List of works - Jean-François Carpentier

1,5-Diphenyl-4,8-bis(3-phenylpyrazol-1-yl)pyrazabole

scientific article published on 30 July 2005

A Theoretical Outlook on the Stereoselectivity Origins of Isoselective Zirconocene Propylene Polymerization Catalysts

scientific article published on 25 June 2018

A dual organic/organometallic approach for catalytic ring-opening polymerization

scientific article published on 04 August 2011

A versatile nitrogen ligand for alkaline-earth chemistry

scientific article published on 18 August 2020

Alkali aminoether-phenolate complexes: synthesis, structural characterization and evidence for an activated monomer ROP mechanism.

scientific article published on 18 January 2013

Alkaline Earth-Olefin Complexes with Secondary Interactions

scientific article published on 9 March 2016

Alkaline-Earth-Catalysed Cross-Dehydrocoupling of Amines and Hydrosilanes: Reactivity Trends, Scope and Mechanism

scientific article published on 11 February 2016

Alkaline-earth complexes with macrocyclic-functionalised bis(phenolate)s and bis(fluoroalkoxide)s

scientific article published on 11 September 2020

Allyl ansa-lanthanidocenes: single-component, single-site catalysts for controlled syndiospecific styrene and styrene-ethylene (Co)polymerization

scientific article published on 01 January 2007

Allyl strontium compounds: synthesis, molecular structure and properties

scientific article published on 12 June 2012

Aluminum and zinc complexes based on an amino-bis(pyrazolyl) ligand: synthesis, structures, and use in MMA and lactide polymerization

scientific article published on 01 January 2007

Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight

scientific article published on 25 February 2020

Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight

scientific article published on 21 February 2020

Barium-mediated cross-dehydrocoupling of hydrosilanes with amines: a theoretical and experimental approach

scientific article published on 27 May 2015

Base-induced cyclization of trimethoxy-o-aroyldiphenylphosphoryl methylbenzamide: a formal synthesis of (±) cherylline and (±) cherylline dimethylether

Beyond stereoselectivity, switchable catalysis: some of the last frontier challenges in ring-opening polymerization of cyclic esters.

scientific article published on April 2015

Bis(guanidinate) alkoxide complexes of lanthanides: synthesis, structures and use in immortal and stereoselective ring-opening polymerization of cyclic esters.

scientific article published in January 2008

C(sp₃)-H bond activation with triel metals: indium and gallium zwitterions through internal hydride abstraction in rigid salan ligands.

scientific article published on 19 May 2014

Cadmium complexes bearing Me2N^E^O- (E = S, Se) organochalcogenoalkoxides and their zinc and mercury analogues.

scientific article published on 21 February 2017

Calcium, Strontium and Barium Homogeneous Catalysts for Fine Chemicals Synthesis

scientific article published on 29 June 2016

Carboxylic acid derivatives via catalytic carboxylation of unsaturated hydrocarbons: whether the nature of a reductant may determine the mechanism of CO2 incorporation?

scientific article published on 5 August 2015

Chiral (1,2)-diphenylethylene-salen complexes of triel metals: coordination patterns and mechanistic considerations in the isoselective ROP of lactide

scientific article published on 7 April 2014

Chiral Fluorous Dialkoxy-Diamino Zirconium Complexes: Synthesis and Use in Stereospecific Polymerization of 1-Hexene

scientific article published on 12 January 2007

Conformationally dynamic titanium and zirconium cationic complexes of bis(naphthoxy)pyridine ligands: structure, "oscillation" and olefin polymerization catalysis.

scientific article published on 30 January 2017

Controlled ROP of β-butyrolactone simply mediated by amidine, guanidine, and phosphazene organocatalysts.

scientific article

Cyclohydroamination of aminoalkenes catalyzed by disilazide alkaline-earth metal complexes: reactivity patterns and deactivation pathways.

scientific article

Dinuclear vs. mononuclear complexes: accelerated, metal-dependent ring-opening polymerization of lactide

scientific article published on 01 December 2013

Direct Zn-diamine promoted reduction of C=O and C=N bonds by polymethylhydrosiloxane in methanol

scientific article published on 01 February 2003

Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides

scientific article published on 21 April 2015

Discrete Metal Catalysts for Stereoselective Ring‐Opening Polymerization of Chiral Racemic β‐Lactones ⬇️

scientific article published on 01 October 2010

Discrete cationic zinc and magnesium complexes for dual organic/organometallic-catalyzed ring-opening polymerization of trimethylene carbonate

scientific article published on 26 June 2012

Discrete, solvent-free alkaline-earth metal cations: metal···fluorine interactions and ROP catalytic activity

scientific article published on 18 May 2011

Divalent heteroleptic ytterbium complexes--effective catalysts for intermolecular styrene hydrophosphination and hydroamination.

