List of works - José Alemán

"Anti-Michael addition" of Grignard reagents to sulfonylacetylenes: synthesis of alkynes

scientific article published on 01 May 2017

2-Hydroxybenzophenone as a Chemical Auxiliary for the Activation of Ketiminoesters for Highly Enantioselective Addition to Nitroalkenes under Bifunctional Catalysis.

scientific article published on 14 April 2018

8-Mercaptoquinoline as a Ligand for Enhancing the Photocatalytic Activity of Pt(II) Coordination Complexes: Reactions and Mechanistic Insights

scientific article published on 30 April 2019

A General Asymmetric Formal Synthesis of Aza-Baylis-Hillman Type Products under Bifunctional Catalysis.

scientific article published on 28 November 2017

A General Method for the Preparation ofN-Sulfonyl Aldimines and Ketimines†

scientific article published on 01 January 2005

A New General Method for the Preparation ofN-Sulfonyloxaziridines

scientific article published on 01 November 2005

A New Strategy for the Synthesis of Optically Pure β-Fluoroalkyl β-Amino Acid Derivatives

scientific article published on 01 February 2009

A novel asymmetric vinylogous tin-Pummerer rearrangement

scientific article published on 01 May 2004

A straightforward alkynylation of Li and Mg metalated heterocycles with sulfonylacetylenes

scientific article published on 14 November 2014

An Unexpected Organocatalytic Asymmetric Tandem Michael/Morita–Baylis–Hillman Reaction

scientific article published in January 2008

Applications of asymmetric organocatalysis in medicinal chemistry ⬇️

scientific article published on January 21, 2013

Arylsulfonylacetylenes as Alkynylating Reagents of C sp 2H Bonds Activated with Lithium Bases

scientific article published on 01 February 2012

Asymmetric 1,4-addition of oxazolones to nitroalkenes by bifunctional cinchona alkaloid thiourea organocatalysts: synthesis of alpha,alpha-disubstituted alpha-amino acids.

scientific article

Asymmetric Intramolecular Pauson–Khand Reaction Mediated by a Remote Sulfenyl or Sulfinyl Group

scientific article published on 25 July 2012

Asymmetric Organocatalytic α-Arylation of Aldehydes

scientific article published on 16 July 2007

Asymmetric Synthesis of 1,2-Diamines bearing Tetrasubstituted Centers from Nonstabilized Azomethine Ylides and N-Sulfinylketimines under Brønsted Acid Catalysis

scientific article published on 14 December 2015

Asymmetric Synthesis of Cyclobutanes by a Formal [2+2] Cycloaddition Controlled by Dienamine Catalysis

scientific article published on 22 August 2012

Asymmetric Synthesis of Rauhut-Currier type Products by a Regioselective Mukaiyama Reaction under Bifunctional Catalysis

scientific article published on 22 December 2016

Asymmetric Synthesis of Secondary and Tertiary Propargylic Alcohols by Umpolung of Acetylenic Sulfones and ortho-Sulfinyl Carbanions.

scientific article published on 15 January 2018

Asymmetric Synthesis of α-Trifluoromethylthio-β-Amino Acids under Phase Transfer Catalysis

scientific article published on 13 December 2019

Asymmetric [2,3]-Wittig Rearrangement: Synthesis of Homoallylic, Allenylic, and Enynyl α-Benzyl Alcohols

scientific article published on 10 December 2018

Asymmetric aza-Henry reactions from N-p-tolylsulfinylimines

scientific article published on 01 September 2005

Asymmetric radical alkylation of N-sulfinimines under visible light photocatalytic conditions.

scientific article

Asymmetric synthesis of 4-amino-4H-chromenes by organocatalytic oxa-Michael/aza-Baylis-Hillman tandem reactions

scientific article published on 01 August 2010

Asymmetric synthesis of Rauhut-Currier-type esters via Mukaiyama-Michael reaction to acylphosphonates under bifunctional catalysis

scientific article published on 01 December 2018

Asymmetric synthesis of quaternary α-amino acid derivatives and their fluorinated analogues

scientific article published on 22 March 2011

Asymmetric synthesis of trans-dihydroarylfurans in a Friedel–Crafts/substitution domino reaction under squaramide catalysis

scientific article published on 01 March 2013

Asymmetric synthesis of α-alkyl α-selenocarbonyl compounds catalyzed by bifunctional organocatalysts

scientific article published on 17 May 2011

Asymmetric trifluoromethylthiolation of azlactones under chiral phase transfer catalysis

scientific article published on 01 April 2020

Asymmetric vinylogous Mukaiyama aldol reaction of isatins under bifunctional organocatalysis: enantioselective synthesis of substituted 3-hydroxy-2-oxindoles

scientific article published on 27 February 2018

BODIPY as electron withdrawing group for the activation of double bonds in asymmetric cycloaddition reactions

scientific article published on 20 March 2019

Bioinspired Electro-Organocatalytic Material Efficient for Hydrogen Production.

