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List of works by Antonio M. Echavarren

A Redox-ActiveC3-Symmetric Triindole-Based Triazacyclophane

scientific article published on 01 July 2006

A hexanuclear gold cluster supported by three-center-two-electron bonds and aurophilic interactions

scientific article published on 15 July 2013

A multipurpose gold(I) precatalyst

scientific article published on 23 March 2011

Access to the Protoilludane Core by Gold-Catalyzed Allene-vinylcyclopropane Cycloisomerization

scientific article published in 2013

Access to the protoilludane core by gold-catalyzed allene-vinylcyclopropane cycloisomerization.

scientific article published on 20 August 2013

Acetylene as a Dicarbene Equivalent for Gold(I) Catalysis: Total Synthesis of Waitziacuminone in One Step

scientific article published on 31 January 2020

Allyl stannanes as electrophiles or nucleophiles in the palladium-catalyzed reactions with alkynes

scientific article published in December 2003

Anatomy of gold catalysts: facts and myths

scientific article

Aryl transfer between Pd(II) centers or Pd(IV) intermediates in Pd-catalyzed domino reactions

scientific article published on 01 April 2006

Assembly of Complex 1,4-Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non-Acceptor Carbenes

scientific article published on 20 October 2020

Bridgehead Modifications of Englerin A Reduce TRPC4 Activity and Intravenous Toxicity but not Cell Growth Inhibition

scientific article published on 03 August 2020

Broad Scope Aminocyclization of Enynes with Cationic JohnPhos-Gold(I) Complex as the Catalyst.

scientific article published on 3 February 2016

Broad scope gold(i)-catalysed polyenyne cyclisations for the formation of up to four carbon-carbon bonds.

scientific article

Broad-Scope Rh-Catalyzed Inverse-Sonogashira Reaction Directed by Weakly Coordinating Groups.

scientific article

Buchwald‐Type Ligands on Gold(I) Catalysis

Carbocations or Cyclopropyl Gold Carbenes in Cyclizations of Enynes ⬇️

scientific article published on 08 October 2010

Cationic eta(1)/eta(2)-gold(I) complexes of simple arenes

scientific article published on 01 August 2006

Cationic gold(I) complexes: highly alkynophilic catalysts for the exo- and endo-cyclization of enynes

scientific article published on 01 April 2004

Coinage metals in organic synthesis

scientific article published on 18 July 2016

Collected mass spectrometry data on monoterpene indole alkaloids from natural product chemistry research

scientific article published on 03 April 2019

Concise Total Synthesis of Lundurines A-C Enabled by Gold Catalysis and a Homodienyl Retro-Ene/Ene Isomerization.

scientific article

Contacting a conjugated molecule with a surface dangling bond dimer on a hydrogenated Ge(001) surface allows imaging of the hidden ground electronic state.

scientific article

Correction to "Cyclopropanation with Gold(I) Carbenes by Retro-Buchner Reaction from Cycloheptatrienes".

scientific article published on 3 February 2017

Couplings with monoorganotin compounds: a "radical" twist from the original Stille reaction

scientific article published on 01 June 2005

Cover Feature: Gold(I)‐Catalyzed Intramolecular C(sp<sup>3</sup>)−H Insertion by Decarbenation of Cycloheptatrienes (Chem. Eur. J. 40/2019)

Cyclobutene vs 1,3-Diene Formation in the Gold-Catalyzed Reaction of Alkynes with Alkenes: The Complete Mechanistic Picture.

scientific article

Cyclopropanation by Gold- or Zinc-Catalyzed Retro-Buchner Reaction at Room Temperature

scientific article published on 05 July 2018

Cyclopropanation with gold(I) carbenes by retro-Buchner reaction from cycloheptatrienes

scientific article published on 20 July 2011

Cyclopropane-alkene metathesis by gold(i)-catalyzed decarbenation of persistent cyclopropanes

scientific article published on 01 April 2019

Decarboxylative Csp3-N Bond Formation by Electrochemical Oxidation of Amino Acids

scientific article published on 29 October 2019

Diastereospecific Gold(I)-Catalyzed Cyclization Cascade for the Controlled Preparation of N- and N,O-Heterocycles

scientific article published on 21 September 2018

Diels-Alder attachment of a planar organic molecule to a dangling bond dimer on a hydrogenated semiconductor surface.

