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List of works by Didier Gigmes

A Multicolor Photoinitiator for Cationic Polymerization and Interpenetrated Polymer Network Synthesis: 2,7‐Di‐tert‐butyldimethyldihydropyrene ⬇️

scientific article published on June 4, 2013

A complete kinetic study of a versatile functional monomer: acetoacetoxyethyl methacrylate (AAEMA)

A comprehensive kinetic study of the conventional free-radical polymerization of seven-membered cyclic ketene acetals

A glance at violet LED sensitive photoinitiators based on the spiroxanthene scaffold

A pH-driven ring translocation switch against cancer cells

scientific article published on 01 December 2018

A ring to rule them all: a cyclic ketene acetal comonomer controls the nitroxide-mediated polymerization of methacrylates and confers tunable degradability

scientific article published on July 2015

AaTX1, from Androctonus australis scorpion venom: purification, synthesis and characterization in dopaminergic neurons

scientific article

Adduction of ammonium to polylactides to modify their dissociation behavior in CID.

scientific article published on 13 December 2017

Alkoxyamine C–ON Bond Homolysis: Stereoelectronic Effects

Alkoxyamines of Stable Aromatic Nitroxides: NOvs. CO Bond Homolysis

scholarly article by Didier Gigmes et al published October 2006 in Helvetica Chimica Acta

Anomerization of Acrylated Glucose During Traveling Wave Ion Mobility Spectrometry

scientific article published on 4 June 2015

ArgTX-636, a polyamine isolated from spider venom: A novel class of melanogenesis inhibitors

scientific article

Block copolymers via macromercaptan initiated ring opening polymerization

Can the First Addition of Alkyl Radicals Play a Role in the Fate of NMP?

Catalyst- and initiator-free radical addition in mild conditions and its use as a macromolecular conjugation tool

scientific article published on 4 January 2018

Catalyzed chain growth of polyethylene on magnesium for the synthesis of macroalkoxyamines: Application to the production of block copolymers using controlled radical polymerization

article

Chemically Induced Dynamic Nuclear Polarization during the Thermolysis of Alkoxyamines: A New Approach to Detect the Occurrence of H-Transfer Reactions

Convenient access to biocompatible block copolymers from SG1-based aliphatic polyester macro-alkoxyamines.

scientific article published in June 2009

Correction: A ring to rule them all: a cyclic ketene acetal comonomer controls the nitroxide-mediated polymerization of methacrylates and confers tunable degradability

scientific article

Design of Iodonium Salts for UV or Near-UV LEDs for Photoacid Generator and Polymerization Purposes

scientific article published on 30 December 2019

Diastereomeric excess upon cleavage and reformation of diastereomeric alkoxyamines

scientific article published on 29 January 2004

Dispersion nitroxide mediated polymerization of methyl methacrylate in supercritical carbon dioxide using in situ formed stabilizers

Effect of the carboxylate salt on the C--ON bond homolysis of SG1-based alkoxyamines

scientific article

Efficient dual radical/cationic photoinitiator under visible light: a new concept

scholarly article by Jacques Lalevée et al published 2011 in Polymer Chemistry

Elaboration of Glycopolymer-Functionalized Micelles from anN-Vinylpyrrolidone/Lactide-Based Reactive Copolymer Platform ⬇️

scientific article published on July 4, 2013

Elucidation of a side reaction occurring during nitroxide-mediated polymerization of cyclic ketene acetals by tandem mass spectrometric end-group analysis of aliphatic polyesters

scientific article published on December 2015

End-Group Cleavage in MALDI of ATRP-Made Polystyrene: A Silver-Catalyzed Reaction during Sample Preparation ⬇️

scientific article published on May 22, 2013

Enediynes bearing polyfluoroaryl sulfoxide as new antiproliferative agents with dual targeting of microtubules and DNA.

scientific article published on 12 February 2018

Enhanced Spin Capturing Polymerization of Ethylene

Facile Synthesis of Innocuous Comb-Shaped Polymethacrylates with PEG Side Chains by Nitroxide-Mediated Radical Polymerization in Hydroalcoholic Solutions

Factors influencing C-ON bond homolysis in alkoxyamines: unexpected behavior of SG1 (N-(2-methyl-2-propyl)- N-(1-diethylphosphono-2,2-dimethylpropyl)-N-oxyl)-based alkoxyamines

scientific article published in July 2004

First Effective Nitroxide-Mediated Polymerization of Methyl Methacrylate

article published in 2007

H-transfer reaction during decomposition ofN-(2-methylpropyl)-N-(1-diethylphosphono-2,2-dimethylpropyl)-N-oxyl (SG1)-based alkoxyamines

