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List of works by Melanie S. Sanford

A Simple Catalytic Method for the Regioselective Halogenation of Arenes

scientific article published on 01 June 2006

A detailed study of acetate-assisted C-H activation at palladium(IV) centers.

scientific article published on 19 April 2013

A highly selective catalytic method for the oxidative functionalization of C-H bonds

scientific article published in March 2004

A spot test for determination of residual TBA levels in 18F-radiotracers for human use using Dragendorff reagent

scientific article published on 01 October 2020

Acyl Azolium Fluorides for Room Temperature Nucleophilic Aromatic Fluorination of Chloro- and Nitroarenes

scientific article published on 30 March 2015

Aerobic Pd-catalyzed sp3 C-H olefination: a route to both N-heterocyclic scaffolds and alkenes

scientific article published on 8 April 2011

An organic super-electron-donor as a high energy density negative electrolyte for nonaqueous flow batteries

scientific article published on 27 August 2019

Anhydrous Tetramethylammonium Fluoride for Room-Temperature SNAr Fluorination

scientific article published on 09 December 2015

Anti-Markovnikov hydrofunctionalization of olefins mediated by rhodium-porphyrin complexes

scientific article published in February 2004

Application of recyclable, polymer-immobilized iodine(III) oxidants in catalytic C–H bond functionalization

scholarly article by Eric W. Kalberer et al published May 2006 in Journal of Molecular Catalysis A

Aryl-CF(3) bond-forming reductive elimination from palladium(IV)

scientific article published on March 2010

Aryl-Fluoride Bond-Forming Reductive Elimination from Nickel(IV) Centers

scientific article published on 13 August 2019

Aryl–CF3 Coupling from Phosphinoferrocene-Ligated Palladium(II) Complexes

Asymmetric chiral ligand-directed alkene dioxygenation

scientific article published on 18 December 2012

Automated synthesis of PET radiotracers by copper-mediated 18 F-fluorination of organoborons: Importance of the order of addition and competing protodeborylation.

scientific article

Base-free nickel-catalysed decarbonylative Suzuki-Miyaura coupling of acid fluorides

scientific article published in Nature

Bis(diisopropylamino)cyclopropenium-arene Cations as High Oxidation Potential and High Stability Catholytes for Non-aqueous Redox Flow Batteries

scientific article published on 02 October 2020

C(sp³)-O bond-forming reductive elimination from Pd(IV) with diverse oxygen nucleophiles

scientific article published on 26 August 2014

C-H 18F-fluorination of 8-methylquinolines with Ag[18F]F

scientific article published on 01 March 2019

C-H Amination of Arenes with Hydroxylamine

scientific article published on 27 March 2020

C-H bond activation at palladium(IV) centers

scientific article published on 21 October 2011

Carbon(sp3)Fluorine Bond-Forming Reductive Elimination from Palladium(IV) Complexes

scientific article published on 28 February 2012

Carbon-Carbon Bond-Forming Reductive Elimination from Isolated Nickel(III) Complexes

scientific article published on 02 December 2016

Carbon-Hydrogen (C-H) Bond Activation at Pd(IV): A Frontier in C-H Functionalization Catalysis

scientific article published on January 2015

Carbon–Heteroatom Bond-Forming Reductive Elimination from Palladium(IV) Complexes

scholarly article by Joy M. Racowski & Melanie S. Sanford published 2011 in Topics in Organometallic Chemistry

Carbon− nitrogen bond-forming reactions of palladacycles with hypervalent iodine reagents

2007 scholarly article

Cascade Catalysis for the Homogeneous Hydrogenation of CO2to Methanol

scientific article published on 26 October 2011

Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene

Catalyst-controlled selectivity in the C-H borylation of methane and ethane.

scientific article published in March 2016

Catalytic CO2 Hydrogenation to Formate by a Ruthenium Pincer Complex

article

Catalytic Cycle for Palladium-Catalyzed Decarbonylative Trifluoromethylation using Trifluoroacetic Esters as the CF3 Source

scholarly article by Ansis Maleckis & Melanie S. Sanford published 12 May 2014 in Organometallics

