List of works - Sylvain Marque

Alkoxyamine Re-Formation Reaction. Effects of the Nitroxide Fragment: A Multiparameter Analysis

scientific article published on 14 May 2012

Alkoxyamine-mediated radical synthesis of indolinones and indolines

scientific article published on 01 December 2003

Alkoxyamines: a new family of pro-drugs against cancer. Concept for theranostics.

scientific article

Alkoxyamines: toward a new family of theranostic agents against cancer

scientific article

Alpha-phenyl-N-tert-butylnitrone-type derivatives bound to beta-cyclodextrins: syntheses, thermokinetics of self-inclusion and application to superoxide spin-trapping

scientific article published on 01 January 2007

Aminomethylation of Michael acceptors: complementary radical and polar approaches mediated by dialkylzincs

scientific article published on 10 February 2012

C-ON Bond Homolysis of Alkoxyamines, Part 11: Activation of the Nitroxyl Fragment.

scientific article

C-ON bond homolysis in alkoxyamines. Part 12: the effect of the para-substituent in the 1-phenylethyl fragment

scientific article published on 15 March 2016

C-ON bond homolysis of alkoxyamines: when too high polarity is detrimental.

scientific article published on 10 July 2017

Chemically Triggered C-ON Bond Homolysis in Alkoxyamines. Part 2: DFT Investigation and Application of the pH Effect on NMP

scientific article published on 21 November 2011

Chemically Triggered C–ON Bond Homolysis in Alkoxyamines. 6. Effect of the Counteranion ⬇️

scientific article published on July 15, 2013

Chemically triggered C-ON bond homolysis in alkoxyamines: regioselectivity and chemoselectivity.

scientific article published on 10 October 2013

Chemically triggered C-ON bond homolysis of alkoxyamines. 5. Cybotactic effect

scientific article published on 10 October 2012

Chemically triggered C-ON bond homolysis of alkoxyamines. 8. Quaternization and steric effects

scientific article published on 23 September 2013

Chemically triggered C-ON bond homolysis of alkoxyamines. Quaternization of the alkyl fragment

scientific article published on 16 December 2011

Correction to Shifting-Nitroxides to Investigate Enzymatic Hydrolysis of Fatty Acids by Lipases Using Electron Paramagnetic Resonance in Turbid Media

scientific article published on 18 May 2020

Development and Application of Spin Traps, Spin Probes, and Spin Labels

article

Diversification of EPR signatures in Site Directed Spin Labeling using a β-phosphorylated nitroxide

scientific article published on 01 March 2014

Dynamics of the intrinsically disordered protein CP12 in its association with GAPDH in the green alga Chlamydomonas reinhardtii: a fuzzy complex.

scientific article published in November 2013

EPR investigation of zinc/iodine exchange between propargyl iodides and diethylzinc: detection of propargyl radical by spin trapping

scientific article published on 10 October 2012

Electron Paramagnetic Resonance Spin Trapping of Glutathiyl Radicals by PBN in the Presence of Cyclodextrins and by PBN Attached to β-Cyclodextrin

scientific article published on 18 September 2008

Enlarging the Panoply of Site-Directed Spin Labeling Electron Paramagnetic Resonance (SDSL-EPR): Sensitive and Selective Spin-Labeling of Tyrosine Using an Isoindoline-Based Nitroxide ⬇️

scientific article published on May 22, 2013

Enzymatically Shifting Nitroxides for EPR Spectroscopy and Overhauser-Enhanced Magnetic Resonance Imaging

scientific article published on 17 September 2015

Factors influencing the C-O bond homolysis of alkoxyamines: effects of H-bonding and polar substituents.

scientific article published in February 2001

First proton triggered C-ON bond homolysis in alkoxyamines

scientific article published on 28 February 2011

How intramolecular hydrogen bonding (IHB) controls the C-ON bond homolysis in alkoxyamines

scientific article published on 27 September 2017

Hyperfine coupling constants of β-phosphorylated nitroxides: a tool to probe the cybotactic effect by electron paramagnetic resonance

scientific article published on 07 August 2012

Imidazoline-N-oxyl: a DFT study of its protonation reaction.

scientific article published in October 2009

In vivo Overhauser-enhanced MRI of proteolytic activity

scientific article

In vivo high‐resolution 3D Overhauser‐enhanced MRI in mice at 0.2 T ⬇️

scientific article published on January 1, 2012

Influence of the nitroxide structure on the homolysis rate constant of alkoxyamines: a Taft-Ingold analysis.

scientific article published in October 2003

Intramolecular proton transfer (IPT) in alkoxyamine: a theoretical investigation.

scientific article

Kinetic investigation of thermal and photoinduced homolysis of alkylated verdazyls

scientific article published on 24 September 2020

Kinetic subtleties of nitroxide mediated polymerization ⬇️

scientific article published on January 13, 2011

Labile alkoxyamines: past, present, and future.

