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List of works by Gary A. Molander

(1)H, (13)C, (19)F and (11)B NMR spectral reference data of some potassium organotrifluoroborates

scientific article published in October 2009

1,4-Dihydropyridines as Alkyl Radical Precursors: Introducing the Aldehyde Feedstock to Nickel/Photoredox Dual Catalysis

scientific article published on 27 October 2016

A convergent, modular approach to functionalized 2,1-borazaronaphthalenes from 2-aminostyrenes and potassium organotrifluoroborates

scientific article

A facile one-pot preparation of potassium hydroxyaryl- and (hydroxyalkyl)aryltrifluoroborates.

scientific article published on 23 February 2008

A general route toward the synthesis of the cladiellin skeleton utilizing a SmI2-mediated cyclization

scientific article published on February 2006

A modified procedure for the palladium catalyzed borylation/Suzuki-Miyaura cross-coupling of aryl and heteroaryl halides utilizing bis-boronic acid

scientific article published in September 2015

Accessing 2,1-borazaronaphthols: self-arylation of 1-alkyl-2-aryl-3-bromo-2,1-borazaronaphthalenes

scientific article published on 18 August 2014

Accessing 2-(hetero)arylmethyl-, -allyl-, and -propargyl-2,1-borazaronaphthalenes: palladium-catalyzed cross-couplings of 2-(chloromethyl)-2,1-borazaronaphthalenes

scientific article

Accessing Elaborated 2,1-Borazaronaphthalene Cores Using Photoredox/Nickel Dual-Catalytic Functionalization

scientific article published on 17 March 2016

Accessing an azaborine building block: synthesis and substitution reactions of 2-chloromethyl-2,1-borazaronaphthalene

scientific article published on 15 October 2014

Accessing molecularly complex azaborines: palladium-catalyzed Suzuki-Miyaura cross-couplings of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates

scientific article

Accurate mass determination of organotrifluoroborates

scientific article published on 16 November 2006

Activation of Si-Si Bonds for Copper(I)-Catalyzed Conjugate Silylation

scientific article

Amide-forming ligation of acyltrifluoroborates and hydroxylamines in water

scientific article published on 26 April 2012

Aminomethylation of Aryl Halides using α-Silylamines Enabled by Ni/Photoredox Dual Catalysis

scientific article published on 16 August 2017

Aminomethylations via cross-coupling of potassium organotrifluoroborates with aryl bromides

scientific article published on 17 March 2007

Application of lanthanide reagents in organic synthesis

article

Arylation and heteroarylation of thienylsulfonamides with organotrifluoroborates

scientific article published on 14 July 2014

B-Alkyl Suzuki−Miyaura Cross-Coupling Reactions with Air-Stable Potassium Alkyltrifluoroborates

scientific article published on 01 July 2003

Base-Free Photoredox/Nickel Dual-Catalytic Cross-Coupling of Ammonium Alkylsilicates

scientific article

Beta-aminoethyltrifluoroborates: efficient aminoethylations via Suzuki-Miyaura cross-coupling

scientific article published on January 2007

C(sp3)-C(sp2) cross-coupling of alkylsilicates with borylated aryl bromides - an iterative platform to alkylated aryl- and heteroaryl boronates

scientific article published on 9 September 2016

Carbonylative Suzuki couplings of aryl bromides with boronic acid derivatives under base-free conditions

scientific article published on 17 March 2014

Complementary regioselectivity in Rh(III)-catalyzed insertions of potassium vinyltrifluoroborate via C-H activation: preparation and use of 4-trifluoroboratotetrahydroisoquinolones

scientific article published on 15 March 2013

Condensation reactions to form oxazoline-substituted potassium organotrifluoroborates

scientific article

Construction of Bicyclic Ring Systems via a Transannular SmI2-Mediated Ketone−Olefin Cyclization Strategy

scientific article (publication date: March 2007)

Copper(II)-mediated O-arylation of protected serines and threonines

scientific article published on 10 September 2014

Copper-Catalyzed β-Boration of α,β-Unsaturated Carbonyl Compounds with Tetrahydroxydiborane

scientific article published on August 5, 2011

Copper-mediated N-Arylation of Methyl 2-Aminothiophene-3-carboxylate with Organoboron Reagents

scientific article

Copper-mediated radical trifluoromethylation of unsaturated potassium organotrifluoroborates

scientific article published on 19 November 2013

Correction to "Engaging Alkenyl Halides with Alkylsilicates via Photoredox Dual Catalysis".

