List of works - Akkattu T Biju

A practical and general Diels-Alder reaction of pentafulvenes with arynes

scientific article published on 03 August 2012

Arynes in transition-metal-free multicomponent coupling reactions

scientific article published on 13 January 2012

Asymmetric N-heterocyclic carbene (NHC)-catalyzed annulation of modified enals with enolizable aldehydes

scientific article published on 04 October 2013

Base-Free and Catalyst-Free Synthesis of Functionalized Dihydrobenzoxazoles via Vinylogous Carbonate to Carbamate Rearrangement.

scientific article

Catalytic, Enantioselective C2-Functionalization of 3-Aminobenzofurans Using N-Heterocyclic Carbenes

scientific article published on 04 May 2020

Diels-Alder reaction of tropones with arynes: synthesis of functionalized benzobicyclo[3.2.2]nonatrienones

scientific article published on 02 May 2014

Efficient Diels-Alder reaction of 1,2-benzoquinones with arynes and its utility in one-pot reactions

scientific article published on 10 December 2012

Efficient Synthesis of Benzofuranones: N-Heterocyclic Carbene (NHC)/Base-Catalyzed Hydroacylation–Stetter–Rearrangement Cascade

scientific article published on 16 September 2011

Efficient synthesis of 9-aryldihydrophenanthrenes by a cascade reaction involving arynes and styrenes

scientific article published on 09 January 2014

Efficient synthesis of γ-keto sulfones by NHC-catalyzed intermolecular Stetter reaction

scientific article published on 14 May 2012

Employing Arynes for the Generation of Aryl Anion Equivalents and Subsequent Reaction with Aldehydes

scientific article published on 19 July 2018

Employing Arynes in Diels-Alder Reactions and Transition-Metal-Free Multicomponent Coupling and Arylation Reactions

scientific article published on 25 August 2016

Employing arynes in transition-metal-free monoarylation of aromatic tertiary amines

scientific article published on 14 October 2013

Enantioselective Synthesis of Functionalized β-Lactones by NHC-Catalyzed Aldol Lactonization of Ketoacids.

scientific article

Enantioselective Synthesis of Spirocyclohexadienones by NHC-Catalyzed Formal [3+3] Annulation Reaction of Enals

scientific article published on 21 October 2015

Enantioselective Synthesis of Tricyclic β-Lactones by NHC-Catalyzed Desymmetrization of Cyclic 1,3-Diketones

scientific article published on 01 July 2020

Enantioselective synthesis of functionalized pyrazoles by NHC-catalyzed reaction of pyrazolones with α,β-unsaturated aldehydes

scientific article published on 27 February 2015

Enantioselective synthesis of spiro γ-butyrolactones by N-heterocyclic carbene (NHC)-catalyzed formal [3 + 2] annulation of enals with 3-hydroxy oxindoles.

scientific article published on 15 February 2017

Facile synthesis of N-acyl 2-aminobenzothiazoles by NHC-catalyzed direct oxidative amidation of aldehydes.

scientific article published on 13 January 2017

Facile synthesis of γ-ketophosphonates by an intermolecular Stetter reaction onto vinylphosphonates

scientific article published on 05 September 2014

From insertion to multicomponent coupling: temperature dependent reactions of arynes with aliphatic alcohols

scientific article published on 14 December 2015

Imines as acceptors and donors in N-heterocyclic carbene (NHC) organocatalysis

scientific article published on 30 June 2020

Iodide as a Nucleophilic Trigger in Aryne Three-Component Coupling for the Synthesis of 2-Iodobenzyl Alcohols

scientific article published on 29 May 2019

Lewis Acid Catalyzed Ring-Opening 1,3-Aminothiolation of Donor-Acceptor Cyclopropanes Using Sulfenamides

scientific article published on 04 March 2020

Lewis Acid Catalyzed Selective Reactions of Donor-Acceptor Cyclopropanes with 2-Naphthols

scientific article published on 08 July 2016

Metal-Free, Brønsted Acid-Catalyzed Formal [3+2] Annulation of Quinone Monoacetals with 2-Naphthols

scientific article

Multicomponent reactions involving arynes, quinolines, and aldehydes

scientific article published on 28 August 2013

Multicomponent reactions involving phosphines, arynes and aldehydes

scientific article published on 01 October 2014

N-Heterocyclic Carbene Catalysis Exploiting Oxidative Imine Umpolung for the Generation of Imidoyl Azoliums

scientific article published on 20 March 2020

N-Heterocyclic Carbene-Catalyzed Enantioselective Synthesis of Spiro-glutarimides via α,β-Unsaturated Acylazoliums