scientific article published on 14 January 2014

Engineering of Syndiotactic and Isotactic Polystyrene-Based Copolymers via Stereoselective Catalytic Polymerization.

scientific article published on 7 April 2017

Ethylene oligomerization promoted by chromium complexes bearing pyrrolide-imine-amine/ether tridentate ligands

scientific article published on 01 September 2015

Evaluation of Band-Selective HSQC and HMBC: Methodological Validation on the Cyclosporin Cyclic Peptide and Application for Poly(3-hydroxyalkanoate)s Stereoregularity Determination

scientific article published on 16 May 2018

Exploitation of a chain-end-control mechanism for the synthesis of alternating copolymers

scientific article published on 01 April 2010

Exploring electronic versus steric effects in stereoselective ring-opening polymerization of lactide and β-butyrolactone with amino-alkoxy-bis(phenolate)-yttrium complexes.

scientific article

From syndiotactic homopolymers to chemically tunable alternating copolymers: highly active yttrium complexes for stereoselective ring-opening polymerization of β-malolactonates

scientific article published on 03 February 2014

Generation of cationic [Zr-[tert-butyl enolate]] reactive species: methyl abstraction versus hydride abstraction.

scientific article published in September 2004

Group 3 metal complexes supported by tridentate pyridine- and thiophene-linked bis(naphtholate) ligands: synthesis, structure, and use in stereoselective ring-opening polymerization of racemic lactide and beta-butyrolactone.

scientific article published on 7 January 2010

Heterobi- and -trimetallic Ion Pairs of Zirconocene-Based Isoselective Olefin Polymerization Catalysts with AlMe₃.

scientific article

Heteroleptic alkyl and amide iminoanilide alkaline earth and divalent rare earth complexes for the catalysis of hydrophosphination and (cyclo)hydroamination reactions

scientific article published on 19 August 2013

Heteroleptic silylamido phenolate complexes of calcium and the larger alkaline earth metals: β-agostic Ae⋅⋅⋅Si-H stabilization and activity in the ring-opening polymerization of L-lactide

scientific article published on 11 April 2012

Heteroleptic tin(II) initiators for the ring-opening (co)polymerization of lactide and trimethylene carbonate: mechanistic insights from experiments and computations

scientific article published on 19 August 2013

Highly Active, Productive, and Syndiospecific Yttrium Initiators for the Polymerization of Racemic β-Butyrolactone

scientific article published on 01 April 2006

Highly Effective Alkaline Earth Catalysts for the Sterically Governed Hydrophosphonylation of Aldehydes and Nonactivated Ketones ⬇️

scientific article published on September 13, 2012

Highly Effective and Green Catalytic Approach Toward α,ω-Dihydroxy-Telechelic Poly(trimethylenecarbonate).

scientific article published on 3 September 2009

Highly Stereocontrolled Ring-Opening Polymerization of Racemic Alkyl β-Malolactonates Mediated by Yttrium [Amino-alkoxy-bis(phenolate)] Complexes

scientific article published on 15 April 2016

Highly Syndiotactic or Isotactic Polyhydroxyalkanoates by Ligand-Controlled Yttrium-Catalyzed Stereoselective Ring-Opening Polymerization of Functional Racemic β-Lactones.

scientific article

Highly active, chemo- and regioselective Yb(II) and Sm(II) catalysts for the hydrophosphination of styrene with phenylphosphine

scientific article published on 11 March 2015

Highly fluorinated tris(indazolyl)borate silylamido complexes of the heavier alkaline earth metals: synthesis, characterization, and efficient catalytic intramolecular hydroamination

scientific article published on 23 January 2015

Highly isospecific styrene polymerization catalyzed by single-component bridged bis(indenyl) allyl yttrium and neodymium complexes

scientific article published on 01 January 2007

Low-Coordinate Barium Boryloxides: Synthesis and Dehydrocoupling Catalysis for the Production of Borasiloxanes

scientific article published on 08 August 2018

Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates.

scientific article published on 27 April 2010

On the coordination chemistry of organochalcogenolates R(NMe2)^E(-) and R(NMe2)^E^O(-) (E = S, Se) onto lead(II) and lighter divalent tetrel elements.

scientific article published in November 2014

On the initiation mechanism of syndiospecific styrene polymerization catalyzed by single-component ansa-lanthanidocenes.

scientific article published in January 2009

Organocatalysts for the controlled "immortal" ring-opening polymerization of six-membered-ring cyclic carbonates: a metal-free, green process.