scientific article published on 15 March 2016

Cross-Coupling of Mesylated Phenol Derivatives with Potassium Ammonio- and Amidomethyltrifluoroborates

scientific article published on February 4, 2011

Cross-Coupling of Mesylated Phenol Derivatives with Potassium Cyclopropyltrifluoroborate

scientific article published on September 2, 2011

Cross-coupling of cyclopropyl- and cyclobutyltrifluoroborates with aryl and heteroaryl chlorides

scientific article published on 30 August 2008

Cross-coupling of mesylated phenol derivatives with potassium alkoxymethyltrifluoroborates

scientific article

Direct Alkylation of Heteroaryls Using Potassium Alkyl- and Alkoxymethyltrifluoroborates

scientific article published on March 10, 2011

Direct Conversion of Carboxylic Acids to Alkyl Ketones.

scientific article

Direct Synthesis of Secondary Benzylic Alcohols Enabled by Photoredox/Ni Dual-Catalyzed Cross-Coupling

scientific article published on 27 November 2017

Direct α-Arylation/Heteroarylation of 2-Trifluoroboratochromanones via Photoredox/Nickel Dual Catalysis.

scientific article published on 12 January 2017

Dual catalysis. Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

scientific article published on 5 June 2014

Efficient cross-coupling of secondary alkyltrifluoroborates with aryl chlorides--reaction discovery using parallel microscale experimentation

scientific article

Efficient hydrolysis of organotrifluoroborates via silica gel and water

scientific article published on October 2009

Efficient ligandless palladium-catalyzed Suzuki reactions of potassium aryltrifluoroborates.

scientific article published in May 2002

Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer

scientific article

Engaging Alkenyl Halides with Alkylsilicates via Photoredox Dual Catalysis

scientific article

Expanding organoboron chemistry: epoxidation of potassium organotrifluoroborates

scientific article

Facile synthesis of highly functionalized ethyltrifluoroborates

scientific article published on 28 June 2008

Formal total synthesis of oximidine II via a Suzuki-type cross-coupling macrocyclization employing potassium organotrifluoroborates

scientific article

Functionalization of organotrifluoroborates: reductive amination

scientific article published on 16 April 2008

Haloselective Cross-Coupling via Ni/Photoredox Dual Catalysis

scientific article published on 7 July 2017

Highly stereoselective synthesis of cis-alkenyl pinacolboronates and potassium cis-alkenyltrifluoroborates via a hydroboration/protodeboronation approach

scientific article

Iridium‐Catalyzed Allylic Amination Route to α‐Aminoboronates: Illustration of the Decisive Role of Boron Substituents

scientific article published on December 1, 2011

Lanthanides in organic synthesis. 2. Reduction of .alpha.-heterosubstituted ketones

article

Lanthanides in organic synthesis. 4. Reduction of .alpha.,.beta.-epoxy ketones with samarium diiodide. A route to chiral, nonracemic aldols

article

Lanthanocene catalysts in selective organic synthesis

scientific article

Linchpin synthons: metalation of aryl bromides bearing a potassium trifluoroborate moiety

scientific article published on September 2006

Metal-Free Chlorodeboronation of Organotrifluoroborates

scientific article published on August 3, 2011

Method for Accessing Nitrogen-Containing, B-Heteroaryl-Substituted 2,1-Borazaronaphthalenes

scientific article published on 14 December 2016

Mild, Redox-Neutral Alkylation of Imines Enabled by an Organic Photocatalyst

scientific article published on 6 February 2017

Nickel-Catalyzed Cross-Coupling of Potassium Aryl- and Heteroaryltrifluoroborates with Unactivated Alkyl Halides

scientific article published on November 19, 2010

Nickel-catalyzed C-O activation of phenol derivatives with potassium heteroaryltrifluoroborates

scientific article

Nickel-catalyzed borylation of halides and pseudohalides with tetrahydroxydiboron [B2(OH)4]

scientific article published on 18 June 2013

Nickel-catalyzed cross-coupling of photoredox-generated radicals: uncovering a general manifold for stereoconvergence in nickel-catalyzed cross-couplings