Catalytic and Highly Regioselective Cross-Coupling of Aromatic C−H Substrates

scientific article published on 11 September 2007

Catalytically Relevant Intermediates in the Ni-Catalyzed C(sp2)-H and C(sp3)-H Functionalization of Aminoquinoline Substrates

scientific article published on 16 October 2019

Celebrating Women in Organic Chemistry

scientific article published on 11 February 2020

Chelate-Directed Oxidative Functionalization of Carbon–Hydrogen Bonds: Synthetic Applications and Mechanistic Insights

article published in 2007

Chelating N-Heterocyclic Carbene Alkoxide as a Supporting Ligand for PdII/IVC−H Bond Functionalization Catalysis

scientific article published on 01 October 2009

Combining Transition Metal Catalysis with Radical Chemistry: Dramatic Acceleration of Palladium-Catalyzed C-H Arylation with Diaryliodonium Salts

scientific article published on December 2012

Competition between sp3-C–N vs sp3-C–F Reductive Elimination from PdIV Complexes

article

Complexes Containing Redox Noninnocent Ligands for Symmetric, Multielectron Transfer Nonaqueous Redox Flow Batteries

article published in 2015

Computational Study of Intramolecular Arene Palladation at a Palladium(IV) Center

scholarly article by Allan J. Canty et al published 4 March 2015 in Organometallics

Computational and Experimental Studies of Methyl Group Exchange between Palladium(II) Centers

scholarly article by Matthew S. Remy et al published 12 April 2010 in Organometallics

Computational study of C(sp3)-O bond formation at a PdIV centre

scientific article published on 6 March 2017

Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage

scientific article published on 17 July 2012

Connecting Organometallic Ni(III) and Ni(IV): Reactions of Carbon-Centered Radicals with High-Valent Organonickel Complexes

scientific article published on 28 May 2019

Construction of Tetrahydrofurans by PdII/PdIV-Catalyzed Aminooxygenation of Alkenes

scientific article published on 01 January 2007

Controlling Site Selectivity in Pd-Catalyzed Oxidative Cross-Coupling Reactions

scientific article published on 07 March 2011

Controlling site selectivity in palladium-catalyzed C-H bond functionalization

scientific article published on 3 May 2012

Copper(II)-Mediated [C]Cyanation of Arylboronic Acids and Arylstannanes

scientific article published on 27 February 2018

Copper-Mediated Aminoquinoline-Directed Radiofluorination of Aromatic C−H Bonds with K18 F

scientific article published on 18 January 2019

Copper-Mediated Radiofluorination of Arylstannanes with [18F]KF.

scientific article published on 10 October 2016

Copper-catalyzed [18F]fluorination of (mesityl)(aryl)iodonium salts

scientific article published on 3 June 2014

Cu(OTf)2-Mediated Fluorination of Aryltrifluoroborates with Potassium Fluoride

scientific article published on 01 November 2013

Cu-Mediated C-H 18F-Fluorination of Electron-Rich (Hetero)arenes

scientific article published on 30 June 2017

Cu-catalyzed fluorination of diaryliodonium salts with KF.

scientific article

Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C2N2O2−Ligated Palladium(IV) Complexes

scientific article published on 01 August 2009

Developing Efficient Nucleophilic Fluorination Methods and Application to Substituted Picolinate Esters

Developing a Predictive Solubility Model for Monomeric and Oligomeric Cyclopropenium-Based Flow Battery Catholytes

scientific article published on 20 June 2019

Development of Customized [18F]Fluoride Elution Techniques for the Enhancement of Copper-Mediated Late-Stage Radiofluorination.

scientific article published on 22 March 2017

Development of SNAr Nucleophilic Fluorination: A Fruitful Academia-Industry Collaboration

scientific article published on 24 September 2020

Effect of Solvent and Ancillary Ligands on the Catalytic H/D Exchange Reactivity of Cp*IrIII(L) Complexes

