List of works - Makoto Yasuda

1,8-Diphenyl-9,10-Bis(arylethynyl)phenanthrenes: Synthesis, Distorted Structure, and Optical Properties.

scientific article published on 23 February 2018

Allylic tantalums as highly imine-selective reagents.

scientific article published in March 2004

Alpha-alkylation of carbonyl compounds by direct addition of alcohols to enol acetates

scientific article published on 01 January 2009

Anti-Carboalumination of Alkynes Using Aluminum Trihalide and Silyl Ketene Imines: Stereo- and Regioselective Synthesis of Alkenylaluminum Compounds Bearing a Cyano Group

scientific article published on 30 May 2018

Bu2SnIH-promoted proximal bond cleavage of methylenecyclopropanes and successive radical cyclization and/or Pd-catalyzed coupling reaction.

scientific article

C3 -Symmetric Boron Lewis Acid with a Cage-Shape for Chiral Molecular Recognition and Asymmetric Catalysis

scientific article

Cage-shaped borate esters with tris(2-oxyphenyl)methane or -silane system frameworks bearing multiple tuning factors: geometric and substituent effects on their Lewis acid properties

scientific article published on 07 March 2011

Carbogallation of alkynes using gallium tribromide and silyl ketene acetals and synthetic application to cross-coupling with aryl iodides

scientific article published on 23 August 2011

Carbometalation and Heterometalation of Carbon-Carbon Multiple-Bonds Using Group-13 Heavy Metals: Carbogallation, Carboindation, Heterogallation, and Heteroindation

scientific article published on 03 February 2020

Catalytic generation of indium hydride in a highly diastereoselective reductive aldol reaction.

scientific article published in January 2004

Construction of Polycyclic π-Conjugated Systems Incorporating an Azulene Unit Following the Oxidation of 1,8-Diphenyl-9,10-bis(phenylethynyl)phenanthrene

scientific article published on 30 May 2018

Coupling Reaction of Enol Derivatives with Silyl Ketene Acetals Catalyzed by Gallium Trihalides.

scientific article published on 11 July 2016

Coupling reaction of alkyl chlorides with silyl enolates catalyzed by indium trihalide.

scientific article published on 2 November 2007

Cross-coupling reaction of alpha-chloroketones and organotin enolates catalyzed by zinc halides for synthesis of gamma-diketones

scientific article published on 01 June 2002

Cyclopropylmethylation of benzylic and allylic chlorides with cyclopropylmethylstannane catalyzed by gallium or indium halide

scientific article

Diastereoselective addition of gamma-substituted allylic nucleophiles to ketones: highly stereoselective synthesis of tertiary homoallylic alcohols using an allylic tributylstannane/stannous chloride system.

scientific article published in November 2002

Diastereoselective production of homoallylic alcohols bearing quaternary centers from gamma-substituted allylic indiums and ketones.

scientific article

Diastereoselective reductive aldol reaction of enones to ketones catalyzed by halogenotin hydride

scientific article published on 01 December 2010

Direct carbon-carbon bond formation from alcohols and active methylenes, alkoxyketones, or indoles catalyzed by indium trichloride.

scientific article published in January 2006

Direct conversion of carbonyl compounds into organic halides: indium(III) hydroxide-catalyzed deoxygenative halogenation using chlorodimethylsilane.

scientific article published in November 2002

Direct coupling of alcohols with alkenylsilanes catalyzed by indium trichloride or bismuth tribromide.

scientific article published on 4 November 2008

Direct coupling reaction between alcohols and silyl compounds: enhancement of Lewis acidity of Me3SiBr using InCl3.

scientific article published in October 2006

Direct reduction of alcohols: highly chemoselective reducing system for secondary or tertiary alcohols using chlorodiphenylsilane with a catalytic amount of indium trichloride.

