List of works - Sensuke Ogoshi

A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes.

scientific article published on 28 August 2015

Axial Chirality around N-P Bonds Induced by Complexation between E(C6F5)3 (E = B, Al) and an N-Phosphine Oxide-Substituted Imidazolinylidene: A Key Intermediate in the Catalytic Phosphinoylation of CO2

scientific article published on 10 January 2020

Aza-nickelacycle key intermediate in nickel(0)-catalyzed transformation reactions

scientific article published on 13 May 2015

Bis-cyclooctatetraene tripalladium sandwich complexes

scientific article published on 01 January 2014

Bridging π-coordination of pyrrole and indole over a Pd(I)-Pd(I) bond

scientific article published on 20 December 2012

Catalytic Transformation of Aldehydes with Nickel Complexes through η(2) Coordination and Oxidative Cyclization

scientific article published on 08 May 2015

Cleavage of C(sp3)-F Bonds in Trifluoromethylarenes Using a Bis(NHC)nickel(0) Complex

scientific article published on 28 October 2020

Copolymerisation of ethylene with polar monomers by using palladium catalysts bearing an N-heterocyclic carbene-phosphine oxide bidentate ligand.

scientific article published on 14 February 2017

Copper-Catalyzed Reaction of Trifluoromethylketones with Aldehydes via a Copper Difluoroenolate.

scientific article published on 30 October 2015

Copper-Catalyzed Regioselective Monodefluoroborylation of Polyfluoroalkenes en Route to Diverse Fluoroalkenes.

scientific article

Dimerization of terminal alkynes catalyzed by a nickel complex having a bulky phosphine ligand.

scientific article published on 8 October 2004

Direct Transformation of Tetrafluoroethylene to Trifluorovinylzinc via sp2 C-F Bond Activation

scientific article published on 29 September 2020

Direct observation of oxidative cyclization of eta2-alkene and eta2-aldehyde on Ni(0) center. Significant acceleration by addition of Me3SiOTf.

scientific article published in September 2004

Efficient Synthesis of Polycyclic γ-Lactams by Catalytic Carbonylation of Ene-Imines via Nickelacycle Intermediates

scientific article published on 12 June 2017

Enantioselective Synthesis of Polycyclic γ-Lactams with Multiple Chiral Carbon Centers via Ni(0)-Catalyzed Asymmetric Carbonylative Cycloadditions without Stirring

scientific article published on 08 January 2020

Fluorinated Vinylsilanes from the Copper-Catalyzed Defluorosilylation of Fluoroalkene Feedstocks

scientific article

Formation of an aza-nickelacycle by reaction of an imine and an alkyne with nickel(0): oxidative cyclization, insertion, and reductive elimination.

scientific article published in January 2007

Formation of nickeladihydropyran by oxidative addition of cyclopropyl ketone. Key intermediate in nickel-catalyzed cycloaddition.

scientific article published in April 2006

Highly efficient activation of organosilanes with η2-aldehyde nickel complexes: key for catalytic syntheses of aryl-, vinyl-, and alkynyl-benzoxasiloles

scientific article

Hydrofluoroarylation of alkynes with fluoroarenes

scientific article published on 12 October 2010

Intramolecular arylcyanation of alkenes catalyzed by nickel/AlMe2Cl

scientific article published on 06 September 2008

Kinetic and Theoretical Studies on Ni0 /N-Heterocyclic Carbene-Catalyzed Intramolecular Alkene Hydroacylation.

scientific article published on 17 October 2016

Main-Group-Catalyzed Reductive Alkylation of Multiply Substituted Amines with Aldehydes Using H2

scientific article published on 05 June 2018

N-Phosphine Oxide-Substituted Imidazolylidenes (PoxIms): Multifunctional Multipurpose Carbenes.