Equity and Inclusion in the Chemical Sciences Requires Actions not Just Words

scientific article published on 17 June 2020

Evaluation of Tris-Bipyridine Chromium Complexes for Flow Battery Applications: Impact of Bipyridine Ligand Structure on Solubility and Electrochemistry

scientific article published on 15 October 2015

Evolutionary Design of Low Molecular Weight Organic Anolyte Materials for Applications in Nonaqueous Redox Flow Batteries

scientific article published on 30 October 2015

Experimental and Computational Assessment of Reactivity and Mechanism in C(sp(3))-N Bond-Forming Reductive Elimination from Palladium(IV).

scientific article

Facial Tridentate Ligands for Stabilizing Palladium(IV) Complexes

scholarly article by Ansis Maleckis & Melanie S. Sanford published 26 December 2011 in Organometallics

Formation of ethane from mono-methyl palladium(II) complexes.

scientific article published on 2 June 2014

Heterogenization of homogeneous catalysts in metal-organic frameworks via cation exchange

scientific article published on 9 July 2013

High-Performance Oligomeric Catholytes for Effective Macromolecular Separation in Nonaqueous Redox Flow Batteries.

scientific article published on 17 January 2018

High-valent organometallic copper and palladium in catalysis

scientific article published on 11 April 2012

Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic and Mechanistic Investigations

scientific article published on 01 November 2006

Highly dispersed palladium(II) in a defective metal-organic framework: application to C-H activation and functionalization.

scientific article published on 28 November 2011

Impact of Oxidation State on Reactivity and Selectivity Differences between Nickel(III) and Nickel(IV) Alkyl Complexes

scientific article published on 24 May 2019

Improved Synthesis of [CpRRhCl2]2 Complexes

Insights into directing group ability in palladium-catalyzed C-H bond functionalization

scientific article published on 10 September 2008

Investigations into Transition Metal Catalyzed Arene Trifluoromethylation Reactions

scientific article published on September 2012

Iron-Catalyzed Oxyfunctionalization of Aliphatic Amines at Remote Benzylic C-H Sites

scientific article published on 16 August 2016

Late-stage [(18)F]Fluorination: New Solutions to Old Problems

scientific article published on December 2014

Mechanism and Scope of Nickel-Catalyzed Decarbonylative Borylation of Carboxylic Acid Fluorides

scientific article published on 16 October 2019

Mechanism of Pd-Catalyzed Ar–Ar Bond Formation Involving Ligand-Directed C–H Arylation and Diaryliodonium Oxidants: Computational Studies of Orthopalladation at Binuclear Pd(II) Centers, Oxidation To Form Binuclear Palladium(III) Species, and Ar?

article

Mechanism of benzoquinone-promoted palladium-catalyzed oxidative cross-coupling reactions.

scientific article published in July 2009

Mechanism of the palladium-catalyzed arene C-H acetoxylation: a comparison of catalysts and ligand effects

scientific article published on 23 February 2015

Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow Battery

scientific article published on 10 September 2019

Mechanism-Based Development of a Low-Potential, Soluble, and Cyclable Multielectron Anolyte for Nonaqueous Redox Flow Batteries

scientific article published on 15 November 2016

Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the Cu(I)/Cu(III) Manifold in Copper Catalysis

scientific article

Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation

scientific article

Mechanistic comparison between Pd-catalyzed ligand-directed C-H chlorination and C-H acetoxylation

scientific article published on October 2009

Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin

scientific article published on 15 December 2005

Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I.

scientific article published on 24 May 2012

Mild Copper-Mediated Fluorination of Aryl Stannanes and Aryl Trifluoroborates

scientific article published on 13 March 2013

Mild Fluorination of Chloropyridines with in Situ Generated Anhydrous Tetrabutylammonium Fluoride

