List of works by Gerard Roelfes

A "Broad Spectrum" Carbene Transferase for Synthesis of Chiral α-Trifluoromethylated Organoborons

scientific article published on 04 February 2019

A designer enzyme for hydrazone and oxime formation featuring an unnatural catalytic aniline residue

scientific article published on 02 July 2018

A metal ion regulated artificial metalloenzyme.

scientific article

Alkylidene malonates and α,β-unsaturated α'-hydroxyketones as practical substrates for vinylogous Friedel-Crafts alkylations in water catalysed by scandium(III) triflate/SDS

scientific article published on 01 March 2015

Alpha,beta-unsaturated 2-acyl imidazoles as a practical class of dienophiles for the DNA-based catalytic asymmetric Diels-Alder reaction in water

scientific article published on 09 August 2007

An Artificial Heme Enzyme for Cyclopropanation Reactions.

scientific article published on 2 May 2018

Artificial Metalloenzymes based on TetR Proteins and Cu(II) for Enantioselective Friedel-Crafts Alkylation Reactions

scientific article published on 29 April 2020

Artificial Metalloproteins for Binding and Stabilization of a Semiquinone Radical

scientific article published on 13 October 2017

Artificial metalloenzymes for enantioselective catalysis.

scientific article published on 05 March 2014

Asymmetric catalysis with helical polymers

scientific article published on 28 June 2011

Author Correction: A simple and versatile design concept for fluorophore derivatives with intramolecular photostabilization

scientific article published in Nature Communications

Bioorthogonal Metalloporphyrin-Catalyzed Selective Methionine Alkylation in the Lanthipeptide Nisin

scientific article published on 30 October 2018

Boron catalysis in a designer enzyme

scientific article published on 8 May 2024

Catalytic Modification of Dehydroalanine in Peptides and Proteins by Palladium-Mediated Cross-Coupling

scientific article published on 18 July 2018

Catalytic enantioselective syn hydration of enones in water using a DNA-based catalyst

scientific article published on 19 September 2010

Cationic iron porphyrins with sodium dodecyl sulphate for micellar catalysis of cyclopropanation reactions

scientific article published on 09 January 2020

Characterisation of the interactions between substrate, copper(II) complex and DNA and their role in rate acceleration in DNA-based asymmetric catalysis

scientific article published in February 2015

Chemical Modification of Dehydrated Amino Acids in Natural Antimicrobial Peptides by Photoredox Catalysis ⬇️

scientific article published on 10 July 2018

Control over enzymatic activity by DNA-directed split enzyme reassembly.

scientific article published on November 2010

Corrigendum: A simple and versatile design concept for fluorophore derivatives with intramolecular photostabilization.

scientific article published on 4 August 2017

Corrigendum: A simple and versatile design concept for fluorophore derivatives with intramolecular photostabilization.

scientific article published on 16 November 2017

Cu(ii)-Catalysed β-silylation of dehydroalanine residues in peptides and proteins

scientific article published on 19 August 2020

DNA and RNA induced enantioselectivity in chemical synthesis.

scientific article published on 5 December 2006

DNA cleavage activity of Fe(II)N4Py under photo irradiation in the presence of 1,8-naphthalimide and 9-aminoacridine: unexpected effects of reactive oxygen species scavengers.

scientific article published on 22 July 2011

DNA-Accelerated Catalysis of Carbene-Transfer Reactions by a DNA/Cationic Iron Porphyrin Hybrid

scientific article published on 12 October 2016

DNA-Accelerated Copper Catalysis of Friedel-Crafts Conjugate Addition/Enantioselective Protonation Reactions in Water

scientific article published on 06 December 2016

DNA-based asymmetric catalysis

scientific article published on 21 April 2010

DNA-based catalytic enantioselective intermolecular oxa-Michael addition reactions

scientific article published on 22 May 2012

DNA-based hybrid catalysis.

scientific article published on 08 January 2015

Design and synthesis of ATP-based nucleotide analogues and profiling of nucleotide-binding proteins

scientific article published on 30 June 2011

Design of an enantioselective artificial metallo-hydratase enzyme containing an unnatural metal-binding amino acid.

