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List of works by Maria Schlangen

"Roll-over" cyclometalation of 2,2'-bipyridine platinum(II) complexes in the gas phase: a combined experimental and computational study

scientific article

"Stripping" the carbon atom of methyl halide by a cationic holmium complex: a gas-phase study.

scientific article published on 25 August 2015

A computational study on the intriguing mechanisms of the gas-phase thermal activation of methane by bare [Ni(H)(OH)]+

scientific article published on 03 February 2012

A redox non-innocent ligand controls the life time of a reactive quartet excited state - an MCSCF study of [Ni(H)(OH)](+)

scientific article published on 01 September 2009

Activation of Methane and Carbon Dioxide Mediated by Transition-Metal Doped Magnesium Oxide Clusters [MMgO](+/0/-) (M=Sc-Zn).

scientific article published on 13 April 2015

Bond Activation by Metal-Carbene Complexes in the Gas Phase.

scientific article published on 12 February 2016

Breaking and Making of Carbon-Carbon Bonds by Lanthanides and Third-Row Transition Metals.

scientific article published on 27 January 2016

C-N coupling in the gas-phase reactions of ammonia and [M(CH)]+ (M = Ni, Pd, Pt): a combined experimental/computational exercise

scientific article

Carbon-Atom Extrusion from Halobenzenes and Its Coupling with a Methylene Ligand to Form Acetylene.

scientific article published on 3 June 2015

Catalytic redox reactions in the CO/N2O system mediated by the bimetallic oxide-cluster couple AlVO3+/AlVO4+.

scientific article published on 27 September 2011

Control of Product Distribution and Mechanism by Ligation and Electric Field in the Thermal Activation of Methane

scientific article

Conversion of methane to methanol: nickel, palladium, and platinum (d9) cations as catalysts for the oxidation of methane by ozone at room temperature

scientific article published on 08 September 2010

Correction to Effect of Adduct Formation with Molecular Nitrogen on the Measured Collisional Cross Sections of Transition Metal-1,10- Phenanthroline Complexes in Traveling Wave Ion-Mobility Spectrometry: N2 Is Not Always an "Inert" Buffer Gas.

scientific article published on 28 October 2015

CN and CC Bond Formations in the Thermal Reactions of “Bare” Ni(NH2)+with C2H4: Mechanistic Insight on the Metal‐Mediated Hydroamination of an Unactivated Olefin ⬇️

scientific article published on February 10, 2012

Diatomic [CuO]+ and Its Role in the Spin-Selective Hydrogen- and Oxygen-Atom Transfers in the Thermal Activation of Methane

scientific article published on 21 April 2011

Differences and Commonalities in the Gas-Phase Reactions of Closed-Shell Metal Dioxide Clusters [MO2 ](+) (M=V, Nb, and Ta) with Methane.

scientific article

Direct Identification of Acetaldehyde Formation and Characterization of the Active Site in the [VPO4 ].+ /C2 H4 Couple by Gas-Phase Vibrational Spectroscopy

scientific article published on 08 November 2019

Direct Room-temperature Conversion of Methane to Protonated Formaldehyde: the Unique Gas-Phase Chemistry of Mercury Among the Zinc Triad Oxide Cations.

scientific article published on 24 January 2018

Direct conversion of methane into formaldehyde mediated by [Al2O3]˙+ at room temperature

Directed, remote gas-phase C-H and C-C bond activations by metal oxide cations anchored to a nitrile group.

scientific article published on 5 January 2011

Distinct mechanistic differences in the hydrogen-atom transfer from methane and water by the heteronuclear oxide cluster [Ga2 MgO4](.).

scientific article published on 01 July 2015

Effect of adduct formation with molecular nitrogen on the measured collisional cross sections of transition metal-1,10-phenanthroline complexes in traveling wave ion-mobility spectrometry: N2 is not always an "inert" buffer gas.

scientific article published on 17 September 2015

Efficient Room-Temperature Activation of Methane by TaN(+) under C-N Coupling.

scientific article published on 11 August 2016

Efficient Room-Temperature Methane Activation by the Closed-Shell, Metal-Free Cluster [OSiOH](+) : A Novel Mechanistic Variant.