scientific article

Direct Observation of Aryl Gold(I) Carbenes that Undergo Cyclopropanation, C-H Insertion, and Dimerization Reactions

scientific article published on 11 February 2019

Direct Synthesis of N-Arylquinone Imine Acetals and Quinol Imines from Acetals

scientific article published on 01 May 1999

Dissecting Anion Effects in Gold(I)-Catalyzed Intermolecular Cycloadditions

scientific article published on January 2014

Divergent mechanisms for the skeletal rearrangement and [2+2] cycloaddition of enynes catalyzed by gold

scientific article published on 01 September 2005

Divergent titanium-mediated allylations with modulation by nickel or palladium

scientific article published on 01 January 2008

Donor Rhodium Carbenes by Retro-Buchner Reaction

scientific article published on 18 January 2019

Enantioselective Catalysis with Pyrrolidinyl Gold(I) Complexes: DFT and NEST Analysis of the Chiral Binding Pocket

Enantioselective Folding of Enynes by Gold(I) Catalysts with a Remote C2-Chiral Element

scientific article published on 16 July 2019

Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non-C2 Symmetric Digold Catalysts.

scientific article published on 19 September 2017

Enantioselective synthesis of (-)-englerins A and B.

scientific article published in May 2010

Enantioselective total synthesis of (-)-nardoaristolone B via a gold(I)-catalyzed oxidative cyclization

scientific article published on 7 January 2015

Evolution of propargyl ethers into allylgold cations in the cyclization of enynes.

scientific article published in January 2009

Ferrocene derivatives of liquid chiral molecules allow assignment of absolute configuration by X-ray crystallography

scientific article published in October 2017

Formal (4+1) cycloaddition of methylenecyclopropanes with 7-aryl-1,3,5-cycloheptatrienes by triple gold(I) catalysis

scientific article published on 4 June 2014

From Palladium to Gold Catalysis for the Synthesis of Crushed Fullerenes and Acenes

scientific article published on 02 July 2019

Fullerenes from aromatic precursors by surface-catalysed cyclodehydrogenation

scientific article published in Nature

Functional-Group-Tolerant, Silver-Catalyzed N-N Bond Formation by Nitrene Transfer to Amines

scientific article published on 18 January 2017

Functionalized truxenes: adsorption and diffusion of single molecules on the KBr(001) surface.

scientific article

Gold carbene or carbenoid: is there a difference?

scientific article published on 18 March 2015

Gold catalysis: Carbene or cation?

scientific article published on 01 September 2009

Gold for the Generation and Control of Fluxional Barbaralyl Cations

scientific article published on 19 November 2012

Gold(I) Carbenoids: On-Demand Access to Gold(I) Carbenes in Solution

scientific article published on 16 January 2017

Gold(I) as an artificial cyclase: short stereodivergent syntheses of (-)-epiglobulol and (-)-4β,7α- and (-)-4α,7α-aromadendranediols

scientific article published in April 2014

Gold(I) carbenes by retro-Buchner reaction: generation and fate

scientific article published on 31 December 2013

Gold(I) complexes with hydrogen-bond supported heterocyclic carbenes as active catalysts in reactions of 1,6-enynes

scientific article

Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.

scientific article published on 6 April 2015

Gold(I)-Catalyzed Inter- and Intramolecular Additions of Carbonyl Compounds to Allenenes.

scientific article

Gold(I)-Catalyzed Intramolecular C(sp3 )-H Insertion by Decarbenation of Cycloheptatrienes

scientific article published on 20 May 2019

Gold(I)-Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)-Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols.

scientific article published on 20 September 2017

Gold(I)-catalysed arylation of 1,6-enynes: different site reactivity of cyclopropyl gold carbenes

scientific article published on 19 December 2006

Gold(I)-catalyzed cyclizations of 1,6-enynes: alkoxycyclizations and exo/endo skeletal rearrangements

scientific article published on 01 February 2006

Gold(I)-catalyzed intermolecular [2+2] cycloaddition of alkynes with alkenes

scientific article published on 01 July 2010

Gold(I)-catalyzed intermolecular addition of carbon nucleophiles to 1,5- and 1,6-enynes

scientific article published on 30 August 2008

Gold(I)-catalyzed intermolecular cyclopropanation of enynes with alkenes: trapping of two different gold carbenes

scientific article published on 01 September 2006

Gold(I)-catalyzed intramolecular [4+2] cycloadditions of arylalkynes or 1,3-enynes with alkenes: scope and mechanism

scientific article published on 13 December 2007

Gold(I)-catalyzed intramolecular cyclopropanation of dienynes

scientific article published on 01 February 2006

Gold(I)-catalyzed macrocyclization of 1,n-enynes

scientific article published on 13 March 2013

Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates.

