List of works - Enrique García-España

A Binuclear MnIII Complex of a Scorpiand-Like Ligand Displaying a Single Unsupported MnIII–O–MnIII Bridge

article

A Ferromagnetic [Cu3(OH)2]4+Cluster Formed inside a Tritopic Nonaazapyridinophane: Crystal Structure and Solution Studies

article

A dinucleating ligand which promotes DNA cleavage with one and without a transition metal ion

scientific article published on 27 March 2013

A highly enantioselective abiotic receptor for malate dianion in aqueous solution.

scientific article

A simple helical macrocyclic polyazapyridinophane as a stereoselective receptor of biologically important dicarboxylates under physiological conditions.

scientific article

A thermodynamic insight into the recognition of hydrophilic and hydrophobic amino acids in pure water by aza-scorpiand type receptors

article

Acid-base properties of functionalised tripodal polyamines and their interaction with nucleotides and nucleic acids.

scientific article

Anion binding with two polyammonium macrocycles of different dimensionality.

scientific article

Anion detection by fluorescent Zn(II) complexes of functionalized polyamine ligands.

scientific article published on 26 June 2008

Aryl-bis-(scorpiand)-aza receptors differentiate between nucleotide monophosphates by a combination of aromatic, hydrogen bond and electrostatic interactions

scientific article published on 01 February 2015

Aza-Macrocyclic Triphenylamine Ligands for G-Quadruplex Recognition

scientific article published on 27 June 2018

Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal-organic frameworks

scientific article published on 01 June 2017

Binuclear Cu2+ complex mediated discrimination between L-glutamate and L-aspartate in water.

scientific article published on 13 May 2005

CO2 fixation by copper(II) complexes of a terpyridinophane aza receptor.

scientific article published in April 2004

Coordination Chemistry of Cu2+ Complexes of Small N-Alkylated Tetra-azacyclophanes with SOD Activity

scientific article published on 21 August 2018

Copper(II) complexes of quinoline polyazamacrocyclic scorpiand-type ligands: X-ray, equilibrium and kinetic studies

scientific article published on 16 March 2012

Correlation between the molecular structure and the kinetics of decomposition of azamacrocyclic copper(ii) complexes

scientific article

Cu2+ and AMP complexation of enlarged tripodal polyamines.

scientific article

Cyclic voltammetric analysis of pH-dependent complex formation equilibria in anion coordination chemistry

scientific article published on 01 November 1995

Development of Polyamine-Substituted Triphenylamine Ligands with High Affinity and Selectivity for G-Quadruplex DNA

scientific article published on 08 November 2019

Diazatetraester 1H-pyrazole crowns as fluorescent chemosensors for AMPH, METH, MDMA (ecstasy), and dopamine.

scientific article

Dicopper(II) Metallacyclophanes with N,N′-2,6-Pyridinebis(oxamate): Solution Study, Synthesis, Crystal Structures, and Magnetic Properties

article

Dopamine interaction in the absence and in the presence of Cu2+ ions with macrocyclic and macrobicyclic polyamines containing pyrazole units. Crystal structures of [Cu2(L1)(H2O)2](ClO4)4 and [Cu2(H-1L3)](ClO4)3*2H2O.

scientific article published in October 2001

Dramatic selectivity differences in the association of DNA and RNA models with new ethylene- and propylene diamine derivatives and their copper complexes

scientific article published on 31 March 2006

Effect of Nitrogen Methylation on Cation and Anion Coordination by Hexa- and Heptaazamacrocycles. Catalytic Properties of These Ligands in ATP Dephosphorylation

scientific article published on 01 February 1996

Electrochemical determination of the stability of complexes formed by proton-ionizable ligands of 3,5-disubstituted 1H-pyrazole with phenethylamine

scientific article published on 01 April 2000

Electrochemistry of copper complexes with macrocyclic polyamines containing pyrazole units

scientific article published on 30 August 2006

Empirical modeling of material composition and size in MOFs prepared with ligand mixtures

scientific article published on 01 February 2019

Enhancement of SOD activity in boehmite supported nanoreceptors.