scientific article published on 10 September 2017

New Direction in Organopalladium Chemistry: Structure and Reactivity of Unsaturated Hydrocarbon Ligands Bound to Multipalladium Units ⬇️

scientific article published on January 1, 2003

Ni(0)-Catalyzed Three-Component Coupling Reaction of Tetrafluoroethylene and N-Sulfonyl-Substituted Imines with Silanes via Aza-Nickelacycles

scientific article published on 24 December 2018

Ni(0)-catalyzed formation of azaaluminacyclopentenes via azanickelacyclopentenes: a unique nickel/aluminum double transmetalation reaction

scientific article published on 01 July 2009

Ni-catalyzed [4+3+2] cycloaddition of ethyl cyclopropylideneacetate and dienynes: scope and mechanistic insights

scientific article published on 25 January 2013

Nickel(0)-Catalyzed Enantio- and Diastereoselective Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process

scientific article published on 24 August 2015

Nickel(0)-Mediated Transformation of Tetrafluoroethylene and Vinylarenes into Fluorinated Cyclobutyl Compounds

scientific article published on 23 January 2017

Nickel(0)-catalyzed [2 + 2 + 1] carbonylative cycloaddition of imines and alkynes or norbornene leading to γ-lactams.

scientific article published on 4 November 2014

Nickel(0)-catalyzed intramolecular reductive coupling of alkenes and aldehydes or ketones with hydrosilanes

scientific article published on 14 April 2016

Nickel(0)/N-Heterocyclic Carbene-Catalyzed Asymmetric [2 + 2 + 2] Cycloaddition of Two Enones and an Alkyne: Access to Cyclohexenes with Four Contiguous Stereogenic Centers

scientific article published on 30 November 2015

Nickel-Catalyzed Formation of 1,3-Dienes via a Highly Selective Cross-Tetramerization of Tetrafluoroethylene, Styrenes, Alkynes, and Ethylene

scientific article

Nickel-Catalyzed Formation of Fluorine-Containing Ketones via the Selective Cross-Trimerization Reaction of Tetrafluoroethylene, Ethylene, and Aldehydes

scientific article published on 14 May 2015

Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex

scientific article published on 25 March 2010

Nickel-catalyzed [2 + 2 + 2] cycloaddition of two enones and an alkyne

scientific article published on 01 August 2010

Nickel-catalyzed decarbonylation of N-acylated N-heteroarenes

scientific article published on 29 May 2019

Nickel-catalyzed direct conjugate addition of simple alkenes to enones

scientific article published on 01 August 2009

Nickel-catalyzed selective conversion of two different aldehydes to cross-coupled esters

scientific article published on 15 March 2011

Nickel-catalyzed synthesis of N-aryl-1,2-dihydropyridines by [2+2+2] cycloaddition of imines with alkynes through T-shaped 14-electron aza-nickelacycle key intermediates

scientific article published on 27 February 2014

Nickel/Lewis acid-catalyzed cyanoesterification and cyanocarbamoylation of alkynes.

scientific article published on July 2010

Palladium-catalyzed coupling reaction of perfluoroarenes with diarylzinc compounds

scientific article published on 15 January 2014

Palladium-catalyzed coupling reactions of tetrafluoroethylene with arylzinc compounds

scientific article published on 15 February 2011

Palladium/Me(3)SiOTf-catalyzed bis-silylation of alpha,beta-unsaturated carbonyl compounds without involving oxidative addition of disilane

scientific article published on 01 October 2002

Pentacoordinated carboxylate π-allyl nickel complexes as key intermediates for the Ni-catalyzed direct amination of allylic alcohols

scientific article published on 26 August 2015

Regioselective C-F bond activation of hexafluoropropylene on palladium(0): formation of a cationic η(2) -perfluoroallylpalladium complex

scientific article published on 07 October 2014

Selective Catalytic Formation of Cross-Tetramers from Tetrafluoroethylene, Ethylene, Alkynes, and Aldehydes via Nickelacycles as Key Reaction Intermediates

scientific article published on 10 December 2018

Strain-Induced Double Carbon-Carbon Bond Activations of Cycloparaphenylenes by a Platinum Complex: Application to the Synthesis of Cyclic Diketones

scientific article published on 31 July 2018

Strategic Utilization of Multifunctional Carbene for Direct Synthesis of Carboxylic-Phosphinic Mixed Anhydride from CO2.