scientific article published on 3 January 2018

Complete regio- and stereoselectivity control in the halohydroxylation of non-activated allenes mediated by a remote sulfinyl group

scientific article published on 01 January 2009

Complete stereocontrol in organocatalytic additions of β-ketosulfoxides to conjugated aldehydes

scientific article published on 25 February 2011

Configurational control of benzyl carbanion-copper complexes by sulfinyl groups: synthesis of optically pure allenes with central and axial chirality.

scientific article published in January 2008

Control of the Dual Reactivity (Iminium-Dienamine) of β-Arylmethyl α,β-Unsaturated Aldehydes in Organocatalytic 1,3-Dipolar Cycloadditions with N-Benzoyl C,N-Cyclic Azomethine Imines

scientific article published on 24 October 2014

Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates

scientific article published in 2012

Development and Application of Asymmetric Organocatalytic Mukaiyama and Vinylogous Mukaiyama-Type Reactions

scientific article published on 06 July 2018

Dienamine and Friedel-Crafts one-pot synthesis, and antitumor evaluation of diheteroarylalkanals.

scientific article published on 23 April 2015

Effect of electronic and steric properties of 8-substituted quinolines in gold(III) complexes: Synthesis, electrochemistry, stability, interactions and antiproliferative studies.

scientific article published on 17 June 2017

Enantioselective aza-Henry reactions of cyclic α-carbonyl ketimines under bifunctional catalysis

scientific article published on 01 October 2012

Evaluation of novel trans-sulfonamide platinum complexes against tumor cell lines.

scientific article published on 11 February 2014

Expanding the Scope of Arylsulfonylacetylenes as Alkynylating Reagents and Mechanistic Insights in the Formation of Csp2Csp and Csp3Csp Bonds from Organolithiums

scientific article published on 04 June 2012

Expanding the synthesis of new trans-sulfonamide platinum complexes: cytotoxicity, SAR, fluorescent cell assays and stability studies.

scientific article published on 8 February 2013

Facile synthesis of optically pure 1,2-diaryl (and 1-Alkyl-2-aryl) ethyl and propylamines

scientific article published on 01 March 2003

Gold(III) complexes with hydroxyquinoline, aminoquinoline and quinoline ligands: Synthesis, cytotoxicity, DNA and protein binding studies.

scientific article published on 3 October 2015

Highly Enantioselective Construction of Tricyclic Derivatives by the Desymmetrization of Cyclohexadienones

scientific article published on 20 June 2014

Highly stereoselective benzylation of N-sulfinylketimines.

scientific article

Highly stereoselective synthesis of tertiary propargylic centers and their isomerization to enantiomerically enriched allenes

scientific article published on 02 July 2012

Intramolecular Homolytic Substitution Enabled by Photoredox Catalysis: Sulfur, Phosphorus, and Silicon Heterocycle Synthesis from Aryl Halides

scientific article published on 18 June 2019

Intramolecular Hydrogen Bond Activation: Thiourea-Organocatalyzed Enantioselective 1,3-Dipolar Cycloaddition of Salicylaldehyde-Derived Azomethine Ylides with Nitroalkenes.

scientific article

Intramolecular hydrogen-bond activation for the addition of nucleophilic imines: 2-hydroxybenzophenone as a chemical auxiliary.

scientific article

Mechanistic added value of a trans-Sulfonamide-Platinum-Complex in human melanoma cell lines and synergism with cis-Platin

scientific article published on 23 February 2017

Metallic organophosphates as catalysts in asymmetric synthesis: a return journey.

scientific article published on 09 May 2012

Mono- and Bimetallic Alkynyl Metallocenes and Half-Sandwich Complexes: A Simple and Versatile Synthetic Approach.

scientific article

Monoalkylation of primary amines and N-sulfinylamides

scientific article published on 24 November 2008

New reactions of anticancer-platinum complexes and their intriguing behaviour under various experimental conditions

scientific article published on 05 October 2010

Novel Oxidative Ugi Reaction for the Synthesis of Highly Active, Visible-Light, Imide-Acridinium Organophotocatalysts

scientific article published on 25 July 2018

Novel clioquinol and its analogous platinum complexes: importance, role of the halogen substitution and the hydroxyl group of the ligand.