scientific article published in November 2001

Direct synthesis of alkynylstannanes: ZnBr2 catalyst for the reaction of tributyltin methoxide and terminal alkynes

scientific article published on 13 September 2011

Direct use of esters in the Mukaiyama aldol reaction: a powerful and convenient alternative to aldehydes

scientific article published on 08 February 2012

Enhancement of Antiaromatic Character via Additional Benzoannulation into Dibenzo[ a, f]pentalene: Syntheses and Properties of Benzo[ a]naphtho[2,1- f]pentalene and Dinaphtho[2,1- a, f]pentalene

scientific article published on 21 December 2018

Esters as acylating reagent in a Friedel-Crafts reaction: indium tribromide catalyzed acylation of arenes using dimethylchlorosilane.

scientific article

Fine-tuning of boron complexes with cage-shaped ligand geometry: rational design of triphenolic ligand as a template for structure control

scientific article published on 26 January 2008

First Isolation and Characterization of the Highly Coordinated Group 14 Enolates: Effects of the Coordination Controls on the Geometry and Tautomerization of Germyl Enolates.

scientific article published on 5 July 2016

Gallium tribromide catalyzed coupling reaction of alkenyl ethers with ketene silyl acetals

scientific article published on 02 July 2012

Gallium trihalide catalyzed sequential addition of two different carbon nucleophiles to esters by using silyl cyanide and ketene silyl acetals

scientific article published on 05 August 2014

Generation of allylic indium by hydroindation of 1,3-dienes and one-pot reaction with carbonyl compounds

scientific article published on 01 September 2006

Generation of α-Iminyl Radicals from α-Bromo Cyclic N-Sulfonylimines and Application to Coupling with Various Radical Acceptors Using a Photoredox Catalyst.

scientific article

Geometrically Selective Synthesis of (E)-Enamides via Radical Allylation of Alkyl Halides with α-Aminoallylic Stannanes

scientific article published on 05 July 2019

Germanium(II)-mediated reductive cross-aldol reaction of bromoaldehydes with aldehydes: NMR studies and ab initio calculations.

scientific article published on 17 July 2008

High chelation control of three contiguous stereogenic centers in the Reformatsky reactions of indium enolates with alpha-hydroxy ketones: unexpected stereochemistry of lactone formation.

scientific article published in July 2006

In(III)-mediated chemoselective dehydrogenative interaction of ClMe(2)SiH with carboxylic acids: direct chemo- and regioselective Friedel-Crafts acylation of aromatic ethers.

scientific article published in February 2007

In- or In(I)-employed tailoring of the stereogenic centers in the Reformatsky-type reactions of simple ketones, alpha-alkoxy ketones, and beta-keto esters.

scientific article published in December 2005

In- or in(I)-employed diastereoselective Reformatsky-type reactions with ketones: 1H NMR investigations on the active species.

scientific article published in November 2004

InCl3/I2-catalyzed cross-coupling of alkyl trimethylsilyl ethers and allylsilanes via an in situ derived combined Lewis acid of InCl3 and Me3SiI.

scientific article published on 3 October 2007

InCl3/Me3SiBr-catalyzed direct coupling between silyl ethers and enol acetates

scientific article published on 28 April 2011

InCl3/Me3SiCl-catalyzed direct Michael addition of enol acetates to α,β-unsaturated ketones

scientific article published on 06 November 2012

Indium Catalyzed Hydrofunctionalization of Styrene Derivatives Bearing a Hydroxy Group with Organosilicon Nucleophiles.

scientific article published on 11 December 2017

Indium Tribromide Catalyzed Coupling Reaction of Enol Ethers with Silyl Ketene Imines toward the Synthesis of β,γ-Unsaturated Nitriles.

scientific article published on 30 October 2015

Indium chloride catalyzed alkylative rearrangement of propargylic acetates using alkyl chlorides, alcohols, and acetates: facile synthesis of α-alkyl-α,β-unsaturated carbonyl compounds.

scientific article

Indium tribromide catalyzed cross-Claisen condensation between carboxylic acids and ketene silyl acetals using alkoxyhydrosilanes

scientific article published on 26 July 2011

Indium triiodide catalyzed reductive functionalization of amides via the single-stage treatment of hydrosilanes and organosilicon nucleophiles

scientific article published on 25 June 2013

Indium(III) halide-catalyzed UV-irradiated radical coupling of iodomethylphosphorus compounds with various organostannanes

scientific article published on 21 March 2013

Indium-catalyzed direct chlorination of alcohols using chlorodimethylsilane-benzil as a selective and mild system.

