List of works - Emmanuel Lacôte

A general strategy for ligation of organic and biological molecules to Dawson and Keggin polyoxotungstates

scientific article published on 08 September 2007

A new practical one-pot access to sulfonimidates

scientific article published on 01 November 2002

Boryltrihydroborate: synthesis, structure, and reactivity as a reductant in ionic, organometallic, and radical reactions

scientific article published on August 2010

CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃ ⬇️

scientific article published on August 2, 2010

Carbonyl-Inserted Organo-Hybrids of a Dawson-Type Phosphovanadotungstate: Scope and Chemoselective Oxidation Catalysis

scientific article published on 26 October 2011

Chemoselective catalysis with organosoluble Lewis acidic polyoxotungstates

scientific article published on 01 June 2010

Chiral recognition of hybrid metal oxide by peptides

scientific article published on 01 January 2009

Complexes of borane and N-heterocyclic carbenes: a new class of radical hydrogen atom donor

scientific article published on 9 July 2008

Difluorination at Boron Leads to the First Electrophilic Ligated Boryl Radical (NHC-BF2. )

scientific article published on 17 July 2018

EPR studies of the generation, structure, and reactivity of n-heterocyclic carbene borane radicals

scientific article published in February 2010

Efficient copper-mediated reactions of nitrenes derived from sulfonimidamides

scientific article published on 01 September 2004

Efficient preparation of functionalized hybrid organic/inorganic Wells-Dawson-type polyoxotungstates

scientific article published on 01 May 2005

Electron paramagnetic resonance and computational studies of radicals derived from boron-substituted N-heterocyclic carbene boranes

scientific article published on 14 June 2011

Elucidation of the Conformation of Polyglycine Organo-Polyoxotungstates: Evidence for Zipper Folding

scientific article published in August 2017

Estimated rate constants for hydrogen abstraction from N-heterocyclic carbene-borane complexes by an alkyl radical

scientific article published in July 2010

Exception to the ortho effect in palladium/norbornene catalysis

scientific article published on 21 October 2011

Expeditious Synthesis of Phenanthridines from Benzylamines via Dual Palladium Catalysis

scientific article published on 17 November 2010

Formation of cyclic sulfinates and sulfinamides through homolytic substitution at the sulfur atom

scientific article published on 01 January 2006

Generation and Reactions of an Unsubstituted N-Heterocyclic Carbene Boryl Anion

article

Generation of phosphorus-centered radicals via homolytic substitution at sulfur.

scientific article published on 23 February 2007

High Glass-Transition Temperature Polymer Networks Harnessing the Dynamic Ring Opening of Pinacol Boronates

scientific article published on 25 July 2019

Highly efficient peptide bond formation to functionalized Wells-Dawson-type polyoxotungstates

scientific article published on 01 July 2003

Identification of polyoxometalates as nanomolar noncompetitive inhibitors of protein kinase CK2.

scientific article published in July 2008

Improved method for the iodine(III)-mediated preparation of aryl sulfonimidates

scientific article published on 01 January 2006

Increased Lewis acidity in hafnium-substituted polyoxotungstates

scientific article published on 01 January 2007

Insertion of amides into a polyoxometalate

scientific article published on 01 January 2009

Intramolecular anion effect in polyoxometalate-based organocatalysts: reactivity enhancement and chirality transfer by a metal oxide-organic cation interaction

scientific article published on 24 October 2014

Intramolecular homolytic substitution of sulfinates and sulfinamides

scientific article published in October 2009

Intramolecular homolytic substitution of sulfinates and sulfinamides--a computational study

scientific article published on 29 March 2011

Iodine(III)-mediated preparations of nitrogen-containing sulfur derivatives: dramatic influence of the sulfur oxidation state.

scientific article published in February 2004

Ionic and organometallic reductions with N-heterocyclic carbene boranes

scientific article published on 01 December 2009

Iron-catalyzed reductive radical cyclization of organic halides in the presence of NaBH4: evidence of an active hydrido iron(I) catalyst

scientific article published on 11 June 2012

Lanthanide complexes of the monovacant Dawson polyoxotungstate [alpha1-P2W17O61]10- as selective and recoverable Lewis acid catalysts

scientific article published on 01 May 2006

Lanthanide polyoxocationic complexes: experimental and theoretical stability studies and Lewis acid catalysis

scientific article

Lewis-acidic polyoxometalates as reusable catalysts for the synthesis of glucuronic acid esters under microwave irradiation

scientific article published on 01 November 2010

N-heterocyclic carbene boryl radicals: a new class of boron-centered radical.