Mild palladium-catalyzed C-H alkylation using potassium alkyltrifluoroborates in combination with MnF3

scientific article published on 19 April 2013

Model Complexes for the Palladium-Catalyzed Transannular C-H Functionalization of Alicyclic Amines.

scientific article published on 24 September 2018

Modulating Sterics in Trimethylplatinum(IV) Diimine Complexes To Achieve C–C Bond-Forming Reductive Elimination

Moving Metal-Mediated (18)F-Fluorination from Concept to Clinic.

scientific article published on 14 March 2016

Multiple Approaches to the In Situ Generation of Anhydrous Tetraalkylammonium Fluoride Salts for SNAr Fluorination Reactions

scientific article

N-Acyloxyphthalimides as nitrogen radical precursors in the visible light photocatalyzed room temperature C-H amination of arenes and heteroarenes

scientific article published on 4 April 2014

NHC-Copper Mediated Ligand-Directed Radiofluorination of Aryl Halides

scientific article published on 10 April 2020

Nickel(II/IV) Manifold Enables Room-Temperature C(sp3)-H Functionalization

scientific article published on 26 November 2019

Nickel(IV)-Catalyzed C-H Trifluoromethylation of (Hetero)arenes

scientific article published on 05 August 2019

Nickel-Catalyzed Decarbonylative Amination of Carboxylic Acid Esters

scientific article published on 24 March 2020

Nitrate as a Redox Co-Catalyst for the Aerobic Pd-Catalyzed Oxidation of Unactivated sp(3)-C-H Bonds

scientific article published on January 2012

Nucleophilic Deoxyfluorination of Phenols via Aryl Fluorosulfonate Intermediates

scientific article published on 23 January 2017

O-acetyl oximes as transformable directing groups for Pd-catalyzed C-H bond functionalization

scientific article published on February 2010

On the role of anionic ligands in the site-selectivity of oxidative C–H functionalization reactions of arenes

article published in 2013

One-pot synthesis of high molar activity 6-[18F]fluoro-l-DOPA by Cu-mediated fluorination of a BPin precursor

scientific article published on 19 September 2019

Oxidation of Ni(II) to Ni(IV) with Aryl Electrophiles Enables Ni-Mediated Aryl–CF3 Coupling

scientific article published on 16 June 2015

Oxidation of a cyclometalated Pd(II) dimer with "CF3+": formation and reactivity of a catalytically competent monomeric Pd(IV) aquo complex

scientific article published on October 2010

Oxidative C−H Activation/C−C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights

scientific article published on 01 May 2005

Oxidatively Induced C-H Activation at High Valent Nickel

scientific article published on 20 April 2017

Oxidatively Induced Carbon−Halogen Bond-Forming Reactions at Nickel

scholarly article by Andrew T. Higgs et al published 9 November 2009 in Organometallics

Oxidatively induced reductive elimination from ((t)Bu2bpy)Pd(Me)2: palladium(IV) intermediates in a one-electron oxidation reaction

scientific article published in November 2009

Oxidatively intercepting Heck intermediates: Pd-catalyzed 1,2- and 1,1-arylhalogenation of alkenes

scientific article published on 30 January 2008

Oxone as an Inexpensive, Safe, and Environmentally Benign Oxidant for C−H Bond Oxygenation

article

Palladium (II/IV) catalyzed cyclopropanation reactions: scope and mechanism

scientific article published in April 2009

Palladium Catalysts Containing Pyridinium-Substituted Pyridine Ligands for the C–H Oxygenation of Benzene with K2S2O8

scholarly article by J. Brannon Gary et al published 13 March 2013 in ACS Catalysis

Palladium- and Nickel-Catalyzed Decarbonylative C-S Coupling to Convert Thioesters to Thioethers.

scientific article published on 7 December 2017

Palladium-Catalyzed C-H Arylation Using Aryltrifluoroborates in Conjunction with a Mn(III) Oxidant under Mild Conditions

scientific article published in July 2013

Palladium-Catalyzed C-H Bond Acetoxylation via Electrochemical Oxidation.