scientific article published on December 2010

Pentacoordinated carboxylate π-allyl nickel complexes as key intermediates for the Ni-catalyzed direct amination of allylic alcohols

scientific article published on 26 August 2015

Recent Advances in Metal-Mediated Stereoselective Ring-Opening Polymerization of Functional Cyclic Esters towards Well-Defined Poly(hydroxy acid)s: From Stereoselectivity to Sequence-Control

scientific article published on 09 December 2019

Ring-opening polymerization of 3,6-dimethyl-2,5-morpholinedione with discrete amino-alkoxy-bis(phenolate) yttrium initiators: mechanistic insights

scientific article published on 01 November 2006

Ring-opening polymerization of lactide with group 3 metal complexes supported by dianionic alkoxy-amino-bisphenolate ligands: combining high activity, productivity, and selectivity.

scientific article

Scandium versus yttrium{amino-alkoxy-bis(phenolate)} complexes for the stereoselective ring-opening polymerization of racemic lactide and β-butyrolactone

scientific article published on 01 October 2014

Sequential Barium-Catalysed N-H/H-Si Dehydrogenative Cross-Couplings: Cyclodisilazanes versus Linear Oligosilazanes

scientific article published on 26 September 2016

Stable divalent germanium, tin and lead amino(ether)-phenolate monomeric complexes: structural features, inclusion heterobimetallic complexes, and ROP catalysis

scientific article published on 01 March 2014

Stereoselective ring-opening polymerization of racemic lactide using alkoxy-amino-bis(phenolate) group 3 metal complexes.

scientific article

Steric vs. electronic stereocontrol in syndio- or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes

scientific article published on 01 July 2018

Synthesis and structure of the first discrete dinuclear cationic aluminum complexes.

scientific article

Synthetic and Mechanistic Aspects of the Immortal Ring-Opening Polymerization of Lactide and Trimethylene Carbonate with New Homo- and Heteroleptic Tin(II)-Phenolate Catalysts

scientific article published on 20 January 2012

Tailored Cyclic and Linear Polycarbosilazanes by Barium-Catalyzed N-H/H-Si Dehydrocoupling Reactions.

scientific article published on 16 February 2016

Tandem C(sp(2))-OMe Activation/C(sp(2))-C(sp(2)) Coupling in Early Transition-Metal Complexes: Aromatic C-O Activation beyond Late Transition Metals

scientific article published on 23 March 2016

Tethered cationic alkaline earth - olefin complexes.

scientific article published on 18 October 2017

Well-defined syndiotactic polystyrene-b-atactic polystyrene stereoblock polymers

scientific article published on 30 March 2011

When bigger is better: intermolecular hydrofunctionalizations of activated alkenes catalyzed by heteroleptic alkaline Earth complexes

scientific article published on 11 April 2012

When single-site polymerization catalysis meets chirality: optical activity of stereoregular polyolefins

scientific article published on 01 January 2007

Yttrium-Mediated Ring-Opening Copolymerization of Oppositely Configurated 4-Alkoxymethylene-β-Propiolactones: Effective Access to Highly Alternated Isotactic Functional PHAs

scientific article published on 08 April 2019

α,ω-Epoxide, Oxetane, and Dithiocarbonate Telechelic Copolyolefins: Access by Ring-Opening Metathesis/Cross-Metathesis Polymerization (ROMP/CM) of Cycloolefins in the Presence of Functional Symmetric Chain-Transfer Agents

scientific article published on 09 November 2018

List of works by Jean-François Carpentier

1,5-Diphenyl-4,8-bis(3-phenylpyrazol-1-yl)pyrazabole

A Theoretical Outlook on the Stereoselectivity Origins of Isoselective Zirconocene Propylene Polymerization Catalysts

A dual organic/organometallic approach for catalytic ring-opening polymerization

A versatile nitrogen ligand for alkaline-earth chemistry

Alkali aminoether-phenolate complexes: synthesis, structural characterization and evidence for an activated monomer ROP mechanism.

Alkaline Earth-Olefin Complexes with Secondary Interactions

Alkaline-Earth-Catalysed Cross-Dehydrocoupling of Amines and Hydrosilanes: Reactivity Trends, Scope and Mechanism

Alkaline-earth complexes with macrocyclic-functionalised bis(phenolate)s and bis(fluoroalkoxide)s

Allyl ansa-lanthanidocenes: single-component, single-site catalysts for controlled syndiospecific styrene and styrene-ethylene (Co)polymerization

Allyl strontium compounds: synthesis, molecular structure and properties

Aluminum and zinc complexes based on an amino-bis(pyrazolyl) ligand: synthesis, structures, and use in MMA and lactide polymerization

Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight

Barium-Catalysed Dehydrocoupling of Hydrosilanes and Borinic Acids: A Mechanistic Insight

Barium-mediated cross-dehydrocoupling of hydrosilanes with amines: a theoretical and experimental approach

Base-induced cyclization of trimethoxy-o-aroyldiphenylphosphoryl methylbenzamide: a formal synthesis of (±) cherylline and (±) cherylline dimethylether

Beyond stereoselectivity, switchable catalysis: some of the last frontier challenges in ring-opening polymerization of cyclic esters.

