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List of works by Marcetta Y. Darensbourg

A Coordination Polymer of Nickel(II) Based on a Pentadentate N, S, and O Donor Ligand

scientific article published in August 1996

A Cyclodextrin Host/Guest Approach to a Hydrogenase Active Site Biomimetic Cavity

scientific article published on 01 July 2010

A Mixed-Valent, Fe(II)Fe(I), Diiron Complex Reproduces the Unique Rotated State of the [FeFe]Hydrogenase Active Site

scientific article published on 11 May 2007

A New Macrocyclic N3S2Ligand and Its Nickel(II), Cobalt(II), Rhodium(III)-103, and Rhodium(III)-105 Complexes

scholarly article by Dawn C. Goodman et al published May 1997 in Journal of the American Chemical Society

A Reduced 2Fe2S Cluster Probe of Sulfur-Hydrogen versus Sulfur-Gold Interactions

A dinitrosyl iron complex as a platform for metal-bound imidazole to N-heterocyclic carbene conversion

scientific article

A kinetic study of the ring-opening process in tungsten carbonyl complexes containing hemilabile metallodithiolate ligands

scientific article published in January 2006

A matrix of heterobimetallic complexes for interrogation of hydrogen evolution reaction electrocatalysts

scientific article published on 12 October 2017

A nickel tripeptide as a metallodithiolate ligand anchor for resin-bound organometallics

scientific article published in May 2006

A paramagnetic trigonal paddlewheel complex with iron-dithiolato ligand paddles: {[(C9H18N2S2)Fe(NO)]3Ag2}(BF4)2

A reactivity study of addition of organic halides to CpMo(CO)3−: counterion and RX dependences

article

A reduced 2Fe2S cluster probe of sulfur-hydrogen versus sulfur-gold interactions

scientific article published in September 2015

A {Fe(NO)3}10 trinitrosyliron complex stabilized by an n-heterocyclic carbene and the cationic and neutral {Fe(NO)2}(9/10) products of its NO release

scientific article published on October 2010

Accommodation of the irregular coordination geometry of lead(II) by a square planar N2S2 ligand and its preference for zinc(II).

scientific article published in September 2004

Activation of alkenes and H2 by [Fe]-H2ase model complexes

scientific article

Adamantane-like cluster complexes of mixed-valent copper-copper and nickel-copper thiolates

scientific article published in May 2003

Addendum to Immobilization-Enabled Proton-Reduction Catalysis by a Di-iron Hydrogenase Mimic

Addition of acrylonitrile to anionic transition metal hydrides. An ionic model for homogeneous olefin processes

article

Alkylation-Induced O-Atom Rearrangement in Nickel S-Oxygenates

scholarly article by John A. Bellefeuille et al published October 1998 in Organometallics

Alkylation-Induced O-Atom Rearrangement in Nickel S-Oxygenates

scholarly article by John A. Bellefeuille et al published November 1998 in Organometallics

Alternate synthetic routes to the pentacarbonylhydrides of chromium, molybdenum, and tungsten

scholarly article by Marcetta Y. Darensbourg & Sydney Slater published September 1981 in Journal of the American Chemical Society

Ambidentate thiocyanate and cyanate ligands in dinitrosyl iron complexes

scientific article published in February 2013

An experimental and computational study of sulfur-modified nucleophilicity in a dianionic NiN2S2 complex

scientific article published on 8 August 2007

Analysis of a pentacoordinate iron dicarbonyl as synthetic analogue of the Hmd or mono-iron hydrogenase active site

scientific article published in March 2010

Analysis of an Organometallic Iron Site Model for the Heterodimetallic Unit of [NiFe]Hydrogenase

scientific article published in 1997

Anionic Transition Metal Hydrides

Anionic group 6 hydrides and carboxylates as homogeneous catalysts for reduction of aldehydes and ketones

scientific article published in 1986

Anionic group 6 transition-metal carbonyl hydrides as reducing agents. ketones, aldehydes, and epoxides

scientific article published in 1985

Applications of the N2S2 ligand, N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane (BME-DACO), toward the formation of bi- and heterometallics: [(BME-DACO)Fe]2 and [(BME-DACO)NiFeCl2]2

scientific article published in 1991

Arene-transition metal complexes. 1. Site exchange and chemical characteristics of .eta.6-C6(CH3)6Ru-.eta.4-C6(CH3)6

scientific article published in 1978

Axial Ligation of Diazacyclooctanenickel and -Zinc Complexes

Better than platinum? Fuel cells energized by enzymes

scientific article

Beyond fossil fuel-driven nitrogen transformations

scientific article published in Science

Binuclear molybdenum carbonyls bridged both by hydride and bidentate phosphine ligands. Crystal and molecular structures of salts of hydridomolybdenum carbonyls with bidentate phosphine ligands (.mu.-H)(.mu.-Ph2P(CH2)nPPh2)Mo2(CO)8- (n = 1-4) and the

scholarly article by Marcetta Y. Darensbourg et al published May 1984 in Journal of the American Chemical Society