scientific article

Lithium phenolates with a hexagonal-prismatic Li6O6 core isolated via a cage-shaped tripodal ligands system: crystal structures and their behavior in solution

scientific article published on 20 April 2012

One-pot synthesis of nitrogen heterocycles initiated by regio- and diastereoselective carbon-carbon bond formation of bifunctional carbonyl compounds.

scientific article published in January 2004

Open-Shell and Antiaromatic Character Induced by the Highly Symmetric Geometry of the Planar Heptalene Structure: Synthesis and Characterization of a Nonalternant Isomer of Bisanthene

scientific article published on 29 May 2019

Recognition of aromatic compounds by π pocket within a cage-shaped borate catalyst

scientific article published on 12 March 2012

Regio- and Stereoselective Allylindation of Alkynes Using InBr₃ and Allylic Silanes: Synthesis, Characterization, and Application of 1,4-Dienylindiums toward Skipped Dienes.

scientific article published on 27 July 2018

Regio- and Stereoselective Anti-Carbozincation of Alkynyl Ethers Using ZnBr2 toward (Z)-β-Zincated Enol Ether Synthesis

scientific article published on 12 July 2017

Regio- and Stereoselective Carboindation of Internal Alkynyl Ethers with Organosilicon or -stannane Nucleophiles

scientific article published on 09 September 2019

Regio- and stereoselective carbobismuthination of alkynes

scientific article published on 08 December 2011

Regio- and stereoselective hydrostannation of allenes using dibutyliodotin hydride (Bu2SnIH) and successive coupling with aromatic halides.

scientific article published in December 2007

Regioselective Synthesis of 5-Metalated 2-Pyrones by Intramolecular Oxymetalation of Carbonyl-ene-yne Compounds Using Indium Trihalide

scientific article published on 17 October 2019

Regioselective carboindation of simple alkenes with indium tribromide and ketene silyl acetals.

scientific article published in August 2010

Selective oxymetalation of terminal alkynes via 6-endo cyclization: mechanistic investigation and application to the efficient synthesis of 4-substituted isocoumarins

scientific article published on 15 June 2018

Stereocontrolled Synthesis of Triols Containing Four Asymmetric Centers: Application of C, O-Chelated Germyl Enolates to a Diastereoselective Aldol Reaction

scientific article published on 25 June 2018

Synthesis and Characterization of Dibenzo[a,f]pentalene: Harmonization of the Antiaromatic and Singlet Biradical Character.

scientific article

Synthesis and Characterization of Pheox- and Phebox-Aluminum Complexes: Application as Tunable Lewis Acid Catalysts in Organic Reactions

scientific article published on 26 June 2019

Synthesis and theoretical studies of gallium complexes back-shielded by a cage-shaped framework of tris(m-oxybenzyl)arene

scientific article published on 25 May 2010

Synthesis of (Z)-β-(Carbonylamino)alkenylindium through Regioselective anti-Carboindation of Ynamides and Its Transformation to Multisubstituted Enamides

scientific article published on 13 December 2019

Synthesis of 1,4-Dicarbonyl Compounds from Silyl Enol Ethers and Bromocarbonyls, Catalyzed by an Organic Dye under Visible-Light Irradiation with Perfect Selectivity for the Halide Moiety over the Carbonyl Group.

scientific article published on 25 October 2016

Synthesis of Cage-Shaped Aluminum Aryloxides: Efficient Lewis Acid Catalyst for Stereoselective Glycosylation Driven by Flexible Shift of Four- to Five-Coordination

scientific article published on 03 October 2019

Synthesis of Thioethers by InI₃-Catalyzed Substitution of Siloxy Group Using Thiosilanes.