scientific article published on 19 June 2015

Gold-Catalyzed Synthesis of Small Rings

scientific article published on 02 November 2020

Gold-catalyzed addition of carbon nucleophiles to propargyl carboxylates

scientific article published on 01 September 2007

Gold-catalyzed allyl-allyl coupling

scientific article published in January 2008

Gold-catalyzed annulation/fragmentation: formation of free gold carbenes by retro-cyclopropanation

scientific article published on September 2010

Gold-catalyzed cycloisomerizations of enynes: a mechanistic perspective

scientific article published on 18 July 2008

Gold-catalyzed intramolecular reaction of indoles with alkynes: facile formation of eight-membered rings and an unexpected allenylation.

scientific article

Gold-catalyzed reactions of 1,5- and 1,6-enynes with carbonyl compounds: cycloaddition vs. metathesis

scientific article published on 01 June 2009

Gold-catalyzed rearrangements and beyond

scientific article published on 31 October 2013

Gold-catalyzed synthesis of tetrazoles from alkynes by C-C bond cleavage

scientific article published on 13 November 2013

Higher Acenes by On-Surface Dehydrogenation: From Heptacene to Undecacene

scientific article published on 07 June 2018

Hydroacenes Made Easy by Gold(I) Catalysis.

scientific article published on 6 July 2016

Hydroxy- and Alkoxycyclizations of Enynes Catalyzed by Platinum(II) Chloride

scientific article published in 2003

Interaction of a conjugated polyaromatic molecule with a single dangling bond quantum dot on a hydrogenated semiconductor

scientific article published on 14 January 2016

Intermolecular gold(I)-catalyzed cyclization of furans with alkynes: formation of phenols and indenes

scientific article published on 4 April 2013

Intermolecular gold-catalyzed cycloaddition of alkynes with oxoalkenes

scientific article published on 19 February 2013

Intra- and intermolecular reactions of indoles with alkynes catalyzed by gold

scientific article published on 01 January 2007

Intramolecular [4 + 2] cycloadditions of 1,3-enynes or arylalkynes with alkenes with highly reactive cationic phosphine Au(I) complexes

scientific article published in May 2005

Intramolecular carbostannylation of alkynes catalyzed by silver(I) species

scientific article published on 01 January 2007

Intramolecular coupling of allyl carboxylates with allyl stannanes and allyl silanes: a new type of reductive elimination reaction?

scientific article published in August 2002

Intramolecular hydroarylation of alkynes catalyzed by platinum or gold: mechanism and endo selectivity

scientific article

Intramolecular reactions of alkynes with furans and electron rich arenes catalyzed by PtCl2: the role of platinum carbenes as intermediates.

scientific article published in May 2003

Intriguing mechanistic labyrinths in gold(I) catalysis

scientific article published on January 2014

Iridium-Catalyzed β-Alkynylation of Aliphatic Oximes as Masked Carbonyl Compounds and Alcohols

scientific article published on 20 March 2020

Kilian Muñiz (1970-2020)

scientific article published on 06 April 2020

Manipulating molecular quantum states with classical metal atom inputs: demonstration of a single molecule NOR logic gate

scientific article published on 03 February 2011

Meeting the challenge of intermolecular gold(I)-catalyzed cycloadditions of alkynes and allenes

scientific article

Metal cyclopropyl carbenes in the reactions of alkynes with alkenes and furans

scientific article published in January 2004

Metal-arene interactions in dialkylbiarylphosphane complexes of copper, silver, and gold

scientific article published on 01 May 2010

Missing cyclization pathways and new rearrangements unveiled in the gold(I) and platinum(II)-catalyzed cyclization of 1,6-enynes

scientific article published in July 2007

Modular chiral gold(i) phosphite complexes†Electronic supplementary information (ESI) available: Experimental results and NMR data. CCDC 933751 (L11(AuCl)), 933752 (L12(AuCl)a), 933753 (L9(AuCl)), 933754 (L10(AuCl)), 933756 (L8(AuCl)), 933757 [...]

scientific article

Molecular Conformation, Organizational Chirality, and Iron Metalation of meso-Tetramesitylporphyrins on Copper(100)

scientific article published on 21 May 2008

Molecular Panels for Energy Transduction in C60-Based Conjugates

scientific article published on 01 June 2006

Molecular diversity through gold catalysis with alkynes

scientific article published on 09 November 2006

Nature of the Intermediates in Gold(I)‐Catalyzed Cyclizations of 1,5‐Enynes ⬇️

scientific article published on September 19, 2011

New Building Blocks Based on Truxene Cores: Synthesis of Functionalizedsyn-Tri- and -Hexasubstituted Derivatives