Binuclear reductive elimination of water: new route to the (triphenylstannyl)pentacarbonyltungsten anion, Ph3SnW(CO)5-

Bis(Phosphine) Derivatives of Iron Pentacarbonyl and Tetracarbonyl (Tri-tert-Butylphosphine)Iron(0)

article

Bismercaptoethanediazacyclooctane as a N2S2 chelating agent and Cys-X-Cys mimic for Fe(NO) and Fe(NO)2.

scientific article published in September 2004

Bridging cyanides from cyanoiron metalloligands to redox-active dinitrosyl iron units

scientific article published on 01 August 2018

Bridging-hydride influence on the electronic structure of an [FeFe] hydrogenase active-site model complex revealed by XAES-DFT.

scientific article

CO and Ethylene Migratory Insertion Reactions and Copolymerization Involving Palladium Complexes of a NiN2S2Metallodithiolate Ligand

CO-migration in the ligand substitution process of the chelating diphosphite diiron complex (mu-pdt)[Fe(CO)3][Fe(CO){(EtO)2PN(Me)P(OEt)2}].

scientific article published on 9 July 2008

Capture of NiII, CuIand ZnIIby thiolate sulfurs of an N2S2Ni complex: A role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site

scientific article published on 01 August 2003

Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-Only Hydrogenase

article

Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-Only Hydrogenase

scientific article published on 01 November 1999

Carbon monoxide induced reductive elimination of disulfide in an N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complex (DNIC).

scientific article published on 23 May 2013

Carbonyl Ligand Lability in the μ-H[Cr(CO)5]2− Anion

article published in 1976

Catalysis and Mechanism of H2 Release from Amine-Boranes by Diiron Complexes.

scientific article published on 30 December 2015

Catalysis of H(2)/D(2) scrambling and other H/D exchange processes by [Fe]-hydrogenase model complexes

scientific article

Cation interaction with transition metal carbonylates and cyanocarbonylates

article published in 1979

Characteristics of Nickel(0), Nickel(I), and Nickel(II) in Phosphino Thioether Complexes: Molecular Structure andS-Dealkylation of (Ph2P(o-C6H4)SCH3)2Ni0

scholarly article by Jang Sub Kim et al published January 1996 in Journal of the American Chemical Society

Characterization of steric and electronic properties of NiN2S2 complexes as S-donor metallodithiolate ligands

scientific article

ChemInform Abstract: Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry

Chemical issues addressing the construction of the distal Ni[cysteine-glycine-cysteine]2- site of acetyl CoA synthase: why not copper?

scientific article

Chemistry of hydrido carbonyl VIB metalates substituted by P-donor ligands: HW(CO)4PR3- (R = Me, OMe, Ph) and .mu.-H[WM(CO)10-x(P(OMe)3)x] (M = Cr, W; x = 1, 2)

Chemistry of new heteronuclear bridging hydrides: (.mu.-H)[Fe(CO)4M(CO)5]- (M = chromium, molybdenum, or tungsten)

scholarly article by Larry Arndt et al published January 1984 in Journal of the American Chemical Society

Chromium, molybdenum and tungsten

scholarly article by Donald J. Darensbourg et al published December 1974 in Journal of Organometallic Chemistry

Chromium, molybdenum and tungsten

Chromium, molybdenum, and tungsten

scholarly article by Jim D. Atwood et al published December 1981 in Journal of Organometallic Chemistry

Comparisons of MN2S2vs. bipyridine as redox-active ligands to manganese and rhenium in (L-L)M'(CO)3Cl complexes.

scientific article published on 21 March 2017

Comparisons of the heterobimetallic and heterotrimetallic anions HFeW(CO)9- and Ph3PAuFeW(CO)9-

scientific article published in 1985

Comparisons of zinc with cadmium in N2S2coordination and as S-bonded adducts to tungsten carbonyls

scientific article published on 15 November 2011

Competing nucleophilic displacement and radical-chain reduction in reactions of transition-metal hydride anions with alkyl bromides

scientific article published in 1987

Complexation of organotin halides with ambidentate, S, N, and O donor ligands

Complexes of MN2S2·Fe(η5-C5R5)(CO) as platform for exploring cooperative heterobimetallic effects in HER electrocatalysis

scientific article published on 8 February 2017

Computational definition of a mixed valent Fe(II)Fe(I) model of the [FeFe]hydrogenase active site resting state

scientific article published on 07 July 2007

Conformational Mobility and Pendent Base Effects on Electrochemistry of Synthetic Analogues of the [FeFe]-Hydrogenase Active Site