scientific article published on 29 March 2018

Equilibrium and kinetic studies on complex formation and decomposition and the movement of Cu(2+)metal ions within polytopic receptors

scientific article published on 11 February 2013

Equilibrium, kinetic, and computational studies on the formation of Cu2+ and Zn2+ complexes with an indazole-containing azamacrocyclic scorpiand: evidence for metal-induced tautomerism.

scientific article published on 30 January 2015

Exceedingly Fast Oxygen Atom Transfer to Olefins via a Catalytically Competent Nonheme Iron Species

scientific article published on 13 April 2016

Geometric isomerism in pentacoordinate Cu2+ complexes: equilibrium, kinetic, and density functional theory studies reveal the existence of equilibrium between square pyramidal and trigonal bipyramidal forms for a tren-derived ligand.

scientific article published in February 2009

Grafted squaramide monoamine nanoparticles as simple systems for sulfate recognition in pure water

scientific article published on 01 February 2012

Guanosine-5'-Monophosphate Polyamine Hybrid Hydrogels: Enhanced Gel Strength Probed by z-Spectroscopy.

scientific article published on 12 April 2017

Homo- and heterobinuclear Cu²⁺ and Zn²⁺ complexes of abiotic cyclic hexaazapyridinocyclophanes as SOD mimics

scientific article published on 01 August 2013

Hybrid GMP-polyamine hydrogels as new biocompatible materials for drug encapsulation

scientific article published on 29 June 2020

Hydrogen and copper ion induced molecular reorganizations in two new scorpiand-like ligands appended with pyridine rings.

scientific article

Hydrogen and copper ion-induced molecular reorganizations in scorpionand-like ligands. A potentiometric, mechanistic, and solid-state study

scientific article published on 08 June 2007

Hydrogen-ion driven molecular motions in Cu2+-complexes of a ditopic phenanthrolinophane ligand

scientific article published on 01 December 2003

Imaging atoms in medicine.

scientific article published on 2 December 2008

Imidazolate bridged Cu(II)-Cu(II) and Cu(II)-Zn(II) complexes of a terpyridinophane azamacrocycle: a solution and solid state study.

scientific article

In vitro activity of scorpiand-like azamacrocycle derivatives in promastigotes and intracellular amastigotes of Leishmania infantum and Leishmania braziliensis.

scientific article published on 19 January 2013

In vitro and in vivo antileishmanial and trypanocidal studies of new N-benzene- and N-naphthalenesulfonamide derivatives.

scientific article published on 12 November 2013

In vitro and in vivo trypanosomicidal activity of pyrazole-containing macrocyclic and macrobicyclic polyamines: their action on acute and chronic phases of Chagas disease

article

In vitro leishmanicidal activity of pyrazole-containing polyamine macrocycles which inhibit the Fe-SOD enzyme of Leishmania infantum and Leishmania braziliensis species

scientific article published on 17 March 2014

Influence of the chain length and metal : ligand ratio on the self-organization processes of Cu2+ complexes of [1 + 1] 1H-pyrazole azamacrocycles

scientific article published on 16 June 2020

Intermolecular Binding Modes in a Novel [1 + 1] Condensation 1H-Pyrazole Azamacrocycle: A Solution and Solid State Study with Evidence for CO2Fixation

article

Kinetics of Zn2+ complexation by a ditopic phenanthroline-azamacrocyclic scorpiand-like receptor

scientific article published on 11 January 2012

Lanthanide complexes as imaging agents anchored on nano-sized particles of boehmite.

scientific article

MWCNTs-Supported Pd(II) Complexes with High Catalytic Efficiency in Oxygen Reduction Reaction in Alkaline Media

article

Macrocyclic Pyclen-Based Gd3+ Complex with High Relaxivity and pH Response

scientific article published on 07 May 2020

Manganese(II) complexes of scorpiand-like azamacrocycles as MnSOD mimics

scientific article published on 03 May 2011

Molecular recognition of nucleotides in water by scorpiand-type receptors based on nucleobase discrimination.

scientific article

New efficient procedure for the use of diethoxyphosphoryl as a protecting group in the synthesis of polyazamacrocycles. Preparation of polyazacyclophanes derived from resorcinol.

scientific article published in December 2003

New insight to the chemistry of polyaza[n]paracyclophanes. A (15)N NMR study

scientific article published on 01 November 2001

Oxaaza cyclophanes in the recognition of nucleotides. The role of oxygen and electron-rich aromatic rings

scientific article published on 15 May 2007

Pb2+ complexes of small-cavity azamacrocyclic ligands: thermodynamic and kinetic studies.