scientific article published on 12 August 2016

Efficient Room-Temperature, Au(+)-Mediated Coupling of a Carbene Ligand with Methane To Generate C2Hx (x = 4, 6).

scientific article published on 18 November 2015

Efficient and Selective Gas‐Phase Monomethylation versus NH Bond Activation of Ammonia by “Bare” Zn(CH3)+: Atomic Zinc as a Leaving Group in an SN2 Reaction ⬇️

scientific article published on April 28, 2011

Electronic Origin of the Competitive Mechanisms in the Thermal Activation of Methane by the Heteronuclear Cluster Oxide [Al2 ZnO4 ].

scientific article published in June 2017

Electronic Origins of the Variable Efficiency of Room-Temperature Methane Activation by Homo- and Heteronuclear Cluster Oxide Cations [XYO2](+) (X, Y = Al, Si, Mg): Competition between Proton-Coupled Electron Transfer and Hydrogen-Atom Transfer.

scientific article published on 30 May 2016

Electrostatic and Charge-Induced Methane Activation by a Concerted Double C-H Bond Insertion.

scientific article

Facile dissociation of [(LNi(II))2E2] dichalcogenides: evidence for [LNi(II)E2] superselenides and supertellurides in solution.

scientific article published in January 2009

Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and NH-transfer to activated olefins

scientific article published on 8 March 2008

Gas-phase reactions of cationic vanadium-phosphorus oxide clusters with C2H(x) (x=4, 6): a DFT-based analysis of reactivity patterns.

scientific article published on 15 January 2013

Generation, reactivity towards hydrocarbons, and electronic structure of heteronuclear vanadium phosphorous oxygen cluster ions.

scientific article published on 5 January 2011

Hidden Hydride Transfer as a Decisive Mechanistic Step in the Reactions of the Unligated Gold Carbide [AuC](+) with Methane under Ambient Conditions.

scientific article published on 20 September 2016

Highly regioselective hydride transfer, oxidative dehydrogenation, and hydrogen-atom abstraction in the thermal gas-phase chemistry of [Zn(OH)](+)/C3H8

scientific article published on 01 December 2014

Intermediates of N-Heterocyclic Carbene (NHC) Dimerization Probed in the Gas Phase by Ion Mobility Mass Spectrometry: C-H⋅⋅⋅:C Hydrogen Bonding Versus Covalent Dimer Formation

scientific article published on 17 January 2019

Isomer-selective thermal activation of methane in the gas phase by [HMO]+ and [M(OH)]+ (M=Ti and V)

scientific article published on 25 April 2013

Ligand and electronic-structure effects in metal-mediated gas-phase activation of methane: a cold approach to a hot problem

scientific article published on 05 October 2009

Ligand and substrate effects in gas-phase reactions of NiX(+)/RH couples (X=F, Cl, Br, I; R=CH3, C2H5, nC3H7, nC4H9).

scientific article

Ligand-Controlled CO2 Activation Mediated by Cationic Titanium Hydride Complexes, [LTiH](+) (L=Cp2 , O)

scientific article published on 04 May 2015

Mechanistic Aspects of the Holmium-Mediated, Reciprocal Hydrogen/Sulfur Exchange in the Gas Phase: C6 H5 CH3 +CH2 S→C6 H5 CHS+CH4.

scientific article published on 20 January 2016

Mechanistic Variants in Gas-Phase Metal-Oxide Mediated Activation of Methane at Ambient Conditions.

scientific article published on 12 August 2016

Mechanistic aspects and elementary steps of N-H bond activation of ammonia and C-N coupling induced by gas-phase ions: a combined experimental/computational exercise.

scientific article published on 05 December 2011

Mechanistic aspects of gas-phase hydrogen-atom transfer from methane to [CO](·+) and [SiO](·+) : why do they differ?

scientific article published on 27 March 2013

Mechanistic aspects of the gas-phase coupling of thioanisole and chlorobenzene to dibenzothiophene catalyzed by atomic Ho(+).

scientific article published on 13 March 2015

Mechanistic aspects of the gas-phase reactions of halobenzenes with bare lanthanide cations: a combined experimental/theoretical investigation.

