List of works - Takashi Hayashi

A Heterogeneous Hydrogen-Evolution Catalyst Based on a Mesoporous Organosilica with a Diiron Catalytic Center Modelling [FeFe]-Hydrogenase

A Highly Active Biohybrid Catalyst for Olefin Metathesis in Water: Impact of a Hydrophobic Cavity in a β-Barrel Protein

A Pyrene-Linked Cavity within a β-Barrel Protein Promotes an Asymmetric Diels-Alder Reaction

scientific article published on 9 August 2017

A Pyrene-Linked Cavity within a β-Barrel Protein Promotes an Asymmetric Diels-Alder Reaction

scientific article published on 31 August 2017

A chemically-controlled supramolecular protein polymer formed by a myoglobin-based self-assembly system

article

A hydrogenase model system based on the sequence of cytochrome c: photochemical hydrogen evolution in aqueous media

article

A matrix isolation study of 2-isopropylidenecyclopentane-1,3-diyl (Berson-type diradical).

scientific article published in August 2006

A rhodium complex-linked β-barrel protein as a hybrid biocatalyst for phenylacetylene polymerization

scientific article

A ring-shaped hemoprotein trimer thermodynamically controlled by the supramolecular heme-heme pocket interaction

scientific article published on 01 January 2019

A role of the heme-7-propionate side chain in cytochrome P450cam as a gate for regulating the access of water molecules to the substrate-binding site

scientific article

A structural isomer of nonaromatic porphyrin: preparation of 20pi-conjugated porphycene based on electronic perturbation

scientific article published on 15 November 2007

A supramolecular assembly based on an engineered hemoprotein exhibiting a thermal stimulus-driven conversion to a new distinct supramolecular structure.

scientific article published on 12 June 2017

A supramolecular receptor of diatomic molecules (O2, CO, NO) in aqueous solution

scientific article published on 30 May 2008

A water-soluble supramolecular complex that mimics the heme/copper hetero-binuclear site of cytochrome c oxidase

scientific article published on 15 January 2018

An extremely long-lived singlet 4,4-dimethoxy-3,5-diphenylpyrazolidine-3,5-diyl derivative: a notable nitrogen-atom effect on intra- and intermolecular reactivity

scientific article published in November 2006

Anchoring Cytochromeb562on a Gold Nanoparticle by a Heme-Heme Pocket Interaction

Artificial Diels-Alderase based on the transmembrane protein FhuA.

scientific article published on 24 June 2016

Artificial Metalloenzymes Containing an Organometallic Active Site

Artificial hydrogenase: biomimetic approaches controlling active molecular catalysts

scientific article

Blue myoglobin reconstituted with an iron porphycene shows extremely high oxygen affinity

scientific article published in September 2002

C(sp3)-H bond hydroxylation catalyzed by myoglobin reconstituted with manganese porphycene

scientific article

Catalytic Cyclopropanation by Myoglobin Reconstituted with Iron Porphycene: Acceleration of Catalysis due to Rapid Formation of the Carbene Species

scientific article

Cathodic photocurrent generation from zinc-substituted cytochrome b562 assemblies immobilized on an apocytochrome b562-modified gold electrode

article

Chemically programmed supramolecular assembly of hemoprotein and streptavidin with alternating alignment

scientific article published on 14 February 2012

Co(II)/Co(I) reduction-induced axial histidine-flipping in myoglobin reconstituted with a cobalt tetradehydrocorrin as a methionine synthase model

scientific article

Cobalt tetradehydrocorrins coordinated by imidazolate-like histidine in the heme pocket of horseradish peroxidase.

scientific article

Cofactor-specific covalent anchoring of cytochrome b562 on a single-walled carbon nanotube by click chemistry

scholarly article in RSC Advances, vol. 6 no. 70, 2016

Complimenting a Metal Complex with Protein Environment toward a New Hybrid Biocatalyst

Construction of a hybrid biocatalyst containing a covalently-linked terpyridine metal complex within a cavity of aponitrobindin

scientific article published on 2 January 2016

Construction of glycosylated myoglobin by reconstitutional method

scientific article published on 14 June 2006

Cover Picture: A Pyrene-Linked Cavity within a β-Barrel Protein Promotes an Asymmetric Diels-Alder Reaction (Angew. Chem. Int. Ed. 44/2017)

scientific article published on 5 October 2017

Creation of an artificial metalloprotein with a Hoveyda-Grubbs catalyst moiety through the intrinsic inhibition mechanism of α-chymotrypsin

scientific article

Crystal Structure and Spectroscopic Studies of a Stable Mixed-Valent State of the Hemerythrin-like Domain of a Bacterial Chemotaxis Protein