scientific article published on 6 October 2016

Synthesis of a wide range of thioethers by indium triiodide catalyzed direct coupling between alkyl acetates and thiosilanes

scientific article published on 19 March 2012

Synthesis of alkylbismuths by regiodivergent carbobismuthination of simple alkenes.

scientific article

Synthesis of oxazolidinones initiated by regio- and diastereo-controlled crotylation of alpha-dicarbonyl compounds

scientific article published on 16 March 2010

Synthesis of α-Alkenyl α,β-Unsaturated Ketones via Dehydrogermylation of Oxagermacycles with Regeneration of the Germanium(II) Species

scientific article published on 04 November 2019

Synthesis, characterization, and properties of a benzofuran-based cage-shaped borate: photo activation of Lewis acid catalysts.

scientific article published on 29 January 2016

The reductive amination of aldehydes and ketones by catalytic use of dibutylchlorotin hydride complex.

scientific article published on 29 August 2006

Tuning Lewis Acidity by a Transannular pπ -σ* Interaction between Boron and Silicon/Germanium Atoms Supported by a Cage-Shaped Framework

scientific article

Zn(II) chloride-catalyzed direct coupling of various alkynes with acetals: facile and inexpensive access to functionalized propargyl ethers.

scientific article published in December 2013

List of works by Makoto Yasuda

1,8-Diphenyl-9,10-Bis(arylethynyl)phenanthrenes: Synthesis, Distorted Structure, and Optical Properties.

Allylic tantalums as highly imine-selective reagents.

Alpha-alkylation of carbonyl compounds by direct addition of alcohols to enol acetates

Anti-Carboalumination of Alkynes Using Aluminum Trihalide and Silyl Ketene Imines: Stereo- and Regioselective Synthesis of Alkenylaluminum Compounds Bearing a Cyano Group

Bu2SnIH-promoted proximal bond cleavage of methylenecyclopropanes and successive radical cyclization and/or Pd-catalyzed coupling reaction.

C3 -Symmetric Boron Lewis Acid with a Cage-Shape for Chiral Molecular Recognition and Asymmetric Catalysis

Cage-shaped borate esters with tris(2-oxyphenyl)methane or -silane system frameworks bearing multiple tuning factors: geometric and substituent effects on their Lewis acid properties

Carbogallation of alkynes using gallium tribromide and silyl ketene acetals and synthetic application to cross-coupling with aryl iodides

Carbometalation and Heterometalation of Carbon-Carbon Multiple-Bonds Using Group-13 Heavy Metals: Carbogallation, Carboindation, Heterogallation, and Heteroindation

Catalytic generation of indium hydride in a highly diastereoselective reductive aldol reaction.

Construction of Polycyclic π-Conjugated Systems Incorporating an Azulene Unit Following the Oxidation of 1,8-Diphenyl-9,10-bis(phenylethynyl)phenanthrene

Coupling Reaction of Enol Derivatives with Silyl Ketene Acetals Catalyzed by Gallium Trihalides.

Coupling reaction of alkyl chlorides with silyl enolates catalyzed by indium trihalide.

Cross-coupling reaction of alpha-chloroketones and organotin enolates catalyzed by zinc halides for synthesis of gamma-diketones

Cyclopropylmethylation of benzylic and allylic chlorides with cyclopropylmethylstannane catalyzed by gallium or indium halide

Diastereoselective addition of gamma-substituted allylic nucleophiles to ketones: highly stereoselective synthesis of tertiary homoallylic alcohols using an allylic tributylstannane/stannous chloride system.

Diastereoselective production of homoallylic alcohols bearing quaternary centers from gamma-substituted allylic indiums and ketones.

Diastereoselective reductive aldol reaction of enones to ketones catalyzed by halogenotin hydride

Direct carbon-carbon bond formation from alcohols and active methylenes, alkoxyketones, or indoles catalyzed by indium trichloride.

Direct conversion of carbonyl compounds into organic halides: indium(III) hydroxide-catalyzed deoxygenative halogenation using chlorodimethylsilane.

Direct coupling of alcohols with alkenylsilanes catalyzed by indium trichloride or bismuth tribromide.