article by Danielle J. Crouthers et al published 12 May 2014 in Organometallics

Conformations of (.eta.5-C5H5)2Nb(S-p-C6H4X)2n(n=0,1): responsiveness to para substituents on aryl groups and to d-electron count

scientific article published in 1990

Control of S-Based Aggregation: Designed Synthesis of NiM2and Ni2M Trinuclear Complexes

scientific article published on 01 January 2007

Controlling O2 Reactivity in Synthetic Analogues of [NiFeS]- and [NiFeSe]-Hydrogenase Active Sites

scientific article published on 13 September 2019

Coordination sphere flexibility of active-site models for Fe-only hydrogenase: studies in intra- and intermolecular diatomic ligand exchange

scientific article published in April 2001

Correlation between computed gas-phase and experimentally determined solution-phase infrared spectra: Models of the iron–iron hydrogenase enzyme active site

scientific article published on 01 September 2006

Correlation of electrochemistry, nucleophilicity and density functional calculations of the cis-dithiolate (bme*-daco)Ni

Cyanide Docking and Linkage Isomerism in Models for the Artificial [FeFe]-Hydrogenase Maturation Process

scientific article published on 27 July 2018

Cyanide-bridged iron complexes as biomimetics of tri-iron arrangements in maturases of the H cluster of the di-iron hydrogenase

scientific article published on 29 February 2016

De Novo Design of Synthetic Di-Iron(I) Complexes as Structural Models of the Reduced Form of Iron−Iron Hydrogenase

scientific article published on 01 February 2006

Deprotonation of molybdenum carbonyl hydrido diphosphine [HMo(CO)2(PP)2]BF4 complexes: hard anions as proton carriers

Development of five-coordinate zinc mono- and dithiolates as S-donor metalloligands: formation of a Zn-W coordination polymer.

scientific article published in June 2009

Dinitrosyl iron adducts of (N2S2)M(NO) complexes (M=Fe, Co) as metallodithiolate ligands

Discrete Air-Stable Nickel(II)–Palladium(II) Complexes as Catalysts for Suzuki–Miyaura Reactions

scholarly article by Tiankun Zhao et al published 25 April 2017 in Organometallics

Divergent pathways for the addition of dioxygen to sulfur in nickel cis-dithiolates: an isotopomeric analysis

article

Dual Electron Uptake by Simultaneous Iron and Ligand Reduction in an N-Heterocyclic Carbene Substituted [FeFe] Hydrogenase Model Compound

scientific article published on 01 August 2005

Effects of Glutathione and Histidine on NO Release from a Dimeric Dinitrosyl Iron Complex (DNIC)

scientific article published on 13 November 2020

Effects of sulfur site modification on the redox potentials of derivatives of [N,N'-bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II)

scholarly article by Patrick J. Farmer et al published June 1993 in Journal of the American Chemical Society

Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: structure/function relationships

Electrocatalytic O₂ reduction by [Fe-Fe]-hydrogenase active site models

scientific article published on 10 June 2014

Electron paramagnetic resonance and electrochemical study of the oxidation chemistry of mononuclear and binuclear chromium carbonyl thiolates

article

Electronic effects of (N2S2)M(NO) complexes (M = Fe, Co) as metallodithiolate ligands

scientific article published on 9 February 2008

Enzymes activated by synthetic components

scientific article published in Nature

Erratum to “Fundamental properties of small molecule models of Fe-only hydrogenase: computations relative to the definition of an entatic state in the active site” [Coord. Chem. Rev. 238/239 (2003) 255-266]

scholarly article published in Coordination Chemistry Reviews

Facile reduction of carbon dioxide by anionic Group 6b metal hydrides. Chemistry relevant to catalysis of the water-gas shift reaction

scientific article published in 1981

H/D exchange reactions in dinuclear iron thiolates as activity assay models of Fe-H2ase

scientific article published in October 2001

HYDROGENASE ACTIVE SITES: A NEW PARADIGM FOR NATURAL PRODUCT-INSPIRED SYNTHESIS BASED ON ORGANOMETALLIC CHEMISTRY

Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes

Hemilabile Bridging Thiolates as Proton Shuttles in Bioinspired H2 Production Electrocatalysts

scientific article published on 19 August 2016

Heterobimetallics of Nickel−Iron Dinitrosyl: Electronic Control by Chelate and Diatomic Ligands

article

Heterobinuclear Nonacarbonyl Complexes and Hydride Complexes of Iron-Chromium, Iron-Molybdenum, and Iron-Tungsten

scholarly article by Larry W. Arndt et al published 5 January 2007 in Inorganic Syntheses

Heterogenization of a Water-Insoluble Molecular Complex for Catalysis of the Proton-Reduction Reaction in Highly Acidic Aqueous Solutions

Hydrogenases (Eur. J. Inorg. Chem. 7/2011)