scientific article published on 29 December 2014

Metal-Dependent Strengthening and Weakening of M-H and M-C Bonds by an Oxo Ligand: Thermal Gas-Phase Activation of Methane by [OMH]+ and [MH]+ (M=Mo, Ti).

scientific article published on 26 May 2017

Metal-Free, Room-Temperature Oxygen-Atom Transfer in the N2 O/CO Redox Couple as Catalyzed by [Si2 Ox ].+ (x=2-5).

scientific article published on 16 June 2017

Metal-dependent alternative activation of O-H and C-H bonds of methanol: on the formation and structure of "bare" [M,C,H3,O]+ complexes (M = Fe, Co, Ni) in the gas phase.

scientific article published on 14 January 2010

O-O Bond Formation and Liberation of Dioxygen Mediated by N5 -Coordinate Non-Heme Iron(IV) Complexes

scientific article published on 13 August 2019

On the Activation of Methane and Carbon Dioxide by [HTaO](+) and [TaOH](+) in the Gas Phase: A Mechanistic Study.

scientific article published on 29 June 2016

On the Electronic Origin of Remarkable Ligand Effects on the Reactivities of [NiL]+ Complexes (L=C6 H5 , C5 H4 N, CN) towards Methane.

scientific article published in September 2017

On the Mechanisms of Hydrogen-Atom Transfer from Water to the Heteronuclear Oxide Cluster [Ga2 Mg2 O5 ](.+) : Remarkable Electronic Structure Effects.

scientific article published on 14 August 2015

On the Origin of Reactivity Enhancement/Suppression upon Sequential Ligation: [Re(CO)x ]+ /CH4 (x=0-3) Couples.

scientific article

On the Origin of the Distinctly Different Reactivity of Ruthenium in [MO]+ /CH4 Systems (M=Fe, Ru, Os).

scientific article published on 8 March 2018

On the Origin of the Remarkably Variable Reactivities of [AlCeOx ]+ (x=2-4) towards Methane as a Function of Oxygen Content.

scientific article published on 2 December 2016

On the Remarkable Role of the Nitrogen Ligand in the Gas-Phase Redox Reaction of the N2 O/CO Couple Catalyzed by [NbN]

scientific article published on 04 February 2019

On the mechanisms of degenerate ligand exchange in [M(CH(3))](+)/CH(4) Couples (M=Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt) as explored by mass spectrometric and computational studies: oxidative addition/reductive elimination versus sigma-complex-assisted

scientific article published in January 2008

On the origin of the surprisingly sluggish redox reaction of the N2O/CO couple mediated by [Y2O2]+˙ and [YAlO2]+˙ cluster ions in the gas phase

scientific article (publication date: 21 January 2013)

On the role of the electronic structure of the heteronuclear oxide cluster [Ga2Mg2O5 ](.+) in the thermal activation of methane and ethane: an unusual doping effect.

scientific article published on 27 February 2015

Oriented external electric fields as mimics for probing the role of metal ions and ligands in the thermal gas-phase activation of methane

scientific article published on 10 September 2018

Penetrating the Elusive Mechanism of Copper-Mediated Fluoromethylation in the Presence of Oxygen through the Gas-Phase Reactivity of Well-Defined [LCuO](+) Complexes with Fluoromethanes (CH(4-n)Fn, n = 1-3).

scientific article published on 9 February 2016

Pronounced ligand effects and the role of formal oxidation states in the nickel-mediated thermal activation of methane.

scientific article published in January 2007

Selective C-O Coupling Hidden in the Thermal Reaction of [Al2 CuO5 ]+ with Methane

scientific article published on 06 September 2018

Selective Nitrogen-Atom Transfer Driven by a Highly Efficient Intersystem Crossing in the [CeON]+/CH₄ System

scientific article published on 05 November 2018

Sequential Gas-Phase Activation of Carbon Dioxide and Methane by [Re(CO)2]+: The Sequence of Events Matters!

scientific article published on 12 April 2017

Single and double N-H bond activation of ammonia by [Al2O3 ]˙+: room temperature formation of the aminyl radical and nitrene.

