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List of works by Axel Schulz

"Tamed" silylium ions: versatile in catalysis

scientific article published on 15 March 2012

1,3-Diphenyl-2,2,2,4,4,4-hexazido-1,3-diaza-2,4-diphosphetidine: synthesis and structural characterisation of the first nitrogen-penta-coordinated phosphorus with three azide-groups

1,4-Bis-[1-Methyltetrazol-5-yl]-1,4-Dimethyl-2-Tetrazene: A Stable, Highly Energetic Hexamer of Diazomethane (CH2N2)6

1,5-diamino-4-methyltetrazolium dinitramide

scientific article published in February 2005

3,5-Dimethyl-1,3,5-oxadiazane-2,4,6-trione: short intermolecular contacts determining the crystal packing

scientific article published on 10 August 2005

A Dimer of Hydrogen Cyanide Stabilized by a Lewis Acid

scientific article published on 19 June 2018

A Systematic Survey of the Reactivity of Chlorinated N2 P2 , NP3 and P4 Ring Systems

scientific article published on 22 November 2019

A Theoretical and Experimental Study on the Lewis Acid−Base Adducts (P4E3)·(BX3) (E = S, Se; X = Br, I) and (P4Se3)·(NbCl5)

scientific article published on 01 September 2001

A Triazadiphosphole

scientific article published on 2 December 2005

A Tricyclic Hexaphosphane

scientific article published on 05 November 2015

A blue homoleptic bismuth-nitrogen cation.

scientific article published in January 2008

A cationic cyclic phosphorus(III) azide

scientific article published on 01 January 2008

A chemical reaction controlled by light-activated molecular switches based on hetero-cyclopentanediyls

scientific article published on 18 February 2019

A mixed arsenic-phosphorus centered biradicaloid

scientific article published on 17 November 2014

A neutral low-coordinate heterocyclic bismuth-tin species.

scientific article

A new class of azadipnictiridines generated by an unusual rearrangement reaction

scientific article

Accessing heavy allyl-analogous [(TerN)2E](-) (E = Sb, Bi) ions and their reactivity towards ECl3

scientific article published on 01 July 2015

Activation of small molecules by phosphorus biradicaloids

scientific article published on 29 September 2014

An arsenic-nitrogen biradicaloid: synthesis, properties, and reactivity

scientific article published on 14 January 2013

An unusual isomerization to tetraazastiboles

scientific article published on 21 April 2011

An unusual reaction: a GaCl3-assisted methyl/chlorine exchange in silylated hydrazinodichloroarsane

scientific article published on 29 August 2007

Arsa-diazonium salts with an arsenic-nitrogen triple bond.

scientific article published on 5 June 2013

Arsenic-Mediated C-C Coupling of Cyanides Leading to Cyanido Arsazolide [AsC4 N4 ].

scientific article

Aza-diphospha-indane-1,3-diyls: A class of resonance-stabilized biradicals

scientific article published on 10 October 2020

Azidophosphenium cations: versatile reagents in inorganic synthesis

scientific article published on 21 March 2014

Azidotris(trifluoromethyl)germane, (CF(3))(3)GeN(3): Spectroscopic Characterization and Density Functional Computations.

scientific article published in August 1996

Binary Polyazides of Cerium and Gadolinium

Binary Zinc Azides.

scientific article published on 8 January 2016

Binary bismuth(III) azides: Bi(N3)3, [Bi(N3)4]-, and [Bi(N3)6]3-

scientific article published on 01 October 2010

Binary pnictogen azides--an experimental and theoretical study: [As(N3)4]-, [Sb(N3)4]-, and [Bi(N3)5(dmso)]2-

scientific article published on 15 February 2012

Binary polyazides of cadmium and mercury.