scientific article published on 14 August 2013

Nucleophilic halo-Michael addition under Lewis-base activation

scientific article published on 01 October 2019

Old tricks, new dogs: organocatalytic dienamine activation of α,β-unsaturated aldehydes

scientific article published on 2 November 2016

One-pot synthesis of pentasubstituted cyclohexanes by a Michael addition followed by a tandem inter-intra double Henry reaction

scientific article published on 01 July 2009

Organocatalytic Highly enantioselective alpha-arylation of beta-ketoesters

scientific article published on 01 January 2007

Organocatalytic asymmetric "anti-Michael" reaction of beta-ketoesters

scientific article published on 16 August 2007

Organocatalytic asymmetric direct alpha-alkynylation of cyclic beta-ketoesters

scientific article published on 01 January 2007

Organocatalytic asymmetric vinylogous addition to quinones - formation of optically active alpha-aryl ketones

scientific article published on 28 November 2007

Organocatalytic vs. Ru-based electrochemical hydrogenation of nitrobenzene in competition with the hydrogen evolution reaction

scientific article published on 01 May 2020

Oxidative C-H bond functionalization and ring expansion with TMSCHN2 : a copper(I)-catalyzed approach to dibenzoxepines and dibenzoazepines

scientific article published on 03 March 2015

Oxidative addition of Pd0 to Ar-SO2R bonds: heck-type reactions of sulfones

scientific article published on 01 June 2006

Photocatalytic Water-Soluble Cationic Platinum(II) Complexes Bearing Quinolinate and Phosphine Ligands

scientific article published on 25 September 2020

Pt(ii) coordination complexes as visible light photocatalysts for the oxidation of sulfides using batch and flow processes

scientific article published in 2016

Squaramides: Bridging from Molecular Recognition to Bifunctional Organocatalysis

scientific article published on 17 May 2011

Stereocontrolled Addition of Scrambling ortho-Sulfinyl Carbanions: Easy Access to Homopropargylamines and α-Allenylamines

scientific article published on 10 March 2020

Stereocontrolled reactions mediated by a remote sulfoxide group: synthesis of optically pure anti-beta-amino alcohols

scientific article published on 01 November 2003

Stereodivergent Aminocatalytic Synthesis of Z- and E-Trisubstituted Double Bonds from Alkynals

scientific article published on 19 October 2016

Synthesis and Stereoselective Halogenolysis of Optically Pure Benzylstannanes

scientific article published on 01 March 2009

Synthesis of chiral cyclic nitrones by asymmetric addition of β-ketosulfones to nitroalkenes followed by reductive cyclization

scientific article published on 24 November 2010

Synthesis of unfunctionalized carbonated fragments containing two vicinal chiral centers: stereocontrolled benzylation of vinylsulfones mediated by a remote sulfinyl group

scientific article published on 01 August 2010

Tandem cyclization-Michael reaction by combination of metal- and organocatalysis

scientific article published on 05 August 2011

The organocatalytic addition of bis(arylsulfonyl)methane to alpha,beta-unsaturated aldehydes and the synthesis of optically-enriched 3-methyl-alkanols.

scientific article published on 12 June 2009

Thiol-ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides.

scientific article

Unlocking the direct photocatalytic difluoromethylation of C[double bond, length as m-dash]N bonds

scientific article published on 01 March 2020

Visible light photocatalysis - from racemic to asymmetric activation strategies

scientific article published on 01 September 2020

Visible-Light Photocatalytic Intramolecular Cyclopropane Ring Expansion

scientific article published on 10 May 2017

π–π Stacking versus Steric Effects in Stereoselectivity Control: Highly Diastereoselective Synthesis ofsyn-1,2-Diarylpropylamines

scientific article published on 01 January 2007

List of works by José Alemán

"Anti-Michael addition" of Grignard reagents to sulfonylacetylenes: synthesis of alkynes

2-Hydroxybenzophenone as a Chemical Auxiliary for the Activation of Ketiminoesters for Highly Enantioselective Addition to Nitroalkenes under Bifunctional Catalysis.

8-Mercaptoquinoline as a Ligand for Enhancing the Photocatalytic Activity of Pt(II) Coordination Complexes: Reactions and Mechanistic Insights

A General Asymmetric Formal Synthesis of Aza-Baylis-Hillman Type Products under Bifunctional Catalysis.