Direct coupling reaction between alcohols and silyl compounds: enhancement of Lewis acidity of Me3SiBr using InCl3.

Direct reduction of alcohols: highly chemoselective reducing system for secondary or tertiary alcohols using chlorodiphenylsilane with a catalytic amount of indium trichloride.

Direct synthesis of alkynylstannanes: ZnBr2 catalyst for the reaction of tributyltin methoxide and terminal alkynes

Direct use of esters in the Mukaiyama aldol reaction: a powerful and convenient alternative to aldehydes

Enhancement of Antiaromatic Character via Additional Benzoannulation into Dibenzo[ a, f]pentalene: Syntheses and Properties of Benzo[ a]naphtho[2,1- f]pentalene and Dinaphtho[2,1- a, f]pentalene

Esters as acylating reagent in a Friedel-Crafts reaction: indium tribromide catalyzed acylation of arenes using dimethylchlorosilane.

Fine-tuning of boron complexes with cage-shaped ligand geometry: rational design of triphenolic ligand as a template for structure control

First Isolation and Characterization of the Highly Coordinated Group 14 Enolates: Effects of the Coordination Controls on the Geometry and Tautomerization of Germyl Enolates.

Gallium tribromide catalyzed coupling reaction of alkenyl ethers with ketene silyl acetals

Gallium trihalide catalyzed sequential addition of two different carbon nucleophiles to esters by using silyl cyanide and ketene silyl acetals

Generation of allylic indium by hydroindation of 1,3-dienes and one-pot reaction with carbonyl compounds

Generation of α-Iminyl Radicals from α-Bromo Cyclic N-Sulfonylimines and Application to Coupling with Various Radical Acceptors Using a Photoredox Catalyst.

Geometrically Selective Synthesis of (E)-Enamides via Radical Allylation of Alkyl Halides with α-Aminoallylic Stannanes

Germanium(II)-mediated reductive cross-aldol reaction of bromoaldehydes with aldehydes: NMR studies and ab initio calculations.

High chelation control of three contiguous stereogenic centers in the Reformatsky reactions of indium enolates with alpha-hydroxy ketones: unexpected stereochemistry of lactone formation.

In(III)-mediated chemoselective dehydrogenative interaction of ClMe(2)SiH with carboxylic acids: direct chemo- and regioselective Friedel-Crafts acylation of aromatic ethers.

In- or In(I)-employed tailoring of the stereogenic centers in the Reformatsky-type reactions of simple ketones, alpha-alkoxy ketones, and beta-keto esters.

In- or in(I)-employed diastereoselective Reformatsky-type reactions with ketones: 1H NMR investigations on the active species.

InCl3/I2-catalyzed cross-coupling of alkyl trimethylsilyl ethers and allylsilanes via an in situ derived combined Lewis acid of InCl3 and Me3SiI.

InCl3/Me3SiBr-catalyzed direct coupling between silyl ethers and enol acetates

InCl3/Me3SiCl-catalyzed direct Michael addition of enol acetates to α,β-unsaturated ketones

Indium Catalyzed Hydrofunctionalization of Styrene Derivatives Bearing a Hydroxy Group with Organosilicon Nucleophiles.

Indium Tribromide Catalyzed Coupling Reaction of Enol Ethers with Silyl Ketene Imines toward the Synthesis of β,γ-Unsaturated Nitriles.

Indium chloride catalyzed alkylative rearrangement of propargylic acetates using alkyl chlorides, alcohols, and acetates: facile synthesis of α-alkyl-α,β-unsaturated carbonyl compounds.

Indium tribromide catalyzed cross-Claisen condensation between carboxylic acids and ketene silyl acetals using alkoxyhydrosilanes

Indium triiodide catalyzed reductive functionalization of amides via the single-stage treatment of hydrosilanes and organosilicon nucleophiles

Indium(III) halide-catalyzed UV-irradiated radical coupling of iodomethylphosphorus compounds with various organostannanes

Indium-catalyzed direct chlorination of alcohols using chlorodimethylsilane-benzil as a selective and mild system.