Heterogeneous modification of chitosan via nitroxide-mediated polymerization

Hydrogen-transfer reaction in nitroxide mediated polymerization of methyl methacrylate: 2,2-Diphenyl-3-phenylimino-2,3-dihydroindol-1-yloxyl nitroxide (DPAIO) vs. TEMPO

Importance of the position of the chromophore group on the dissociation process of light sensitive alkoxyamines

scientific article published on 31 August 2010

Improved Structural Elucidation of Synthetic Polymers by Dynamic Nuclear Polarization Solid-State NMR Spectroscopy

article published in 2013

Improving bioassay sensitivity through immobilization of bio-probes onto reactive micelles

scientific article published on 01 July 2017

In situnitroxide-mediated polymerization of styrene promoted by theN-tert-butyl-α-isopropylnitrone/bpo pair: ESR investigations

Indolinic nitroxides: evaluation of their potential as universal control agents for nitroxide mediated polymerization

Influence of pyrene grafting on PMMA nanosecond laser ablation at 248 nm.

scientific article

Intramolecular Hydrogen Bonding: The Case ofβ-Phosphorylated Nitroxide (= Aminoxyl) Radical

article

Iridium Photocatalysts in Free Radical Photopolymerization under Visible Lights

scholarly article by Jacques Lalevée et al published 18 January 2012 in ACS Macro Letters

Joining Efforts of Nitroxide-Mediated Polymerization (NMP) and Cobalt-Mediated Radical Polymerization (CMRP) for the Preparation of Novel ABC Triblock Copolymers

Kinetic study of H-atom transfer in imidazoline-, imidazolidine-, and pyrrolidine-based alkoxyamines: Consequences for nitroxide-mediated polymerization

Kinetic subtleties of nitroxide mediated polymerization ⬇️

scientific article published on January 13, 2011

Leveled Steric Effect in Alkoxyamines of SG1-Type

Light-Induced Thermal Decomposition of Alkoxyamines upon Infrared CO2 Laser: Toward Spatially Controlled Polymerization of Methacrylates in Laser Write Experiments

scientific article published on 05 February 2020

Light-Sensitive Alkoxyamines as Versatile Spatially- and Temporally- Controlled Precursors of Alkyl Radicals and Nitroxides

scientific article published on 12 February 2018

Light‐Harvesting Organic Photoinitiators of Polymerization ⬇️

scientific article published on December 2, 2012

Liquid chromatography at the critical conditions in pure eluent: an efficient tool for the characterization of functional polystyrenes

scientific article

Long-Range Polar Effect on the C-ON Bond Homolysis in (tert-Butyl[1-(diethylphosphonyl)-2,2-dimethylpropyl]aminoxyl) SG1-Based Alkoxyamines

Long-range polar and steric effects in propionate-SG1-type alkoxyamines (SG1-CHMeCOOX): a multiparameter analysis

Mechanistic investigation and selectivity of the grafting onto C60 of macroradicals prepared by cobalt-mediated radical polymerization

Metal and metal-free photocatalysts: mechanistic approach and application as photoinitiators of photopolymerization

scientific article

Negative mode MS/MS to read digital information encoded in sequence-defined oligo(urethane)s: A mechanistic study

New Functional Polyolefins: Towards a Bridge Between Catalytic and RAFT Polymerizations?

New core-pyrene π structure organophotocatalysts usable as highly efficient photoinitiators

scientific article

New thioxanthone and xanthone photoinitiators based on silyl radical chemistry

Nitroxide mediated polymerization of methacrylates at moderate temperature

article

Nitroxide-Mediated Polymerization of Methyl Methacrylate Using an SG1-Based Alkoxyamine: How the Penultimate Effect Could Lead to Uncontrolled and Unliving Polymerization

Nitroxide-mediated controlled radical polymerizations of styrene derivatives

Nitroxide-mediated polymerization

scientific article from 2013

Nitroxide-mediated radical ring-opening copolymerization: chain-end investigation and block copolymer synthesis

scientific article

Observing Apparent Nonuniform Sensitivity Enhancements in Dynamic Nuclear Polarization Solid-State NMR Spectra of Polymers

On the Synthesis, Characterization and Reactivity of N-Heteroaryl-Boryl Radicals, a New Radical Class Based on Five-Membered Ring Ligands

On the structure–control relationship of amide-functionalized SG1-based alkoxyamines for nitroxide-mediated polymerization and conjugation

On-surface synthesis of aligned functional nanoribbons monitored by scanning tunnelling microscopy and vibrational spectroscopy

scientific article

Optimizing Sample Preparation Methods for Dynamic Nuclear Polarization Solid-state NMR of Synthetic Polymers