A General Method for the Preparation ofN-Sulfonyl Aldimines and Ketimines†

A New General Method for the Preparation ofN-Sulfonyloxaziridines

A New Strategy for the Synthesis of Optically Pure β-Fluoroalkyl β-Amino Acid Derivatives

A novel asymmetric vinylogous tin-Pummerer rearrangement

A straightforward alkynylation of Li and Mg metalated heterocycles with sulfonylacetylenes

An Unexpected Organocatalytic Asymmetric Tandem Michael/Morita–Baylis–Hillman Reaction

Applications of asymmetric organocatalysis in medicinal chemistry ⬇️

Arylsulfonylacetylenes as Alkynylating Reagents of C sp 2H Bonds Activated with Lithium Bases

Asymmetric 1,4-addition of oxazolones to nitroalkenes by bifunctional cinchona alkaloid thiourea organocatalysts: synthesis of alpha,alpha-disubstituted alpha-amino acids.

Asymmetric Intramolecular Pauson–Khand Reaction Mediated by a Remote Sulfenyl or Sulfinyl Group

Asymmetric Organocatalytic α-Arylation of Aldehydes

Asymmetric Synthesis of 1,2-Diamines bearing Tetrasubstituted Centers from Nonstabilized Azomethine Ylides and N-Sulfinylketimines under Brønsted Acid Catalysis

Asymmetric Synthesis of Cyclobutanes by a Formal [2+2] Cycloaddition Controlled by Dienamine Catalysis

Asymmetric Synthesis of Rauhut-Currier type Products by a Regioselective Mukaiyama Reaction under Bifunctional Catalysis

Asymmetric Synthesis of Secondary and Tertiary Propargylic Alcohols by Umpolung of Acetylenic Sulfones and ortho-Sulfinyl Carbanions.

Asymmetric Synthesis of α-Trifluoromethylthio-β-Amino Acids under Phase Transfer Catalysis

Asymmetric [2,3]-Wittig Rearrangement: Synthesis of Homoallylic, Allenylic, and Enynyl α-Benzyl Alcohols

Asymmetric aza-Henry reactions from N-p-tolylsulfinylimines

Asymmetric radical alkylation of N-sulfinimines under visible light photocatalytic conditions.

Asymmetric synthesis of 4-amino-4H-chromenes by organocatalytic oxa-Michael/aza-Baylis-Hillman tandem reactions

Asymmetric synthesis of Rauhut-Currier-type esters via Mukaiyama-Michael reaction to acylphosphonates under bifunctional catalysis

Asymmetric synthesis of quaternary α-amino acid derivatives and their fluorinated analogues

Asymmetric synthesis of trans-dihydroarylfurans in a Friedel–Crafts/substitution domino reaction under squaramide catalysis

Asymmetric synthesis of α-alkyl α-selenocarbonyl compounds catalyzed by bifunctional organocatalysts

Asymmetric trifluoromethylthiolation of azlactones under chiral phase transfer catalysis

Asymmetric vinylogous Mukaiyama aldol reaction of isatins under bifunctional organocatalysis: enantioselective synthesis of substituted 3-hydroxy-2-oxindoles

BODIPY as electron withdrawing group for the activation of double bonds in asymmetric cycloaddition reactions

Bioinspired Electro-Organocatalytic Material Efficient for Hydrogen Production.

Complete regio- and stereoselectivity control in the halohydroxylation of non-activated allenes mediated by a remote sulfinyl group

Complete stereocontrol in organocatalytic additions of β-ketosulfoxides to conjugated aldehydes

Configurational control of benzyl carbanion-copper complexes by sulfinyl groups: synthesis of optically pure allenes with central and axial chirality.

Control of the Dual Reactivity (Iminium-Dienamine) of β-Arylmethyl α,β-Unsaturated Aldehydes in Organocatalytic 1,3-Dipolar Cycloadditions with N-Benzoyl C,N-Cyclic Azomethine Imines

Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates

Development and Application of Asymmetric Organocatalytic Mukaiyama and Vinylogous Mukaiyama-Type Reactions

Dienamine and Friedel-Crafts one-pot synthesis, and antitumor evaluation of diheteroarylalkanals.

Effect of electronic and steric properties of 8-substituted quinolines in gold(III) complexes: Synthesis, electrochemistry, stability, interactions and antiproliferative studies.

