List of works - Gerd-Volker Röschenthaler

A Selectfluor-promoted oxidative reaction of disulfides and amines: access to sulfinamides

scientific article published on 06 May 2020

A novel type of formation of zwitterionic compounds, containing two phosphorus atoms of opposite charge and different coordination number.

scientific article

Are intramolecular frustrated Lewis pairs also intramolecular catalysts? A theoretical study on H2 activation

scientific article published on 01 April 2015

Asymmetric Synthesis of 4,4-(Difluoro)glutamic Acid via Chiral Ni(II)-Complexes of Dehydroalanine Schiff Bases. Effect of the Chiral Ligands Structure on the Stereochemical Outcome

scientific article published on 29 January 2020

Asymmetric synthesis of phosphonotrifluoroalanine and its derivatives using N-tert-butanesulfinyl imine derived from fluoral

CF2-Containing acetylenephosphonates in heterocyclization reactions: the first synthesis of 2-difluoromethyl azaxanth-3-ylphosphonates ⬇️

scientific article published on October 19, 2011

Carbamoylphosphonate-based matrix metalloproteinase inhibitor metal complexes: solution studies and stability constants. Towards a zinc-selective binding group

scientific article published on 5 February 2004

Carbamoylphosphonates, a new class of in vivo active matrix metalloproteinase inhibitors. 1. Alkyl- and cycloalkylcarbamoylphosphonic acids

scientific article published on May 2004

Carbene complexes of phosphorus(V) fluorides substituted with perfluoroalkyl-groups synthesized by oxidative addition. Cleavage of the complexes reveals a new synthetic protocol for ionic liquids.

scientific article published in February 2014

Click-chemistry approach to isoxazole-containing α-CF3-substituted α-aminocarboxylates and α-aminophosphonates

scientific article published on 02 September 2011

Complementary bonding analysis of the N-Si interaction in pentacoordinated silicon compounds using quantum crystallography

scientific article published on 17 October 2019

Complexes of Ge(IV)- and Sn(IV)-fluorides with cyclic and acyclic carbenes: bis(dialkylamino)-difluoromethylenes as carbene sources

scientific article published on 03 January 2012

Control of Regio- and Enantioselectivity in the Asymmetric Organocatalytic Addition of Acetone to 4-(Trifluoromethyl)pyrimidin-2(1H)-ones

article

Convenient synthesis of ethyl 4-aryl-6-(trifluoromethyl)-2-oxo-2H-pyran-3-carboxylates and 4-aryl-6-(trifluoromethyl)-2H-pyran-2-ones: novel highly reactive CF3-containing building blocks

scientific article published on 07 June 2008

Copper-catalyzed trifluoromethylation of aryl iodides with potassium (trifluoromethyl)trimethoxyborate.

scientific article

Darstellung und Struktur von Dispiro-diazaphosphetidinen

Darstellung und Strukturbestimmung von Ammoniak-Phosphorpentafluorid (1/1)

article published in 1983

Darstellung von 2-Amino-1.3.2λ3(λ5)-dioxaphospholanen / Synthesis of 2-Amino-1,3,2λ3 (λ5)-dioxaphospholanes

Design, cytotoxic and fluorescent properties of novel N-phosphorylalkyl substituted E,E-3,5-bis(arylidene)piperid-4-ones.

scientific article

Different fluoride anion sources and (trifluoromethyl)trimethylsilane: molecular structure of tris(dimethylamino)sulfonium bis(trifluoromethyl)trimethylsiliconate, the first isolated pentacoordinate silicon species with five Si–C bonds

article

Diphosphates and diphosphonates in polyoxometalate chemistry.

scientific article published on 13 July 2012

Elemental F2 with transannular dienes: regioselectivities and mechanisms

scientific article published on 07 July 2014

Fluorinated Cyclic Phosphorus(III)-Based Electrolyte Additives for High Voltage Application in Lithium-Ion Batteries: Impact of Structure-Reactivity Relationships on CEI Formation and Cell Performance

scientific article published on 26 April 2019

Fluorine and Lithium: Ideal Partners for High-Performance Rechargeable Battery Electrolytes

scientific article published on 24 July 2019

Guanidinophosphazenes: design, synthesis, and basicity in THF and in the gas phase

scientific article

Heterocyclization of N-(1-chloro-2,2,2-trifluoroethylidene)carbamates with β-enaminoesters—a novel synthetic strategy to functionalized trifluoromethylated pyrimidines