scientific article published on 15 May 2013

Spin-Selective Thermal Activation of Methane by Closed-Shell [TaO3 ](.).

scientific article published on 9 May 2016

Spin-Selective, Competitive Hydrogen-Atom Transfer versus CH2 O-Generation from the CH4 /[ReO4 ]+ Couple at Ambient Conditions

scientific article published on 2 November 2017

Striking Doping Effects on Thermal Methane Activation Mediated by the Heteronuclear Metal Oxides [XAlO4 ].+ (X=V, Nb, and Ta).

scientific article published on 24 November 2016

Structure and chemistry of the heteronuclear oxo-cluster [VPO4]•+: a model system for the gas-phase oxidation of small hydrocarbons.

scientific article published on 22 February 2013

Structure of the oxygen-rich cluster cation Al2O7+ and its reactivity toward methane and water

scientific article published on 30 September 2011

The Electric Field as a "Smart" Ligand in Controlling the Thermal Activation of Methane and Molecular Hydrogen

scientific article published on 13 July 2018

The Origin of the Efficient, Thermal Chemisorption of Methane by the Heteronuclear Metal-Oxide Cluster [Al2 TaO5 ]().

scientific article published on 24 October 2016

The Unique Gas-Phase Chemistry of the [AuO](+) /CH4 Couple: Selective Oxygen-Atom Transfer to, Rather than Hydrogen-Atom Abstraction from, Methane.

scientific article published on 8 July 2016

Thermal Activation of Ammonia by Transition-Metal Hydroxide Cations

scientific article published on 24 July 2013

Thermal Activation of Ammonia by Transition-Metal Hydroxide Cations

scientific article published on 19 June 2013

Thermal Activation of CH4 and H2 as Mediated by the Ruthenium Oxide Cluster Ions [RuOx ]+ (x=1-3): On the Influence of Oxidation States

scientific article published on 21 February 2019

Thermal Activation of Methane by [HfO](.+) and [XHfO](+) (X=F, Cl, Br, I) and the Origin of a Remarkable Ligand Effect.

scientific article published on 18 April 2016

Thermal Dehydrogenation of Methane by [ReN]().

scientific article published on 11 October 2016

Thermal Methane Activation by [Si2 O5 ](.+) and [Si2 O5 H2 ](.+) : Reactivity Enhancement by Hydrogenation.

scientific article published on 21 September 2016

Thermal Methane Activation by the Metal-Free Cluster Cation [Si2 O4 ].

scientific article published on 12 December 2016

Thermal activation of N-H bonds by transition-metal oxide cations: does a hierarchy exist in the first row?

scientific article published on 2 March 2011

Thermal activation of methane and ethene by bare MO·+ (M=Ge, Sn, and Pb): a combined theoretical/experimental study

scientific article published on 04 August 2011

Thermal activation of methane by group 10 metal hydrides MH+: the same and not the same.

scientific article published in January 2007

Thermal ammonia activation by cationic transition-metal hydrides of the first row--small but mighty.

scientific article published on 7 March 2012

Thermal ethane activation by bare [V₂O₅]⁺ and [Nb₂O₅]⁺ cluster cations: on the origin of their different reactivities.

scientific article published on 23 April 2014

Thermal hydrogen-atom transfer from methane: the role of radicals and spin states in oxo-cluster chemistry.

scientific article published on 16 March 2012

Thermal methane activation by a binary V-Nb transition-metal oxide cluster cation: a further example for the crucial role of oxygen-centered radicals.

scientific article published on 9 August 2013

Thermal reactions of YAlO3+˙ with methane: increasing the reactivity of Y2O3+˙ and the selectivity of Al2O3+˙ by doping.

scientific article published on 4 May 2012

Tuning the Reactivities of the Heteronuclear [Aln V3-n O7-n ]+ (n=1, 2) Cluster Oxides towards Methane by Varying the Composition of the Metal Centers

scientific article published on 07 February 2019

Unravelling Mechanistic Aspects of the Gas-Phase Ethanol Conversion: An Experimental and Computational Study on the Thermal Reactions of MO2 (+) (M=Mo, W) with Ethanol.

scientific article published on 2 February 2016

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