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List of works by Kay M. Brummond

(3R,7aS)-3-(TRICHLOROMETHYL)TETRAHYDROPYRROLO[1,2-C]OXAZOL-1(3H)-ONE: AN AIR AND MOISTURE STABLE REAGENT FOR THE SYNTHESIS OF OPTICALLY ACTIVE a-BRANCHED PROLINES ⬇️

scientific article published on January 1, 2009

A Thermal Dehydrogenative Diels–Alder Reaction of Styrenes for the Concise Synthesis of Functionalized Naphthalenes ⬇️

scientific article published on August 22, 2012

A formal total synthesis of (-)-FR901483, using a tandem cationic aza-Cope rearrangement/Mannich cyclization approach

scientific article

A general synthetic route to differentially functionalized angularly and linearly fused [6-7-5] ring systems: a Rh(I)-catalyzed cyclocarbonylation reaction

scientific article published on 04 June 2008

A redox economical synthesis of bioactive 6,12-guaianolides.

scientific article published on 10 May 2013

A rhodium(I)-catalyzed formal allenic Alder ene reaction for the rapid and stereoselective assembly of cross-conjugated trienes

scientific article published on 01 December 2002

A thermally-induced, tandem [3,3]-sigmatropic rearrangement/[2 + 2] cycloaddition approach to carbocyclic spirooxindoles

scientific article

Alkyne Ligation Handles: Propargylation of Hydroxyl, Sulfhydryl, Amino, and Carboxyl Groups via the Nicholas Reaction

scientific article published on 29 August 2016

Allene chemistry ⬇️

scientific article published on April 7, 2011

Allenes and transition metals: a diverging approach to heterocycles

scientific article published on 01 June 2004

An Allenic Pauson–Khand Approach to 6,12-Guaianolides ⬇️

scientific article published on November 9, 2011

An allenic Pauson-Khand-type reaction: a reversal in pi-bond selectivity and the formation of seven-membered rings

scientific article published on 01 May 2002

Attachable Solvatochromic Fluorophores and Bioconjugation Studies ⬇️

scientific article published on May 13, 2013

Cdc25B dual-specificity phosphatase inhibitors identified in a high-throughput screen of the NIH compound library

scientific article published in June 2009

Chemical methodology as a source of small-molecule checkpoint inhibitors and heat shock protein 70 (Hsp70) modulators

scientific article

Chiral nonracemic alpha-alkylidene and alpha-silylidene cyclopentenones from chiral allenes using an intramolecular allenic Pauson-Khand-type cycloaddition

scientific article

Complete transfer of chirality in an intramolecular, thermal [2 + 2] cycloaddition of allene-ynes to form non-racemic spirooxindoles

scientific article

Computational Insight Concerning Catalytic Decision Points of the Transition Metal Catalyzed [2 + 2 + 1] Cyclocarbonylation Reaction of Allenes

scientific article published on October 2006

Computationally Guided Catalyst Design in the Type I Dynamic Kinetic Asymmetric Pauson-Khand Reaction of Allenyl Acetates.

scientific article published on 12 October 2017

Conditions for a Rh(I)-catalyzed [2 + 2 + 1] cycloaddition reaction with methyl substituted allenes and alkynes

scientific article published in June 2015

Consecutive Rh(I)-catalyzed Alder-ene/Diels–Alder/Diels–Alder reaction sequence affording rapid entry to polycyclic compounds

scientific article (publication date: June 2005)

Covalent Modifiers: A Chemical Perspective on the Reactivity of α,β-Unsaturated Carbonyls with Thiols via Hetero-Michael Addition Reactions

scientific article (publication date: 20 December 2016)

Cyclopenta[b]naphthalene cyanoacrylate dyes: synthesis and evaluation as fluorescent molecular rotors

scientific article

Design and synthesis of a 3,4-dehydroproline amide discovery library

scientific article

Design and synthesis of a library of tetracyclic hydroazulenoisoindoles

scientific article

Differentiating mechanistic possibilities for the thermal, intramolecular [2 + 2] cycloaddition of allene-ynes

scientific article published on September 2010

Diverging DOS Strategy Using an Allene-Containing Tryptophan Scaffold and a Library Design that Maximizes Biologically Relevant Chemical Space While Minimizing the Number of Compounds ⬇️

scientific article published on February 18, 2011

Diverging Rh(I)-catalyzed carbocylization strategy to prepare a library of unique cyclic ethers

