List of works - Shigeki Matsunaga

A Cp*CoI2-dimer as a precursor for cationic Co(III)-catalysis: application to C-H phosphoramidation of indoles.

scientific article published in March 2015

A heterobimetallic Ga/Yb-Schiff base complex for catalytic asymmetric alpha-addition of isocyanides to aldehydes.

scientific article published in June 2009

A heterobimetallic Ni/La-salan complex for catalytic asymmetric decarboxylative 1,4-addition of malonic acid half-thioester.

scientific article published on November 2010

A heterobimetallic Pd/La/Schiff base complex for anti-selective catalytic asymmetric nitroaldol reactions and applications to short syntheses of beta-adrenoceptor agonists.

scientific article

A homodinuclear Mn(III)2-Schiff base complex for catalytic asymmetric 1,4-additions of oxindoles to nitroalkenes.

scientific article

A method for the synthesis of an oseltamivir PET tracer.

scientific article published on 28 November 2007

A stable homodinuclear biscobalt(III)-Schiff base complex for catalytic asymmetric 1,4-addition reactions of beta-keto esters to alkynones

scientific article published on 01 January 2009

An efficient synthesis of bicyclic amidines by intramolecular cyclization

scientific article published on 01 January 2004

Ba-catalyzed direct Mannich-type reactions of a beta,gamma-unsaturated ester providing beta-methyl aza-Morita-Baylis-Hillman-type products

scientific article published on 26 July 2007

Bismuth- and hafnium-catalyzed hydroamination of vinyl arenes with sulfonamides, carbamates, and carboxamides

scientific article published on 01 January 2007

Bismuth-catalyzed direct substitution of the hydroxy group in alcohols with sulfonamides, carbamates, and carboxamides

scientific article published on 01 January 2007

C-H γ,γ,γ-Trifluoroalkylation of Quinolines via Visible-Light-Induced Sequential Radical Additions

scientific article published on 06 May 2019

Catalytic Asymmetric Aza-Morita−Baylis−Hillman Reaction of Methyl Acrylate: Role of a Bifunctional La(O-iPr)3/Linked-BINOL Complex ⬇️

scientific article published on September 1, 2010

Catalytic Asymmetric Iterative/Domino Aldehyde Cross-Aldol Reactions for the Rapid and Flexible Synthesis of 1,3-Polyols.

scientific article

Catalytic Enantioselective Methylene C(sp3 )-H Amidation of 8-Alkylquinolines Using a Cp*RhIII /Chiral Carboxylic Acid System

scientific article published on 11 November 2019

Catalytic asymmetric 1,4-addition reactions using alpha,beta-unsaturated N-acylpyrroles as highly reactive monodentate alpha,beta-unsaturated ester surrogates.

scientific article

Catalytic asymmetric 1,4-additions of beta-keto esters to nitroalkenes promoted by a bifunctional homobimetallic Co2-Schiff base complex

scientific article published on 22 January 2010

Catalytic asymmetric epoxidation of alpha,beta-unsaturated esters with chiral yttrium-biaryldiol complexes

scientific article published on 01 February 2007

Catalytic asymmetric epoxidation of alpha,beta-unsaturated phosphane oxides with a Y(O-iPr)3/biphenyldiol complex.

scientific article published in September 2008

Catalytic asymmetric ring-opening of meso-aziridines with malonates under heterodinuclear rare earth metal Schiff base catalysis

scientific article published on 28 March 2011

Catalytic asymmetric synthesis of 2,2-disubstituted terminal epoxides via dimethyloxosulfonium methylide addition to ketones.

scientific article published on 10 July 2008

Catalytic asymmetric synthesis of spirooxindoles by a mannich-type reaction of isothiocyanato oxindoles

scientific article published on 04 June 2012

Catalytic asymmetric synthesis of spirooxindoles via addition of isothiocyanato oxindoles to aldehydes under dinuclear nickel Schiff base catalysis

scientific article published on 15 April 2013

Catalytic asymmetric total synthesis of chimonanthine, folicanthine, and calycanthine through double Michael reaction of bisoxindole

scientific article published on 12 April 2012

Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination.