scientific article published on 4 September 2017

Directed Evolution of a Designer Enzyme Featuring an Unnatural Catalytic Amino Acid

scientific article published on 14 January 2019

Dramatic micellar rate enhancement of the Cu2+ catalyzed vinologous Friedel–Crafts alkylation in water ⬇️

scientific article published on September 8, 2010

Efficient nuclear DNA cleavage in human cancer cells by synthetic bleomycin mimics.

scientific article published on 26 February 2014

Enantioselective Artificial Metalloenzymes by Creation of a Novel Active Site at the Protein Dimer Interface

scientific article published on 15 June 2012

Enantioselective Friedel-Crafts reactions in water using a DNA-based catalyst

scientific article published on 01 January 2009

Enantioselective artificial metalloenzymes based on a bovine pancreatic polypeptide scaffold

scientific article published on 01 January 2009

End-On and Side-On Peroxo Derivatives of Non-Heme Iron Complexes with Pentadentate Ligands: Models for Putative Intermediates in Biological Iron/Dioxygen Chemistry ⬇️

scientific article published on April 21, 2003

Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(iv)O species

scientific article published on 14 October 2004

Folic acid conjugates of a bleomycin mimic for selective targeting of folate receptor positive cancer cells

scientific article published on 24 May 2019

Hierarchical Self-Assembly of a Biomimetic Light-Harvesting Antenna Based on DNA G-Quadruplexes

scientific article published on 27 December 2012

Highly enantioselective DNA-based catalysis

scientific article published on 06 January 2006

Impact of binding to the multidrug resistance regulator protein LmrR on the photo-physics and -chemistry of photosensitizers

scientific article published on 20 May 2020

Importance of Metal-Ion Exchange for the Biological Activity of Coordination Complexes of the Biomimetic Ligand N4Py.

scientific article

Ligand denticity controls enantiomeric preference in DNA-based asymmetric catalysis

scientific article published on 23 January 2012

LmrR: A Privileged Scaffold for Artificial Metalloenzymes

scientific article published on 22 February 2019

Mechanism of intramolecular photostabilization in self-healing cyanine fluorophores.

scientific article

Modular assembly of novel DNA-based catalysts

scientific article published on 14 October 2008

Multidrug resistance regulators (MDRs) as scaffolds for the design of artificial metalloenzymes.

scientific article

Novel artificial metalloenzymes by in vivo incorporation of metal-binding unnatural amino acids.

scientific article published on 9 October 2014

Organic co-solvents in aqueous DNA-based asymmetric catalysis

scientific article published on 15 January 2010

Photo-induced oxidation of [Fe(II)(N4Py)CH3CN] and related complexes.

scientific article published in November 2012

Photoenhanced oxidative DNA cleavage with non-heme iron(II) complexes.

scientific article

Probing the molecular basis of protein function through chemistry

scientific article published on 01 March 2006

Protein engineering: The power of four.

scientific article published in April 2015

Responsive DNA G-quadruplex micelles.

scientific article published on 12 December 2017

Selective Modification of Ribosomally Synthesized and Post-Translationally Modified Peptides (RiPPs) through Diels-Alder Cycloadditions on Dehydroalanine Residues

scientific article published on 09 September 2019

Selective chemical modification of DNA with alkoxy- and benzyloxyamines

scientific article published on 07 May 2015

Selenoglutaredoxin as a glutathione peroxidase mimic.

scientific article published in July 2008

Supramolecular Assembly of Artificial Metalloenzymes Based on the Dimeric Protein LmrR as Promiscuous Scaffold

scientific article published on 04 August 2015

Targeting Nrf2 in healthy and malignant ovarian epithelial cells: Protection versus promotion.

scientific article published on 19 March 2015

The Power of Two: Covalent Coupling of Photostabilizers for Fluorescence Applications

scientific article published on 17 October 2014

The frontiers of organic chemistry at the Bürgenstock conference

scientific article published on 01 January 2009

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