Organic Electronics: An El Dorado in the Quest of New Photocatalysts for Polymerization Reactions

scientific article

Organized formation of 2D extended covalent organic frameworks at surfaces

scientific article published on 30 April 2008

Peptide ligation from alkoxyamine based radical addition

scientific article published in March 2014

Photodissociation rate constants of new light sensitive alkoxyamines

scientific article published on 22 June 2010

Photoredox catalysis for polymerization reactions

scientific article published in January 2012

Preparation and in vitro evaluation of imiquimod loaded polylactide-based micelles as potential vaccine adjuvants

scientific article published on 24 September 2014

Preparation of PVDF-grafted-PS involving nitroxides

Radical Copolymerization of Vinyl Ethers and Cyclic Ketene Acetals as a Versatile Platform to Design Functional Polyesters

scientific article published on 5 November 2017

Radical Ring-Opening Polymerization: Scope, Limitations, and Application to (Bio)Degradable Materials

scientific article published on 13 January 2017

Reactions of nitric oxide and nitrogen dioxide with coenzyme Q: involvement of the isoprenic chain

scientific article published in February 2013

Red-light-induced cationic photopolymerization: perylene derivatives as efficient photoinitiators

scientific article

Robust supramolecular network on Ag(111): hydrogen-bond enhancement through partial alcohol dehydrogenation

scientific article published in May 2009

Role of matrix metalloproteinases in migration and neurotrophic properties of nasal olfactory stem and ensheathing cells

scientific article published on 3 October 2012

Scope and limitations of the nitroxide-mediated radical ring-opening polymerization of cyclic ketene acetals

Selective Bond Cleavage in Informational Poly(Alkoxyamine Phosphodiester)s

scientific article published on 24 May 2020

Sequential Linking To Control Growth of a Surface Covalent Organic Framework

Side functionalization of diboronic acid precursors for covalent organic frameworks

Stability of SG1 nitroxide towards unprotected sugar and lithium salts: a preamble to cellulose modification by nitroxide-mediated graft polymerization

scientific article (publication date: 2013)

Stimuli-responsive behavior of micelles prepared from a poly(vinyl alcohol)-block-poly(acrylic acid)-block-poly(4-vinylpyridine) triblock terpolymer

article published in 2015

Structural effects on the photodissociation of alkoxyamines

scientific article

Subtle ligand effects in oxidative photocatalysis with iridium complexes: application to photopolymerization

scientific article published on 28 November 2011

Successful MALDI-MS analysis of synthetic polymers with labile end-groups: the case of nitroxide-mediated polymerization using the MAMA-SG1 alkoxyamine

scientific article

Superior Electrochemical Performance of Thin-Film Thermoplastic Elastomer-Coated SnSb as an Anode for Li-ion Batteries

Synthesis of highly labile SG1-based alkoxyamines under photochemical conditions

scientific article published on 22 May 2008

Synthesis of polystyrene-grafted cellulose acetate copolymers via nitroxide-mediated polymerization

Synthetic polymer-based electrospun fibers: biofunctionalization strategies and recent advances in tissue engineering, drug delivery and diagnostics Vincent Pertici

scientific article published on 29 November 2017

Tetrathiophosphoric acid tri(1-phenylethyl) ester and1-phenylethyl-diphenylphosphinodithioate as controlled radical polymerization agents

article published in 2003

The use of poly(N-[2-hydroxypropyl]-methacrylamide) hydrogel to repair a T10 spinal cord hemisection in rat: a behavioural, electrophysiological and anatomical examination

scientific article published on 30 May 2013

UV-Induced Micropatterning of Complex Functional Surfaces by Photopolymerization Controlled by Alkoxyamines

scientific article published on 2 September 2015

Ultra-Fast Synthesis of Multivalent Radical Nanoparticles by Ring-Opening Metathesis Polymerization-Induced Self-Assembly

scientific article published on 01 March 2019

Understanding the Controlled Polymerization of Methyl Methacrylate with Low Concentrations of 9-(4-Vinylbenzyl)-9H-carbazole Comonomer by Nitroxide-Mediated Polymerization: The Pivotal Role of Reactivity Ratios

Up to 100% Improvement in Dynamic Nuclear Polarization Solid-State NMR Sensitivity Enhancement of Polymers by Removing Oxygen

scientific article published on 26 May 2015

Venom conjugated polylactide applied as biocompatible material for passive and active immunotherapy against scorpion envenomation

scientific article

Water Sensitive Coatings Deposited by Aerosol Assisted Atmospheric Plasma Process: Tailoring the Hydrolysis Rate by the Precursor Chemistry

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