scientific article published on 9 June 2005

Cationic bismuth-catalyzed hydroamination and direct substitution of the hydroxy group in alcohols with amides

scientific article published on 01 January 2012

Chemoselective Cleavage of Si-C(sp<sup>3</sup>) Bonds in Unactivated Tetraalkylsilanes Using Iodine Tris(trifluoroacetate)

scientific article published on 24 December 2020

Chiral Carboxylic Acid Enabled Achiral Rhodium(III)-Catalyzed Enantioselective C-H Functionalization

scientific article published on 16 August 2018

Chiral gamma-amino amide synthesis by heterobimetallic lanthanum/lithium/Pybox-catalyzed direct asymmetric mannich-type reactions of alpha-keto anilides

scientific article published on 01 January 2008

Cobalt-Catalyzed Allylic Alkylation Enabled by Organophotoredox Catalysis

scientific article published on 24 May 2019

Cobalt-catalyzed C4-selective direct alkylation of pyridines

scientific article published on 01 February 2013

Construction of contiguous tetrasubstituted chiral carbon stereocenters via direct catalytic asymmetric aldol reaction of alpha-isothiocyanato esters with ketones

scientific article published on 01 December 2009

Cp*Co(III) Catalyzed Site-Selective C-H Activation of Unsymmetrical O-Acyl Oximes: Synthesis of Multisubstituted Isoquinolines from Terminal and Internal Alkynes

scientific article published on 28 September 2015

Cp*Co(III)-Catalyzed Dehydrative C-H Allylation of 6-Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohols

scientific article published on 27 April 2016

Cp*Co(III)-catalyzed C2-selective addition of indoles to imines

scientific article published on 31 May 2013

Dehydrative Direct C-H Allylation with Allylic Alcohols under [Cp*Co(III)] Catalysis

scientific article published on 01 July 2015

Dinuclear Ni2-Schiff base complex-catalyzed asymmetric 1,4-addition of β-keto esters to nitroethylene toward γ(2,2)-amino acid synthesis

scientific article published on 04 October 2010

Direct anti-selective catalytic asymmetric Mannich-type reactions of alpha-ketoanilides for the synthesis of gamma-amino amides and azetidine-2-amides.

scientific article

Direct catalytic aldol-type reactions using RCH2CN

scientific article published on 01 August 2003

Direct catalytic asymmetric Mannich-type reaction of beta-keto phosphonate using a dinuclear Ni2-Schiff base complex

scientific article published on 09 July 2008

Direct catalytic asymmetric Mannich-type reactions of N-(2-hydroxyacetyl)pyrrole as an ester-equivalent donor.

scientific article published in July 2005

Direct catalytic asymmetric Mannich-type reactions of gamma-butenolides: effectiveness of Brønsted acid in chiral metal catalysis

scientific article published on 07 May 2008

Direct catalytic asymmetric Michael reaction of hydroxyketones: asymmetric Zn catalysis with a Et2Zn/linked-BINOL complex.

scientific article published in March 2003

Direct catalytic asymmetric aldol reaction of beta-keto esters with formaldehyde promoted by a dinuclear Ni2-Schiff base complex

scientific article published on 24 July 2009

Direct catalytic asymmetric aldol reaction of hydroxyketones: asymmetric Zn catalysis with a Et(2)Zn/linked-BINOL complex.

scientific article published in February 2003

Direct catalytic asymmetric aldol reaction: synthesis of either syn- or anti-alpha,beta-dihydroxy ketones.