Hyperfine interactions and electron distribution in Fe(II)Fe (I) and Fe (I)Fe (I) models for the active site of the [FeFe] hydrogenases: Mössbauer spectroscopy studies of low-spin Fe(I.).

scientific article published on 23 May 2013

Imidazole-containing (N3S)-Ni(II) complexes relating to nickel containing biomolecules

scientific article

Immobilization-Enabled Proton Reduction Catalysis by a Di-iron Hydrogenase Mimic

scientific article

Influence of Sulfur Metalation on the Accessibility of the NiII/ICouple in [N,N‘-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II): Insight into the Redox Properties of [NiFe]-Hydrogenase

scientific article published on 01 April 1996

Influence of sulf-oxygenation on CO/L substitution and Fe(CO)3 rotation in thiolate-bridged diiron complexes

scientific article published in September 2009

Interactions of CpM'(CO)3- (M' = chromium, molybdenum, or tungsten) with cations: effects on CO exchange and RX addition reactions

article

Interplay of hemilability and redox activity in models of hydrogenase active sites

scientific article published on 30 October 2017

Intramolecular iron-mediated C-H bond heterolysis with an assist of pendant base in a [FeFe]-hydrogenase model.

scientific article published on 7 October 2014

Intramolecular ligand rearrangements in anionic group 6 metal pentacarbonyl hydride derivatives

Iron nitrosyl complexes as models for biological nitric oxide transfer reagents

scientific article published on 7 March 2006

Iron(0) mediated C-H activation of 1-hexyne: a mechanistic study using time-resolved infrared spectroscopy

scientific article published on 20 July 2016

Isolation of chromium(0) thiols: molecular structure of (tert-butylmercaptan)pentacarbonylchromium

article

Isotopic labeling investigation of the oxygenation of nickel-bound thiolates by molecular oxygen

scholarly article by Patrick J. Farmer et al published June 1992 in Journal of the American Chemical Society

Ligand Displacement Reaction Paths in a Diiron Hydrogenase Active Site Model Complex.

scientific article published on 2 August 2016

Ligand lability studies in bridging hydride complexes of Group 6B metal carbonylates

Lightinduced sulfur-dealkylation of phosphino-thioether nickel(0) complexes

scholarly article by Jang Sub Kim et al published September 1996 in Inorganica Chimica Acta

Mechanism of electrocatalytic hydrogen production by a di-iron model of iron-iron hydrogenase: a density functional theory study of proton dissociation constants and electrode reduction potentials

scientific article published on 23 February 2010

Merging the old with the new

scientific article published on 15 December 2011

Metal donor to metal acceptor complexes. Fe(CO)42-, HFe(CO)4-, and trans-HFe(CO)3P(OMe)3- as anionic ligands to M(CO)50, M = Cr, W

scientific article published in 1986

Metal-Templated, Tight Loop Conformation of a Cys-X-Cys Biomimetic Assembles a Dimanganese Complex

scientific article published on 21 January 2020

Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry

scientific article published on 07 May 2015

Metallodithiolates as ligands to dinitrosyl iron complexes: toward the understanding of structures, equilibria, and spin coupling

scientific article

Metallodithiolato ligands as bridges in multiply bonded dimolybdenum complexes

scientific article published on 26 January 2005

Metallosulfoxides and -sulfones: Sulfur Oxygenates of [1,5-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]palladium(II)

Methylation of Tethered Thiolates in [(bme-daco)Zn]2and [(bme-daco)Cd]2as a Model of Zinc Sulfur-Methylation Proteins

scientific article published on 01 August 1998

Modeling Structures and Vibrational Frequencies for Dinitrosyl Iron Complexes (DNICs) with Density Functional Theory

scientific article published on 05 August 2011

Molecular catalysis that transpires only when the complex is heterogenized: Studies of a hydrogenase complex surface-tethered on polycrystalline and (111)-faceted gold by EC, PM-FT-IRRAS, HREELS, XPS and STM

N,N′-Bis(Mercaptoethyl)-1,4-Diazacycloheptane (H2BME-DACH) and its Nickel Complex: A Model for Bioinorganic Chemistry

scholarly article by Melissa Golden et al published 11 April 2014 in Inorganic Syntheses

N-heterocyclic carbene ligands as mimics of imidazoles/histidine for the stabilization of di- and trinitrosyl iron complexes

scientific article published on 8 August 2011

N2S2Ni Metallothiolates as a Class of Ligands that Support Organometallic and Bioorganometallic Reactivity

scientific article published on 01 February 2005

N2S2Ni metallodithiolate complexes as ligands: structural and aqueous solution quantitative studies of the ability of metal ions to form M-S-Ni bridges to mercapto groups coordinated to nickel(II). implications for acetyl coenzyme A synthase

scientific article published in February 2005

NiN(2)S(2) complexes as metallodithiolate ligands to Rh(I), Rh(II) and Rh(III).