scientific article published in May 2017

Polyfunctional recognition of pyridinedicarboxylate anions with macrocyclic polyamine receptors containing heteroaromatic groups.

scientific article

Properties of a Triazolopyridine System as a Molecular Chemosensor for Metal Ions, Anions, and Amino Acids†

scientific article published in November 2006

Protonation, coordination chemistry, cyanometallate "supercomplex" formation and fluorescence chemosensing properties of a bis(2,2'-bipyridino)cyclophane receptor

scientific article published on 4 December 2013

Scorpiand-like azamacrocycles prevent the chronic establishment of Trypanosoma cruzi in a murine model.

scientific article

Selective recognition of sulfate anions by a cyclopeptide-derived receptor in aqueous phosphate buffer.

scientific article

Shape-complementarity in the recognition of tricarboxylic acids by a [3+3] polyazacyclophane receptor.

scientific article

Specific interaction of citrate with bis(fluorophoric) bibrachial lariat aza-crown in comparison with the other components of the Krebs cycle

article

Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-oxo Intermediate

scientific article published on 20 February 2018

Squaramide-based reagent for selective chromogenic sensing of Cu(II) through a zwitterion radical.

scientific article published on September 2010

Structural reorganisation in polytopic receptors revealed by kinetic studies

scientific article published on 23 July 2010

Studies on the interaction of phosphate anions with N-functionalised polyaza[n]paracyclophanes: the role of N-methylation

scientific article published on 18 February 2004

Supramolecular complexation for environmental control.

scientific article published on 22 March 2012

Surface-enhanced Raman study of the interactions between tripodal cationic polyamines and polynucleotides

scientific article published on 22 June 2011

Synthesis and H+, Cu2+, and Zn2+ coordination behavior of a bis(fluorophoric) bibrachial lariat aza-crown.

scientific article published in September 2004

Synthesis and Structural Characterization of a Cyclen-Derived Molecular Cage

scientific article published on 17 November 2015

The sodium salt of diethyl 1H-pyrazole-3,5-dicarboxylate as an efficient amphiphilic receptor for dopamine and amphetamines. crystal structure and solution studies

scientific article published on 01 December 2006

The structure of ammonium pyrazolates in the solid state

article

Thermodynamic and Steady-State Fluorescence Emission Studies on Metal Complexes of Receptors Containing Benzene Subunits.

scientific article

Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C-H Bonds with Stereoretention.

scientific article published on 24 November 2015

Tripyridinophane Platform Containing Three Acetate Pendant Arms: An Attractive Structural Entry for the Development of Neutral Eu(III) and Tb(III) Complexes in Aqueous Solution

scientific article published on 08 January 2020

Unveiling the reaction mechanism of novel copper N-alkylated tetra-azacyclophanes with outstanding superoxide dismutase activity

scientific article published on 08 June 2020

Visualizing the atherosclerotic plaque: a chemical perspective

scientific article published on 14 February 2014

Zn2+ and Cu2+ complexes of a fluorescent scorpiand-type oxadiazole azamacrocyclic ligand: crystal structures, solution studies and optical properties

scientific article published on 23 January 2020

“3 + 1 = 6 + 2” in Cu(ii) coordination chemistry of 1H-pyrazole aza cryptands

article

List of works by Enrique García-España

A Binuclear MnIII Complex of a Scorpiand-Like Ligand Displaying a Single Unsupported MnIII–O–MnIII Bridge

A Ferromagnetic [Cu3(OH)2]4+Cluster Formed inside a Tritopic Nonaazapyridinophane: Crystal Structure and Solution Studies

A dinucleating ligand which promotes DNA cleavage with one and without a transition metal ion

A highly enantioselective abiotic receptor for malate dianion in aqueous solution.

A simple helical macrocyclic polyazapyridinophane as a stereoselective receptor of biologically important dicarboxylates under physiological conditions.

A thermodynamic insight into the recognition of hydrophilic and hydrophobic amino acids in pure water by aza-scorpiand type receptors

Acid-base properties of functionalised tripodal polyamines and their interaction with nucleotides and nucleic acids.