scientific article

Nickel/Photoredox-Catalyzed Amidation via Alkylsilicates and Isocyanates

scientific article published on 25 October 2017

Nitrosation of aryl and heteroaryltrifluoroborates with nitrosonium tetrafluoroborate

scientific article published on 24 April 2012

O-Benzyl Xanthate Esters under Ni/Photoredox Dual Catalysis: Selective Radical Generation and Csp3-Csp2 Cross-Coupling

scientific article published on 9 May 2017

One-pot synthesis of trisubstituted conjugated dienes via sequential Suzuki-Miyaura cross-coupling with alkenyl- and alkyltrifluoroborates

scientific article

Organocatalyzed, Photoredox Heteroarylation of 2-Trifluoroboratochromanones via C-H Functionalization

scientific article

Organotrifluoroborates and monocoordinated palladium complexes as catalysts--a perfect combination for Suzuki-Miyaura coupling

scientific article

Organotrifluoroborates: Another Branch of the Mighty Oak.

scientific article published on 7 July 2015

Organotrifluoroborates: protected boronic acids that expand the versatility of the Suzuki coupling reaction

scientific article

Orthogonal reactivity in boryl-substituted organotrifluoroborates

scientific article published in November 2008

Oxidation of Organotrifluoroborates via Oxone

scientific article published on December 30, 2010

Oxidative Condensations To Form Benzimidazole-Substituted Potassium Organotrifluoroborates

scientific article published on August 8, 2012

Ozonolysis of unsaturated organotrifluoroborates

scientific article published on 5 April 2007

Palladium(0)-catalyzed synthesis of chiral ene-allenes using alkenyl trifluoroborates

scientific article published on February 2006

Palladium-Catalyzed Borylation of Aryl and Heteroaryl Halides Utilizing Tetrakis(dimethylamino)diboron: One Step Greener

scientific article published on September 4, 2012

Palladium-Catalyzed Hiyama Cross-Coupling of Aryltrifluorosilanes with Aryl and Heteroaryl Chlorides

scientific article published on October 6, 2011

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions of Enantiomerically Enriched Potassium β-Trifluoroboratoamides with Various Aryl- and Hetaryl Chlorides

scientific article published on October 1, 2010

Palladium-Catalyzed, Direct Boronic Acid Synthesis from Aryl Chlorides: A Simplified Route to Diverse Boronate Ester Derivatives

scientific article published on November 24, 2010

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of potassium aryl- and heteroaryltrifluoroborates

scientific article

Palladium-catalyzed cross-alkynylation of aryl bromides by sodium tetraalkynylaluminates.

scientific article published in September 2002

Palladium-catalyzed cross-coupling reaction of alkenyl bromides with potassium alkyltrifluoroborates

scientific article published on January 2007

Palladium-catalyzed α-arylation of 2-chloroacetates and 2-chloroacetamides

scientific article published on 9 April 2013

Pd-catalyzed Suzuki-Miyaura cross-coupling reactions between sulfamates and potassium Boc-protected aminomethyltrifluoroborates

scientific article published on 6 May 2013

Pd-catalyzed aldehyde to ester conversion: a hydrogen transfer approach

scientific article published on 15 January 2013

Pd-catalyzed alkynylation of 2-chloroacetates and 2-chloroacetamides with potassium alkynyltrifluoroborates

scientific article published on 16 September 2013

Pd-catalyzed cross-coupling of potassium alkenyltrifluoroborates with 2-chloroacetates and 2-chloroacetamides

scientific article published on 14 June 2013

Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis

scientific article published on 3 June 2016

Photochemical Nickel-Catalyzed C-H Arylation: Synthetic Scope and Mechanistic Investigations

scientific article published on 21 September 2016

Photoredox Catalysis in Nickel-Catalyzed Cross-Coupling

scientific article

Photoredox Cross-Coupling: Ir/Ni Dual Catalysis for the Synthesis of Benzylic Ethers

scientific article published on 16 June 2015

Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development

scientific article

Potassium Boc-Protected Secondary Aminomethyltrifluoroborates: Synthesis and Suzuki–Miyaura Cross-Coupling Reactions

scientific article published on August 29, 2012

Potassium trifluoroborate salts as convenient, stable reagents for difficult alkyl transfers

