Sphere Effects in Dinuclear FeIIIZnII Hydrolase Biomimetics: Tuning Binding and Reactivity Properties.

scientific article published on 13 December 2017

Second-coordination-sphere effects increase the catalytic efficiency of an extended model for Fe(III)M(II) purple acid phosphatases

scientific article published on 15 March 2013

Self-assembled monolayer of nickel(II) complex and thiol on gold electrode for the determination of catechin.

scientific article published on 24 January 2009

Sensor for fisetin based on gold nanoparticles in ionic liquid and binuclear nickel complex immobilized in silica

scientific article published in March 2010

Spectroscopic and catalytic characterization of a functional Fe(III)Fe(II) biomimetic for the active site of uteroferrin and protein cleavage

scientific article

Structural, spectroscopic and redox studies of a new ruthenium(III) complex with an imidazole-rich tripodal ligand

Study of the antimicrobial activity of metal complexes and their ligands through bioassays applied to plant extracts

scientific article published in May 2014

Synthesis and characterization of FeIII(μ-OH)ZnII complexes: effects of a second coordination sphere and increase in the chelate ring size on the hydrolysis of a phosphate diester and DNA.

scientific article published on 16 August 2017

Synthesis of substituted dipyrido[3,2-a:2′,3′-c]phenazines and a new heterocyclic dipyrido[3,2-f:2′,3′-h]quinoxalino[2,3-b]quinoxaline

scientific article published in May 2008

Synthesis, Structure, Physicochemical Properties and Catecholase-like Activity of a New Dicopper(II) Complex

Synthesis, X-ray structure and antimycobacterial activity of silver complexes with alpha-hydroxycarboxylic acids

scientific article

Synthesis, characterization and biological evaluation of new manganese metal carbonyl compounds that contain sulfur and selenium ligands as a promising new class of CORMs

scientific article published on 01 April 2019

Synthesis, characterization and photoinduced CO-release by manganese(i) complexes

scientific article published in 2020

Synthesis, characterization, hydrolase and catecholase activity of a dinuclear iron(III) complex: Catalytic promiscuity

scientific article published on 5 March 2015

Synthesis, crystal structure and luminescent properties of new tris-β-diketonate Eu(III) complex with thiadiazolophenanthroline derivative ligand

scientific article published in October 2008

Synthesis, magnetostructural correlation, and catalytic promiscuity of unsymmetric dinuclear copper(II) complexes: models for catechol oxidases and hydrolases

scientific article published on 19 January 2012

Synthesis, photophysical properties and spectroelectrochemical characterization of 10-(4-methyl-bipyridyl)-5,15-(pentafluorophenyl)corrole

scientific article published in January 2017

Synthesis, physicochemical properties and in vitro catalytic activity of a dinuclear nickel(II) complex with a N5O-hexadentate ligand: A functional model for phosphohydrolases

scientific article published in April 2016

Synthesis, spectroscopic/electrochemical characterization and DNA interaction study of novel ferrocenyl-substituted porphyrins

scientific article published on 8 March 2018

Synthesis, structure and physicochemical properties of zinc and copper complexes based on sulfonamides containing 8-aminoquinoline ligands

scientific article published in 2008

Synthesis, structure and properties of a new unsymmetric tetranuclear mixed-valence vanadium(IV/V) complex containing distinct V2O33+ cores

Synthesis, structure and properties of the first dinuclear copper(II) complex as a structural model for the phenolic intermediate in tyrosinase–cresolase activity

Synthesis, structure and properties of unsymmetrical μ-alkoxo-dicopper(II) complexes: biological relevance to phosphodiester and DNA cleavage and cytotoxic activity

Synthesis, structure, and phosphatase-like activity of a new trinuclear Gd complex with the unsymmetrical ligand H3L as a model for nucleases

scientific article published in March 2010

Synthesis, structure, and physicochemical properties of dinuclear NiII complexes as highly efficient functional models of phosphohydrolases.

scientific article published on 9 January 2008

Synthesis, structure, magnetism, and hydrolase and catecholase activity of a new trinuclear copper(II) complex

scientific article published in August 2015

Synthesis, structure, properties, and phosphatase-like activity of the first heterodinuclear Fe(III)Mn(II) complex with the unsymmetric ligand H(2)BPBPMP as a model for the PAP in sweet potato

scientific article published on 01 September 2002

Targeting an Artificial Metal Nuclease to DNA by a Simple Chemical Modification and Its Drastic Effect on Catalysis

scientific article published on 12 August 2019

The catalytic mechanisms of binuclear metallohydrolases.

scientific article published on August 2006

The effect of chain size on the modeling of second sphere effects in biomimetic complexes

scientific article published in February 2015

The reaction mechanism of the Ga(III)Zn(II) derivative of uteroferrin and corresponding biomimetics

scientific article published on 15 August 2007

Theoretical investigation of the reaction mechanism for the phosphate diester hydrolysis using an asymmetric dinuclear metal complex as a biomimetic model of the purple acid phosphatase enzyme

scientific article published on 14 October 2008

Three new dinuclear nickel(II) complexes with amine pendant-armed ligands: Characterization, DFT study, antibacterial and hydrolase-like activity

scientific article published in July 2020

Two New Ternary Complexes of Copper(II) with Tetracycline or Doxycycline and 1,10-Phenanthroline and Their Potential as Antitumoral: Cytotoxicity and DNA Cleavage

Unsymmetrical Fe(III)Co(II) and Ga(III)Co(II) complexes as chemical hydrolases: biomimetic models for purple acid phosphatases (PAPs).

scientific article published in August 2009

Unusual hydrolase-like activity of a mononuclear Fe(III) complex

scientific article published in April 2019

Uso de equações lineares na determinação dos parâmetros de Michaelis-Menten

bis-(1H-Benzimidazol-2-yl)-methanone: New preparation method, crystal structure, vibrational spectroscopy and DFT calculations

meso-Mono-[4-(1,4,7-triazacyclononanyl)]-tri(phenyl)]porphyrin and the respective zinc(ii)-complex: complete characterization and biomolecules binding abilities.

scientific article published on 4 April 2016

trans-Diaqua-bis{1,3-bis-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]propane}zinc(II) bis-(perchlorate).

scientific article published on 14 March 2008

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