scientific article published on 28 November 2016

Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroethylene

scientific article published on 6 June 2017

Synthesis and reactivity of six-membered oxa-nickelacycles: a ring-opening reaction of cyclopropyl ketones.

scientific article published in October 2009

Synthesis of cyclobutenes and allenes by cobalt-catalyzed cross-dimerization of simple alkenes with 1,3-enynes

scientific article published on 29 April 2014

Synthesis, characterization, and unique catalytic activities of a fluorinated nickel enolate

scientific article published on 26 February 2015

Transition-Metal-Free Catalytic Hydrodefluorination of Polyfluoroarenes by Concerted Nucleophilic Aromatic Substitution with a Hydrosilicate.

scientific article published on 26 October 2017

Two-step synthesis of chiral fused tricyclic scaffolds from phenols via desymmetrization on nickel.

scientific article published on 26 June 2017

List of works by Sensuke Ogoshi

A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes.

Axial Chirality around N-P Bonds Induced by Complexation between E(C6F5)3 (E = B, Al) and an N-Phosphine Oxide-Substituted Imidazolinylidene: A Key Intermediate in the Catalytic Phosphinoylation of CO2

Aza-nickelacycle key intermediate in nickel(0)-catalyzed transformation reactions

Bis-cyclooctatetraene tripalladium sandwich complexes

Bridging π-coordination of pyrrole and indole over a Pd(I)-Pd(I) bond

Catalytic Transformation of Aldehydes with Nickel Complexes through η(2) Coordination and Oxidative Cyclization

Cleavage of C(sp3)-F Bonds in Trifluoromethylarenes Using a Bis(NHC)nickel(0) Complex

Copolymerisation of ethylene with polar monomers by using palladium catalysts bearing an N-heterocyclic carbene-phosphine oxide bidentate ligand.

Copper-Catalyzed Reaction of Trifluoromethylketones with Aldehydes via a Copper Difluoroenolate.

Copper-Catalyzed Regioselective Monodefluoroborylation of Polyfluoroalkenes en Route to Diverse Fluoroalkenes.

Dimerization of terminal alkynes catalyzed by a nickel complex having a bulky phosphine ligand.

Direct Transformation of Tetrafluoroethylene to Trifluorovinylzinc via sp2 C-F Bond Activation

Direct observation of oxidative cyclization of eta2-alkene and eta2-aldehyde on Ni(0) center. Significant acceleration by addition of Me3SiOTf.

Efficient Synthesis of Polycyclic γ-Lactams by Catalytic Carbonylation of Ene-Imines via Nickelacycle Intermediates

Enantioselective Synthesis of Polycyclic γ-Lactams with Multiple Chiral Carbon Centers via Ni(0)-Catalyzed Asymmetric Carbonylative Cycloadditions without Stirring

Fluorinated Vinylsilanes from the Copper-Catalyzed Defluorosilylation of Fluoroalkene Feedstocks

Formation of an aza-nickelacycle by reaction of an imine and an alkyne with nickel(0): oxidative cyclization, insertion, and reductive elimination.

Formation of nickeladihydropyran by oxidative addition of cyclopropyl ketone. Key intermediate in nickel-catalyzed cycloaddition.

Highly efficient activation of organosilanes with η2-aldehyde nickel complexes: key for catalytic syntheses of aryl-, vinyl-, and alkynyl-benzoxasiloles

Hydrofluoroarylation of alkynes with fluoroarenes

Intramolecular arylcyanation of alkenes catalyzed by nickel/AlMe2Cl

Kinetic and Theoretical Studies on Ni0 /N-Heterocyclic Carbene-Catalyzed Intramolecular Alkene Hydroacylation.

Main-Group-Catalyzed Reductive Alkylation of Multiply Substituted Amines with Aldehydes Using H2

N-Phosphine Oxide-Substituted Imidazolylidenes (PoxIms): Multifunctional Multipurpose Carbenes.