Crystal Structure, Exogenous Ligand Binding, and Redox Properties of an Engineered Diiron Active Site in a Bacterial Hemerythrin

scientific article

Crystal Structures and Coordination Behavior of Aqua- and Cyano-Co(III) Tetradehydrocorrins in the Heme Pocket of Myoglobin

scientific article

Crystal structure and peroxidase activity of myoglobin reconstituted with iron porphycene

scientific article

CuAAC in a Distal Pocket: Metal Active-Template Synthesis of Strapped-Porphyrin [2]Rotaxanes.

scientific article published on 11 July 2017

DNA-Binding Hemoproteins Tethering Polyamine Interface

Directed Evolution of a Cp*Rh(III)-linked Biohybrid Catalyst Based on a Screening Platform with Affinity Purification

scientific article published on 07 October 2020

Effect of peripheral trifluoromethyl groups in artificial iron porphycene cofactor on ligand binding properties of myoglobin

scientific article published on 7 August 2007

Electrochemical CO2 reduction by a cobalt bipyricorrole complex: decrease of an overpotential value derived from monoanionic ligand character of the porphyrinoid species

scientific article published on 01 January 2019

Energy migration within hexameric hemoprotein reconstituted with Zn porphyrinoid molecules

scientific article published in 2015

Enhanced visible light response of a WO3 photoelectrode with an immobilized fibrous gold nanoparticle assembly using an amyloid-β peptide

scholarly article in RSC Advances, vol. 7 no. 2, 2017

Enzyme-substrate complex structures of CYP154C5 shed light on its mode of highly selective steroid hydroxylation

scientific article

Evaluation of the functional role of the heme-6-propionate side chain in cytochrome P450cam

scientific article

Experimental probe for hyperconjugative resonance contribution in stabilizing the singlet state of 2,2-dialkoxy-1,3-diyls: Regioselective 1,2-oxygen migration.

scientific article

Fabrication of enzyme-degradable and size-controlled protein nanowires using single particle nano-fabrication technique

scientific article (publication date: 28 April 2014)

Fibrous Supramolecular Hemoprotein Assemblies Connected with Synthetic Heme Dimer and Apohemoprotein Dimer

scientific article published on 01 September 2012

Generation of New Artificial Metalloproteins by Cofactor Modification of Native Hemoproteins

article

H 2 O 2 -dependent substrate oxidation by an engineered diiron site in a bacterial hemerythrin

scientific article

Hemoprotein-based supramolecular assembling systems.

scientific article published on 20 March 2014

Hemoproteins Reconstituted with Artificial Metal Complexes as Biohybrid Catalysts

scientific article published on 01 April 2019

Hybridization of modified-heme reconstitution and distal histidine mutation to functionalize sperm whale myoglobin

scientific article

Incorporation of a Cp*Rh(III)-dithiophosphate Cofactor with Latent Activity into a Protein Scaffold Generates a Biohybrid Catalyst Promoting C(sp2)-H Bond Functionalization

scientific article published on 11 September 2020

Incorporation of modified and artificial cofactors into naturally occurring protein scaffolds

scientific article published on January 2014

Interdomain flip-flop motion visualized in flavocytochrome cellobiose dehydrogenase using high-speed atomic force microscopy during catalysis.

scientific article published on 3 August 2017

Intraprotein transmethylation via a CH3-Co(iii) species in myoglobin reconstituted with a cobalt corrinoid complex

scientific article published on 8 December 2015

Investigation of aromaticity and photophysical properties in [18]/[20]π porphycene derivatives

scientific article published on 30 May 2011

Iron porphyrin-cyclodextrin supramolecular complex as a functional model of myoglobin in aqueous solution

scientific article

Iron twin-coronet porphyrins as models of myoglobin and hemoglobin: amphibious electrostatic effects of overhanging hydroxyl groups for successful CO/O2 discrimination.