Lithium phenolates with a hexagonal-prismatic Li6O6 core isolated via a cage-shaped tripodal ligands system: crystal structures and their behavior in solution

One-pot synthesis of nitrogen heterocycles initiated by regio- and diastereoselective carbon-carbon bond formation of bifunctional carbonyl compounds.

Open-Shell and Antiaromatic Character Induced by the Highly Symmetric Geometry of the Planar Heptalene Structure: Synthesis and Characterization of a Nonalternant Isomer of Bisanthene

Recognition of aromatic compounds by π pocket within a cage-shaped borate catalyst

Regio- and Stereoselective Allylindation of Alkynes Using InBr₃ and Allylic Silanes: Synthesis, Characterization, and Application of 1,4-Dienylindiums toward Skipped Dienes.

Regio- and Stereoselective Anti-Carbozincation of Alkynyl Ethers Using ZnBr2 toward (Z)-β-Zincated Enol Ether Synthesis

Regio- and Stereoselective Carboindation of Internal Alkynyl Ethers with Organosilicon or -stannane Nucleophiles

Regio- and stereoselective carbobismuthination of alkynes

Regio- and stereoselective hydrostannation of allenes using dibutyliodotin hydride (Bu2SnIH) and successive coupling with aromatic halides.

Regioselective Synthesis of 5-Metalated 2-Pyrones by Intramolecular Oxymetalation of Carbonyl-ene-yne Compounds Using Indium Trihalide

Regioselective carboindation of simple alkenes with indium tribromide and ketene silyl acetals.

Selective oxymetalation of terminal alkynes via 6-endo cyclization: mechanistic investigation and application to the efficient synthesis of 4-substituted isocoumarins

Stereocontrolled Synthesis of Triols Containing Four Asymmetric Centers: Application of C, O-Chelated Germyl Enolates to a Diastereoselective Aldol Reaction

Synthesis and Characterization of Dibenzo[a,f]pentalene: Harmonization of the Antiaromatic and Singlet Biradical Character.

Synthesis and Characterization of Pheox- and Phebox-Aluminum Complexes: Application as Tunable Lewis Acid Catalysts in Organic Reactions

Synthesis and theoretical studies of gallium complexes back-shielded by a cage-shaped framework of tris(m-oxybenzyl)arene

Synthesis of (Z)-β-(Carbonylamino)alkenylindium through Regioselective anti-Carboindation of Ynamides and Its Transformation to Multisubstituted Enamides

Synthesis of 1,4-Dicarbonyl Compounds from Silyl Enol Ethers and Bromocarbonyls, Catalyzed by an Organic Dye under Visible-Light Irradiation with Perfect Selectivity for the Halide Moiety over the Carbonyl Group.

Synthesis of Cage-Shaped Aluminum Aryloxides: Efficient Lewis Acid Catalyst for Stereoselective Glycosylation Driven by Flexible Shift of Four- to Five-Coordination

Synthesis of Thioethers by InI₃-Catalyzed Substitution of Siloxy Group Using Thiosilanes.

Synthesis of a wide range of thioethers by indium triiodide catalyzed direct coupling between alkyl acetates and thiosilanes

Synthesis of alkylbismuths by regiodivergent carbobismuthination of simple alkenes.

Synthesis of oxazolidinones initiated by regio- and diastereo-controlled crotylation of alpha-dicarbonyl compounds

Synthesis of α-Alkenyl α,β-Unsaturated Ketones via Dehydrogermylation of Oxagermacycles with Regeneration of the Germanium(II) Species

Synthesis, characterization, and properties of a benzofuran-based cage-shaped borate: photo activation of Lewis acid catalysts.

The reductive amination of aldehydes and ketones by catalytic use of dibutylchlorotin hydride complex.

Tuning Lewis Acidity by a Transannular pπ -σ* Interaction between Boron and Silicon/Germanium Atoms Supported by a Cage-Shaped Framework

Zn(II) chloride-catalyzed direct coupling of various alkynes with acetals: facile and inexpensive access to functionalized propargyl ethers.