Enantioselective aza-Henry reactions of cyclic α-carbonyl ketimines under bifunctional catalysis

Evaluation of novel trans-sulfonamide platinum complexes against tumor cell lines.

Expanding the Scope of Arylsulfonylacetylenes as Alkynylating Reagents and Mechanistic Insights in the Formation of Csp2Csp and Csp3Csp Bonds from Organolithiums

Expanding the synthesis of new trans-sulfonamide platinum complexes: cytotoxicity, SAR, fluorescent cell assays and stability studies.

Facile synthesis of optically pure 1,2-diaryl (and 1-Alkyl-2-aryl) ethyl and propylamines

Gold(III) complexes with hydroxyquinoline, aminoquinoline and quinoline ligands: Synthesis, cytotoxicity, DNA and protein binding studies.

Highly Enantioselective Construction of Tricyclic Derivatives by the Desymmetrization of Cyclohexadienones

Highly stereoselective benzylation of N-sulfinylketimines.

Highly stereoselective synthesis of tertiary propargylic centers and their isomerization to enantiomerically enriched allenes

Intramolecular Homolytic Substitution Enabled by Photoredox Catalysis: Sulfur, Phosphorus, and Silicon Heterocycle Synthesis from Aryl Halides

Intramolecular Hydrogen Bond Activation: Thiourea-Organocatalyzed Enantioselective 1,3-Dipolar Cycloaddition of Salicylaldehyde-Derived Azomethine Ylides with Nitroalkenes.

Intramolecular hydrogen-bond activation for the addition of nucleophilic imines: 2-hydroxybenzophenone as a chemical auxiliary.

Mechanistic added value of a trans-Sulfonamide-Platinum-Complex in human melanoma cell lines and synergism with cis-Platin

Metallic organophosphates as catalysts in asymmetric synthesis: a return journey.

Mono- and Bimetallic Alkynyl Metallocenes and Half-Sandwich Complexes: A Simple and Versatile Synthetic Approach.

Monoalkylation of primary amines and N-sulfinylamides

New reactions of anticancer-platinum complexes and their intriguing behaviour under various experimental conditions

Novel Oxidative Ugi Reaction for the Synthesis of Highly Active, Visible-Light, Imide-Acridinium Organophotocatalysts

Novel clioquinol and its analogous platinum complexes: importance, role of the halogen substitution and the hydroxyl group of the ligand.

Nucleophilic halo-Michael addition under Lewis-base activation

Old tricks, new dogs: organocatalytic dienamine activation of α,β-unsaturated aldehydes

One-pot synthesis of pentasubstituted cyclohexanes by a Michael addition followed by a tandem inter-intra double Henry reaction

Organocatalytic Highly enantioselective alpha-arylation of beta-ketoesters

Organocatalytic asymmetric "anti-Michael" reaction of beta-ketoesters

Organocatalytic asymmetric direct alpha-alkynylation of cyclic beta-ketoesters

Organocatalytic asymmetric vinylogous addition to quinones - formation of optically active alpha-aryl ketones

Organocatalytic vs. Ru-based electrochemical hydrogenation of nitrobenzene in competition with the hydrogen evolution reaction

Oxidative C-H bond functionalization and ring expansion with TMSCHN2 : a copper(I)-catalyzed approach to dibenzoxepines and dibenzoazepines

Oxidative addition of Pd0 to Ar-SO2R bonds: heck-type reactions of sulfones

Photocatalytic Water-Soluble Cationic Platinum(II) Complexes Bearing Quinolinate and Phosphine Ligands

Pt(ii) coordination complexes as visible light photocatalysts for the oxidation of sulfides using batch and flow processes

Squaramides: Bridging from Molecular Recognition to Bifunctional Organocatalysis

Stereocontrolled Addition of Scrambling ortho-Sulfinyl Carbanions: Easy Access to Homopropargylamines and α-Allenylamines

Stereocontrolled reactions mediated by a remote sulfoxide group: synthesis of optically pure anti-beta-amino alcohols

Stereodivergent Aminocatalytic Synthesis of Z- and E-Trisubstituted Double Bonds from Alkynals

Synthesis and Stereoselective Halogenolysis of Optically Pure Benzylstannanes

Synthesis of chiral cyclic nitrones by asymmetric addition of β-ketosulfones to nitroalkenes followed by reductive cyclization

Synthesis of unfunctionalized carbonated fragments containing two vicinal chiral centers: stereocontrolled benzylation of vinylsulfones mediated by a remote sulfinyl group

Tandem cyclization-Michael reaction by combination of metal- and organocatalysis