scientific article

Palladium-Catalyzed C−H Arylation of 2,5-Substituted Pyrroles

scientific article published on 08 December 2010

Palladium-Catalyzed Difluoromethylation of Aryl Chlorides and Bromides with TMSCF2H

scientific article published on 21 February 2019

Palladium-Catalyzed Fluorination of Carbon−Hydrogen Bonds

scientific article published on 01 June 2006

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

scientific article (publication date: 10 February 2010)

Palladium-Catalyzed Ligand-Directed Oxidative Functionalization of Cyclopropanes

scientific article published on August 2011

Palladium-catalysed transannular C-H functionalization of alicyclic amines

scientific article (publication date: 10 March 2016)

Palladium-catalyzed 1,1-aryloxygenation of terminal olefins

scientific article

Palladium-catalyzed C-H perfluoroalkylation of arenes.

scientific article published on 22 April 2011

Palladium-catalyzed oxidative arylhalogenation of alkenes: synthetic scope and mechanistic insights

scientific article published on June 2010

Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds

scientific article

Participation of Carbonyl Oxygen in Carbon–Carboxylate Bond-Forming Reductive Elimination from Palladium

scholarly article by J. Brannon Gary & Melanie S. Sanford published 28 November 2011 in Organometallics

Pd-Catalyzed Decarbonylative Cross-Couplings of Aroyl Chlorides

scientific article published on 19 July 2017

Pd-catalyzed C-H fluorination with nucleophilic fluoride

scientific article published on 30 July 2012

Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applications.

scientific article published on 21 February 2017

Platinum Model Studies for Palladium-Catalyzed Oxidative Functionalization of C− H Bonds

2005 scholarly article

Platinum and Palladium Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation

scientific article published on 01 August 2010

Platinum(II) Complexes Containing Quaternized Nitrogen Ligands: Synthesis, Stability, and Evaluation as Catalysts for Methane and Benzene H/D Exchange

Platinum-Catalyzed, Terminal-Selective C(sp(3))-H Oxidation of Aliphatic Amines

scientific article

Platinum-catalyzed C-H arylation of simple arenes

scientific article published on 15 October 2013

Practical method for the Cu-mediated trifluoromethylation of arylboronic acids with CF3 radicals derived from NaSO2CF3 and tert-butyl hydroperoxide (TBHP).

scientific article published on 17 September 2012

Pyridine Ligands as Promoters in PdII/0-Catalyzed C–H Olefination Reactions

scientific article published on 12 March 2012

Quantitative Assay for the Direct Comparison of Platinum Catalysts in Benzene H/D Exchange

article

Radiosynthesis of [C]LY2795050 for Preclinical and Clinical PET Imaging Using Cu(II)-Mediated Cyanation

scientific article published on 13 November 2018

Reactions of Arylsulfonate Electrophiles with NMe4F: Mechanistic Insight, Reactivity, and Scope

scientific article published on 31 August 2018

Reactions of Platinum(II) Complexes with Chloride-Based Oxidants: Routes to Pt(III) and Pt(IV) Products

Reactions of hypervalent iodine reagents with palladium: mechanisms and applications in organic synthesis

scientific article published on March 2007

Reactivity of Pd(II) complexes with electrophilic chlorinating reagents: isolation of Pd(IV) products and observation of C-Cl bond-forming reductive elimination

scientific article published on 16 November 2007

Realization of an Asymmetric Non-Aqueous Redox Flow Battery Through Molecular Design to Minimize Active Species Crossover and Decomposition

scientific article published on 12 February 2020

Regioselectivity in Palladium-Catalyzed C−H Activation/Oxygenation Reactions

scientific article published on 01 September 2005

Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes

scientific article published on 24 August 2011

Remote C(sp3)-H Oxygenation of Protonated Aliphatic Amines with Potassium Persulfate

scientific article

Reversible carbon-carbon bond formation between carbonyl compounds and a ruthenium pincer complex

scientific article published in August 2013

Rh(III) Pyridinium Substituted Bipyridine Complexes as Catalysts for Arene H/D Exchange