scientific article

Enantioselective Synthesis of 5,7-Bicyclic Ring Systems from Axially Chiral Allenes Using a Rh(I)-Catalyzed Cyclocarbonylation Reaction ⬇️

scientific article published on March 29, 2013

Heterocyclic alpha-alkylidene cyclopentenones obtained via a Pauson-Khand reaction of amino acid derived allenynes. A scope and limitation study directed toward the preparation of a tricyclic pyrrole library

scientific article published in March 2005

Hexacarbonylmolybdenum

article

Identification of ATR-Chk1 pathway inhibitors that selectively target p53-deficient cells without directly suppressing ATR catalytic activity

scientific article

Intramolecular Didehydro-Diels-Alder Reaction for the Synthesis of Benzo- and Dihydrobenzo-Fused Heterocycles

scientific article published on 07 March 2017

Intramolecular dehydro-Diels-Alder reaction affords selective entry to arylnaphthalene or aryldihydronaphthalene lignans

scientific article

Intramolecular didehydro-Diels-Alder reaction and its impact on the structure-function properties of environmentally sensitive fluorophores

scientific article

Mechanistic Insight into the Dehydro-Diels-Alder Reaction of Styrene-Ynes.

scientific article published on 11 February 2015

Metal Free C-C Coupling of an Allenyl Sulfone with Picolyl Amides to Access Vinyl Sulfones via Pyridine-Initiated In-Situ Generation of Sulfinate Anion

scientific article published on 19 May 2020

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes ⬇️

scientific article published on April 1, 2013

Microwave-assisted intramolecular [2 + 2] Allenic cycloaddition reaction for the rapid assembly of bicyclo[4.2.0]octa-1,6-dienes and bicyclo[5.2.0]nona-1,7-dienes

scientific article published on 01 August 2005

Mo(CO)6- and [Rh(CO)2Cl]2-catalyzed allenic cyclocarbonylation reactions of alkynones: efficient access to bicyclic dienediones

scientific article published on 31 January 2008

PHOSPHINE-CATALYZED [4+2] ANNULATION: SYNTHESIS OF ETHYL 6-PHENYL-1-TOSYL-1,2,5,6-TETRAHYDROPYRIDINE-3-CARBOXYLATE.

scientific article published on March 2009

Rh(I)-catalyzed cyclocarbonylation of allenol esters to prepare acetoxy 4-alkylidenecyclopent-3-en-2-ones

scientific article

Rhodium(I)-catalyzed allenic carbocyclization reaction affording delta- and epsilon-lactams

scientific article published on January 2007

Rhodium(I)-catalyzed ene-allene carbocyclization strategy for the formation of azepines and oxepines

scientific article published on 01 June 2004

Solid-Phase Synthesis of BRL 49653 ⬇️

scientific article published on March 5, 1999

Solution-phase synthesis of a tricyclic pyrrole-2-carboxamide discovery library applying a stetter-Paal-Knorr reaction sequence

scientific article published in May 2006

Strategy for the Preparation of Allenes from α,β-Unsaturated and Saturated Ketones via Enol Phosphates ⬇️

scientific article published on September 6, 1996

Structurally unique inhibitors of human mitogen-activated protein kinase phosphatase-1 identified in a pyrrole carboxamide library

scientific article

Synthesis and Photophysical Properties of a Series of Cyclopenta[b]naphthalene Solvatochromic Fluorophores ⬇️

scientific article published on July 20, 2012

Synthesis and in silico screening of a library of β-carboline-containing compounds ⬇️

scientific article published on July 10, 2012

Synthesis of Guaianolide Analogues with a Tunable α-Methylene-γ-lactam Electrophile and Correlating Bioactivity with Thiol Reactivity

scientific article published on 17 November 2020

Synthesis of the Naturally Occurring (-)-1,3,5-Tri-O-Caffeoylquinic Acid

scientific article published on February 2009

The first total synthesis of 15-deoxy-Delta12,14-prostaglandin J2 and the unambiguous assignment of the C14 stereochemistry

scientific article published on 01 January 2004

Toward a molecular understanding of the interaction of dual specificity phosphatases with substrates: insights from structure-based modeling and high throughput screening

scientific article

Unique strategy for the assembly of the carbon skeleton of guanacastepene A using an allenic Pauson-Khand-type reaction

scientific article published on 01 September 2003

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