scientific article published in August 2009

N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes

scientific article published on 27 July 2011

N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation

scientific article published in May 2013

Oxidation of alpha-alkoxy allenes into alpha'-alkoxy enones

scientific article published on 01 September 2010

Preparation of NHC Borane Complexes by Lewis Base Exchange with Amine− and Phosphine−Boranes ⬇️

scientific article published on October 15, 2010

Production and reactions of organic-soluble lanthanide complexes of the monolacunary Dawson [alpha1-P2W17O61]10- polyoxotungstate.

scientific article

Radical Cyclization/β-Elimination Tandem Reactions: Enantiopure Sulfoxides as Temporary Chiral Auxiliaries

scientific article published on 01 August 1998

Radical deoxygenation of xanthates and related functional groups with new minimalist N-heterocyclic carbene boranes

scientific article published in July 2010

Radical migration of substituents of aryl groups on quinazolinones derived from N-acyl cyanamides.

scientific article published in March 2010

Radical reductions of alkyl halides bearing electron withdrawing groups with N-heterocyclic carbene boranes

scientific article published on 21 March 2011

Radical synthesis of guanidines from N-acyl cyanamides.

scientific article published in March 2010

Reactivity of beta-lactamido N-sulfonyl radicals

scientific article published on 01 March 2004

Rearrangements of N-acyl isothioureas. Alternate access to acylguanidines from cyanamides

scientific article published on 23 October 2012

Recent advances in the use of phosphorus-centered radicals in organic chemistry

scientific article

Regioselective Activation of Oxo Ligands in Functionalized Dawson Polyoxotungstates

scientific article published on 11 March 2008

Self-buffering hybrid gold-polyoxometalate catalysts for the catalytic cyclization of acid-sensitive substrates

scientific article published on 03 September 2012

Sensing the chirality of Dawson lanthanide polyoxometalates [alpha1-LnP2W17O61]7- by multinuclear NMR spectroscopy

scientific article published in January 2008

Silver and Brønsted acid catalyzed nazarov-type cyclizations to generate benzofulvenes

scientific article published on 01 January 2009

Stereoselective transition metal-catalyzed and radical polycyclizations

scientific article

Substitution Reactions at Tetracoordinate Boron: Synthesis of N-Heterocyclic Carbene Boranes with Boron−Heteroatom Bonds ⬇️

scientific article published on October 27, 2010

Suzuki-Miyaura coupling of NHC-boranes: a new addition to the C-C coupling toolbox

scientific article published on 01 November 2009

Synthesis and reactions of N-heterocyclic carbene boranes

scientific article published on 07 September 2011

Synthesis of triangular tripalladium cations as noble-metal analogues of the cyclopropenyl cation

scientific article published on 22 January 2014

Titanium-mediated domino radical cyclization/beta elimination of phosphine oxides

scientific article published on 01 August 2004

Tunable Hydrogen Release from Amine-Boranes via their Insertion into Functional Polystyrenes

scientific article published on 12 September 2019

Visible-Light Emulsion Photopolymerization of Styrene

scientific article published on 6 December 2017

Visible-light-induced photoreductive generation of radicals from epoxides and aziridines

scientific article published on 12 April 2011

Water Dissociation on α1-Hafnium and Ytterbium Substituted Dawson Polyoxotungstates: A Density Functional Theory Study†

scientific article published on 01 December 2008

List of works by Emmanuel Lacôte

A general strategy for ligation of organic and biological molecules to Dawson and Keggin polyoxotungstates

A new practical one-pot access to sulfonimidates

Boryltrihydroborate: synthesis, structure, and reactivity as a reductant in ionic, organometallic, and radical reactions

CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃ ⬇️

Carbonyl-Inserted Organo-Hybrids of a Dawson-Type Phosphovanadotungstate: Scope and Chemoselective Oxidation Catalysis

Chemoselective catalysis with organosoluble Lewis acidic polyoxotungstates

Chiral recognition of hybrid metal oxide by peptides

Complexes of borane and N-heterocyclic carbenes: a new class of radical hydrogen atom donor

Difluorination at Boron Leads to the First Electrophilic Ligated Boryl Radical (NHC-BF2. )

EPR studies of the generation, structure, and reactivity of n-heterocyclic carbene borane radicals

Efficient copper-mediated reactions of nitrenes derived from sulfonimidamides

Efficient preparation of functionalized hybrid organic/inorganic Wells-Dawson-type polyoxotungstates

Electron paramagnetic resonance and computational studies of radicals derived from boron-substituted N-heterocyclic carbene boranes

Elucidation of the Conformation of Polyglycine Organo-Polyoxotungstates: Evidence for Zipper Folding

Estimated rate constants for hydrogen abstraction from N-heterocyclic carbene-borane complexes by an alkyl radical

Exception to the ortho effect in palladium/norbornene catalysis

Expeditious Synthesis of Phenanthridines from Benzylamines via Dual Palladium Catalysis

Formation of cyclic sulfinates and sulfinamides through homolytic substitution at the sulfur atom

Generation and Reactions of an Unsubstituted N-Heterocyclic Carbene Boryl Anion

Generation of phosphorus-centered radicals via homolytic substitution at sulfur.