Ring opening of epoxides with [18F]FeF species to produce [18F]fluorohydrin PET imaging agents

scientific article published on 01 May 2019

Role of a Noninnocent Pincer Ligand in the Activation of CO2 at (PNN)Ru(H)(CO)

article

Room Temperature Deoxyfluorination of Benzaldehydes and α-Ketoesters with Sulfuryl Fluoride and Tetramethylammonium Fluoride

scientific article published on 18 February 2019

Room Temperature Palladium-Catalyzed 2-Arylation of Indoles

scientific article published on 01 April 2006

Room-temperature C-H arylation: merger of Pd-catalyzed C-H functionalization and visible-light photocatalysis

scientific article

Scope and selectivity in palladium-catalyzed directed C–H bond halogenation reactions

scholarly article by Dipannita Kalyani et al published December 2006 in Tetrahedron

Second-Generation Palladium Catalyst System for Transannular C-H Functionalization of Azabicycloalkanes.

scientific article published on 13 April 2018

Silver-mediated trifluoromethylation of arenes using TMSCF3.

scientific article published on 20 September 2011

Steric Control of Site Selectivity in the Pd-Catalyzed C–H Acetoxylation of Simple Arenes

scientific article published on 14 October 2013

Stoichiometric and Catalytic Aryl-Perfluoroalkyl Coupling at Tri-tert-butylphosphine Palladium(II) Complexes

scientific article published on 11 August 2017

Structure Activity Relationship Study of Diimine PtII Catalysts for H/D Exchange

Structure activity relationships in metal–organic framework catalysts for the continuous flow synthesis of propylene carbonate from CO2 and propylene oxide

scholarly article in RSC Advances, vol. 8 no. 4, 2018

Synthesis and Reactivity of NiII(Phpy)2(Phpy = 2-Phenylpyridine)†

article

Synthesis and activity of ruthenium alkylidene complexes coordinated with phosphine and N-heterocyclic carbene ligands

scientific article published in March 2003

Synthesis and reactivity of a mono-sigma-aryl palladium(IV) fluoride complex

scientific article published on March 2009

Synthesis and reactivity of palladium(II) fluoride complexes containing nitrogen-donor ligands

scientific article published on 26 November 2009

Synthesis of Cyclopropanes via Pd(II/IV)-Catalyzed Reactions of Enynes

scientific article published on 14 April 2007

Synthesis of Fluoroalkyl Palladium and Nickel Complexes via Decarbonylation of Acylmetal Species

article

Synthesis of [18F]-γ-fluoro-α,β,-unsaturated esters and ketones via vinylogous 18F-fluorination of α-diazoacetates with [18F]AgF

scientific article published on 01 December 2019

Synthesis of [18F]Arenes via the Copper-Mediated [18F]Fluorination of Boronic Acids

scientific article published on 14 November 2015

Synthesis of high-molar-activity [18F]6-fluoro-L-DOPA suitable for human use via Cu-mediated fluorination of a BPin precursor

scientific article published on 08 April 2020

Synthesis, structure, and activity of enhanced initiators for olefin metathesis

scientific article published in August 2003

Synthetic and mechanistic studies of Pd-catalyzed C-H arylation with diaryliodonium salts: evidence for a bimetallic high oxidation state Pd intermediate

scientific article published on August 2009

Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2 to Methanol

scientific article published on 16 January 2015

Transition metal catalyzed oxidative functionalization of carbon-hydrogen bonds

2006 scholarly article

Transition-Metal-Free Acid-Mediated Synthesis of Aryl Sulfides from Thiols and Thioethers

Unusually stable palladium(IV) complexes: detailed mechanistic investigation of C-O bond-forming reductive elimination

scientific article

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