Anion binding with two polyammonium macrocycles of different dimensionality.

Anion detection by fluorescent Zn(II) complexes of functionalized polyamine ligands.

Aryl-bis-(scorpiand)-aza receptors differentiate between nucleotide monophosphates by a combination of aromatic, hydrogen bond and electrostatic interactions

Aza-Macrocyclic Triphenylamine Ligands for G-Quadruplex Recognition

Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal-organic frameworks

Binuclear Cu2+ complex mediated discrimination between L-glutamate and L-aspartate in water.

CO2 fixation by copper(II) complexes of a terpyridinophane aza receptor.

Coordination Chemistry of Cu2+ Complexes of Small N-Alkylated Tetra-azacyclophanes with SOD Activity

Copper(II) complexes of quinoline polyazamacrocyclic scorpiand-type ligands: X-ray, equilibrium and kinetic studies

Correlation between the molecular structure and the kinetics of decomposition of azamacrocyclic copper(ii) complexes

Cu2+ and AMP complexation of enlarged tripodal polyamines.

Cyclic voltammetric analysis of pH-dependent complex formation equilibria in anion coordination chemistry

Development of Polyamine-Substituted Triphenylamine Ligands with High Affinity and Selectivity for G-Quadruplex DNA

Diazatetraester 1H-pyrazole crowns as fluorescent chemosensors for AMPH, METH, MDMA (ecstasy), and dopamine.

Dicopper(II) Metallacyclophanes with N,N′-2,6-Pyridinebis(oxamate): Solution Study, Synthesis, Crystal Structures, and Magnetic Properties

Dopamine interaction in the absence and in the presence of Cu2+ ions with macrocyclic and macrobicyclic polyamines containing pyrazole units. Crystal structures of [Cu2(L1)(H2O)2](ClO4)4 and [Cu2(H-1L3)](ClO4)3*2H2O.

Dramatic selectivity differences in the association of DNA and RNA models with new ethylene- and propylene diamine derivatives and their copper complexes

Effect of Nitrogen Methylation on Cation and Anion Coordination by Hexa- and Heptaazamacrocycles. Catalytic Properties of These Ligands in ATP Dephosphorylation

Electrochemical determination of the stability of complexes formed by proton-ionizable ligands of 3,5-disubstituted 1H-pyrazole with phenethylamine

Electrochemistry of copper complexes with macrocyclic polyamines containing pyrazole units

Empirical modeling of material composition and size in MOFs prepared with ligand mixtures

Enhancement of SOD activity in boehmite supported nanoreceptors.

Equilibrium and kinetic studies on complex formation and decomposition and the movement of Cu(2+)metal ions within polytopic receptors

Equilibrium, kinetic, and computational studies on the formation of Cu2+ and Zn2+ complexes with an indazole-containing azamacrocyclic scorpiand: evidence for metal-induced tautomerism.

Exceedingly Fast Oxygen Atom Transfer to Olefins via a Catalytically Competent Nonheme Iron Species

Geometric isomerism in pentacoordinate Cu2+ complexes: equilibrium, kinetic, and density functional theory studies reveal the existence of equilibrium between square pyramidal and trigonal bipyramidal forms for a tren-derived ligand.

Grafted squaramide monoamine nanoparticles as simple systems for sulfate recognition in pure water

Guanosine-5'-Monophosphate Polyamine Hybrid Hydrogels: Enhanced Gel Strength Probed by z-Spectroscopy.

Homo- and heterobinuclear Cu²⁺ and Zn²⁺ complexes of abiotic cyclic hexaazapyridinocyclophanes as SOD mimics

Hybrid GMP-polyamine hydrogels as new biocompatible materials for drug encapsulation

Hydrogen and copper ion induced molecular reorganizations in two new scorpiand-like ligands appended with pyridine rings.

Hydrogen and copper ion-induced molecular reorganizations in scorpionand-like ligands. A potentiometric, mechanistic, and solid-state study

Hydrogen-ion driven molecular motions in Cu2+-complexes of a ditopic phenanthrolinophane ligand

Imaging atoms in medicine.

Imidazolate bridged Cu(II)-Cu(II) and Cu(II)-Zn(II) complexes of a terpyridinophane azamacrocycle: a solution and solid state study.