Bis(guanidinate) alkoxide complexes of lanthanides: synthesis, structures and use in immortal and stereoselective ring-opening polymerization of cyclic esters.

C(sp₃)-H bond activation with triel metals: indium and gallium zwitterions through internal hydride abstraction in rigid salan ligands.

Cadmium complexes bearing Me2N^E^O- (E = S, Se) organochalcogenoalkoxides and their zinc and mercury analogues.

Calcium, Strontium and Barium Homogeneous Catalysts for Fine Chemicals Synthesis

Carboxylic acid derivatives via catalytic carboxylation of unsaturated hydrocarbons: whether the nature of a reductant may determine the mechanism of CO2 incorporation?

Chiral (1,2)-diphenylethylene-salen complexes of triel metals: coordination patterns and mechanistic considerations in the isoselective ROP of lactide

Chiral Fluorous Dialkoxy-Diamino Zirconium Complexes: Synthesis and Use in Stereospecific Polymerization of 1-Hexene

Conformationally dynamic titanium and zirconium cationic complexes of bis(naphthoxy)pyridine ligands: structure, "oscillation" and olefin polymerization catalysis.

Controlled ROP of β-butyrolactone simply mediated by amidine, guanidine, and phosphazene organocatalysts.

Cyclohydroamination of aminoalkenes catalyzed by disilazide alkaline-earth metal complexes: reactivity patterns and deactivation pathways.

Dinuclear vs. mononuclear complexes: accelerated, metal-dependent ring-opening polymerization of lactide

Direct Zn-diamine promoted reduction of C=O and C=N bonds by polymethylhydrosiloxane in methanol

Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides

Discrete Metal Catalysts for Stereoselective Ring‐Opening Polymerization of Chiral Racemic β‐Lactones ⬇️

Discrete cationic zinc and magnesium complexes for dual organic/organometallic-catalyzed ring-opening polymerization of trimethylene carbonate

Discrete, solvent-free alkaline-earth metal cations: metal···fluorine interactions and ROP catalytic activity

Divalent heteroleptic ytterbium complexes--effective catalysts for intermolecular styrene hydrophosphination and hydroamination.

Engineering of Syndiotactic and Isotactic Polystyrene-Based Copolymers via Stereoselective Catalytic Polymerization.

Ethylene oligomerization promoted by chromium complexes bearing pyrrolide-imine-amine/ether tridentate ligands

Evaluation of Band-Selective HSQC and HMBC: Methodological Validation on the Cyclosporin Cyclic Peptide and Application for Poly(3-hydroxyalkanoate)s Stereoregularity Determination

Exploitation of a chain-end-control mechanism for the synthesis of alternating copolymers

Exploring electronic versus steric effects in stereoselective ring-opening polymerization of lactide and β-butyrolactone with amino-alkoxy-bis(phenolate)-yttrium complexes.

From syndiotactic homopolymers to chemically tunable alternating copolymers: highly active yttrium complexes for stereoselective ring-opening polymerization of β-malolactonates

Generation of cationic [Zr-[tert-butyl enolate]] reactive species: methyl abstraction versus hydride abstraction.

Group 3 metal complexes supported by tridentate pyridine- and thiophene-linked bis(naphtholate) ligands: synthesis, structure, and use in stereoselective ring-opening polymerization of racemic lactide and beta-butyrolactone.

Heterobi- and -trimetallic Ion Pairs of Zirconocene-Based Isoselective Olefin Polymerization Catalysts with AlMe₃.

Heteroleptic alkyl and amide iminoanilide alkaline earth and divalent rare earth complexes for the catalysis of hydrophosphination and (cyclo)hydroamination reactions

Heteroleptic silylamido phenolate complexes of calcium and the larger alkaline earth metals: β-agostic Ae⋅⋅⋅Si-H stabilization and activity in the ring-opening polymerization of L-lactide

Heteroleptic tin(II) initiators for the ring-opening (co)polymerization of lactide and trimethylene carbonate: mechanistic insights from experiments and computations

Highly Active, Productive, and Syndiospecific Yttrium Initiators for the Polymerization of Racemic β-Butyrolactone

Highly Effective Alkaline Earth Catalysts for the Sterically Governed Hydrophosphonylation of Aldehydes and Nonactivated Ketones ⬇️

Highly Effective and Green Catalytic Approach Toward α,ω-Dihydroxy-Telechelic Poly(trimethylenecarbonate).