scientific article published in March 2001

Direct catalytic asymmetric vinylogous Mannich-type and Michael reactions of an alpha,beta-unsaturated gamma-butyrolactam under dinuclear nickel catalysis

scientific article published on 01 March 2010

Direct catalytic enantio- and diastereoselective aldol reaction using a Zn-Zn-linked-BINOL complex: a practical synthesis of syn-1,2-diols

scientific article published on 01 May 2001

Diverse Approaches for Enantioselective C-H Functionalization Reactions Using Group 9 Cpx MIII Catalysts

scientific article published on 28 January 2020

Efficient two-step conversion of alpha,beta-unsaturated aldehydes to optically active gamma-oxy-alpha,beta-unsaturated nitriles and its application to the total synthesis of (+)-patulolide C

scientific article published on 01 August 2003

Enantioselective 1,4-addition of unmodified ketone catalyzed by a bimetallic Zn-Zn-linked-BINOL complex

scientific article published on 01 December 2001

Enantioselective C(sp3 )-H Amidation of Thioamides Catalyzed by a CobaltIII /Chiral Carboxylic Acid Hybrid System

scientific article published on 20 December 2018

Enantioselective Ring Opening of Epoxides with 4-Methoxyphenol Catalyzed by Gallium Heterobimetallic Complexes: An Efficient Method for the Synthesis of Optically Active 1,2-Diol Monoethers

scientific article published on 01 September 1998

Enantioselective synthesis of 2,2-disubstituted terminal epoxides via catalytic asymmetric Corey-Chaykovsky epoxidation of ketones.

scientific article published on 7 February 2012

Heterobimetallic transition metal/rare earth metal bifunctional catalysis: a Cu/Sm/Schiff base complex for syn-selective catalytic asymmetric nitro-Mannich reaction.

scientific article published in April 2010

Imidate as the Intact Directing Group for the Cobalt-Catalyzed C-H Allylation

scientific article published on 06 September 2019

Lewis acid catalyzed benzylic C-H bond functionalization of azaarenes: addition to enones

scientific article published on 03 March 2011

Lewis base assisted Brønsted base catalysis: bidentate phosphine oxides as activators and modulators of Brønsted basic lanthanum-aryloxides

scientific article published on 01 January 2008

Ligand accelerated indium(iii)-catalyzed asymmetric alkynylation of aldehydes with 2-methyl-3-butyn-2-ol as an ethyne equivalent donor

scientific article published on 01 December 2006

Mg-catalyzed enantioselective benzylic C-H bond functionalization of isoindolinones: addition to imines

scientific article published on 21 May 2012

Mixed La-Li heterobimetallic complexes for tertiary nitroaldol resolution

scientific article published on 01 September 2006

Non-C2-symmetric, chirally economical, and readily tunable linked-binols: design and application in a direct catalytic asymmetric mannich-type reaction

scientific article published on 01 May 2005

Pyrroloindolone synthesis via a Cp*Co(III)-catalyzed redox-neutral directed C-H alkenylation/annulation sequence

scientific article published on 31 March 2014

Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes

scientific article published in February 2014

Recent progress in asymmetric bifunctional catalysis using multimetallic systems.

scientific article published on August 2009

Regiodivergent kinetic resolution of terminal and internal rac-aziridines with malonates under dinuclear Schiff base catalysis

scientific article published on 16 June 2014

Rh-Catalyzed AldehydeAldehyde Cross-Aldol Reaction under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through Orthogonal Activation

article

Rhodium(III)/Chiral Carboxylic Acid Catalyzed Enantioselective C(sp3)-H Alkylation of 8-Ethylquinolines with α,β-Unsaturated Carbonyl Compounds

scientific article published on 16 October 2020

Rhodium-Catalyzed Cross-Aldol Reaction: In Situ Aldehyde-Enolate Formation from Allyloxyboranes and Primary Allylic Alcohols

scientific article published on 13 September 2012

Sc3+-catalyzed aldol-type additions of N-benzoylcyclopropanecarboxamides via iodide-mediated ring-opening: stereoselective synthesis of gamma-lactams

scientific article published on 18 March 2008

Sequential Wittig olefination-catalytic asymmetric epoxidation with reuse of waste Ph3P(O): application of alpha,beta-unsaturated N-acyl pyrroles as ester surrogates.

