List of works - Rahul L Khade

A distonic radical-ion for detection of traces of adventitious molecular oxygen (O2) in collision gases used in tandem mass spectrometers.

scientific article published on 8 July 2014

Biocatalytic Strategy for Highly Diastereo- and Enantioselective Synthesis of 2,3-Dihydrobenzofuran-Based Tricyclic Scaffolds

scientific article published on 24 June 2019

Bisphosphonate-Generated ATP-Analogs Inhibit Cell Signaling Pathways.

scientific article

C-H Insertions by Iron Porphyrin Carbene: Basic Mechanism and Origin of Substrate Selectivity.

scientific article published on 25 October 2017

Catalytic Role of Conserved Asparagine, Glutamine, Serine, and Tyrosine Residues in Isoprenoid Biosynthesis Enzymes

scientific article published on 06 April 2018

Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand.

scientific article published on 16 June 2015

HNO-Binding in Heme Proteins: Effects of Iron Oxidation State, Axial Ligand, and Protein Environment.

scientific article published on 31 October 2016

Hydride Attack on a Coordinated Ferric Nitrosyl: Experimental and DFT Evidence for the Formation of a Heme Model-HNO Derivative

scientific article published on 17 December 2015

Inhibition of Aβ42 peptide aggregation by a binuclear ruthenium(II)-platinum(II) complex: Potential for multi-metal organometallics as anti-amyloid agents.

scientific article published on August 2010

Iron porphyrin carbenes as catalytic intermediates: structures, Mössbauer and NMR spectroscopic properties, and bonding

scientific article published on 6 June 2014

Isoprenoid biosynthesis: ferraoxetane or allyl anion mechanism for IspH catalysis?

scientific article published on 6 May 2013

Lewis Acid Activation of the Ferrous Heme-NO Fragment toward the N-N Coupling Reaction with NO To Generate N2O.

scientific article published on 4 March 2018

Mechanistic Investigation of Biocatalytic Heme Carbenoid Si-H Insertions

scientific article published on 08 May 2019

Not Limited to Iron: A Cobalt Heme-NO Model Facilitates N-N Coupling with External NO in the Presence of a Lewis Acid to Generate N2 O

scientific article published on 31 October 2019

Over or under: hydride attack at the metal versus the coordinated nitrosyl ligand in ferric nitrosyl porphyrins

scientific article published in November 2016

Solid-state ¹⁷O NMR spectroscopy of paramagnetic coordination compounds

scientific article published on 18 February 2015

Structural, EPR superhyperfine, and NMR hyperfine properties of the Cu-octarepeat binding site in the prion protein.