scientific article published in February 2003

Iron-Strapped Porphyrins with Carboxylic Acid Groups Hanging over the Coordination Site: Synthesis, X-ray Characterization, and Dioxygen Binding

scientific article

Ligand binding properties of myoglobin reconstituted with iron porphycene: unusual O2 binding selectivity against CO binding

scientific article published in December 2004

Ligand binding properties of two kinds of reconstituted myoglobins with iron porphycene having propionates: effect of beta-pyrrolic position of two propionate side chains in porphycene framework

scientific article published on 3 March 2006

Light triggers molecular shuttling in rotaxanes: control over proximity and charge recombination

scientific article published on 27 February 2019

Manganese(V) Porphycene Complex Responsible for Inert C-H Bond Hydroxylation in a Myoglobin Matrix

scientific article published on 14 December 2017

Meso-unsubstituted iron corrole in hemoproteins: remarkable differences in effects on peroxidase activities between myoglobin and horseradish peroxidase

scientific article published in October 2009

Methane Generation and Reductive Debromination of Benzylic Position by Reconstituted Myoglobin Containing Nickel Tetradehydrocorrin as a Model of Methyl-coenzyme M Reductase

scientific article published on 14 August 2020

Mitochondria-Targeting Polyamine-Protoporphyrin Conjugates for Photodynamic Therapy.

scientific article

Myoglobin Reconstituted with Ni Tetradehydrocorrin as a Methane-Generating Model of Methyl-coenzyme M Reductase

scientific article published on 23 August 2019

Myoglobin-based non-precious metal carbon catalysts for an oxygen reduction reaction

Olefin metathesis catalysts embedded in β-barrel proteins: creating artificial metalloproteins for olefin metathesis

scientific article published on 19 November 2018

Oxygen-binding Protein Fiber and Microgel: Supramolecular Myoglobin-Poly(acrylate) Conjugates.

scientific article published on 17 February 2016

Pathway of information transmission from heme to protein upon ligand binding/dissociation in myoglobin revealed by UV resonance raman spectroscopy.

scientific article

Photocatalytic Properties of TiO2 Composites Immobilized with Gold Nanoparticle Assemblies Using the Streptavidin-Biotin Interaction

scientific article published on 7 June 2016

Photocatalytic hydrogen evolution by a diiron hydrogenase model based on a peptide fragment of cytochrome c556 with an attached diiron carbonyl cluster and an attached ruthenium photosensitizer

article

Photocatalytic hydrogen generation using a protein-coated photosensitizer with anionic patches and a monocationic electron mediator

scientific article published on 23 June 2008

Photochemical Property of a Myoglobin–CdTe Quantum Dot Conjugate Formed by Supramolecular Host–Guest Interactions

article published in 2014

Photochemical properties of a myoglobin–CdTe quantum dot conjugate

Photocurrent Generation from Hierarchical Zinc-Substituted Hemoprotein Assemblies Immobilized on a Gold Electrode

scientific article published on 01 March 2012

Photoinduced Hydrogen Evolution Catalyzed by a Synthetic Diiron Dithiolate Complex Embedded within a Protein Matrix

Photoinduced electron transfer within supramolecular hemoprotein co-assemblies and heterodimers containing Fe and Zn porphyrins

scientific article published on 14 January 2019

Porphyrinoid chemistry in hemoprotein matrix: detection and reactivities of iron(IV)-oxo species of porphycene incorporated into horseradish peroxidase

scientific article published on 4 October 2007

Precise design of artificial cofactors for enhancing peroxidase activity of myoglobin: myoglobin mutant H64D reconstituted with a "single-winged cofactor" is equivalent to native horseradish peroxidase in oxidation activity

scientific article published on 09 June 2011

Preparation and O2 binding study of myoglobin having a cobalt porphycene

scientific article published in December 2005

Preparation and reactivity of a tetranuclear Fe(II) core in the metallothionein α-domain

scientific article published on 26 January 2011

Redox Potentials of Cobalt Corrinoids with Axial Ligands Correlate with Heterolytic Co-C Bond Dissociation Energies.

scientific article published on 6 February 2017

Reductive activation of dioxygen by a myoglobin reconstituted with a flavohemin

scientific article published in September 2002

Residues in the distal heme pocket of neuroglobin. Implications for the multiple ligand binding steps

scientific article

Rhodium-Complex-Linked Hybrid Biocatalyst: Stereo-Controlled Phenylacetylene Polymerization within an Engineered Protein Cavity

scholarly article by Kazuki Fukumoto et al published 13 February 2014 in ChemCatChem