scientific article published in October 2003

Stereodivergent catalytic doubly diastereoselective nitroaldol reactions using heterobimetallic complexes

scientific article published on 09 May 2008

Stereodivergent direct catalytic asymmetric Mannich-type reactions of α-isothiocyanato ester with ketimines

scientific article published on 11 April 2011

Sultam synthesis via Cu-catalyzed intermolecular carboamination of alkenes with N-fluorobenzenesulfonimide

scientific article published on 29 April 2013

Synthesis of 1,1'-Spirobiindane-7,7'-Disulfonic Acid and Disulfonimide: Application for Catalytic Asymmetric Aminalization.

scientific article published on 12 April 2018

Synthesis of Functionalized Monoaryl-λ3 -iodanes through Chemo- and Site-Selective ipso-Substitution Reactions

scientific article published on 18 December 2018

Weinreb Amide Directed Versatile C-H Bond Functionalization under (η5 -Pentamethylcyclopentadienyl)cobalt(III) Catalysis

scientific article published on 06 May 2018

anti-Selective direct catalytic asymmetric Mannich-type reaction of hydroxyketone providing beta-amino alcohols.

scientific article published in April 2003

syn-Selective catalytic asymmetric 1,4-addition of alpha-ketoanilides to nitroalkenes under dinuclear nickel catalysis.

scientific article published in July 2010

syn-Selective catalytic asymmetric nitro-Mannich reactions using a heterobimetallic Cu-Sm-Schiff base complex

scientific article published on 30 March 2007

syn-selective direct catalytic asymmetric Mannich-type reactions of hydroxyketones using Y{N(SiMe3)2}3/linked-BINOL complexes

scientific article published on 01 November 2005

List of works by Shigeki Matsunaga

A Cp*CoI2-dimer as a precursor for cationic Co(III)-catalysis: application to C-H phosphoramidation of indoles.

A heterobimetallic Ga/Yb-Schiff base complex for catalytic asymmetric alpha-addition of isocyanides to aldehydes.

A heterobimetallic Ni/La-salan complex for catalytic asymmetric decarboxylative 1,4-addition of malonic acid half-thioester.

A heterobimetallic Pd/La/Schiff base complex for anti-selective catalytic asymmetric nitroaldol reactions and applications to short syntheses of beta-adrenoceptor agonists.

A homodinuclear Mn(III)2-Schiff base complex for catalytic asymmetric 1,4-additions of oxindoles to nitroalkenes.

A method for the synthesis of an oseltamivir PET tracer.

A stable homodinuclear biscobalt(III)-Schiff base complex for catalytic asymmetric 1,4-addition reactions of beta-keto esters to alkynones

An efficient synthesis of bicyclic amidines by intramolecular cyclization

Ba-catalyzed direct Mannich-type reactions of a beta,gamma-unsaturated ester providing beta-methyl aza-Morita-Baylis-Hillman-type products

Bismuth- and hafnium-catalyzed hydroamination of vinyl arenes with sulfonamides, carbamates, and carboxamides

Bismuth-catalyzed direct substitution of the hydroxy group in alcohols with sulfonamides, carbamates, and carboxamides

C-H γ,γ,γ-Trifluoroalkylation of Quinolines via Visible-Light-Induced Sequential Radical Additions

Catalytic Asymmetric Aza-Morita−Baylis−Hillman Reaction of Methyl Acrylate: Role of a Bifunctional La(O-iPr)3/Linked-BINOL Complex ⬇️

Catalytic Asymmetric Iterative/Domino Aldehyde Cross-Aldol Reactions for the Rapid and Flexible Synthesis of 1,3-Polyols.

Catalytic Enantioselective Methylene C(sp3 )-H Amidation of 8-Alkylquinolines Using a Cp*RhIII /Chiral Carboxylic Acid System

Catalytic asymmetric 1,4-addition reactions using alpha,beta-unsaturated N-acylpyrroles as highly reactive monodentate alpha,beta-unsaturated ester surrogates.

Catalytic asymmetric 1,4-additions of beta-keto esters to nitroalkenes promoted by a bifunctional homobimetallic Co2-Schiff base complex

Catalytic asymmetric epoxidation of alpha,beta-unsaturated esters with chiral yttrium-biaryldiol complexes

Catalytic asymmetric epoxidation of alpha,beta-unsaturated phosphane oxides with a Y(O-iPr)3/biphenyldiol complex.

