List of works - Cyrille Kouklovsky

2,2-Dimethyl-5-nitroso-1,3-dioxan-5-yl benzoate, 2,2-dimethyl-5-nitroso-1,3-dioxan-5-yl 4-chlorobenzoate and 5-nitroso-1,3-dioxan-5-yl 4-chlorobenzoate

3-Aminopyrrolidines from alpha-aminoacids: total synthesis of (+)-nemonapride from D-alanine

scientific article published on 5 January 2008

A stereoselective entry into functionalized 1,2-diamines by zinc-mediated homologation of alpha-aminoacids

scientific article published on 02 June 2007

Amino acid homologation by the Blaise reaction: a new entry into nitrogen heterocycles.

scientific article published in June 2009

Base-Mediated Fragmentation of Bicyclic Dihydro-3,6-oxazines: Transformation of Nitroso Diels-Alder Cycloadducts

scientific article published on 09 March 2018

Bioinspired Oxidative Cyclization of the Geissoschizine Skeleton for Enantioselective Total Synthesis of Mavacuran Alkaloids

scientific article published on 21 June 2019

Bioinspired Oxidative Cyclization of the Geissoschizine Skeleton for the Total Synthesis of (-)-17-nor-Excelsinidine

scientific article published on 23 April 2018

Constrained α/γ-peptides: a new stable extended structure in solution without any hydrogen bond and characterized by a four-fold symmetry

scientific article published on 11 January 2012

Dearomative Diallylation of N-Acylindoles Mediated by FeCl3

scientific article published on 12 March 2018

Domino metathesis of 3,6-dihydro-1,2-oxazine: access to isoxazolo[2,3-a]pyridin-7-ones

scientific article published on 13 March 2007

Efficient cleavage of the N-O bond of 3,6-dihydro-1,2-oxazines mediated by some alpha-hetero substituted carbonyl compounds in mild conditions

scientific article published on 12 February 2008

Electrochemical Dearomative 2,3-Difunctionalization of Indoles

scientific article published on 28 January 2019

Enantioselective Total Synthesis of Cymoside through a Bioinspired Oxidative Cyclization of a Strictosidine Derivative

scientific article published on 04 December 2019

Enantioselective total synthesis of pyrinodemin A.

scientific article published on 10 March 2008

Foldamers containing γ-amino acid residues or their analogues: structural features and applications ⬇️

scientific article published on April 1, 2011

Frozen Chirality of Tertiary Aromatic Amides: Access to Enantioenriched Tertiary α-Amino Acid or Amino Alcohol without Chiral Reagent

scientific article published on 22 February 2017

Intermolecular nitroso Diels–Alder cycloaddition of α-acetoxynitroso derivatives in aqueous medium

Lewis acid-promoted hetero Diels-Alder cycloaddition of alpha-acetoxynitroso dienophiles

scientific article

Memory of Chirality of Tertiary Aromatic Amide: Application to the Asymmetric Synthesis of (S)-α-MethylDOPA ⬇️

scientific article published on September 14, 2012

Memory of chirality of tertiary aromatic amides: a simple and efficient method for the enantioselective synthesis of quaternary alpha-amino acids

scientific article

Regio- and stereochemical studies on the nitroso-Diels-Alder reaction with 1,2-disubstituted dienes

scientific article

Ring-rearrangement metathesis of nitroso Diels-Alder cycloadducts

scientific article published on 08 February 2011

Stereodivergent synthesis of substituted N,O-containing bicyclic compounds by sequential addition of nucleophiles to N-alkoxybicyclolactams

scientific article published on 29 December 2010

Studies towards the total synthesis of rapamycin: Preparation of the cyclohexyl C33C42 fragment and further coupling to afford the C22C42 carbon unit

Substrate control in enantioselective and diastereoselective aldol reaction by memory of chirality: a rapid access to enantiopure β-hydroxy quaternary α-amino acids

scientific article published on 16 January 2014

Synthesis and biological evaluation of bengacarboline derivatives

scientific article published on 4 December 2007

Synthesis of 3,3-Spirocyclic 2-Phosphonoindolines via a Dearomative Addition of Phosphonyl Radicals to Indoles

scientific article published on 18 June 2019

Synthesis of 3,3-Spiroindolines via FeCl3-Mediated Cyclization of Aryl- or Alkene-Containing 3-Substituted N-Ac Indoles

scientific article published on 25 March 2016

Synthesis of Polysubstituted Pyrroles from Nitroso-Diels-Alder Cycloadducts

Synthesis of oxaspirannic building blocks by regioselective nitroso-Diels-Alder reactions

scientific article

Tertiary aromatic amide for memory of chirality: access to enantioenriched alpha-substituted valine

scientific article published on 15 April 2008

Total synthesis of rapamycin

scientific article published in January 2009

Towards the synthesis of the C37-C42 fragment of rapamycin: intramolecular reactions of allyl silanes with oxonium ions generated from α-alkoxy sulfones