Roles of N- and C-terminal domains in the ligand-binding properties of cytoglobin.

scientific article

Self-assembly of one- and two-dimensional hemoprotein systems by polymerization through heme-heme pocket interactions.

scientific article published in January 2009

Site-Specific Modification of Proteins through N-Terminal Azide Labeling and a Chelation-Assisted CuAAC Reaction

scientific article published on 04 September 2019

Structure and ligand binding properties of myoglobins reconstituted with monodepropionated heme: functional role of each heme propionate side chain

scientific article

Substrate binding induces structural changes in cytochrome P450cam

scientific article

Successive energy transfer within multiple photosensitizers assembled in a hexameric hemoprotein scaffold.

scientific article published on 25 October 2017

Supramolecular Hemoprotein Assembly with a Periodic Structure Showing Heme-Heme Exciton Coupling

scientific article published on 03 August 2018

Supramolecular Linear Assemblies of Cytochrome b 562 Immobilized on a Gold Electrode

article

Supramolecular assembling systems formed by heme–heme pocket interactions in hemoproteins ⬇️

scientific article published on October 18, 2012

Supramolecular hemoprotein linear assembly by successive interprotein heme-heme pocket interactions.

scientific article published on 3 August 2007

Supramolecular hemoprotein–gold nanoparticle conjugates

article

Supramolecular protein–protein complexation via specific interaction between glycosylated myoglobin and sugar-binding protein

article by Hirokazu Nagai et al published January 2010 in Supramolecular Chemistry

Synthesis and Characterization of meso-Substituted Cobalt Tetradehydrocorrin and Evaluation of Its Electrocatalytic Behavior Toward CO2 Reduction and H2 Evolution

scientific article published on 12 November 2018

Synthesis, characterization, and autoreduction of a highly electron-deficient porphycenatoiron(III) with trifluoromethyl substituents

scientific article

Synthesis, structure, and chemical property of the first fluorine-containing porphycene

scientific article published in August 2003

Thermodynamically controlled supramolecular polymerization of cytochrome b 562.

scientific article published in March 2009

Thermoresponsive Micellar Assembly Constructed from a Hexameric Hemoprotein Modified with Poly(N-isopropylacrylamide) toward an Artificial Light-Harvesting System

scientific article published on 16 January 2020

Time-resolved Raman evidence for energy ‘funneling’ through propionate side chains in heme ‘cooling’ upon photolysis of carbonmonoxy myoglobin

Titelbild: A Pyrene-Linked Cavity within a β-Barrel Protein Promotes an Asymmetric Diels-Alder Reaction (Angew. Chem. 44/2017)

scientific article published on 5 October 2017

Triazolecarbaldehyde Reagents for One-Step N-Terminal Protein Modification

scientific article published on 03 December 2019

Unusual ligand discrimination by a myoglobin reconstituted with a hydrophobic domain-linked heme

scientific article published in January 2005

meso-Dibenzoporphycene has a Large Bathochromic Shift and a Porphycene Framework with an Unusual cis Tautomeric Form.

scientific article published on 30 March 2015

List of works by Takashi Hayashi

A Heterogeneous Hydrogen-Evolution Catalyst Based on a Mesoporous Organosilica with a Diiron Catalytic Center Modelling [FeFe]-Hydrogenase

A Highly Active Biohybrid Catalyst for Olefin Metathesis in Water: Impact of a Hydrophobic Cavity in a β-Barrel Protein

A Pyrene-Linked Cavity within a β-Barrel Protein Promotes an Asymmetric Diels-Alder Reaction

A Pyrene-Linked Cavity within a β-Barrel Protein Promotes an Asymmetric Diels-Alder Reaction

A chemically-controlled supramolecular protein polymer formed by a myoglobin-based self-assembly system

A hydrogenase model system based on the sequence of cytochrome c: photochemical hydrogen evolution in aqueous media

A matrix isolation study of 2-isopropylidenecyclopentane-1,3-diyl (Berson-type diradical).