Catalytic asymmetric ring-opening of meso-aziridines with malonates under heterodinuclear rare earth metal Schiff base catalysis

Catalytic asymmetric synthesis of 2,2-disubstituted terminal epoxides via dimethyloxosulfonium methylide addition to ketones.

Catalytic asymmetric synthesis of spirooxindoles by a mannich-type reaction of isothiocyanato oxindoles

Catalytic asymmetric synthesis of spirooxindoles via addition of isothiocyanato oxindoles to aldehydes under dinuclear nickel Schiff base catalysis

Catalytic asymmetric total synthesis of chimonanthine, folicanthine, and calycanthine through double Michael reaction of bisoxindole

Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination.

Cationic bismuth-catalyzed hydroamination and direct substitution of the hydroxy group in alcohols with amides

Chemoselective Cleavage of Si-C(sp<sup>3</sup>) Bonds in Unactivated Tetraalkylsilanes Using Iodine Tris(trifluoroacetate)

Chiral Carboxylic Acid Enabled Achiral Rhodium(III)-Catalyzed Enantioselective C-H Functionalization

Chiral gamma-amino amide synthesis by heterobimetallic lanthanum/lithium/Pybox-catalyzed direct asymmetric mannich-type reactions of alpha-keto anilides

Cobalt-Catalyzed Allylic Alkylation Enabled by Organophotoredox Catalysis

Cobalt-catalyzed C4-selective direct alkylation of pyridines

Construction of contiguous tetrasubstituted chiral carbon stereocenters via direct catalytic asymmetric aldol reaction of alpha-isothiocyanato esters with ketones

Cp*Co(III) Catalyzed Site-Selective C-H Activation of Unsymmetrical O-Acyl Oximes: Synthesis of Multisubstituted Isoquinolines from Terminal and Internal Alkynes

Cp*Co(III)-Catalyzed Dehydrative C-H Allylation of 6-Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohols

Cp*Co(III)-catalyzed C2-selective addition of indoles to imines

Dehydrative Direct C-H Allylation with Allylic Alcohols under [Cp*Co(III)] Catalysis

Dinuclear Ni2-Schiff base complex-catalyzed asymmetric 1,4-addition of β-keto esters to nitroethylene toward γ(2,2)-amino acid synthesis

Direct anti-selective catalytic asymmetric Mannich-type reactions of alpha-ketoanilides for the synthesis of gamma-amino amides and azetidine-2-amides.

Direct catalytic aldol-type reactions using RCH2CN

Direct catalytic asymmetric Mannich-type reaction of beta-keto phosphonate using a dinuclear Ni2-Schiff base complex

Direct catalytic asymmetric Mannich-type reactions of N-(2-hydroxyacetyl)pyrrole as an ester-equivalent donor.

Direct catalytic asymmetric Mannich-type reactions of gamma-butenolides: effectiveness of Brønsted acid in chiral metal catalysis

Direct catalytic asymmetric Michael reaction of hydroxyketones: asymmetric Zn catalysis with a Et2Zn/linked-BINOL complex.

Direct catalytic asymmetric aldol reaction of beta-keto esters with formaldehyde promoted by a dinuclear Ni2-Schiff base complex

Direct catalytic asymmetric aldol reaction of hydroxyketones: asymmetric Zn catalysis with a Et(2)Zn/linked-BINOL complex.

Direct catalytic asymmetric aldol reaction: synthesis of either syn- or anti-alpha,beta-dihydroxy ketones.