Hexaalkylguanidinium and 2-(dialkylamino)-1,3-dimethylimidazolinium trimethyldifluorosiliconates and perfluoroalkoxides. Accidental isolation and molecular structure of [C(NMe2)3]+F-*6CH2Cl2.

scientific article published in November 2002

Hypervalent-iodine mediated one-pot synthesis of isoxazolines and isoxazoles bearing a difluoromethyl phosphonate moiety

scientific article

Janus face all-cis 1,2,4,5-tetrakis(trifluoromethyl)- and all-cis 1,2,3,4,5,6-hexakis(trifluoromethyl)- cyclohexanes

scientific article published on 21 July 2020

Methylenebisphosphonates with Dienone Pharmacophore: Synthesis, Structure, Antitumor and Fluorescent Properties ⬇️

scientific article published on January 2, 2012

Methyltrifluoropyruvate imines possessing N-oxalyl and N-phosphonoformyl groups--precursors to a variety of alpha-CF3-alpha-amino acid derivatives

scientific article published on 17 August 2006

NHC→SiCl4 : an ambivalent carbene-transfer reagent.

scientific article published on 31 October 2014

New Chiral Reagent for Installation of Pharmacophoric (S)- or (R)-2-(Alkoxyphosphono)-1-amino-2,2-difluoroethyl Groups

scientific article published on 8 March 2016

Noncyclic [10-S-5] Sulfuranide Dioxide Salts with Three S−C Bonds: A New Class of Stable Hypervalent Compounds ⬇️

scientific article published on October 15, 2003

On the mechanism of hydrogen activation by frustrated Lewis pairs

scientific article

Pentakis(trifluoromethyl)phenyl, a sterically crowded and electron-withdrawing group: synthesis and acidity of pentakis(trifluoromethyl)benzene, -toluene, -phenol, and -aniline

scientific article

Phosphorus(V) Complexes with Acyclic Monoaminocarbene Ligands via Oxidative Addition ⬇️

scientific article published on April 26, 2013

Polytrifluoromethylation versus polyfluorination of the isomers of Kekulé benzene and phenol: a theoretical study

scientific article published on October 2010

Preparations of SF(5)- and CF(3)-substituted arenes utilizing the 7-oxabicyclo[2.2.1]hept-2-ene synthones.

scientific article published in December 2013

Propargyl-Substituted Phosphonocarboxylates: Efficient Synthesis and Application to Click Chemistry

scientific article published in 2009

Regioselective nucleophilic 1,4-trifluoromethylation of 2-polyfluoroalkylchromones with (trifluoromethyl)trimethylsilane. Synthesis of fluorinated analogs of natural 2,2-dimethylchroman-4-ones and 2,2-dimethylchromenes.

scientific article published in October 2003

SF5-Enolates in Ti(IV)-Mediated Aldol Reactions

scientific article published on 18 July 2016

Selective synthesis of cis- and trans-[(NHC(Me))2PtCl2] and [NHC(Me)Pt(cod)Cl][NHC(Me)PtCl3] using NHC(Me)SiCl4

scientific article published on 01 November 2014

Struktur und Synthese eines spirocyclischen Phosphoranid-Anions: Modell für einen Zwischenzustand bei einer SN2(P)-Reaktion

article published in 1983

Synthesis and Characterization of Oxazaborinin Phosphonate for Blue OLED Emitter Applications

scientific article published on 07 February 2019

Synthesis and reactivity of new functionalized perfluoroalkylfluorophosphates

scientific article published on 14 May 2014

Synthesis of (α,α-Difluoropropargyl)phosphonates via Aldehyde-to-Alkyne Homologation ⬇️

scientific article published on April 19, 2013

Synthesis of 2-perfluoroalkyl 4H- and 2H-chromenylphosphonates mediated by amines and phosphines