In vitro activity of scorpiand-like azamacrocycle derivatives in promastigotes and intracellular amastigotes of Leishmania infantum and Leishmania braziliensis.

In vitro and in vivo antileishmanial and trypanocidal studies of new N-benzene- and N-naphthalenesulfonamide derivatives.

In vitro and in vivo trypanosomicidal activity of pyrazole-containing macrocyclic and macrobicyclic polyamines: their action on acute and chronic phases of Chagas disease

In vitro leishmanicidal activity of pyrazole-containing polyamine macrocycles which inhibit the Fe-SOD enzyme of Leishmania infantum and Leishmania braziliensis species

Influence of the chain length and metal : ligand ratio on the self-organization processes of Cu2+ complexes of [1 + 1] 1H-pyrazole azamacrocycles

Intermolecular Binding Modes in a Novel [1 + 1] Condensation 1H-Pyrazole Azamacrocycle: A Solution and Solid State Study with Evidence for CO2Fixation

Kinetics of Zn2+ complexation by a ditopic phenanthroline-azamacrocyclic scorpiand-like receptor

Lanthanide complexes as imaging agents anchored on nano-sized particles of boehmite.

MWCNTs-Supported Pd(II) Complexes with High Catalytic Efficiency in Oxygen Reduction Reaction in Alkaline Media

Macrocyclic Pyclen-Based Gd3+ Complex with High Relaxivity and pH Response

Manganese(II) complexes of scorpiand-like azamacrocycles as MnSOD mimics

Molecular recognition of nucleotides in water by scorpiand-type receptors based on nucleobase discrimination.

New efficient procedure for the use of diethoxyphosphoryl as a protecting group in the synthesis of polyazamacrocycles. Preparation of polyazacyclophanes derived from resorcinol.

New insight to the chemistry of polyaza[n]paracyclophanes. A (15)N NMR study

Oxaaza cyclophanes in the recognition of nucleotides. The role of oxygen and electron-rich aromatic rings

Pb2+ complexes of small-cavity azamacrocyclic ligands: thermodynamic and kinetic studies.

Polyfunctional recognition of pyridinedicarboxylate anions with macrocyclic polyamine receptors containing heteroaromatic groups.

Properties of a Triazolopyridine System as a Molecular Chemosensor for Metal Ions, Anions, and Amino Acids†

Protonation, coordination chemistry, cyanometallate "supercomplex" formation and fluorescence chemosensing properties of a bis(2,2'-bipyridino)cyclophane receptor

Scorpiand-like azamacrocycles prevent the chronic establishment of Trypanosoma cruzi in a murine model.

Selective recognition of sulfate anions by a cyclopeptide-derived receptor in aqueous phosphate buffer.

Shape-complementarity in the recognition of tricarboxylic acids by a [3+3] polyazacyclophane receptor.

Specific interaction of citrate with bis(fluorophoric) bibrachial lariat aza-crown in comparison with the other components of the Krebs cycle

Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-oxo Intermediate

Squaramide-based reagent for selective chromogenic sensing of Cu(II) through a zwitterion radical.

Structural reorganisation in polytopic receptors revealed by kinetic studies

Studies on the interaction of phosphate anions with N-functionalised polyaza[n]paracyclophanes: the role of N-methylation

Supramolecular complexation for environmental control.

Surface-enhanced Raman study of the interactions between tripodal cationic polyamines and polynucleotides

Synthesis and H+, Cu2+, and Zn2+ coordination behavior of a bis(fluorophoric) bibrachial lariat aza-crown.

Synthesis and Structural Characterization of a Cyclen-Derived Molecular Cage

The sodium salt of diethyl 1H-pyrazole-3,5-dicarboxylate as an efficient amphiphilic receptor for dopamine and amphetamines. crystal structure and solution studies

The structure of ammonium pyrazolates in the solid state

Thermodynamic and Steady-State Fluorescence Emission Studies on Metal Complexes of Receptors Containing Benzene Subunits.

Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C-H Bonds with Stereoretention.

Tripyridinophane Platform Containing Three Acetate Pendant Arms: An Attractive Structural Entry for the Development of Neutral Eu(III) and Tb(III) Complexes in Aqueous Solution

Unveiling the reaction mechanism of novel copper N-alkylated tetra-azacyclophanes with outstanding superoxide dismutase activity