scientific article published on 19 July 2006

Nickel mediated sulfur–selenium and sulfur–sulfur bond formation

scholarly article by Chia-Huei Lai et al published 1999 in Chemical Communications

Olefin isomerization catalysis by heterobimetallic hydrides, HFeM(CO)8L- (M = Cr, Mo, W; L = CO, PR3)

scientific article published in 1985

Organometallic chemistry of sulfur/phosphorus donor ligand complexes of nickel(II) and nickel(0)

scholarly article by Yui May Hsiao et al published March 1993 in Organometallics

Organometallic exchange reactions. X. Cross-association of tert butyllithium. Kinetics of tert butyllithium dissociation

scientific article published in 1970

Orientation and stereodynamic paths of planar monodentate ligands in square planar nickel N2S complexes

scientific article

Oxidative Addition of Phosphine-Tethered Thiols to Iron Carbonyl: Binuclear Phosphinothiolate Complexes, (μ-SCH2CH2PPh2)2Fe2(CO)4, and Hydride Derivatives

article

Oxygen Capture by Sulfur in Nickel Thiolates

scholarly article by Craig A. Grapperhaus & Marcetta Y. Darensbourg published August 1998 in Accounts of Chemical Research

Oxygen uptake in complexes related to [NiFeS]- and [NiFeSe]-hydrogenase active sites.

scientific article published on 5 November 2018

Oxygen-Tolerant H Production by [FeFe]-Hase Active Site Mimics Aided by Second Sphere Proton Shuttle

scientific article published on 18 September 2018

Pentacoordinate (μ-Oxo)diiron(III) Thiolate Complexes and Dimeric Iron(II) Precursors

scientific article published on 01 August 1998

Polydentate N(2)S(2)O and N(2)S(2)O(2) Ligands as Alcoholic Derivatives of (N,N'-Bis(2-mercaptoethyl)-1,5-diazacyclooctane)nickel(II) and (N,N'-Bis(2-mercapto-2-methylpropane)-1,5-diazacyclooctane)nickel(II).

scientific article published in June 1996

Preface for Small Molecule Activation: From Biological Principles to Energy Applications. Part 3: Small Molecules Related to (Artificial) Photosynthesis

scientific article

Preparation of a stereospecifically carbon-13 monoxide-labeled [(.mu.-H)[Mo(CO)5]2]- species and analysis of its carbonyl stretching vibrational modes

Preparations and structures of a zinc(II) dimer and zinc(II)/nickel(II) pentanuclear derivatives of N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane: [(BME-DACO)Zn]2 and {[(BME-DACO)Ni]3[ZnCl]2}{BF4}2

scholarly article by Thawatchai Tuntulani et al published August 1992 in Inorganic Chemistry

Properties and x-ray structure of bis(triphenylphosphine)nitrogen(1+) cis-tricarbonylhydridotris(triphenyl phosphite)ferrate(1-), an unexpected structural isomer

Proton affinity studies of nickel N2S2 complexes and control of aggregation

scientific article published on 07 June 2019

Protonation sites in thiolato iron carbonylates: evidence for an arrested Fe(RS-H) oxidative addition

article

Reaction of (Cy3P)2Ni(H)(CH3) with carbon dioxide. Formation of an hydridonickel formate complex, HNi(O2CH)(Cy3P)2

scientific article published in 1987

Reactions of anionic transition metal carbonyl hydrides with electrophilic metal carbonyls: Nucleophilic addition (hydride transfer) vs. electron transfer mechanisms

article

Reactions of palladium and gold complexes with zinc-thiolate chelates using electrospray mass spectrometry and X-ray diffraction: molecular identification of [Pd(bme-dach)], [Au(bme-dach]+ and [ZnCl(bme-dach)]2Pd

scientific article published on 17 November 2009

Reactions of transition metal carbonyls with organolithium compounds. II. Prediction of nucleophilic attack at carbon and resultant stereochemistry

Redox active iron nitrosyl units in proton reduction electrocatalysis

scientific article published on 2 May 2014

Reduction-Promoted Sulfur-Oxygen Bond Cleavage in a Nickel Sulfenate as a Model for the Activation of [NiFe] Hydrogenase

article

Refining the active site structure of iron-iron hydrogenase using computational infrared spectroscopy

scientific article

Regioselective 12CO/13CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the Hox state of [FeFe]-hydrogenase

scientific article published on 20 February 2008

Regioselectivity in Ligand Substitution Reactions on Diiron Complexes Governed by Nucleophilic and Electrophilic Ligand Properties

scientific article published on 13 March 2015

Relative reactivity and mechanistic studies of the hydride-transfer reagents HM(CO)4L-(M = Cr, W; L = CO, PR3)