scientific article published on 01 December 2010

Synthesis of functionalized bisphosphonates via click chemistry

scientific article published on 21 June 2007

The conformational analysis of push-pull enaminones using Fourier transform IR and NMR spectroscopy, and quantum chemical calculations. V. α-Methyl-, fluorine-β-N,N-dimethylaminovinyl trifluoromethyl ketones

scientific article

The self-disproportionation of enantiomers (SDE) via column chromatography of β-amino-α,α-difluorophosphonic acid derivatives

scientific article published on 29 August 2019

The tris(trifluoromethyl)methyl phosphonium ion, P(CF(3))(3)CH(3)(+), preparation and structure

scientific article published on 01 July 2009

List of works by Gerd-Volker Röschenthaler

A Selectfluor-promoted oxidative reaction of disulfides and amines: access to sulfinamides

A novel type of formation of zwitterionic compounds, containing two phosphorus atoms of opposite charge and different coordination number.

Are intramolecular frustrated Lewis pairs also intramolecular catalysts? A theoretical study on H2 activation

Asymmetric Synthesis of 4,4-(Difluoro)glutamic Acid via Chiral Ni(II)-Complexes of Dehydroalanine Schiff Bases. Effect of the Chiral Ligands Structure on the Stereochemical Outcome

Asymmetric synthesis of phosphonotrifluoroalanine and its derivatives using N-tert-butanesulfinyl imine derived from fluoral

CF2-Containing acetylenephosphonates in heterocyclization reactions: the first synthesis of 2-difluoromethyl azaxanth-3-ylphosphonates ⬇️

Carbamoylphosphonate-based matrix metalloproteinase inhibitor metal complexes: solution studies and stability constants. Towards a zinc-selective binding group

Carbamoylphosphonates, a new class of in vivo active matrix metalloproteinase inhibitors. 1. Alkyl- and cycloalkylcarbamoylphosphonic acids

Carbene complexes of phosphorus(V) fluorides substituted with perfluoroalkyl-groups synthesized by oxidative addition. Cleavage of the complexes reveals a new synthetic protocol for ionic liquids.

Click-chemistry approach to isoxazole-containing α-CF3-substituted α-aminocarboxylates and α-aminophosphonates

Complementary bonding analysis of the N-Si interaction in pentacoordinated silicon compounds using quantum crystallography

Complexes of Ge(IV)- and Sn(IV)-fluorides with cyclic and acyclic carbenes: bis(dialkylamino)-difluoromethylenes as carbene sources

Control of Regio- and Enantioselectivity in the Asymmetric Organocatalytic Addition of Acetone to 4-(Trifluoromethyl)pyrimidin-2(1H)-ones

Convenient synthesis of ethyl 4-aryl-6-(trifluoromethyl)-2-oxo-2H-pyran-3-carboxylates and 4-aryl-6-(trifluoromethyl)-2H-pyran-2-ones: novel highly reactive CF3-containing building blocks

Copper-catalyzed trifluoromethylation of aryl iodides with potassium (trifluoromethyl)trimethoxyborate.

Darstellung und Struktur von Dispiro-diazaphosphetidinen

Darstellung und Strukturbestimmung von Ammoniak-Phosphorpentafluorid (1/1)

Darstellung von 2-Amino-1.3.2λ3(λ5)-dioxaphospholanen / Synthesis of 2-Amino-1,3,2λ3 (λ5)-dioxaphospholanes

Design, cytotoxic and fluorescent properties of novel N-phosphorylalkyl substituted E,E-3,5-bis(arylidene)piperid-4-ones.

Different fluoride anion sources and (trifluoromethyl)trimethylsilane: molecular structure of tris(dimethylamino)sulfonium bis(trifluoromethyl)trimethylsiliconate, the first isolated pentacoordinate silicon species with five Si–C bonds

Diphosphates and diphosphonates in polyoxometalate chemistry.