scientific article published on 26 July 2018

N-Heterocyclic Carbene-Catalyzed Formal [6+2] Annulation Reaction via Cross-Conjugated Aza-Trienolate Intermediates

scientific article published on 23 December 2019

N-Heterocyclic Carbene-Catalyzed Michael-Michael-Lactonization Cascade for the Enantioselective Synthesis of Tricyclic δ-Lactones

scientific article published on 03 May 2018

N-Heterocyclic Carbene-Catalyzed Synthesis of α-Trifluoromethyl Esters

scientific article published on 13 June 2018

N-Heterocyclic carbene (NHC) organocatalysis using aliphatic aldehydes

scientific article published on 26 November 2020

N-Heterocyclic carbene-catalyzed diastereoselective synthesis of β-lactone-fused cyclopentanes using homoenolate annulation reaction

scientific article published on 01 June 2015

N-Heterocyclic carbene-catalyzed enantioselective synthesis of functionalized cyclopentenes via α,β-unsaturated acyl azoliums.

scientific article

N-Heterocyclic-Carbene-Catalyzed Umpolung of Imines.

scientific article

NHC-Catalyzed Generation of α,β-Unsaturated Acylazoliums for the Enantioselective Synthesis of Heterocycles and Carbocycles

scientific article published on 17 January 2019

NHC-Catalyzed [3 + 3] Annulation of Thioamides and Modified Enals for the Enantioselective Synthesis of Functionalized Thiazinones

scientific article published on 16 October 2019

NHC-catalyzed reaction of enals with hydroxy chalcones: diastereoselective synthesis of functionalized coumarins

scientific article published on 27 March 2013

Organocatalytic Enantioselective Vinylogous Michael-Aldol Cascade for the Synthesis of Spirocyclic Compounds.

scientific article published on 27 July 2017

Oxidative NHC-Catalysis for the Generation of Imidoyl Azoliums: Synthesis of Benzoxazoles

scientific article published on 08 November 2018

Practical synthesis of phthalimides and benzamides by a multicomponent reaction involving arynes, isocyanides, and CO2/H2O

scientific article published on 11 March 2014

Rapid access to benzoxaphospholes and their spiro analogues by a three-component coupling involving arynes, phosphines, and activated ketones

scientific article published on 12 September 2014

Reaction of N-heterocyclic carbenes with chalcones leading to the synthesis of deoxy-Breslow intermediates in their oxidized form

scientific article published on 01 September 2015

Recent Advances in the Organocatalytic Enantioselective Synthesis of Functionalized β-Lactones

scientific article published on 15 August 2018

Recent advances in N-heterocyclic carbene (NHC)-catalysed benzoin reactions

scientific article

Recent advances in employing homoenolates generated by N-heterocyclic carbene (NHC) catalysis in carbon-carbon bond-forming reactions.

scientific article published on 27 May 2015

Recent advances in transition-metal-free carbon-carbon and carbon-heteroatom bond-forming reactions using arynes.

scientific article published on 26 January 2012

Selective Synthesis of N-H and N-Aryl Benzotriazoles by the [3 + 2] Annulation of Sodium Azide with Arynes

scientific article published on 19 September 2019

Selective Synthesis of N-Unsubstituted and N-Arylindoles by the Reaction of Arynes with Azirines

scientific article published on 31 August 2016

Substrate-Controlled Selectivity Switch in the Three-Component Coupling Involving Arynes, Aromatic Tertiary Amines, and CO2.

scientific article

Synthesis of 2-Aryl Naphthoquinones by the Cross-Dehydrogenative Coupling Involving an NHC-Catalyzed endo-Stetter Reaction

scientific article published on 09 January 2019

Synthesis of 4-Difluoromethylquinolines by NHC-Catalyzed Umpolung of Imines.

scientific article published on 24 January 2018

Synthesis of 4H-chromenes by an unexpected, K3PO4-mediated intramolecular Rauhut-Currier type reaction.

scientific article published on 25 April 2016

Synthesis of Functionalized β-Keto Arylthioethers by the Aryne Induced [2,3] Stevens Rearrangement of Allylthioethers.