A rhodium complex-linked β-barrel protein as a hybrid biocatalyst for phenylacetylene polymerization

A ring-shaped hemoprotein trimer thermodynamically controlled by the supramolecular heme-heme pocket interaction

A role of the heme-7-propionate side chain in cytochrome P450cam as a gate for regulating the access of water molecules to the substrate-binding site

A structural isomer of nonaromatic porphyrin: preparation of 20pi-conjugated porphycene based on electronic perturbation

A supramolecular assembly based on an engineered hemoprotein exhibiting a thermal stimulus-driven conversion to a new distinct supramolecular structure.

A supramolecular receptor of diatomic molecules (O2, CO, NO) in aqueous solution

A water-soluble supramolecular complex that mimics the heme/copper hetero-binuclear site of cytochrome c oxidase

An extremely long-lived singlet 4,4-dimethoxy-3,5-diphenylpyrazolidine-3,5-diyl derivative: a notable nitrogen-atom effect on intra- and intermolecular reactivity

Anchoring Cytochromeb562on a Gold Nanoparticle by a Heme-Heme Pocket Interaction

Artificial Diels-Alderase based on the transmembrane protein FhuA.

Artificial Metalloenzymes Containing an Organometallic Active Site

Artificial hydrogenase: biomimetic approaches controlling active molecular catalysts

Blue myoglobin reconstituted with an iron porphycene shows extremely high oxygen affinity

C(sp3)-H bond hydroxylation catalyzed by myoglobin reconstituted with manganese porphycene

Catalytic Cyclopropanation by Myoglobin Reconstituted with Iron Porphycene: Acceleration of Catalysis due to Rapid Formation of the Carbene Species

Cathodic photocurrent generation from zinc-substituted cytochrome b562 assemblies immobilized on an apocytochrome b562-modified gold electrode

Chemically programmed supramolecular assembly of hemoprotein and streptavidin with alternating alignment

Co(II)/Co(I) reduction-induced axial histidine-flipping in myoglobin reconstituted with a cobalt tetradehydrocorrin as a methionine synthase model

Cobalt tetradehydrocorrins coordinated by imidazolate-like histidine in the heme pocket of horseradish peroxidase.

Cofactor-specific covalent anchoring of cytochrome b562 on a single-walled carbon nanotube by click chemistry

Complimenting a Metal Complex with Protein Environment toward a New Hybrid Biocatalyst

Construction of a hybrid biocatalyst containing a covalently-linked terpyridine metal complex within a cavity of aponitrobindin

Construction of glycosylated myoglobin by reconstitutional method

Cover Picture: A Pyrene-Linked Cavity within a β-Barrel Protein Promotes an Asymmetric Diels-Alder Reaction (Angew. Chem. Int. Ed. 44/2017)

Creation of an artificial metalloprotein with a Hoveyda-Grubbs catalyst moiety through the intrinsic inhibition mechanism of α-chymotrypsin

Crystal Structure and Spectroscopic Studies of a Stable Mixed-Valent State of the Hemerythrin-like Domain of a Bacterial Chemotaxis Protein

Crystal Structure, Exogenous Ligand Binding, and Redox Properties of an Engineered Diiron Active Site in a Bacterial Hemerythrin

Crystal Structures and Coordination Behavior of Aqua- and Cyano-Co(III) Tetradehydrocorrins in the Heme Pocket of Myoglobin

Crystal structure and peroxidase activity of myoglobin reconstituted with iron porphycene

CuAAC in a Distal Pocket: Metal Active-Template Synthesis of Strapped-Porphyrin [2]Rotaxanes.

DNA-Binding Hemoproteins Tethering Polyamine Interface

Directed Evolution of a Cp*Rh(III)-linked Biohybrid Catalyst Based on a Screening Platform with Affinity Purification

Effect of peripheral trifluoromethyl groups in artificial iron porphycene cofactor on ligand binding properties of myoglobin

Electrochemical CO2 reduction by a cobalt bipyricorrole complex: decrease of an overpotential value derived from monoanionic ligand character of the porphyrinoid species

Energy migration within hexameric hemoprotein reconstituted with Zn porphyrinoid molecules

Enhanced visible light response of a WO3 photoelectrode with an immobilized fibrous gold nanoparticle assembly using an amyloid-β peptide

Enzyme-substrate complex structures of CYP154C5 shed light on its mode of highly selective steroid hydroxylation

Evaluation of the functional role of the heme-6-propionate side chain in cytochrome P450cam

Experimental probe for hyperconjugative resonance contribution in stabilizing the singlet state of 2,2-dialkoxy-1,3-diyls: Regioselective 1,2-oxygen migration.

