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List of works by Thomas Paul Spaniol

1,4-Dihydropyridyl complexes of magnesium: synthesis by pyridine insertion into the magnesium-silicon bond of triphenylsilyls and catalytic pyridine hydrofunctionalization

scientific article published on 01 September 2018

A Dimetalloxycarbene Bonding Mode and Reductive Coupling Mechanism for Oxalate Formation from CO2

scientific article published on 25 June 2015

A Masked Cuprous Hydride as a Catalyst for Carbonyl Hydrosilylation in Aqueous Solutions

scientific article published on 03 January 2019

A cationic calcium hydride cluster stabilized by cyclen-derived macrocyclic N,N,N,N ligands

scientific article published on 23 March 2012

A cationic zinc hydride cluster stabilized by an N-heterocyclic carbene: synthesis, reactivity, and hydrosilylation catalysis

scientific article published on 24 September 2014

Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M = Li, Na, K): Chemoselective Catalysts for Carbonyl and CO2 Hydroboration.

scientific article published on 16 August 2016

Alkaline earth metal complexes of a chiral polyether as initiator for the ring-opening polymerization of lactide

scientific article published on 01 October 2012

Allyl complexes of scandium: synthesis and structure of neutral, cationic and anionic derivatives

scientific article published on 23 September 2011

Allyl strontium compounds: synthesis, molecular structure and properties

scientific article published on 12 June 2012

An ion pair scandium hydride supported by a dianionic (NNNN)-type macrocycle ligand

scientific article published on 01 January 2014

Ancillary Ligand Effect on Single-Site Styrene Polymerization: Isospecificity of Group 4 Metal Bis(phenolate) Catalysts ⬇️

scientific article published on April 30, 2003

Bis(allyl)calcium

scientific article (publication date: 20 July 2009)

Bis(allyl)gallium Cation, Tris(allyl)gallium, and Tetrakis(allyl)gallate: Synthesis, Characterization, and Reactivity

scientific article published on 23 January 2012

Bis(allyl)zinc Revisited: Sigma versus Pi Bonding of Allyl Coordination

scientific article published on 30 May 2012

Calcium Hydride Cation [CaH]+ Stabilized by an NNNN-type Macrocyclic Ligand: A Selective Catalyst for Olefin Hydrogenation.

scientific article

Calcium-mediated dearomatization, C-H bond activation, and allylation of alkylated and benzannulated pyridine derivatives

scientific article published on 09 September 2011

Cationic magnesium hydride [MgH]+ stabilized by an NNNN-type macrocycle

scientific article published on 25 February 2019

Cationic methyl complexes of the rare-earth metals: an experimental and computational study on synthesis, structure, and reactivity.

scientific article published on 25 September 2008

Cationic yttrium methyl complexes as functional models for polymerization catalysts of 1,3-dienes

scientific article published on 01 December 2005

Cationic zirconium hydrides supported by an NNNN-type macrocyclic ligand: synthesis, structure, and reactivity

scientific article published on 31 October 2012

Cationic, Neutral, and Anionic Allyl Magnesium Compounds: Unprecedented Ligand Conformations and Reactivity Toward Unsaturated Hydrocarbons

scientific article published on 31 December 2012

Construction of a hybrid biocatalyst containing a covalently-linked terpyridine metal complex within a cavity of aponitrobindin

scientific article published on 2 January 2016

Crown ether adducts of light alkali metal triphenylsilyls: synthesis, structure and hydrosilylation catalysis

scientific article published on 01 October 2014

Dehydrogenation of amine-borane Me2NH·BH3 catalyzed by a lanthanum-hydride complex

scientific article published on 14 August 2013

Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex

scientific article published on 01 October 2018

Dihydrogen addition in a dinuclear rare-earth metal hydride complex supported by a metalated TREN ligand

scientific article published on 18 October 2011

Dimerization of the Allylzinc Cation: Selective Coupling of Allyl Anions in a Metallo-Ene Reaction

scientific article published on 03 July 2012

Dinuclear zinc hydride supported by an anionic bis(N-heterocyclic carbene) ligand

scientific article published on 01 February 2014

Discrete magnesium hydride aggregates: a cationic Mg13H18 cluster stabilized by NNNN-type macrocycles

scientific article published on 04 February 2015

Enantiomerically pure titanium complexes containing an [OSSO]-type bis(phenolate) ligand: synthesis, structure, and formation of optically active oligostyrenes.

scientific article published in September 2008

Facile ring-opening of THF at a lithium center induced by a pendant Si-H bond and BPh3

scientific article published on 01 June 2017

Formate complexes of titanium(iv) supported by a triamido-amine ligand.

scientific article published on 12 February 2018

Formation and Reactivity of a Molecular Magnesium Hydride with a Terminal Mg-H Bond.

scientific article

Formation of a Cationic Calcium Hydride Cluster with a "Naked" Triphenylsilyl Anion by Hydrogenolysis of Bis(triphenylsilyl)calcium.

scientific article published in May 2015

Formation of α-[KSiH3] by hydrogenolysis of potassium triphenylsilyl

scientific article published on 24 August 2015

Group 2 metal (Mg, Ca, Sr) silylamides supported by a cyclen-derived macrocyclic polyamine

scientific article published on 01 July 2017

Group 3 metal initiators with an [OSSO]-type bis(phenolate) ligand for the stereoselective polymerization of lactide monomers.

scientific article

Highly heteroselective ring-opening polymerization of rac-lactide initiated by bis(phenolato)scandium complexes

scientific article published on 01 November 2006

Homogeneous ethylene-polymerization catalysts based on alkyl cations of the rare-earth metals: are dicationic mono(alkyl) complexes the active species?