Triflic Acid as an Efficient Brønsted Acid Promoter for the Umpolung of N-Ac Indoles in Hydroarylation Reactions

Unexpected dimerization of a tripeptide comprising a β,γ-diamino acid

scientific article published on 21 December 2018

α-Acyloxynitroso dienophiles in [4+2] hetero Diels–Alder cycloadditions: mechanistic insights

β,γ-diamino acids as building blocks for new analogues of Gramicidin S: Synthesis and biological activity

scientific article published on 21 February 2018

List of works by Cyrille Kouklovsky

2,2-Dimethyl-5-nitroso-1,3-dioxan-5-yl benzoate, 2,2-dimethyl-5-nitroso-1,3-dioxan-5-yl 4-chlorobenzoate and 5-nitroso-1,3-dioxan-5-yl 4-chlorobenzoate

3-Aminopyrrolidines from alpha-aminoacids: total synthesis of (+)-nemonapride from D-alanine

A stereoselective entry into functionalized 1,2-diamines by zinc-mediated homologation of alpha-aminoacids

Amino acid homologation by the Blaise reaction: a new entry into nitrogen heterocycles.

Base-Mediated Fragmentation of Bicyclic Dihydro-3,6-oxazines: Transformation of Nitroso Diels-Alder Cycloadducts

Bioinspired Oxidative Cyclization of the Geissoschizine Skeleton for Enantioselective Total Synthesis of Mavacuran Alkaloids

Bioinspired Oxidative Cyclization of the Geissoschizine Skeleton for the Total Synthesis of (-)-17-nor-Excelsinidine

Constrained α/γ-peptides: a new stable extended structure in solution without any hydrogen bond and characterized by a four-fold symmetry

Dearomative Diallylation of N-Acylindoles Mediated by FeCl3

Domino metathesis of 3,6-dihydro-1,2-oxazine: access to isoxazolo[2,3-a]pyridin-7-ones

Efficient cleavage of the N-O bond of 3,6-dihydro-1,2-oxazines mediated by some alpha-hetero substituted carbonyl compounds in mild conditions

Electrochemical Dearomative 2,3-Difunctionalization of Indoles

Enantioselective Total Synthesis of Cymoside through a Bioinspired Oxidative Cyclization of a Strictosidine Derivative

Enantioselective total synthesis of pyrinodemin A.

Foldamers containing γ-amino acid residues or their analogues: structural features and applications ⬇️

Frozen Chirality of Tertiary Aromatic Amides: Access to Enantioenriched Tertiary α-Amino Acid or Amino Alcohol without Chiral Reagent

Intermolecular nitroso Diels–Alder cycloaddition of α-acetoxynitroso derivatives in aqueous medium

Lewis acid-promoted hetero Diels-Alder cycloaddition of alpha-acetoxynitroso dienophiles

Memory of Chirality of Tertiary Aromatic Amide: Application to the Asymmetric Synthesis of (S)-α-MethylDOPA ⬇️

Memory of chirality of tertiary aromatic amides: a simple and efficient method for the enantioselective synthesis of quaternary alpha-amino acids

Regio- and stereochemical studies on the nitroso-Diels-Alder reaction with 1,2-disubstituted dienes

Ring-rearrangement metathesis of nitroso Diels-Alder cycloadducts

Stereodivergent synthesis of substituted N,O-containing bicyclic compounds by sequential addition of nucleophiles to N-alkoxybicyclolactams

Studies towards the total synthesis of rapamycin: Preparation of the cyclohexyl C33C42 fragment and further coupling to afford the C22C42 carbon unit

Substrate control in enantioselective and diastereoselective aldol reaction by memory of chirality: a rapid access to enantiopure β-hydroxy quaternary α-amino acids

Synthesis and biological evaluation of bengacarboline derivatives

Synthesis of 3,3-Spirocyclic 2-Phosphonoindolines via a Dearomative Addition of Phosphonyl Radicals to Indoles

Synthesis of 3,3-Spiroindolines via FeCl3-Mediated Cyclization of Aryl- or Alkene-Containing 3-Substituted N-Ac Indoles

Synthesis of Polysubstituted Pyrroles from Nitroso-Diels-Alder Cycloadducts

Synthesis of oxaspirannic building blocks by regioselective nitroso-Diels-Alder reactions

Tertiary aromatic amide for memory of chirality: access to enantioenriched alpha-substituted valine

Total synthesis of rapamycin

Towards the synthesis of the C37-C42 fragment of rapamycin: intramolecular reactions of allyl silanes with oxonium ions generated from α-alkoxy sulfones

Triflic Acid as an Efficient Brønsted Acid Promoter for the Umpolung of N-Ac Indoles in Hydroarylation Reactions

Unexpected dimerization of a tripeptide comprising a β,γ-diamino acid

α-Acyloxynitroso dienophiles in [4+2] hetero Diels–Alder cycloadditions: mechanistic insights

β,γ-diamino acids as building blocks for new analogues of Gramicidin S: Synthesis and biological activity