List of works - Timothy P. Hanusa

2,4-Pentanediolate as an Alkoxide/Diketonate “Hybrid” Ligand and the Formation of Aluminum and Zirconium Derivatives ⬇️

scientific article published on 04 November 2011

Advances in organometallic synthesis with mechanochemical methods

scientific article published on 01 February 2016

Allyl complexes of the heavy alkaline-earth metals: molecular structure and catalytic behavior

scientific article

Ambient temperature imidazolium-based ionic liquids with tetrachloronickelate(II) anions

An η 3 ‐Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex

scientific article

An η3 -Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex

scientific article published on 11 February 2020

Bis(1,2,3-trimethylindenyl)iron(III) 2,3-dicyanonaphtho-1,4-quinonide, a non-metallocene, charge-transfer salt metamagnet with complementary donor-acceptor geometries

scientific article published in January 2005

Bis(1,3-trimethylsilylallyl)beryllium

scientific article

Bis[1,3-bis(trimethylsilyl)allyl]cobalt(II), a stable electron-deficient allyl complex

scientific article published on 18 September 2004

Cationic, Neutral, and Anionic Allyl Magnesium Compounds: Unprecedented Ligand Conformations and Reactivity Toward Unsaturated Hydrocarbons

scientific article published on 31 December 2012

Classical versus bridged allyl ligands in magnesium complexes: the role of solvent.

scientific article published in May 2009

Cyclopentadienyl ring metathesis with bis(pentamethylcyclopentadienyl)calcium as a route to mixed ring organolanthanide complexes; the crystal structure of (C5Me5)2Nd(C5H5)

Disappearing Polymorphs in Metal-Organic Framework Chemistry: Unexpected Stabilization of a Layered Polymorph over an Interpenetrated Three-Dimensional Structure in Mercury Imidazolate

scientific article published on 16 January 2020

Dispersion and distortion in heavy group 2 and lanthanide decamethylmetallocenes: The (C5Me5)2(Sr,Sm) connection

scientific article

Exploration of Mechanochemical Activation in Solid-State Fluoro-Grignard Reactions

scientific article published on 28 January 2020

Generation of dimethylsilylene and allylidene holmium complexes from trimethylsilylated allyl ligands

scientific article published on 01 August 2006

Geometric Effects in Olefinic Cation−π Interactions with Alkali Metals: A Computational Study ⬇️

scientific article published on December 14, 2010

Halide metathesis in overdrive: mechanochemical synthesis of a heterometallic group 1 allyl complex

scientific article published on 02 August 2019

Ion pairing in [bis(trimethylsilyl)amido]potassium: The x-ray crystal structure of unsolvated [KN(SiMe3)2]2

article

Lithium, Sodium, Potassium, Rubidium, and Cesium

scientific article

Macrocyclic Complexes of the Alkali Metals

scientific article

Mechanochemical Formation, Solution Rearrangements, and Catalytic Behavior of a Polymorphic Ca/K Allyl Complex

scientific article

Mechanochemical Influence on the Stereoselectivity of Halide Metathesis: Synthesis of Group 15 Tris(allyl) Complexes

scientific article

Mechanochemical Synthesis of a Mercury(II) Metal-Organic Framework Reveals a Two-Dimensional Polymorph Stabilized by Weak Interactions

Mechanochemically directed metathesis in group 2 chemistry: calcium amide formation without solvent

scientific article published on 01 February 2019

Mechanochemically driven transformations in organotin chemistry: stereochemical rearrangement, redox behavior, and dispersion-stabilized complexes

scientific article published on 07 November 2018

Metal allyl complexes with bulky ligands: stabilization of homoleptic thorium compounds, [(SiMe3)nC3H(5-n)]4Th (n = 1, 2).

scientific article

Multicomponent Mechanochemical Synthesis of Cyclopentadienyl Titanium tert-Butoxy Halides, Cp x TiX y (O t Bu)4-(x+y) (x, y = 1, 2; X = Cl, Br)

scientific article published on 20 July 2018

Observation of internal electron transfer in bulky allyl ytterbium complexes with substituted terpyridine ligands

scientific article published on 01 August 2006

Reaction environment and ligand lability in group 4 Cp2MXY (X, Y = Cl, OtBu) complexes

scientific article published on 9 November 2016

Redetermination of the Zigzag Modification of Plumbocene at 173 K

scientific article published on 01 January 1998

Solid state structure of bis(pentamethylcyclopentadienyl)barium, (Me5C5)2Ba; the first X-ray crystal structure of an organobarium complex

scholarly article by R. Allen Williams et al published 1988 in Journal of the Chemical Society. Chemical communications

