List of works - Toshio Nishikawa

A Divergent Approach to the Diastereoselective Synthesis of 3,3-Disubstituted Oxindoles from Atropisomeric N-Aryl Oxindole Derivatives

scientific article

A New Ring Expansion for a Chiral Hexahydroazulene Skeleton Possessing an Angular Methyl Group ⬇️

scientific article published on July 13, 2011

A Synthetic Route to the Saxitoxin Skeleton: Synthesis of Decarbamoyl α‐Saxitoxinol, an Analogue of Saxitoxin Produced by the Cyanobacterium Lyngbya wollei ⬇️

scientific article published on June 17, 2011

A Synthetic Strategy for Saxitoxin Skeleton by a Cascade Bromocyclization: Total Synthesis of (+)-Decarbamoyl-α-saxitoxinol.

scientific article published on 5 December 2016

A concise synthesis of peramine, a metabolite of endophytic fungi

scientific article published on 10 September 2018

An Improved Synthesis of (−)-5,11-Dideoxytetrodotoxin ⬇️

scientific article published on January 30, 2013

Asymmetric Synthesis of the Aromatic Fragment of Sespendole

scientific article published on 17 July 2019

Asymmetric synthesis of crambescin A-C carboxylic acids and their inhibitory activity on voltage-gated sodium channels.

scientific article

Biomimetic Synthesis and Structural Revision of Chaxine B and Its Analogues.

scientific article published on 25 January 2017

Biomimetic Synthesis of Chaxine and its Related Compounds

scientific article published on 12 March 2020

De Novo Synthesis of Possible Candidates for the Inagami-Tamura Endogenous Digitalis-like Factor

scientific article published on 8 August 2017

Differential binding of tetrodotoxin and its derivatives to voltage-sensitive sodium channel subtypes (Nav 1.1 to Nav 1.7).

scientific article published on 18 August 2017

Identification of a Fluorescent Compound in the Cuticle of the Train MillipedeParafontaria laminata armigera ⬇️

scientific article published on November 7, 2010

Identification of an Asexual Reproduction Inducer of Phytopathogenic and Toxigenic Fusarium.

scientific article

Improved Conditions for Facile Overman Rearrangement1 ⬇️

scientific article published on January 9, 1998

Inhibition of veratridine-induced delayed inactivation of the voltage-sensitive sodium channel by synthetic analogs of crambescin B.

scientific article published on 19 January 2017

Novel Stereoselective Reaction of Levoglucosenone with Furfural.

scientific article

One-Step Transformation of Trichloroacetamide into Isonitrile

scientific article published on 29 December 2016

One-pot non-enzymatic formation of firefly luciferin in a neutral buffer from p-benzoquinone and cysteine.

scientific article

Palladium-Catalyzed Cascade Wacker/Allylation Sequence with Allylic Alcohols Leading to Allylated Dihydropyrones

scientific article published on 10 February 2017

Palladium-catalyzed Substitution Reaction of Allylic Derivatives with Tinacetylene

scientific article published on 01 January 1999

Semi-synthesis and Structure-Activity Relationship of Neuritogenic Oleanene Derivatives

scientific article published on 16 August 2018

Stereocontrolled Synthesis of an Indole Moiety of Sespendole and Stereochemical Assignment of the Side Chain ⬇️

scientific article published on November 29, 2011

Stereocontrolled Total Synthesis of Polygalolide A ⬇️

scientific article published on May 13, 2013

Stereocontrolled synthesis of the oxathiabicyclo[3.3.1]nonane core structure of tagetitoxin

scientific article published on 23 October 2013

Synthesis of 5- and 8-deoxytetrodotoxin

scientific article published on 26 May 2014

Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki-Heck and Intramolecular Diels-Alder Reactions

scientific article published on 09 September 2019

Synthesis of Tetrodotoxin, a Classic but Still Fascinating Natural Product ⬇️

scientific article published on May 10, 2013

Synthetic Route to Oscillatoxin D and Its Analogues

scientific article published on 01 November 2017

Total Syntheses and Determination of Absolute Configurations of Cep-212 and Cep-210, Predicted Biosynthetic Intermediates of Tetrodotoxin Isolated from Toxic Newt