Direct catalytic asymmetric vinylogous Mannich-type and Michael reactions of an alpha,beta-unsaturated gamma-butyrolactam under dinuclear nickel catalysis

Direct catalytic enantio- and diastereoselective aldol reaction using a Zn-Zn-linked-BINOL complex: a practical synthesis of syn-1,2-diols

Diverse Approaches for Enantioselective C-H Functionalization Reactions Using Group 9 Cpx MIII Catalysts

Efficient two-step conversion of alpha,beta-unsaturated aldehydes to optically active gamma-oxy-alpha,beta-unsaturated nitriles and its application to the total synthesis of (+)-patulolide C

Enantioselective 1,4-addition of unmodified ketone catalyzed by a bimetallic Zn-Zn-linked-BINOL complex

Enantioselective C(sp3 )-H Amidation of Thioamides Catalyzed by a CobaltIII /Chiral Carboxylic Acid Hybrid System

Enantioselective Ring Opening of Epoxides with 4-Methoxyphenol Catalyzed by Gallium Heterobimetallic Complexes: An Efficient Method for the Synthesis of Optically Active 1,2-Diol Monoethers

Enantioselective synthesis of 2,2-disubstituted terminal epoxides via catalytic asymmetric Corey-Chaykovsky epoxidation of ketones.

Heterobimetallic transition metal/rare earth metal bifunctional catalysis: a Cu/Sm/Schiff base complex for syn-selective catalytic asymmetric nitro-Mannich reaction.

Imidate as the Intact Directing Group for the Cobalt-Catalyzed C-H Allylation

Lewis acid catalyzed benzylic C-H bond functionalization of azaarenes: addition to enones

Lewis base assisted Brønsted base catalysis: bidentate phosphine oxides as activators and modulators of Brønsted basic lanthanum-aryloxides

Ligand accelerated indium(iii)-catalyzed asymmetric alkynylation of aldehydes with 2-methyl-3-butyn-2-ol as an ethyne equivalent donor

Mg-catalyzed enantioselective benzylic C-H bond functionalization of isoindolinones: addition to imines

Mixed La-Li heterobimetallic complexes for tertiary nitroaldol resolution

Non-C2-symmetric, chirally economical, and readily tunable linked-binols: design and application in a direct catalytic asymmetric mannich-type reaction

Pyrroloindolone synthesis via a Cp*Co(III)-catalyzed redox-neutral directed C-H alkenylation/annulation sequence

Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes

Recent progress in asymmetric bifunctional catalysis using multimetallic systems.

Regiodivergent kinetic resolution of terminal and internal rac-aziridines with malonates under dinuclear Schiff base catalysis

Rh-Catalyzed AldehydeAldehyde Cross-Aldol Reaction under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through Orthogonal Activation

Rhodium(III)/Chiral Carboxylic Acid Catalyzed Enantioselective C(sp3)-H Alkylation of 8-Ethylquinolines with α,β-Unsaturated Carbonyl Compounds

Rhodium-Catalyzed Cross-Aldol Reaction: In Situ Aldehyde-Enolate Formation from Allyloxyboranes and Primary Allylic Alcohols

Sc3+-catalyzed aldol-type additions of N-benzoylcyclopropanecarboxamides via iodide-mediated ring-opening: stereoselective synthesis of gamma-lactams

Sequential Wittig olefination-catalytic asymmetric epoxidation with reuse of waste Ph3P(O): application of alpha,beta-unsaturated N-acyl pyrroles as ester surrogates.

Stereodivergent catalytic doubly diastereoselective nitroaldol reactions using heterobimetallic complexes

Stereodivergent direct catalytic asymmetric Mannich-type reactions of α-isothiocyanato ester with ketimines

Sultam synthesis via Cu-catalyzed intermolecular carboamination of alkenes with N-fluorobenzenesulfonimide

Synthesis of 1,1'-Spirobiindane-7,7'-Disulfonic Acid and Disulfonimide: Application for Catalytic Asymmetric Aminalization.

Synthesis of Functionalized Monoaryl-λ3 -iodanes through Chemo- and Site-Selective ipso-Substitution Reactions

Weinreb Amide Directed Versatile C-H Bond Functionalization under (η5 -Pentamethylcyclopentadienyl)cobalt(III) Catalysis

anti-Selective direct catalytic asymmetric Mannich-type reaction of hydroxyketone providing beta-amino alcohols.

syn-Selective catalytic asymmetric 1,4-addition of alpha-ketoanilides to nitroalkenes under dinuclear nickel catalysis.