List of works - Roman Tkachov

"Hairy" poly(3-hexylthiophene) particles prepared via surface-initiated Kumada catalyst-transfer polycondensation

scientific article published in November 2009

A core-first preparation of poly(3-alkylthiophene) stars

scientific article from 2010

AB- Versus AA+BB-Suzuki Polycondensation: A Palladium/Tris(tert-butyl)phosphine Catalyst Can Outperform Conventional Catalysts

scientific article published on 01 December 2019

Chain-Growth Polymerization of Unusual Anion-Radical Monomers Based on Naphthalene Diimide: A New Route to Well-Defined n-Type Conjugated Copolymers

article by Volodymyr Senkovskyy et al published 14 December 2011 in Journal of the American Chemical Society

Charge Transport Anisotropy in Highly Oriented Thin Films of the Acceptor Polymer P(NDI2OD-T2)

Convenient route to initiate Kumada Catalyst-Transfer Polycondensation using Ni(dppe)Cl2 or Ni(dppp)Cl2 and sterically hindered Grignard Compounds

scientific article from 2010

Copolymerization of zinc-activated isoindigo- and naphthalene-diimide based monomers: an efficient route to low bandgap π-conjugated random copolymers with tunable properties

Efficient Tin-Free Route to a Donor–Acceptor Semiconducting Copolymer with Variable Molecular Weights

Electrochemical Investigations of the N-Type Semiconducting Polymer P(NDI2OD-T2) and Its Monomer: New Insights in the Reduction Behavior

scientific article from 2015

Facile synthesis of potassium tetrathiooxalate – The “true” monomer for the preparation of electron-conductive poly(nickel-ethylenetetrathiolate)

scholarly article by Roman Tkachov et al published April 2017 in Tetrahedron

Influence of Semiconductor Thickness and Molecular Weight on the Charge Transport of a Naphthalenediimide-Based Copolymer in Thin-Film Transistors

scientific article published on 17 March 2015

Influence of alkyl substitution pattern on reactivity of thiophene-based monomers in kumada catalyst-transfer polycondensation

scientific article from 2011

Laser Treatment as Sintering Process for Dispenser Printed Bismuth Telluride Based Paste

scientific article published on 22 October 2019

Mechanistic Insight into Catalyst-Transfer Polymerization of Unusual Anion-Radical Naphthalene Diimide Monomers: An Observation of Ni(0) Intermediates

scientific article from 2012

Microparticle-supported conjugated polyelectrolyte brushes prepared by surface-initiated kumada catalyst transfer polycondensation for sensor applications

scientific article published on 21 October 2010

On the role of single regiodefects and polydispersity in regioregular poly(3-hexylthiophene): defect distribution, synthesis of defect-free chains, and a simple model for the determination of crystallinity

scientific article published on 5 March 2012

One-Pot Synthesis of All-Conjugated Block-Like Bisthiophene–Naphthalenediimide/Fluorene Copolymer

Palladium-Catalyzed Chain-Growth Polycondensation of AB-type Monomers: High Catalyst Turnover and Polymerization Rates

scholarly article by Roman Tkachov et al published 12 February 2014 in Angewandte Chemie International Edition

Polyethenetetrathiolate or polytetrathiooxalate? Improved synthesis, a comparative analysis of a prominent thermoelectric polymer and implications to the charge transport mechanism

scientific article from 2018

Random catalyst walking along polymerized poly(3-hexylthiophene) chains in Kumada catalyst-transfer polycondensation

scientific article published in June 2010

Solution-Processable Hole-Transporting Polymers: Synthesis, Doping Study and Crosslinking Induced by UV-Irradiation or Huisgen-Click Cycloaddition

scientific article from 2022

Surface-initiated Kumada catalyst-transfer polycondensation of poly(9,9-dioctylfluorene) from organosilica particles: chain-confinement promoted beta-phase formation

scientific article published on 23 December 2009

Synthesis of a bifunctional initiator for controlled kumada catalyst-transfer polycondensation/Nitroxide-mediated polymerization and preparation of poly(3-hexylthiophene)-polystyrene block copolymer therefrom

scientific article published on 9 December 2009

Thermal operating window for PEDOT:PSS films and its related thermoelectric properties

Tuning Aggregation by Regioregularity for High-Performance n-Type P(NDI2OD-T-2) Donor-Acceptor Copolymers

scientific article from 2017

Tuning Orientational Order of Highly Aggregating P(NDI2OD-T2) by Solvent Vapor Annealing and Blade Coating

scientific article published on 17 December 2018

List of works by Roman Tkachov