scientific article published on July 2014

Laser flash photolysis and CIDNP studies of steric effects on coupling rate constants of imidazolidine nitroxide with carbon-centered radicals, methyl isobutyrate-2-yl and tert-butyl propionate-2-yl.

scientific article published in August 2006

New concepts in molecular imaging: non-invasive MRI spotting of proteolysis using an Overhauser effect switch.

scientific article

Nitroxide bound beta-cyclodextrin: is there an inclusion complex?

scientific article published on 01 September 2006

Normal, Leveled, and Enhanced Steric Effects in Alkoxyamines Carrying a β-Phosphorylated Nitroxyl Fragment.

scientific article

Orthogonal Tyrosine and Cysteine Site-Directed Spin Labeling for Dipolar Pulse EPR Spectroscopy on Proteins

scientific article

Persilylated phosphoranyl radicals: the first persistent noncyclic phosphoranyl radicals

scientific article published on 01 September 2006

Power Law Distribution Concerning Absolute Free Energies of Linear Sulfur Chains, Polythiazyls, Polyisoprenes, Linear trans-Polyenes, and Polyynes

scientific article published on 06 February 2019

Probing the dynamic properties of two sites simultaneously in a protein-protein interaction process: a SDSL-EPR study

scientific article published on 07 October 2019

Revised structure, total synthesis, and absolute configuration of kopeolin and kopeolone

scientific article published on 17 February 2014

Scavenging of organic C-centered radicals by nitroxides.

scientific article published on 26 February 2014

Selective On/Off-Nitroxides as Radical Probes to Investigate Non-radical Enzymatic Activity by Electron Paramagnetic Resonance

scientific article published on 03 May 2018

Shifting-Nitroxides to Investigate Enzymatic Hydrolysis of Fatty Acids by Lipases Using Electron Paramagnetic Resonance in Turbid Media

scientific article published on 23 April 2019

Smart Alkoxyamines: A New Tool for Smart Applications

scientific article published on 10 November 2020

Smart Control of Nitroxide-Mediated Polymerization Initiators' Reactivity by pH, Complexation with Metals, and Chemical Transformations

scientific article published on 26 February 2019

Solvent effect in β-phosphorylated nitroxides. Part 4: detection of traces of water by electron paramagnetic resonance

scientific article published on 09 December 2015

Spin-trapping evidence for the formation of alkyl, alkoxyl, and alkylperoxyl radicals in the reactions of dialkylzincs with oxygen

scientific article published on 05 January 2011

Structural Equilibrium in New Nitroxide-Capped Cyclodextrins: CW and Pulse EPR Study ⬇️

scientific article published on June 25, 2013

The β-phosphorus hyperfine coupling constant in nitroxide: part 3: titration of water by electron paramagnetic resonance

scientific article published on 01 December 2015

The β-phosphorus hyperfine coupling constant in nitroxides: 6. Solvent effects in non-cyclic nitroxides.

scientific article

Tyrosine‐Targeted Spin Labeling and EPR Spectroscopy: An Alternative Strategy for Studying Structural Transitions in Proteins ⬇️

scientific article published on August 24, 2011

Unexpectedly High Levels of Organic Compounds Released by Indoor Photocatalytic Paints

scientific article published on 19 September 2018

List of works by Sylvain Marque

Alkoxyamine Re-Formation Reaction. Effects of the Nitroxide Fragment: A Multiparameter Analysis

Alkoxyamine-mediated radical synthesis of indolinones and indolines

Alkoxyamines: a new family of pro-drugs against cancer. Concept for theranostics.

Alkoxyamines: toward a new family of theranostic agents against cancer

Alpha-phenyl-N-tert-butylnitrone-type derivatives bound to beta-cyclodextrins: syntheses, thermokinetics of self-inclusion and application to superoxide spin-trapping

Aminomethylation of Michael acceptors: complementary radical and polar approaches mediated by dialkylzincs

C-ON Bond Homolysis of Alkoxyamines, Part 11: Activation of the Nitroxyl Fragment.

C-ON bond homolysis in alkoxyamines. Part 12: the effect of the para-substituent in the 1-phenylethyl fragment

C-ON bond homolysis of alkoxyamines: when too high polarity is detrimental.

Chemically Triggered C-ON Bond Homolysis in Alkoxyamines. Part 2: DFT Investigation and Application of the pH Effect on NMP

Chemically Triggered C–ON Bond Homolysis in Alkoxyamines. 6. Effect of the Counteranion ⬇️

Chemically triggered C-ON bond homolysis in alkoxyamines: regioselectivity and chemoselectivity.