Requirements for functional models of the iron hydrogenase active site: D2/H2O exchange activity in ((mu-SMe)(mu-pdt)[Fe(CO)2(PMe3)]2+)[BF4-].

scientific article

Resin-bound models of the [FeFe]-hydrogenase enzyme active site and studies of their reactivity

scientific article published on 2 March 2009

Responses of the Fe(CN)2(CO) Unit to Electronic Changes as Related to Its Role in [NiFe]Hydrogenase

article

S K-edge X-ray absorption spectroscopy and density functional theory studies of high and low spin {FeNO}7 thiolate complexes: exchange stabilization of electron delocalization in {FeNO}7 and {FeO2}8.

scientific article

S K-edge XAS and DFT calculations on square-planar NiII-thiolate complexes: effects of active and passive H-bonding

scientific article published on 20 October 2007

SYNERGY BETWEEN THEORY AND EXPERIMENT AS APPLIED TO H/D EXCHANGE ACTIVITY ASSAYS IN [Fe]H2ase ACTIVE SITE MODELS

SYNTHETIC STRATEGIES FOR N2S2O-PENTACOORDINATE NICKEL(II) BASED ON THE HIGHLY STERICALLY ENCUMBERED LIGAND N,N′-BIS(2-MERCAPTO-2-METHYLPROPANE)-1,5-DIAZACYCLOOCTANE

scholarly article by Marcetta Y. Darensbourg et al published June 1994 in Journal of Coordination Chemistry

Selective reduction of acyl chlorides to aldehydes by anionic Group VIB transition metal hydrides

Self-assembly of dinitrosyl iron units into imidazolate-edge-bridged molecular squares: characterization including Mössbauer spectroscopy

scientific article published on 29 November 2011

Sensing of Sulfur Dioxide by Base Metal Thiolates: Structures and Properties of Molecular NiN2S2/SO2Adducts

scientific article published on 01 July 2004

Series of mixed valent Fe(II)Fe(I) complexes that model the Hox state of [FeFe]hydrogenase: redox properties, density-functional theory investigation, and reactivities with extrinsic CO.

scientific article published on 3 July 2008

Singlet Oxygen and the Production of Sulfur Oxygenates of Nickel(II) and Palladium(II) Thiolates

scientific article published on 01 April 1997

Site-specific ion pairing of monosubstituted vanadium carbonylates, LV(CO)5-

article published in 1982

Solution and solid-state structures of salts of trans-HFe(CO)3PR3- including a study of alkali cation contact ion pairing

article published in 1986

Spectroscopic and chemical studies of nickel(II) hydrides

scholarly article by Marcetta Y. Darensbourg et al published May 1989 in Inorganic Chemistry

Spectroscopic studies of some carbene pentacarbonyl complexes of chromium(0) and tungsten(0)

Stereochemical nonrigidity in heterobimetallic complexes containing the bent metallocene-thiolate fragment

Sterically protected nickel(II) in a N2S2 donor environment: 1,5-bis(mercaptoethyl)-1,5-diazacyclooctane and its methylated derivative

scholarly article by Daniel K. Mills et al published October 1990 in Inorganic Chemistry

Structural and Electrochemical Comparison of NiII in an N2S2 Plane with Two, One and No Axial Ligands: Isolation and Characterization of a Five-Coordinate Nickel(II) Complex

scholarly article by Rizalia M. Buonomo et al published July 1996 in European Journal of Inorganic Chemistry

Structural and Electronic Responses to the Three Redox Levels of Fe(NO)N2 S2 -Fe(NO)2

scientific article published on 09 October 2018

Structural and Spectroscopic Features of Mixed Valent FeIIFeI Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase

scientific article published on 25 July 2012

Structural and chemical characterization of a phosphine bound M-H-M bridged carbonylate: Et4N+(.mu.-H)[Mo2(CO)9PPh3]-

article published in 1979

Structural characterizations of salts of HCr(CO)5- and (μ-H)2BH2Cr(CO)4- and studies of their interconversions

article

Structural studies of thiophenoxide niobium complexes (.eta.5-C5H5)2Nb(SC6H5)2, [(.eta.5-C5H5)2Nb(SC6H5)2+], and [(.eta.5-C5H5)2Nb(.mu.-SC6H5)2)Mo(CO)4+]

scholarly article by Marcetta Y. Darensbourg et al published May 1989 in Organometallics

Structure/Function Relationships in Ligand-Based SO2/O2 Conversion to Sulfate As Promoted by Nickel and Palladium Thiolates

scholarly article by Marcetta Y. Darensbourg et al published December 1995 in Inorganic Chemistry

Structures and energetics of models for the active site of acetyl-coenzyme a synthase: role of distal and proximal metals in catalysis

scientific article published in March 2004

Studies using tributylphosphine oxide as a carbon monoxide labilizing ligand in the synthesis of metal carbonyl complexes highly enriched in carbon-13 monoxide