High Glass-Transition Temperature Polymer Networks Harnessing the Dynamic Ring Opening of Pinacol Boronates

Highly efficient peptide bond formation to functionalized Wells-Dawson-type polyoxotungstates

Identification of polyoxometalates as nanomolar noncompetitive inhibitors of protein kinase CK2.

Improved method for the iodine(III)-mediated preparation of aryl sulfonimidates

Increased Lewis acidity in hafnium-substituted polyoxotungstates

Insertion of amides into a polyoxometalate

Intramolecular anion effect in polyoxometalate-based organocatalysts: reactivity enhancement and chirality transfer by a metal oxide-organic cation interaction

Intramolecular homolytic substitution of sulfinates and sulfinamides

Intramolecular homolytic substitution of sulfinates and sulfinamides--a computational study

Iodine(III)-mediated preparations of nitrogen-containing sulfur derivatives: dramatic influence of the sulfur oxidation state.

Ionic and organometallic reductions with N-heterocyclic carbene boranes

Iron-catalyzed reductive radical cyclization of organic halides in the presence of NaBH4: evidence of an active hydrido iron(I) catalyst

Lanthanide complexes of the monovacant Dawson polyoxotungstate [alpha1-P2W17O61]10- as selective and recoverable Lewis acid catalysts

Lanthanide polyoxocationic complexes: experimental and theoretical stability studies and Lewis acid catalysis

Lewis-acidic polyoxometalates as reusable catalysts for the synthesis of glucuronic acid esters under microwave irradiation

N-heterocyclic carbene boryl radicals: a new class of boron-centered radical.

N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes

N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation

Oxidation of alpha-alkoxy allenes into alpha'-alkoxy enones

Preparation of NHC Borane Complexes by Lewis Base Exchange with Amine− and Phosphine−Boranes ⬇️

Production and reactions of organic-soluble lanthanide complexes of the monolacunary Dawson [alpha1-P2W17O61]10- polyoxotungstate.

Radical Cyclization/β-Elimination Tandem Reactions: Enantiopure Sulfoxides as Temporary Chiral Auxiliaries

Radical deoxygenation of xanthates and related functional groups with new minimalist N-heterocyclic carbene boranes

Radical migration of substituents of aryl groups on quinazolinones derived from N-acyl cyanamides.

Radical reductions of alkyl halides bearing electron withdrawing groups with N-heterocyclic carbene boranes

Radical synthesis of guanidines from N-acyl cyanamides.

Reactivity of beta-lactamido N-sulfonyl radicals

Rearrangements of N-acyl isothioureas. Alternate access to acylguanidines from cyanamides

Recent advances in the use of phosphorus-centered radicals in organic chemistry

Regioselective Activation of Oxo Ligands in Functionalized Dawson Polyoxotungstates

Self-buffering hybrid gold-polyoxometalate catalysts for the catalytic cyclization of acid-sensitive substrates

Sensing the chirality of Dawson lanthanide polyoxometalates [alpha1-LnP2W17O61]7- by multinuclear NMR spectroscopy

Silver and Brønsted acid catalyzed nazarov-type cyclizations to generate benzofulvenes

Stereoselective transition metal-catalyzed and radical polycyclizations

Substitution Reactions at Tetracoordinate Boron: Synthesis of N-Heterocyclic Carbene Boranes with Boron−Heteroatom Bonds ⬇️

Suzuki-Miyaura coupling of NHC-boranes: a new addition to the C-C coupling toolbox

Synthesis and reactions of N-heterocyclic carbene boranes

Synthesis of triangular tripalladium cations as noble-metal analogues of the cyclopropenyl cation

Titanium-mediated domino radical cyclization/beta elimination of phosphine oxides

Tunable Hydrogen Release from Amine-Boranes via their Insertion into Functional Polystyrenes

Visible-Light Emulsion Photopolymerization of Styrene

Visible-light-induced photoreductive generation of radicals from epoxides and aziridines

Water Dissociation on α1-Hafnium and Ytterbium Substituted Dawson Polyoxotungstates: A Density Functional Theory Study†