scientific article

Preparation and wittig reactions of organotrifluoroborato phosphonium ylides

scientific article published on 6 February 2007

Preparation of Diisopropylammonium Bis(catecholato)cyclohexylsilicate

scientific article published in January 2017

Preparation of potassium alkoxymethyltrifluoroborates and their cross-coupling with aryl chlorides

scientific article published on 26 April 2008

Preparation of potassium azidoaryltrifluoroborates and their cross-coupling with aryl halides

scientific article published on October 2009

Protecting group-free, selective cross-coupling of alkyltrifluoroborates with borylated aryl bromides via photoredox/nickel dual catalysis

scientific article published on 14 September 2015

Rapid and Efficient Access to Secondary Arylmethylamines

scientific article published on July 5, 2012

Reductions with Samarium(II) Iodide

article

Reductive cross-coupling of 3-bromo-2,1-borazaronaphthalenes with alkyl iodides

scientific article published on 30 June 2014

Reinvestigation of Aminomethyltrifluoroborates and Their Application in Suzuki−Miyaura Cross-Coupling Reactions

scientific article published on March 15, 2011

Samarium(II) Iodide

scientific article by Gary A. Molander and André Charette

Samarium(II) iodide-induced reductive cyclization of unactivated olefinic ketones. Sequential radical cyclization/intermolecular nucleophilic addition and substitution reactions

article

Samarium(II) iodide-mediated intramolecular conjugate additions of alpha,beta-unsaturated lactones

scientific article published on 01 May 2002

Scope of aminomethylations via Suzuki-Miyaura cross-coupling of organotrifluoroborates

scientific article

Scope of the Palladium-Catalyzed Aryl Borylation Utilizing Bis-Boronic Acid

scientific article published on July 6, 2012

Scope of the Suzuki-Miyaura cross-coupling reaction of potassium trifluoroboratoketohomoenolates

scientific article published on February 2009

Scope of the Suzuki-Miyaura cross-coupling reactions of potassium heteroaryltrifluoroborates

scientific article published on February 2009

Scope of the two-step, one-pot palladium-catalyzed borylation/Suzuki cross-coupling reaction utilizing bis-boronic acid

scientific article published on 20 September 2012

Sequenced reactions with samarium(II) iodide. Sequential intramolecular Reformatsky/nucleophilic acyl substitution reactions for the synthesis of medium-sized carbocycles

scientific article published on 01 May 2002

Sequencing Reactions with Samarium(II) Iodide

scientific article

Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp(3)-sp(2) Cross-Coupling

scientific article published on 5 July 2016

Single-Electron Transmetalation: Protecting-Group-Independent Synthesis of Secondary Benzylic Alcohol Derivatives via Photoredox/Nickel Dual Catalysis

scientific article published on 24 May 2016

Single-electron transmetalation: an enabling technology for secondary alkylboron cross-coupling

scientific article published on 4 February 2015

Stereospecific Cross-Coupling of Secondary Alkyl β-Trifluoroboratoamides

scientific article published on November 15, 2010

Stereospecific Cross-Coupling of Secondary Organotrifluoroborates: Potassium 1-(Benzyloxy)alkyltrifluoroborates

scientific article published on October 10, 2012

Stereospecific Ni-catalyzed cross-coupling of potassium alkenyltrifluoroborates with alkyl halides

scientific article

Suzuki Coupling of Potassium Cyclopropyl- and Alkoxymethyltrifluoroborates with Benzyl Chlorides

scientific article published on March 6, 2012

Suzuki-Miyaura cross-coupling of brominated 2,1-borazaronaphthalenes with potassium alkenyltrifluoroborates

scientific article published on 30 October 2014

Suzuki-Miyaura cross-coupling of potassium dioxolanylethyltrifluoroborate and aryl/heteroaryl chlorides

scientific article published on 14 March 2013

Suzuki-Miyaura cross-coupling of potassium trifluoro(N-methylheteroaryl)borates with aryl and heteroaryl halides

scientific article published on 25 June 2013

Suzuki-Miyaura cross-coupling reactions of benzyl halides with potassium aryltrifluoroborates

scientific article

Suzuki-Miyaura cross-coupling reactions of potassium Boc-protected aminomethyltrifluoroborate with aryl and hetaryl mesylates