Chemically triggered C-ON bond homolysis of alkoxyamines. 5. Cybotactic effect

Chemically triggered C-ON bond homolysis of alkoxyamines. 8. Quaternization and steric effects

Chemically triggered C-ON bond homolysis of alkoxyamines. Quaternization of the alkyl fragment

Correction to Shifting-Nitroxides to Investigate Enzymatic Hydrolysis of Fatty Acids by Lipases Using Electron Paramagnetic Resonance in Turbid Media

Development and Application of Spin Traps, Spin Probes, and Spin Labels

Diversification of EPR signatures in Site Directed Spin Labeling using a β-phosphorylated nitroxide

Dynamics of the intrinsically disordered protein CP12 in its association with GAPDH in the green alga Chlamydomonas reinhardtii: a fuzzy complex.

EPR investigation of zinc/iodine exchange between propargyl iodides and diethylzinc: detection of propargyl radical by spin trapping

Electron Paramagnetic Resonance Spin Trapping of Glutathiyl Radicals by PBN in the Presence of Cyclodextrins and by PBN Attached to β-Cyclodextrin

Enlarging the Panoply of Site-Directed Spin Labeling Electron Paramagnetic Resonance (SDSL-EPR): Sensitive and Selective Spin-Labeling of Tyrosine Using an Isoindoline-Based Nitroxide ⬇️

Enzymatically Shifting Nitroxides for EPR Spectroscopy and Overhauser-Enhanced Magnetic Resonance Imaging

Factors influencing the C-O bond homolysis of alkoxyamines: effects of H-bonding and polar substituents.

First proton triggered C-ON bond homolysis in alkoxyamines

How intramolecular hydrogen bonding (IHB) controls the C-ON bond homolysis in alkoxyamines

Hyperfine coupling constants of β-phosphorylated nitroxides: a tool to probe the cybotactic effect by electron paramagnetic resonance

Imidazoline-N-oxyl: a DFT study of its protonation reaction.

In vivo Overhauser-enhanced MRI of proteolytic activity

In vivo high‐resolution 3D Overhauser‐enhanced MRI in mice at 0.2 T ⬇️

Influence of the nitroxide structure on the homolysis rate constant of alkoxyamines: a Taft-Ingold analysis.

Intramolecular proton transfer (IPT) in alkoxyamine: a theoretical investigation.

Kinetic investigation of thermal and photoinduced homolysis of alkylated verdazyls

Kinetic subtleties of nitroxide mediated polymerization ⬇️

Labile alkoxyamines: past, present, and future.

Laser flash photolysis and CIDNP studies of steric effects on coupling rate constants of imidazolidine nitroxide with carbon-centered radicals, methyl isobutyrate-2-yl and tert-butyl propionate-2-yl.

New concepts in molecular imaging: non-invasive MRI spotting of proteolysis using an Overhauser effect switch.

Nitroxide bound beta-cyclodextrin: is there an inclusion complex?

Normal, Leveled, and Enhanced Steric Effects in Alkoxyamines Carrying a β-Phosphorylated Nitroxyl Fragment.

Orthogonal Tyrosine and Cysteine Site-Directed Spin Labeling for Dipolar Pulse EPR Spectroscopy on Proteins

Persilylated phosphoranyl radicals: the first persistent noncyclic phosphoranyl radicals

Power Law Distribution Concerning Absolute Free Energies of Linear Sulfur Chains, Polythiazyls, Polyisoprenes, Linear trans-Polyenes, and Polyynes

Probing the dynamic properties of two sites simultaneously in a protein-protein interaction process: a SDSL-EPR study

Revised structure, total synthesis, and absolute configuration of kopeolin and kopeolone

Scavenging of organic C-centered radicals by nitroxides.

Selective On/Off-Nitroxides as Radical Probes to Investigate Non-radical Enzymatic Activity by Electron Paramagnetic Resonance

Shifting-Nitroxides to Investigate Enzymatic Hydrolysis of Fatty Acids by Lipases Using Electron Paramagnetic Resonance in Turbid Media

Smart Alkoxyamines: A New Tool for Smart Applications

Smart Control of Nitroxide-Mediated Polymerization Initiators' Reactivity by pH, Complexation with Metals, and Chemical Transformations

Solvent effect in β-phosphorylated nitroxides. Part 4: detection of traces of water by electron paramagnetic resonance

Spin-trapping evidence for the formation of alkyl, alkoxyl, and alkylperoxyl radicals in the reactions of dialkylzincs with oxygen

Structural Equilibrium in New Nitroxide-Capped Cyclodextrins: CW and Pulse EPR Study ⬇️

The β-phosphorus hyperfine coupling constant in nitroxide: part 3: titration of water by electron paramagnetic resonance

The β-phosphorus hyperfine coupling constant in nitroxides: 6. Solvent effects in non-cyclic nitroxides.

Tyrosine‐Targeted Spin Labeling and EPR Spectroscopy: An Alternative Strategy for Studying Structural Transitions in Proteins ⬇️

Unexpectedly High Levels of Organic Compounds Released by Indoor Photocatalytic Paints

β-Fragmentation of tertiary alkoxyl radicals: G3(MP2)-RAD and natural bond orbital investigations