Study of Sulfinate and Sulfenate Complexes Derived from the Oxygenation of Thiolate Sulfur in [1,5-Bis(2-mercapto-2-methylpropyl)-1,5-diazacyclooctanato(2-)]nickel(II)

scholarly article by Rizalia M. Buonomo et al published January 1995 in Journal of the American Chemical Society

Study of Sulfinate and Sulfenate Complexes Derived from the Oxygenation of Thiolate Sulfur in [1,5-Bis(2-mercapto-2-methylpropyl)-1,5-diazacyclooctanato(2-)]nickel(II). [Erratum to document cited in CA122:70603]

scholarly article by Rizalia M. Buonomo et al published May 1995 in Journal of the American Chemical Society

Subtle bite-angle influences on N(2)S(2)Ni complexes

scientific article published in July 2001

Sulfonated diiron complexes as water-soluble models of the [Fe-Fe]-hydrogenase enzyme active site

scientific article

Sulfoxygenation of Active Site Models of [NiFe] and [FeFe] Hydrogenases - A Commentary on Possible Chemical Models of Hydrogenase Enzyme Oxygen Sensitivity

Sulfur K-edge XAS and DFT studies on NiII complexes with oxidized thiolate ligands: implications for the roles of oxidized thiolates in the active sites of Fe and Co nitrile hydratase

scientific article published on 15 May 2007

Sulfur Oxygenates of Biomimetics of the Diiron Subsite of the [FeFe]-Hydrogenase Active Site: Properties and Oxygen Damage Repair Possibilities

scientific article published on 01 June 2009

Sulfur Site Iodine Adduct of a Nickel Thiolate Complex

scientific article published on 01 December 1998

Sulfur site adducts of sulfur dioxide in nickel-bound thiolates and their conversion to sulfate

scholarly article by Marcetta Y. Darensbourg et al published February 1994 in Inorganic Chemistry

Synthesis and Characterization of a Stable Iron(II) Hydride-Thiolate Complex: (PhS)Fe(H)(CO)2(P(OPh)3)2

Synthesis and Dimer Cleavage Reactions of the N2S Thiolate Bridged Dimer [(mmp-dach)2Ni2]Cl2

scientific article published on 01 August 1999

Synthesis and Molecular Structures of Mononitrosyl (N2S2)M(NO) Complexes (M = Fe, Co)

scientific article published on 01 November 2005

Synthesis and Mössbauer Characterization of Octahedral Iron(II) Carbonyl Complexes FeI2(CO)3L and FeI2(CO)2L2: Developing Models of the [Fe]-H2ase Active Site

scientific article published on 01 December 2009

Synthesis and characterization of the electron-rich iron hydride HFe(CO)2(P(OPh)3)2- and its ligand-based redox substitution with thiolates

Synthesis of Carboxylic Acid-Modified [FeFe]-Hydrogenase Model Complexes Amenable to Surface Immobilization

Synthesis of metal carbonyl complexes highly enriched in carbon-13: utilization of the carbon monoxide-labilizing ability of (n-Bu)3P:O

scientific article published in 1980

Synthesis, Structures, and Electrochemical Properties of Nickel Complexes of Macrocyclic N2S2Aminothioethers

scholarly article by Ghezai Musie et al published January 1998 in Inorganic Chemistry

Synthetic Metallodithiolato Ligands as Pendant Bases in [FeIFeI], [FeI[Fe(NO)]II], and [(μ-H)FeIIFeII] Complexes

scientific article published on 21 February 2020

Synthetic Support of De Novo Design: Sterically Bulky [FeFe]-Hydrogenase Models

scientific article published on 01 January 2008

Synthetic advances inspired by the bioactive dinitrosyl iron unit

scientific article published on 19 June 2015

Synthetic chemistry: making a natural fuel cell

scientific article published on 01 February 2005

Temperature and solvent dependence of scalar coupling constants in salts of trans-HFe(CO)3PR3-

scientific article published in 1987

Template Effect for O2Addition acrosscis-Sulfur Sites in Nickel Dithiolates

article

Tetracarbonyliron(0) Complexes Containing Group V Donor Ligands

Tetradentate N2S2Vanadyl(IV) Coordination Complexes: Synthesis, Characterization, and Reactivity Studies

scientific article published on 07 February 2011

The .mu.-hydrobis[tetracarbonyl(methyldiphenylphosphine)molybdenum](2-) anion: an example of phosphine enhancement of metal-metal interaction

scientific article published in 1980

The Bioorganometallic Chemistry of Hydrogenase

The Construction of (N2S2)Ni−Pd Clusters: A Slant-Chair, a Basket and a C4-Paddlewheel Structure