scientific article

Suzuki-Miyaura cross-coupling reactions of potassium vinyltrifluoroborate with aryl and heteroaryl electrophiles

scientific article published on December 2006

Suzuki-Miyaura cross-coupling reactions of primary alkyltrifluoroborates with aryl chlorides

scientific article published on May 2009

Suzuki–Miyaura Cross-Coupling of Potassium Alkoxyethyltrifluoroborates: Access to Aryl/Heteroarylethyloxy Motifs

scientific article published on November 6, 2012

Synergistic Photoredox/Nickel Coupling of Acyl Chlorides with Secondary Alkyltrifluoroborates: Dialkyl Ketone Synthesis

scientific article published on 17 January 2017

Synergistic Visible-Light Photoredox/Nickel-Catalyzed Synthesis of Aliphatic Ketones via N-C Cleavage of Imides

scientific article published on 26 April 2017

Synthesis and Cross-Coupling of Sulfonamidomethyltrifluoroborates

scientific article published on March 2, 2011

Synthesis and Reactivity of Solid-Supported Organotrifluoroborates in Suzuki Cross-Coupling

scientific article published on March 9, 2012

Synthesis and Suzuki-Miyaura Cross-Coupling of Enantioenriched Secondary Potassium β-Trifluoroboratoamides: Catalytic, Asymmetric Conjugate Addition of Bisboronic Acid and Tetrakis(dimethylamino)diboron to α,β-Unsaturated Carbonyl Compounds

scientific article published on October 2013

Synthesis and Suzuki–Miyaura Cross-Coupling Reactions of Potassium Boc-Protected Aminomethyltrifluoroborate with Aryl and Hetaryl Halides

scientific article published on July 6, 2011

Synthesis and application of chiral cyclopropane-based ligands in palladium-catalyzed allylic alkylation

scientific article published in November 2004

Synthesis and applications of α-trifluoromethylated alkylboron compounds

scientific article published on 7 November 2013

Synthesis and cross-coupling reactions of imidomethyltrifluoroborates with aryl chlorides

scientific article published on February 29, 2012

Synthesis and minisci reactions of organotrifluoroborato building blocks

scientific article published on 17 April 2013

Synthesis of Functionalized 1,3,2-Benzodiazaborole Cores Using Bench-Stable Components

scientific article

Synthesis of amidomethyltrifluoroborates and their use in cross-coupling reactions

scientific article

Synthesis of an acyltrifluoroborate and its fusion with azides to form amides

scientific article

Synthesis of functionalized organotrifluoroborates via halomethyltrifluoroborates

scientific article published on May 2006

Synthesis of functionalized organotrifluoroborates via the 1,3-dipolar cycloaddition of azides

scientific article published on June 2006

Synthesis of the stereogenic triad of the halicyclamine A core

scientific article published on April 2011

Synthesis of trifluoromethylated isoxazolidines: 1,3-dipolar cycloaddition of nitrosoarenes, (trifluoromethyl)diazomethane, and alkenes

scientific article published on 11 June 2013

Thioetherification via Photoredox/Nickel Dual Catalysis

scientific article

Total Synthesis of (−)-Steganone Utilizing a Samarium(II) Iodide Promoted 8-Endo Ketyl−Olefin Cyclization

scientific article published in 2000

Toward a general route to the eunicellin diterpenes: the asymmetric total synthesis of deacetoxyalcyonin acetate

scientific article published in February 2004

Toxicological investigation and antinociceptive property of potassium thiophene-3-trifluoroborate

scientific article published on 27 March 2009

Use of potassium beta-trifluoroborato amides in Suzuki-Miyaura cross-coupling reactions

scientific article published on August 2009

Visible Light Photoredox Cross-Coupling of Acyl Chlorides with Potassium Alkoxymethyltrifluoroborates: Synthesis of α-Alkoxyketones

scientific article published on February 2016

Visible-Light-Mediated Alkenylation, Allylation, and Cyanation of Potassium Alkyltrifluoroborates with Organic Photoredox Catalysts

scientific article published on 23 June 2016

cis-dihydroxylation of unsaturated potassium alkyl- and aryltrifluoroborates

scientific article published on January 2006

α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis

scientific article published on 23 November 2015