Solution interaction of potassium and calcium bis(trimethylsilyl)amides; preparation of Ca[N(SiMe3)2]2 from dibenzylcalcium

scientific article published in February 2009

Spin-state alteration from sterically enforced ligand rotation in bis(indenyl)chromium(II) complexes

scientific article published in August 2002

Stereochemical activity of the metal-centered lone electron pair in group 14 metallocenes. Crystal structure of the linear sandwich complex [C5(iPr)3H2]2Pb

scientific article published on 01 January 2000

Steric stabilization of homoleptic bis(pi-allyl) complexes of chromium(II) and iron(II)

scientific article published on 01 July 2001

Structural distortions in M[E(SiMe₃)₂]₃ complexes (M = group 15, f-element; E = N, CH): is three a crowd?

scientific article

Structure of 5-hydroxy-2-hydroxymethyl-1-methylpyrid-4-one and 13C NMR relaxation studies of its gadolinium(III) complex

scientific article published on May 1996

Symmetric Assembly of a Sterically Encumbered Allyl Complex: Mechanochemical and Solution Synthesis of the Tris(allyl)beryllate, K[BeA′3] (A′ = 1,3-(SiMe3)2C3H3)

scientific article

Synthesis and crystallographic characterization of an unsolvated, monomeric samarium bis(pentamethylcyclopentadienyl) organolanthanide complex, (C5Me5)2Sm

article

Synthesis and iron(III) binding properties of 3-hydroxypyrid-4-ones derived from kojic acid

scientific article published on 01 August 1994

Synthesis and x-ray crystal structure of bis(pentamethylcyclopentadienyl) complexes of samarium and europium: (C5Me5)2Sm and (C5Me5)2Eu

article

The first noncoordinated phosphonium diylide, [Me2P(C13H8)2]-, and its ylidic and cationic counterparts: synthesis, structural characterization, and interaction with the heavy group 2 metals

scientific article published on 01 December 2000

Trimethylsilylated allyl complexes of nickel. The stabilized bis(pi-allyl)nickel complex [eta3-1,3-(SiMe3)2C3H3]2Ni and its mono(pi-allyl)NiX (X=Br, I) derivatives

scientific article published in March 2005

σ- vs π-Bonding in Manganese(II) Allyl Complexes

scientific article

List of works by Timothy P. Hanusa

2,4-Pentanediolate as an Alkoxide/Diketonate “Hybrid” Ligand and the Formation of Aluminum and Zirconium Derivatives ⬇️

Advances in organometallic synthesis with mechanochemical methods

Allyl complexes of the heavy alkaline-earth metals: molecular structure and catalytic behavior

Ambient temperature imidazolium-based ionic liquids with tetrachloronickelate(II) anions

An η 3 ‐Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex

An η3 -Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex

Bis(1,2,3-trimethylindenyl)iron(III) 2,3-dicyanonaphtho-1,4-quinonide, a non-metallocene, charge-transfer salt metamagnet with complementary donor-acceptor geometries

Bis(1,3-trimethylsilylallyl)beryllium

Bis[1,3-bis(trimethylsilyl)allyl]cobalt(II), a stable electron-deficient allyl complex

Cationic, Neutral, and Anionic Allyl Magnesium Compounds: Unprecedented Ligand Conformations and Reactivity Toward Unsaturated Hydrocarbons

Classical versus bridged allyl ligands in magnesium complexes: the role of solvent.