scientific article published on 28 March 2017

Synthesis of N-Aryl β-Amino Alcohols by Trifluoroacetic Acid Promoted Multicomponent Coupling of Aziridines, Arynes, and Water

scientific article published on 15 October 2015

Synthesis of functionalized amino epoxides by a three-component coupling involving aziridines, arynes and aldehydes

scientific article published on 01 July 2016

Synthesis of functionalized coumarins and quinolinones by NHC-catalyzed annulation of modified enals with heterocyclic C-H acids

scientific article published on 21 April 2014

Tandem [4 + 2]/[2 + 2] cycloaddition reactions involving indene or benzofurans and arynes

scientific article published on 25 June 2014

The Aryne [2,3] Stevens Rearrangement

scientific article published on 13 October 2016

Thiophenols as Protic Nucleophilic Triggers in Aryne Three-Component Coupling

scientific article published on 05 November 2020

Three-Component Aminoselenation of Arynes

scientific article published on 14 November 2019

Three-Component Coupling Involving Arynes, Aromatic Tertiary Amines, and Aldehydes via Aryl-Aryl Amino Group Migration

scientific article published on 10 December 2015

Transition-Metal-Free Thioamination of Arynes Using Sulfenamides

scientific article published on 16 January 2019

Transition-metal-free multicomponent reactions involving arynes, N-heterocycles, and isatins

scientific article published on 01 August 2013

Uncovering the Neglected Similarities of Arynes and Donor-Acceptor Cyclopropanes

scientific article published on 12 December 2019

[8+3]-Cycloaddition of Tropones with Azaoxyallyl Cations

scientific article published on 15 October 2019

List of works by Akkattu T Biju

A practical and general Diels-Alder reaction of pentafulvenes with arynes

Arynes in transition-metal-free multicomponent coupling reactions

Asymmetric N-heterocyclic carbene (NHC)-catalyzed annulation of modified enals with enolizable aldehydes

Base-Free and Catalyst-Free Synthesis of Functionalized Dihydrobenzoxazoles via Vinylogous Carbonate to Carbamate Rearrangement.

Catalytic, Enantioselective C2-Functionalization of 3-Aminobenzofurans Using N-Heterocyclic Carbenes

Diels-Alder reaction of tropones with arynes: synthesis of functionalized benzobicyclo[3.2.2]nonatrienones

Efficient Diels-Alder reaction of 1,2-benzoquinones with arynes and its utility in one-pot reactions

Efficient Synthesis of Benzofuranones: N-Heterocyclic Carbene (NHC)/Base-Catalyzed Hydroacylation–Stetter–Rearrangement Cascade

Efficient synthesis of 9-aryldihydrophenanthrenes by a cascade reaction involving arynes and styrenes

Efficient synthesis of γ-keto sulfones by NHC-catalyzed intermolecular Stetter reaction

Employing Arynes for the Generation of Aryl Anion Equivalents and Subsequent Reaction with Aldehydes

Employing Arynes in Diels-Alder Reactions and Transition-Metal-Free Multicomponent Coupling and Arylation Reactions

Employing arynes in transition-metal-free monoarylation of aromatic tertiary amines

Enantioselective Synthesis of Functionalized β-Lactones by NHC-Catalyzed Aldol Lactonization of Ketoacids.

Enantioselective Synthesis of Spirocyclohexadienones by NHC-Catalyzed Formal [3+3] Annulation Reaction of Enals

Enantioselective Synthesis of Tricyclic β-Lactones by NHC-Catalyzed Desymmetrization of Cyclic 1,3-Diketones

Enantioselective synthesis of functionalized pyrazoles by NHC-catalyzed reaction of pyrazolones with α,β-unsaturated aldehydes

Enantioselective synthesis of spiro γ-butyrolactones by N-heterocyclic carbene (NHC)-catalyzed formal [3 + 2] annulation of enals with 3-hydroxy oxindoles.

Facile synthesis of N-acyl 2-aminobenzothiazoles by NHC-catalyzed direct oxidative amidation of aldehydes.

Facile synthesis of γ-ketophosphonates by an intermolecular Stetter reaction onto vinylphosphonates

From insertion to multicomponent coupling: temperature dependent reactions of arynes with aliphatic alcohols

Imines as acceptors and donors in N-heterocyclic carbene (NHC) organocatalysis

Iodide as a Nucleophilic Trigger in Aryne Three-Component Coupling for the Synthesis of 2-Iodobenzyl Alcohols

Lewis Acid Catalyzed Ring-Opening 1,3-Aminothiolation of Donor-Acceptor Cyclopropanes Using Sulfenamides

Lewis Acid Catalyzed Selective Reactions of Donor-Acceptor Cyclopropanes with 2-Naphthols

Metal-Free, Brønsted Acid-Catalyzed Formal [3+2] Annulation of Quinone Monoacetals with 2-Naphthols

Multicomponent reactions involving arynes, quinolines, and aldehydes

Multicomponent reactions involving phosphines, arynes and aldehydes

N-Heterocyclic Carbene Catalysis Exploiting Oxidative Imine Umpolung for the Generation of Imidoyl Azoliums