New annulations via platinum-catalyzed enyne cyclization and cyclopropane cleavage

scientific article published on 01 September 2004

New‐Generation Ligand Design for the Gold‐Catalyzed Asymmetric Activation of Alkynes

Nitrogen Acyclic Gold(I) Carbenes: Excellent and Easily Accessible Catalysts in Reactions of 1,6-Enynes

Non-stabilized transition metal carbenes as intermediates in intramolecular reactions of alkynes with alkenes

scientific article published on 13 August 2004

Nonacene Generated by On-Surface Dehydrogenation.

scientific article

Novel ortho-OPE metallofoldamers: binding-induced folding promoted by nucleating Ag(i)–alkyne interactions

On the Mechanism of the Puzzling “Endocyclic” Skeletal Rearrangement of 1,6-Enynes

scientific article published in September 2007

On the Structure of Intermediates in Enyne Gold(I)-Catalyzed Cyclizations: Formation of trans-Fused Bicyclo[5.1.0]octanes as a Case Study

scientific article published on 06 November 2020

On the silver effect and the formation of chloride-bridged digold complexes.

scientific article

On-Surface Synthesis and Intermolecular Cycloadditions of Indacenoditetracenes, Antiaromatic Analogues of Undecacene

scientific article published on 21 December 2020

On-surface synthesis of heptacene on Ag(001) from brominated and non-brominated tetrahydroheptacene precursors

scientific article published on 01 September 2018

Organic Molecules Reconstruct Nanostructures on Ionic Surfaces

article

Overcrowded 5,10,15-Trisubstituted Derivatives: Synthesis of 5,10,15-Tri(fluorenylidene)truxene

Palladium catalyzed arylation for the synthesis of polyarenes

scientific article published on 20 July 2007

Palladium(II)-catalyzed isomerization-Claisen rearrangement of 2-alkoxy diallyl ethers

scientific article published in October 2004

Palladium-Catalyzed Coupling of Naphthoquinone Triflates with Stannanes. Unprecedented Nucleophilic Aromatic Substitution on a Hydroxynaphthoquinone Triflate

scientific article published on 01 June 1997

Palladium-catalyzed synthesis of tetraethynyl and tetraethenyl biphenyls: Elongated tetrahedral tectons

Phosphate ligands in the gold(I)-catalysed activation of enynes

scientific article published on 04 November 2011

Photoredox-Assisted Gold-Catalyzed Arylative Alkoxycyclization of 1,6-Enynes

scientific article published on 03 April 2020

Platinum-Catalyzed Alkoxy- and Hydroxycyclization of Enynes

scientific article published in November 2000

Polynuclear Gold [Au(I) ]4 , [Au(I) ]8 , and Bimetallic [Au(I) 4 Ag(I) ] Complexes: C-H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines

scientific article (publication date: 20 June 2016)

Prins cyclizations in Au-catalyzed reactions of enynes

scientific article published on 01 August 2006

Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation.

scientific article published in February 2006

Proton-abstraction mechanism in the palladium-catalyzed intramolecular arylation: substituent effects

scientific article published on 27 April 2007

Pt(II)-Catalyzed Intramolecular Reaction of Furans with Alkynes This work was supported by the DGICYT (project PB97-0002) and the MCyT (predoctoral fellowship to B.M.-M.). We also acknowledge Johnson Matthey PLC for a generous loan of PtCl(2)

Rationale for the sluggish oxidative addition of aryl halides to Au(I).

scientific article published on February 2014

Reaction of allylsilanes and allylstannanes with alkynes catalyzed by electrophilic late transition metal chlorides

scientific article

Reaction of enol ethers with alkynes catalyzed by transition metals: 5-exo-dig versus 6-endo-dig cyclizations via cyclopropyl platinum or gold carbene complexes

scientific article published on 01 June 2003

Ready Access to the Echinopines Skeleton via Gold(I)-Catalyzed Alkoxycyclizations of Enynes.

scientific article published on 16 August 2016

Rhodium(III)-Catalyzed Synthesis of Skipped Enynes via C(sp3)-H Alkynylation of Terminal Alkenes

scientific article published on 06 January 2021

Role of σ,π-Digold(I) Alkyne Complexes in Reactions of Enynes.

scientific article published on 19 December 2017

Ruthenium-Catalyzed Peri- and Ortho-Alkynylation with Bromoalkynes via Insertion and Elimination.