New Direction in Organopalladium Chemistry: Structure and Reactivity of Unsaturated Hydrocarbon Ligands Bound to Multipalladium Units ⬇️

Ni(0)-Catalyzed Three-Component Coupling Reaction of Tetrafluoroethylene and N-Sulfonyl-Substituted Imines with Silanes via Aza-Nickelacycles

Ni(0)-catalyzed formation of azaaluminacyclopentenes via azanickelacyclopentenes: a unique nickel/aluminum double transmetalation reaction

Ni-catalyzed [4+3+2] cycloaddition of ethyl cyclopropylideneacetate and dienynes: scope and mechanistic insights

Nickel(0)-Catalyzed Enantio- and Diastereoselective Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process

Nickel(0)-Mediated Transformation of Tetrafluoroethylene and Vinylarenes into Fluorinated Cyclobutyl Compounds

Nickel(0)-catalyzed [2 + 2 + 1] carbonylative cycloaddition of imines and alkynes or norbornene leading to γ-lactams.

Nickel(0)-catalyzed intramolecular reductive coupling of alkenes and aldehydes or ketones with hydrosilanes

Nickel(0)/N-Heterocyclic Carbene-Catalyzed Asymmetric [2 + 2 + 2] Cycloaddition of Two Enones and an Alkyne: Access to Cyclohexenes with Four Contiguous Stereogenic Centers

Nickel-Catalyzed Formation of 1,3-Dienes via a Highly Selective Cross-Tetramerization of Tetrafluoroethylene, Styrenes, Alkynes, and Ethylene

Nickel-Catalyzed Formation of Fluorine-Containing Ketones via the Selective Cross-Trimerization Reaction of Tetrafluoroethylene, Ethylene, and Aldehydes

Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex

Nickel-catalyzed [2 + 2 + 2] cycloaddition of two enones and an alkyne

Nickel-catalyzed decarbonylation of N-acylated N-heteroarenes

Nickel-catalyzed direct conjugate addition of simple alkenes to enones

Nickel-catalyzed selective conversion of two different aldehydes to cross-coupled esters

Nickel-catalyzed synthesis of N-aryl-1,2-dihydropyridines by [2+2+2] cycloaddition of imines with alkynes through T-shaped 14-electron aza-nickelacycle key intermediates

Nickel/Lewis acid-catalyzed cyanoesterification and cyanocarbamoylation of alkynes.

Palladium-catalyzed coupling reaction of perfluoroarenes with diarylzinc compounds

Palladium-catalyzed coupling reactions of tetrafluoroethylene with arylzinc compounds

Palladium/Me(3)SiOTf-catalyzed bis-silylation of alpha,beta-unsaturated carbonyl compounds without involving oxidative addition of disilane

Pentacoordinated carboxylate π-allyl nickel complexes as key intermediates for the Ni-catalyzed direct amination of allylic alcohols

Regioselective C-F bond activation of hexafluoropropylene on palladium(0): formation of a cationic η(2) -perfluoroallylpalladium complex

Selective Catalytic Formation of Cross-Tetramers from Tetrafluoroethylene, Ethylene, Alkynes, and Aldehydes via Nickelacycles as Key Reaction Intermediates

Strain-Induced Double Carbon-Carbon Bond Activations of Cycloparaphenylenes by a Platinum Complex: Application to the Synthesis of Cyclic Diketones

Strategic Utilization of Multifunctional Carbene for Direct Synthesis of Carboxylic-Phosphinic Mixed Anhydride from CO2.

Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroethylene

Synthesis and reactivity of six-membered oxa-nickelacycles: a ring-opening reaction of cyclopropyl ketones.

Synthesis of cyclobutenes and allenes by cobalt-catalyzed cross-dimerization of simple alkenes with 1,3-enynes

Synthesis, characterization, and unique catalytic activities of a fluorinated nickel enolate

Transition-Metal-Free Catalytic Hydrodefluorination of Polyfluoroarenes by Concerted Nucleophilic Aromatic Substitution with a Hydrosilicate.

Two-step synthesis of chiral fused tricyclic scaffolds from phenols via desymmetrization on nickel.