Highly Stereocontrolled Ring-Opening Polymerization of Racemic Alkyl β-Malolactonates Mediated by Yttrium [Amino-alkoxy-bis(phenolate)] Complexes

Highly Syndiotactic or Isotactic Polyhydroxyalkanoates by Ligand-Controlled Yttrium-Catalyzed Stereoselective Ring-Opening Polymerization of Functional Racemic β-Lactones.

Highly active, chemo- and regioselective Yb(II) and Sm(II) catalysts for the hydrophosphination of styrene with phenylphosphine

Highly fluorinated tris(indazolyl)borate silylamido complexes of the heavier alkaline earth metals: synthesis, characterization, and efficient catalytic intramolecular hydroamination

Highly isospecific styrene polymerization catalyzed by single-component bridged bis(indenyl) allyl yttrium and neodymium complexes

Low-Coordinate Barium Boryloxides: Synthesis and Dehydrocoupling Catalysis for the Production of Borasiloxanes

Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates.

On the coordination chemistry of organochalcogenolates R(NMe2)^E(-) and R(NMe2)^E^O(-) (E = S, Se) onto lead(II) and lighter divalent tetrel elements.

On the initiation mechanism of syndiospecific styrene polymerization catalyzed by single-component ansa-lanthanidocenes.

Organocatalysts for the controlled "immortal" ring-opening polymerization of six-membered-ring cyclic carbonates: a metal-free, green process.

Pentacoordinated carboxylate π-allyl nickel complexes as key intermediates for the Ni-catalyzed direct amination of allylic alcohols

Recent Advances in Metal-Mediated Stereoselective Ring-Opening Polymerization of Functional Cyclic Esters towards Well-Defined Poly(hydroxy acid)s: From Stereoselectivity to Sequence-Control

Ring-opening polymerization of 3,6-dimethyl-2,5-morpholinedione with discrete amino-alkoxy-bis(phenolate) yttrium initiators: mechanistic insights

Ring-opening polymerization of lactide with group 3 metal complexes supported by dianionic alkoxy-amino-bisphenolate ligands: combining high activity, productivity, and selectivity.

Scandium versus yttrium{amino-alkoxy-bis(phenolate)} complexes for the stereoselective ring-opening polymerization of racemic lactide and β-butyrolactone

Sequential Barium-Catalysed N-H/H-Si Dehydrogenative Cross-Couplings: Cyclodisilazanes versus Linear Oligosilazanes

Stable divalent germanium, tin and lead amino(ether)-phenolate monomeric complexes: structural features, inclusion heterobimetallic complexes, and ROP catalysis

Stereoselective ring-opening polymerization of racemic lactide using alkoxy-amino-bis(phenolate) group 3 metal complexes.

Steric vs. electronic stereocontrol in syndio- or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes

Synthesis and structure of the first discrete dinuclear cationic aluminum complexes.

Synthetic and Mechanistic Aspects of the Immortal Ring-Opening Polymerization of Lactide and Trimethylene Carbonate with New Homo- and Heteroleptic Tin(II)-Phenolate Catalysts

Tailored Cyclic and Linear Polycarbosilazanes by Barium-Catalyzed N-H/H-Si Dehydrocoupling Reactions.

Tandem C(sp(2))-OMe Activation/C(sp(2))-C(sp(2)) Coupling in Early Transition-Metal Complexes: Aromatic C-O Activation beyond Late Transition Metals

Tethered cationic alkaline earth - olefin complexes.

Well-defined syndiotactic polystyrene-b-atactic polystyrene stereoblock polymers

When bigger is better: intermolecular hydrofunctionalizations of activated alkenes catalyzed by heteroleptic alkaline Earth complexes

When single-site polymerization catalysis meets chirality: optical activity of stereoregular polyolefins

Yttrium-Mediated Ring-Opening Copolymerization of Oppositely Configurated 4-Alkoxymethylene-β-Propiolactones: Effective Access to Highly Alternated Isotactic Functional PHAs

α,ω-Epoxide, Oxetane, and Dithiocarbonate Telechelic Copolyolefins: Access by Ring-Opening Metathesis/Cross-Metathesis Polymerization (ROMP/CM) of Cycloolefins in the Presence of Functional Symmetric Chain-Transfer Agents