scientific article

Selective Homogeneous and Heterogeneous Gold Catalysis with Alkynes and Alkenes: Similar Behavior, Different Origin

scientific article published on 01 August 2008

Single-Molecule Rotational Switch on a Dangling Bond Dimer Bearing

scientific article

Small Gold(I) and Gold(I)-Silver(I) Clusters via C-Si Auration

scientific article published on 31 March 2020

Sodium tetramethoxyborate: an efficient catalyst for Michael additions of stabilized carbon nucleophiles

scientific article published on 19 September 2007

Stereoselective cis-Vinylcyclopropanation via a Gold(I)-Catalyzed Retro-Buchner Reaction under Mild Conditions

scientific article published on 18 April 2017

Stereoselective gold-catalyzed cycloaddition of functionalized ketoenynes: synthesis of (+)-orientalol F

scientific article published on 05 November 2009

Strategies for the Synthesis of Higher Acenes.

scientific article published on 16 November 2016

Surface assembly of porphyrin nanorods with one-dimensional zinc–oxygen spinal cords

scientific article published in 2011

Synthesis and Biological Evaluation of New (-)-Englerin Analogues

scientific article published on 23 March 2016

Synthesis and self-association of syn-5,10,15-trialkylated truxenes

scientific article

Synthesis of (+)-schisanwilsonene A by tandem gold-catalyzed cyclization/1,5-migration/cyclopropanation

scientific article published on 10 May 2013

Synthesis of (-)-Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)-Catalyzed Cycloisomerization

scientific article published on 27 April 2016

Synthesis of Barbaralones and Bullvalenes Made Easy by Gold Catalysis.

scientific article published on 19 August 2016

Synthesis of Rumphellaone A and Hushinone by a Gold-Catalyzed [2 + 2] Cycloaddition

scientific article published on 14 March 2016

Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation

scientific article

Synthesis of a Triaza Analogue of Crushed-Fullerene by Intramolecular Palladium-Catalyzed Arylation

scientific article published on 01 August 2004

Synthesis of fluoranthenes by hydroarylation of alkynes catalyzed by gold(I) or gallium trichloride.

scientific article published on 14 November 2011

Synthesis ofC3 Benzo[1,2-e:3,4-e′:5,6-e′′]tribenzo[l]acephenanthrylenes (“Crushed Fullerene” Derivatives) by Intramolecular Palladium-Catalyzed Arylation

scientific article published on 01 May 2004

Templated growth of an ordered array of organic bidimensional mesopores

Tetrabenzocircumpyrene: a nanographene fragment with an embedded peripentacene core

scientific article published on 20 March 2015

The final steps of the Oppolzer cyclization: mechanism of the insertion of alkenes into allylpalladium(II) complexes

scientific article published on 01 January 2003

The mechanisms of the Stille reaction

scientific article

The mechanistic puzzle of transition-metal-catalyzed skeletal rearrangements of enynes

scientific article

The role of cyclobutenes in gold(I)-catalysed skeletal rearrangement of 1,6-enynes

scientific article published on 31 May 2012

Ti/Pd Bimetallic Systems for the Efficient Allylation of Carbonyl Compounds and Homocoupling Reactions ⬇️

scientific article published on 02 March 2011

Tin in Organic Synthesis

Total Synthesis of Repraesentin F and Configuration Reassignment by a Gold(I)-Catalyzed Cyclization Cascade.

scientific article published on 10 September 2018

Total synthesis of natural myriaporones

scientific article published in March 2004

Towards the Ideal Synthesis of Homoallylic Ketones

scientific article published on 4 December 2014

Unified Total Synthesis of Pyrroloazocine Indole Alkaloids Sheds Light on Their Biosynthetic Relationship.

scientific article published on 12 February 2018

Unlikeliness of Pd-Free Gold(I)-Catalyzed Sonogashira Coupling Reactions

scientific article published in 2010

Zipping up 'the crushed fullerene' C60H30:C60 by fifteen-fold, consecutive intramolecular H2 losses

scientific article published on 01 February 2002

cis-Selective single-cleavage skeletal rearrangement of 1,6-enynes reveals the multifaceted character of the intermediates in metal-catalyzed cycloisomerizations

scientific article published on 01 January 2008

α,β-Unsaturated Gold(I) Carbenes by Tandem Cyclization and 1,5-Alkoxy Migration of 1,6-Enynes: Mechanisms and Applications.

scientific article published on 16 August 2016

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