Cyclopentadienyl ring metathesis with bis(pentamethylcyclopentadienyl)calcium as a route to mixed ring organolanthanide complexes; the crystal structure of (C5Me5)2Nd(C5H5)

Disappearing Polymorphs in Metal-Organic Framework Chemistry: Unexpected Stabilization of a Layered Polymorph over an Interpenetrated Three-Dimensional Structure in Mercury Imidazolate

Dispersion and distortion in heavy group 2 and lanthanide decamethylmetallocenes: The (C5Me5)2(Sr,Sm) connection

Exploration of Mechanochemical Activation in Solid-State Fluoro-Grignard Reactions

Generation of dimethylsilylene and allylidene holmium complexes from trimethylsilylated allyl ligands

Geometric Effects in Olefinic Cation−π Interactions with Alkali Metals: A Computational Study ⬇️

Halide metathesis in overdrive: mechanochemical synthesis of a heterometallic group 1 allyl complex

Ion pairing in [bis(trimethylsilyl)amido]potassium: The x-ray crystal structure of unsolvated [KN(SiMe3)2]2

Lithium, Sodium, Potassium, Rubidium, and Cesium

Macrocyclic Complexes of the Alkali Metals

Mechanochemical Formation, Solution Rearrangements, and Catalytic Behavior of a Polymorphic Ca/K Allyl Complex

Mechanochemical Influence on the Stereoselectivity of Halide Metathesis: Synthesis of Group 15 Tris(allyl) Complexes

Mechanochemical Synthesis of a Mercury(II) Metal-Organic Framework Reveals a Two-Dimensional Polymorph Stabilized by Weak Interactions

Mechanochemically directed metathesis in group 2 chemistry: calcium amide formation without solvent

Mechanochemically driven transformations in organotin chemistry: stereochemical rearrangement, redox behavior, and dispersion-stabilized complexes

Metal allyl complexes with bulky ligands: stabilization of homoleptic thorium compounds, [(SiMe3)nC3H(5-n)]4Th (n = 1, 2).

Multicomponent Mechanochemical Synthesis of Cyclopentadienyl Titanium tert-Butoxy Halides, Cp x TiX y (O t Bu)4-(x+y) (x, y = 1, 2; X = Cl, Br)

Observation of internal electron transfer in bulky allyl ytterbium complexes with substituted terpyridine ligands

Reaction environment and ligand lability in group 4 Cp2MXY (X, Y = Cl, OtBu) complexes

Redetermination of the Zigzag Modification of Plumbocene at 173 K

Solid state structure of bis(pentamethylcyclopentadienyl)barium, (Me5C5)2Ba; the first X-ray crystal structure of an organobarium complex

Solution interaction of potassium and calcium bis(trimethylsilyl)amides; preparation of Ca[N(SiMe3)2]2 from dibenzylcalcium

Spin-state alteration from sterically enforced ligand rotation in bis(indenyl)chromium(II) complexes

Stereochemical activity of the metal-centered lone electron pair in group 14 metallocenes. Crystal structure of the linear sandwich complex [C5(iPr)3H2]2Pb

Steric stabilization of homoleptic bis(pi-allyl) complexes of chromium(II) and iron(II)

Structural distortions in M[E(SiMe₃)₂]₃ complexes (M = group 15, f-element; E = N, CH): is three a crowd?

Structure of 5-hydroxy-2-hydroxymethyl-1-methylpyrid-4-one and 13C NMR relaxation studies of its gadolinium(III) complex

Symmetric Assembly of a Sterically Encumbered Allyl Complex: Mechanochemical and Solution Synthesis of the Tris(allyl)beryllate, K[BeA′3] (A′ = 1,3-(SiMe3)2C3H3)

Synthesis and crystallographic characterization of an unsolvated, monomeric samarium bis(pentamethylcyclopentadienyl) organolanthanide complex, (C5Me5)2Sm

Synthesis and iron(III) binding properties of 3-hydroxypyrid-4-ones derived from kojic acid

Synthesis and x-ray crystal structure of bis(pentamethylcyclopentadienyl) complexes of samarium and europium: (C5Me5)2Sm and (C5Me5)2Eu

The first noncoordinated phosphonium diylide, [Me2P(C13H8)2]-, and its ylidic and cationic counterparts: synthesis, structural characterization, and interaction with the heavy group 2 metals

Trimethylsilylated allyl complexes of nickel. The stabilized bis(pi-allyl)nickel complex [eta3-1,3-(SiMe3)2C3H3]2Ni and its mono(pi-allyl)NiX (X=Br, I) derivatives

σ- vs π-Bonding in Manganese(II) Allyl Complexes