scientific article published on 10 January 2019

Total Synthesis of Polygalolide A ⬇️

scientific article published on November 17, 2011

Total synthesis of chiriquitoxin, an analogue of tetrodotoxin isolated from the skin of a dart frog

scientific article published in January 2014

Toward a Synthesis of Fawcettimine-Type Lycopodium Alkaloids: Stereocontrolled Synthesis of a Functionalized Azaspirocycle Precursor

scientific article published on 28 August 2018

List of works by Toshio Nishikawa

A Divergent Approach to the Diastereoselective Synthesis of 3,3-Disubstituted Oxindoles from Atropisomeric N-Aryl Oxindole Derivatives

A New Ring Expansion for a Chiral Hexahydroazulene Skeleton Possessing an Angular Methyl Group ⬇️

A Synthetic Route to the Saxitoxin Skeleton: Synthesis of Decarbamoyl α‐Saxitoxinol, an Analogue of Saxitoxin Produced by the Cyanobacterium Lyngbya wollei ⬇️

A Synthetic Strategy for Saxitoxin Skeleton by a Cascade Bromocyclization: Total Synthesis of (+)-Decarbamoyl-α-saxitoxinol.

A concise synthesis of peramine, a metabolite of endophytic fungi

An Improved Synthesis of (−)-5,11-Dideoxytetrodotoxin ⬇️

Asymmetric Synthesis of the Aromatic Fragment of Sespendole

Asymmetric synthesis of crambescin A-C carboxylic acids and their inhibitory activity on voltage-gated sodium channels.

Biomimetic Synthesis and Structural Revision of Chaxine B and Its Analogues.

Biomimetic Synthesis of Chaxine and its Related Compounds

De Novo Synthesis of Possible Candidates for the Inagami-Tamura Endogenous Digitalis-like Factor

Differential binding of tetrodotoxin and its derivatives to voltage-sensitive sodium channel subtypes (Nav 1.1 to Nav 1.7).

Identification of a Fluorescent Compound in the Cuticle of the Train MillipedeParafontaria laminata armigera ⬇️

Identification of an Asexual Reproduction Inducer of Phytopathogenic and Toxigenic Fusarium.

Improved Conditions for Facile Overman Rearrangement1 ⬇️

Inhibition of veratridine-induced delayed inactivation of the voltage-sensitive sodium channel by synthetic analogs of crambescin B.

Novel Stereoselective Reaction of Levoglucosenone with Furfural.

One-Step Transformation of Trichloroacetamide into Isonitrile

One-pot non-enzymatic formation of firefly luciferin in a neutral buffer from p-benzoquinone and cysteine.

Palladium-Catalyzed Cascade Wacker/Allylation Sequence with Allylic Alcohols Leading to Allylated Dihydropyrones

Palladium-catalyzed Substitution Reaction of Allylic Derivatives with Tinacetylene

Semi-synthesis and Structure-Activity Relationship of Neuritogenic Oleanene Derivatives

Stereocontrolled Synthesis of an Indole Moiety of Sespendole and Stereochemical Assignment of the Side Chain ⬇️

Stereocontrolled Total Synthesis of Polygalolide A ⬇️

Stereocontrolled synthesis of the oxathiabicyclo[3.3.1]nonane core structure of tagetitoxin

Synthesis of 5- and 8-deoxytetrodotoxin

Synthesis of Oxy-Functionalized Steroidal Skeletons via Mizoroki-Heck and Intramolecular Diels-Alder Reactions

Synthesis of Tetrodotoxin, a Classic but Still Fascinating Natural Product ⬇️

Synthetic Route to Oscillatoxin D and Its Analogues

Total Syntheses and Determination of Absolute Configurations of Cep-212 and Cep-210, Predicted Biosynthetic Intermediates of Tetrodotoxin Isolated from Toxic Newt

Total Synthesis of Polygalolide A ⬇️

Total synthesis of chiriquitoxin, an analogue of tetrodotoxin isolated from the skin of a dart frog

Toward a Synthesis of Fawcettimine-Type Lycopodium Alkaloids: Stereocontrolled Synthesis of a Functionalized Azaspirocycle Precursor