scientific article published on 01 October 2003

Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium

scientific article published on 21 January 2014

Hypervalent Hydrosilicates Connected to Light Alkali Metal Amides: Synthesis, Structure, and Hydrosilylation Catalysis

scientific article published on 19 August 2018

Insertion of pyridine into the calcium allyl bond: regioselective 1,4-dihydropyridine formation and C-H bond activation.

scientific article published on October 2010

Lanthanide Complexes Supported by a Trizinc-crown Ether as Catalysts for Alternating Copolymerization of Epoxide and CO₂: Telomerization Controlled by Carboxylate Anions.

scientific article published on 2 January 2018

Lanthanum complexes containing a bis(phenolate) ligand with a ferrocene-1,1'-diyldithio backbone: synthesis, characterization, and ring-opening polymerization of rac-lactide

scientific article published in May 2016

Ligand Influence on Carbonyl Hydroboration Catalysis by Alkali Metal Hydridotriphenylborates [(L)M][HBPh3 ] (M=Li, Na, K).

scientific article published on 11 August 2017

Lutetium alkyl and hydride complexes in a non-cyclopentadienyl coordination environment

scientific article published on 02 August 2007

Magnesium hydridotriphenylborate [Mg(thf)6][HBPh3]2: a versatile hydroboration catalyst

scientific article

Molecular Calcium Hydride: Dicalcium Trihydride Cation Stabilized by a Neutral NNNN-Type Macrocyclic Ligand

scientific article published on 08 March 2016

Molecular hydrides of divalent ytterbium supported by a macrocyclic ligand: synthesis, structure and olefin hydrofunctionalization catalysis

scientific article published on 01 October 2018

Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand.

scientific article published on 25 January 2017

Molecular zinc dihydride stabilized by N-heterocyclic carbenes.

scientific article

Mononuclear Alkali Metal Organoperoxides Stabilized by an NNNN-Macrocycle and Short Hydrogen Bonds from ROOH Molecules.

scientific article

Neutral and cationic aluminium complexes containing a chiral (OSSO)-type bis(phenolato) ligand: synthesis, structures and polymerization activity.

scientific article published on 25 August 2009

Olefin hydrosilylation catalysts based on allyl bis(phenolato) complexes of the early lanthanides

scientific article published on 12 November 2010

Polymerization of norbornene using chiral bis(phenolate) zirconium catalysts

scientific article published on 30 September 2014

Rare-earth metal allyl and hydrido complexes supported by an (NNNN)-type macrocyclic ligand: synthesis, structure, and reactivity toward biomass-derived furanics

scientific article published on 01 December 2011

Rare-earth metal complexes supported by 1,omega-dithiaalkanediyl-bridged bis(phenolato) ligands: synthesis, structure, and heteroselective ring-opening polymerization of rac-lactide.

scientific article published on 4 March 2008

Reactivity of a Molecular Magnesium Hydride Featuring a Terminal Magnesium-Hydrogen Bond

scientific article

Reversible 1,4-Insertion of Pyridine Into a Highly Polar Metal-Carbon Bond: Effect of the Second Metal

scientific article published on 19 April 2012

Reversible dihydrogen activation in cationic rare-earth-metal polyhydride complexes

scientific article published on 21 June 2013

Ring-opening of cyclic ethers by aluminum hydridotriphenylborate

scientific article published on 10 March 2017

Selective α-metalation of THF by a cationic zirconium complex supported by an (NNNN)-type macrocyclic ligand.

scientific article published on 10 June 2013

Silyl-Hydrosilane Exchange at a Magnesium Triphenylsilyl Complex Supported by a Cyclen-Derived NNNN-Type Macrocyclic Ligand

scientific article published in December 2017

Stereospecific styrene enchainment at a titanium site within a helical ligand framework: evidence for the formation of homochiral polystyrene

scientific article published on 01 January 2007

Synthesis, Characterization, and Lactide Polymerization Activity of Group 4 Metal Complexes Containing Two Bis(phenolate) Ligands ⬇️

scientific article published on May 9, 2012

Synthesis, structure and hydrosilylation activity of neutral and cationic rare-earth metal silanolate complexes.

scientific article published on 6 December 2005

The Allylcalcium Monocation: A Bridging Allyl Ligand with a Non-Bent Coordination Geometry

scientific article (publication date: 12 May 2011)

The Bis(allyl)bismuth Cation: A Reagent for Direct Allyl Transfer by Lewis Acid Activation and Controlled Radical Polymerization

scientific article published on 14 November 2012

The Nature of the Heavy Alkaline Earth Metal-Hydrogen Bond: Synthesis, Structure, and Reactivity of a Cationic Strontium Hydride Cluster

scientific article published on 7 February 2018

The effect of bulk magnetic susceptibility on solid state NMR spectra of paramagnetic compounds

scientific article published on 01 August 1998

Titanium Carbene Complexes Stabilized by Alkali Metal Amides

scientific article published on 03 January 2019

Titanium(IV) Cations with Trigonal Monopyramidal Geometry: Unusual Lewis Acids Supported by a Triaryl Triamidoamine Ligand

scientific article published on 18 July 2019

Trimethylsilylmethyl complexes of the rare-earth metals with sterically hindered N-heterocyclic carbene ligands: adduct formation and C-H bond activation.

scientific article published on 28 April 2010

Tris(allyl) indium compounds: synthesis and structural characterization

scientific article published on 24 March 2011

Unexpected alkane elimination from cationic group 13 dialkyls in a reaction with a macrocyclic polyamine.

scientific article

Zinc hydridotriphenylborates supported by a neutral macrocyclic polyamine

scientific article published on 01 May 2017

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