N-Heterocyclic Carbene-Catalyzed Enantioselective Synthesis of Spiro-glutarimides via α,β-Unsaturated Acylazoliums

N-Heterocyclic Carbene-Catalyzed Formal [6+2] Annulation Reaction via Cross-Conjugated Aza-Trienolate Intermediates

N-Heterocyclic Carbene-Catalyzed Michael-Michael-Lactonization Cascade for the Enantioselective Synthesis of Tricyclic δ-Lactones

N-Heterocyclic Carbene-Catalyzed Synthesis of α-Trifluoromethyl Esters

N-Heterocyclic carbene (NHC) organocatalysis using aliphatic aldehydes

N-Heterocyclic carbene-catalyzed diastereoselective synthesis of β-lactone-fused cyclopentanes using homoenolate annulation reaction

N-Heterocyclic carbene-catalyzed enantioselective synthesis of functionalized cyclopentenes via α,β-unsaturated acyl azoliums.

N-Heterocyclic-Carbene-Catalyzed Umpolung of Imines.

NHC-Catalyzed Generation of α,β-Unsaturated Acylazoliums for the Enantioselective Synthesis of Heterocycles and Carbocycles

NHC-Catalyzed [3 + 3] Annulation of Thioamides and Modified Enals for the Enantioselective Synthesis of Functionalized Thiazinones

NHC-catalyzed reaction of enals with hydroxy chalcones: diastereoselective synthesis of functionalized coumarins

Organocatalytic Enantioselective Vinylogous Michael-Aldol Cascade for the Synthesis of Spirocyclic Compounds.

Oxidative NHC-Catalysis for the Generation of Imidoyl Azoliums: Synthesis of Benzoxazoles

Practical synthesis of phthalimides and benzamides by a multicomponent reaction involving arynes, isocyanides, and CO2/H2O

Rapid access to benzoxaphospholes and their spiro analogues by a three-component coupling involving arynes, phosphines, and activated ketones

Reaction of N-heterocyclic carbenes with chalcones leading to the synthesis of deoxy-Breslow intermediates in their oxidized form

Recent Advances in the Organocatalytic Enantioselective Synthesis of Functionalized β-Lactones

Recent advances in N-heterocyclic carbene (NHC)-catalysed benzoin reactions

Recent advances in employing homoenolates generated by N-heterocyclic carbene (NHC) catalysis in carbon-carbon bond-forming reactions.

Recent advances in transition-metal-free carbon-carbon and carbon-heteroatom bond-forming reactions using arynes.

Selective Synthesis of N-H and N-Aryl Benzotriazoles by the [3 + 2] Annulation of Sodium Azide with Arynes

Selective Synthesis of N-Unsubstituted and N-Arylindoles by the Reaction of Arynes with Azirines

Substrate-Controlled Selectivity Switch in the Three-Component Coupling Involving Arynes, Aromatic Tertiary Amines, and CO2.

Synthesis of 2-Aryl Naphthoquinones by the Cross-Dehydrogenative Coupling Involving an NHC-Catalyzed endo-Stetter Reaction

Synthesis of 4-Difluoromethylquinolines by NHC-Catalyzed Umpolung of Imines.

Synthesis of 4H-chromenes by an unexpected, K3PO4-mediated intramolecular Rauhut-Currier type reaction.

Synthesis of Functionalized β-Keto Arylthioethers by the Aryne Induced [2,3] Stevens Rearrangement of Allylthioethers.

Synthesis of N-Aryl β-Amino Alcohols by Trifluoroacetic Acid Promoted Multicomponent Coupling of Aziridines, Arynes, and Water

Synthesis of functionalized amino epoxides by a three-component coupling involving aziridines, arynes and aldehydes

Synthesis of functionalized coumarins and quinolinones by NHC-catalyzed annulation of modified enals with heterocyclic C-H acids

Tandem [4 + 2]/[2 + 2] cycloaddition reactions involving indene or benzofurans and arynes

The Aryne [2,3] Stevens Rearrangement

Thiophenols as Protic Nucleophilic Triggers in Aryne Three-Component Coupling

Three-Component Aminoselenation of Arynes

Three-Component Coupling Involving Arynes, Aromatic Tertiary Amines, and Aldehydes via Aryl-Aryl Amino Group Migration

Transition-Metal-Free Thioamination of Arynes Using Sulfenamides

Transition-metal-free multicomponent reactions involving arynes, N-heterocycles, and isatins

Uncovering the Neglected Similarities of Arynes and Donor-Acceptor Cyclopropanes

[8+3]-Cycloaddition of Tropones with Azaoxyallyl Cations