The Modular Assembly of Clusters Is the Natural Synthetic Strategy for the Active Site of [FeFe] Hydrogenase

scientific article published on 01 November 2010

The Vapochromic Behavior, Desulfoxidation and Structural Characterization of the SO2 Adducts of Ni(BME-DACH) from Powder Data

The acetyl CoA synthase paradigm for hybrid bio-organometallics: Quantitative measures for resin-bound Ni–Rh complexes

The anion assisted transfer of a sterically constrained proton: molecular structure of bis[1,2-ethanediylbis(diphenylphosphine)]dicarbonylhydridomolybdenum tetrachloroaluminate [HMo(CO)2(Ph2PCH2CH2PPh2)2+ AlCl4-]

article by John M. Hanckel & Marcetta Y. Darensbourg published November 1983 in Journal of the American Chemical Society

The bio-organometallic chemistry of active site iron in hydrogenases

The effect of bridgehead steric bulk on the ground state and intramolecular exchange processes of (μ-SCH2CR2CH2S)[Fe(CO)3][Fe(CO)2L] complexes

The extent of association of the bis(triphenylphosphine)iminium cation with organometallic anions in tetrahydrofuran solution

scientific article published in 1977

The hydrophilic phosphatriazaadamantane ligand in the development of H2 production electrocatalysts: iron hydrogenase model complexes

scientific article published in September 2004

The ligand unwrapping/rewrapping pathway that exchanges metals in S-acetylated, hexacoordinate N2S2O2 complexes.

scientific article published on 7 September 2015

The nature of alkali cation contact ion pairs with anionic transition-metal hydrides HM(CO)4L- (M = Cr, W; L = CO, PR3)

The organometallic active site of [Fe]hydrogenase: models and entatic states

scholarly article

The reaction of electrophiles with models of iron–iron hydrogenase: A switch in regioselectivity

The synthesis and molecular structure of (Ph3PAu)2Fe(CO)3P(OEt)3: a triangular Au2Fe cluster

The use of ion-pairing phenomena in the assignment of v(co) ir bands of pv(co)5-

Thiolate Bridged Nickel–Iron Complexes Containing both Iron(0) and Iron(II) Carbonyls

scholarly article by Chia-Huei Lai et al published 1 November 1996 in Angewandte Chemie International Edition

Thiolate bridging and metal exchange in adducts of a zinc finger model and Pt(II) complexes: biomimetic studies of protein/Pt/DNA interactions

scientific article published on 19 April 2008

Thiolate, thioether, and thiol derivatives of iron(0) carbonyls

scientific article published in 1989

Thiolate-bridged heterodinuclear platinum-zinc chelates as models for ternary platinum-DNA-protein complexes and zinc ejection from zinc fingers. Evidence from studies using ESI-mass spectrometry

scientific article

Time Resolved Infrared Spectroscopy: Kinetic Studies of Weakly Binding Ligands in an Iron–Iron Hydrogenase Model Compound

scientific article published on 08 June 2012

Toward biocompatible dinitrosyl iron complexes: sugar-appended thiolates

scientific article published on 6 January 2017

Toward the Optimization of Dinitrosyl Iron Complexes as Therapeutics for Smooth Muscle Cells

scientific article published on 20 June 2019

Unique reactivity of a tetradentate N(2)S(2) complex of nickel: intermediates in the production of sulfur oxygenates.

scientific article

Variable modes of nickel(II) coordination with macrocyclic ligands based on 1,5-bis(2-mercaptoethyl)-1,5-diazacyclooctane (BME-DACO)

scholarly article by Marcetta Y. Darensbourg et al published November 1992 in Inorganic Chemistry

Variable oxygenation levels of sulfur in sterically hindered thiolates: molecular structure of [N-(2-mercapto-2-methylpropyl)-N'-(2-sulfeno-2-methylpropyl)-1,5-diazacyclooctanato]nickel(II)

scholarly article by Ivan Font et al published December 1993 in Inorganic Chemistry

Versatile N2S2nickel-dithiolates as mono- and bridging bidentate, S-donor ligands to gold(i)

scientific article published on 01 January 2014

X-ray structure and solution characterization of tetracarbonylmolybdenumbis(.mu.-diphenylphosphinoethanethiolato)nickel (Ni(.mu.-SCH2CH2PPh2)2Mo(CO)4)

scholarly article by Stephen S. Chojnacki et al published August 1993 in Inorganic Chemistry

X-ray structure of [Nb(η5-C5H5)2(SCH2CH2CH2S]

Zinc/nickel exchange and ligand cannibalism in N2S2O(1,2) donor ligand sets

scientific article published on 14 September 2009

cis-Dithiolatonickel as metalloligand to dinitrosyl iron units: the di-metallic structure of Ni(μ-SR)[Fe(NO)2] and an unexpected, abbreviated metalloadamantyl cluster, Ni2(μ-SR)4[Fe(NO)2]3

scientific article published on 06 May 2011

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