Elemental F2 with transannular dienes: regioselectivities and mechanisms

Fluorinated Cyclic Phosphorus(III)-Based Electrolyte Additives for High Voltage Application in Lithium-Ion Batteries: Impact of Structure-Reactivity Relationships on CEI Formation and Cell Performance

Fluorine and Lithium: Ideal Partners for High-Performance Rechargeable Battery Electrolytes

Guanidinophosphazenes: design, synthesis, and basicity in THF and in the gas phase

Heterocyclization of N-(1-chloro-2,2,2-trifluoroethylidene)carbamates with β-enaminoesters—a novel synthetic strategy to functionalized trifluoromethylated pyrimidines

Hexaalkylguanidinium and 2-(dialkylamino)-1,3-dimethylimidazolinium trimethyldifluorosiliconates and perfluoroalkoxides. Accidental isolation and molecular structure of [C(NMe2)3]+F-*6CH2Cl2.

Hypervalent-iodine mediated one-pot synthesis of isoxazolines and isoxazoles bearing a difluoromethyl phosphonate moiety

Janus face all-cis 1,2,4,5-tetrakis(trifluoromethyl)- and all-cis 1,2,3,4,5,6-hexakis(trifluoromethyl)- cyclohexanes

Methylenebisphosphonates with Dienone Pharmacophore: Synthesis, Structure, Antitumor and Fluorescent Properties ⬇️

Methyltrifluoropyruvate imines possessing N-oxalyl and N-phosphonoformyl groups--precursors to a variety of alpha-CF3-alpha-amino acid derivatives

NHC→SiCl4 : an ambivalent carbene-transfer reagent.

New Chiral Reagent for Installation of Pharmacophoric (S)- or (R)-2-(Alkoxyphosphono)-1-amino-2,2-difluoroethyl Groups

Noncyclic [10-S-5] Sulfuranide Dioxide Salts with Three S−C Bonds: A New Class of Stable Hypervalent Compounds ⬇️

On the mechanism of hydrogen activation by frustrated Lewis pairs

Pentakis(trifluoromethyl)phenyl, a sterically crowded and electron-withdrawing group: synthesis and acidity of pentakis(trifluoromethyl)benzene, -toluene, -phenol, and -aniline

Phosphorus(V) Complexes with Acyclic Monoaminocarbene Ligands via Oxidative Addition ⬇️

Polytrifluoromethylation versus polyfluorination of the isomers of Kekulé benzene and phenol: a theoretical study

Preparations of SF(5)- and CF(3)-substituted arenes utilizing the 7-oxabicyclo[2.2.1]hept-2-ene synthones.

Propargyl-Substituted Phosphonocarboxylates: Efficient Synthesis and Application to Click Chemistry

Regioselective nucleophilic 1,4-trifluoromethylation of 2-polyfluoroalkylchromones with (trifluoromethyl)trimethylsilane. Synthesis of fluorinated analogs of natural 2,2-dimethylchroman-4-ones and 2,2-dimethylchromenes.

SF5-Enolates in Ti(IV)-Mediated Aldol Reactions

Selective synthesis of cis- and trans-[(NHC(Me))2PtCl2] and [NHC(Me)Pt(cod)Cl][NHC(Me)PtCl3] using NHC(Me)SiCl4

Struktur und Synthese eines spirocyclischen Phosphoranid-Anions: Modell für einen Zwischenzustand bei einer SN2(P)-Reaktion

Synthesis and Characterization of Oxazaborinin Phosphonate for Blue OLED Emitter Applications

Synthesis and reactivity of new functionalized perfluoroalkylfluorophosphates

Synthesis of (α,α-Difluoropropargyl)phosphonates via Aldehyde-to-Alkyne Homologation ⬇️

Synthesis of 2-perfluoroalkyl 4H- and 2H-chromenylphosphonates mediated by amines and phosphines

Synthesis of functionalized bisphosphonates via click chemistry

The conformational analysis of push-pull enaminones using Fourier transform IR and NMR spectroscopy, and quantum chemical calculations. V. α-Methyl-, fluorine-β-N,N-dimethylaminovinyl trifluoromethyl ketones

The self-disproportionation of enantiomers (SDE) via column chromatography of β-amino-α,α-difluorophosphonic acid derivatives

The tris(trifluoromethyl)methyl phosphonium ion, P(CF(3))(3)CH(3)(+), preparation and structure