Fabrication of enzyme-degradable and size-controlled protein nanowires using single particle nano-fabrication technique

Fibrous Supramolecular Hemoprotein Assemblies Connected with Synthetic Heme Dimer and Apohemoprotein Dimer

Generation of New Artificial Metalloproteins by Cofactor Modification of Native Hemoproteins

H 2 O 2 -dependent substrate oxidation by an engineered diiron site in a bacterial hemerythrin

Hemoprotein-based supramolecular assembling systems.

Hemoproteins Reconstituted with Artificial Metal Complexes as Biohybrid Catalysts

Hybridization of modified-heme reconstitution and distal histidine mutation to functionalize sperm whale myoglobin

Incorporation of a Cp*Rh(III)-dithiophosphate Cofactor with Latent Activity into a Protein Scaffold Generates a Biohybrid Catalyst Promoting C(sp2)-H Bond Functionalization

Incorporation of modified and artificial cofactors into naturally occurring protein scaffolds

Interdomain flip-flop motion visualized in flavocytochrome cellobiose dehydrogenase using high-speed atomic force microscopy during catalysis.

Intraprotein transmethylation via a CH3-Co(iii) species in myoglobin reconstituted with a cobalt corrinoid complex

Investigation of aromaticity and photophysical properties in [18]/[20]π porphycene derivatives

Iron porphyrin-cyclodextrin supramolecular complex as a functional model of myoglobin in aqueous solution

Iron twin-coronet porphyrins as models of myoglobin and hemoglobin: amphibious electrostatic effects of overhanging hydroxyl groups for successful CO/O2 discrimination.

Iron-Strapped Porphyrins with Carboxylic Acid Groups Hanging over the Coordination Site: Synthesis, X-ray Characterization, and Dioxygen Binding

Ligand binding properties of myoglobin reconstituted with iron porphycene: unusual O2 binding selectivity against CO binding

Ligand binding properties of two kinds of reconstituted myoglobins with iron porphycene having propionates: effect of beta-pyrrolic position of two propionate side chains in porphycene framework

Light triggers molecular shuttling in rotaxanes: control over proximity and charge recombination

Manganese(V) Porphycene Complex Responsible for Inert C-H Bond Hydroxylation in a Myoglobin Matrix

Meso-unsubstituted iron corrole in hemoproteins: remarkable differences in effects on peroxidase activities between myoglobin and horseradish peroxidase

Methane Generation and Reductive Debromination of Benzylic Position by Reconstituted Myoglobin Containing Nickel Tetradehydrocorrin as a Model of Methyl-coenzyme M Reductase

Mitochondria-Targeting Polyamine-Protoporphyrin Conjugates for Photodynamic Therapy.

Myoglobin Reconstituted with Ni Tetradehydrocorrin as a Methane-Generating Model of Methyl-coenzyme M Reductase

Myoglobin-based non-precious metal carbon catalysts for an oxygen reduction reaction

Olefin metathesis catalysts embedded in β-barrel proteins: creating artificial metalloproteins for olefin metathesis

Oxygen-binding Protein Fiber and Microgel: Supramolecular Myoglobin-Poly(acrylate) Conjugates.

Pathway of information transmission from heme to protein upon ligand binding/dissociation in myoglobin revealed by UV resonance raman spectroscopy.

Photocatalytic Properties of TiO2 Composites Immobilized with Gold Nanoparticle Assemblies Using the Streptavidin-Biotin Interaction

Photocatalytic hydrogen evolution by a diiron hydrogenase model based on a peptide fragment of cytochrome c556 with an attached diiron carbonyl cluster and an attached ruthenium photosensitizer

Photocatalytic hydrogen generation using a protein-coated photosensitizer with anionic patches and a monocationic electron mediator

Photochemical Property of a Myoglobin–CdTe Quantum Dot Conjugate Formed by Supramolecular Host–Guest Interactions

Photochemical properties of a myoglobin–CdTe quantum dot conjugate

Photocurrent Generation from Hierarchical Zinc-Substituted Hemoprotein Assemblies Immobilized on a Gold Electrode