scientific article

Bissilylated halonium ions: [Me3Si-X-SiMe3][B(C6F5)4] (X = F, Cl, Br, I)

scientific article published on 01 January 2009

Blue alkali dinitrosomethanides: synthesis, structure, and bonding

scientific article published in February 2005

Borane Adducts of Hydrazoic Acid and Organic Azides: Intermediates for the Formation of Aminoboranes

scientific article published on 04 April 2019

Catalytic trimerization of bis-silylated diazomethane

scientific article published on 10 October 2012

Chlorine/methyl exchange reactions in silylated aminostibanes: a new route to stibinostibonium cations

scientific article published on 10 July 2012

Contributions of Erhard Kurras to Organochromium Chemistry – From a Historical Perspective

scientific article

Correction: Increasing steric demand through flexible bulk - primary phosphanes with 2,6-bis(benzhydryl)phenyl backbones

scientific article published on 01 July 2019

Cyanido Antimonate(III) and Bismuthate(III) Anions.

scientific article

Cyanidosilicates-Synthesis and Structure

scientific article published on 15 March 2019

Cyano-, Nitro- and Nitrosomethane Derivatives: Structures and Gas-Phase Acidities

article

Cyclic Group 15 Radical Cations.

scientific article published on 8 May 2015

Cyclic arsenic-nitrogen cations.

scientific article published in August 2009

Cyclic distiba- and dibismadiazenium cations

scientific article published on 05 July 2012

Cyclo-pnicta-triazanes: biradicaloids or zwitterions?

scientific article published on 16 March 2015

Dichloro-Cycloazatriphosphane: The Missing Link between N2 P2 and P4 Ring Systems in the Systematic Development of NP Chemistry

scientific article published on 12 September 2017

Dichlorocyclodibismadiazane

scientific article published on 01 October 2010

Dimeric (tris(tert-butyl)silyl)phosphanyl (tris(tert-butyl)silyl)phosphanediyl gallane: a molecule with a Ga-P-Ga heteroallyl system.

scientific article

Dimers and trimers of diphosphenes: a wealth of cyclo-phosphanes

scientific article published on 21 August 2014

Electronic effects in 12-metallacrown-3 complexes. A theoretical and experimental study

scientific article published in June 2003

GaCl3-assisted [2 + 3] cycloaddition: a route to tetrazaphospholes.

scientific article published on 9 February 2006

GaCl3-assisted cyclization reactions in hypersilyl(trimethylsilyl)aminodichlorophosphine

scientific article published on 20 September 2008

Group 15 biradicals: synthesis and reactivity of cyclobutane-1,3-diyl and cyclopentane-1,3-diyl analogues

scientific article published on 05 September 2018

HPCO-A Phosphorus-Containing Analogue of Isocyanic Acid.

scientific article published on 2 March 2017

Heavy Neutral and Anionic Pnictogen Thiocyanates

scientific article published on 28 March 2019

Hetero-Cyclopentanediyls vs. Hetero-Cyclopentadienes - A Question of Silyl Group Migration

scientific article published on 11 May 2020

Highly selective visible light-induced Ti-O bond splitting in an ansa-titanocene dihydroxido complex

scientific article published in February 2015

Hydroformylation of olefins over rhodium supported metal-organic framework catalysts of different structure

Hydrosilylation of ketones: from metal-organic frameworks to simple base catalysts

scientific article published on November 2010

Hypersilylated cyclodiphosphadiazanes and cyclodiphosphadiazenium salts.

scientific article published on 7 September 2009

Imidazolium-based ionic liquids. 1-methyl imidazolium nitrate: thermochemical measurements and ab initio calculations.

scientific article published in July 2009

Increasing steric demand through flexible bulk - primary phosphanes with 2,6-bis(benzhydryl)phenyl backbones

scientific article published on 01 March 2019

Influence of the textural properties of Rh/MOF-5 on the catalytic properties in the hydroformylation of olefins

Intriguing Gold TrifluorideMolecular Structure of Monomers and Dimers:  An Electron Diffraction and Quantum Chemical Study

scientific article published in April 2000

Ionic liquids containing the triply negatively charged tricyanomelaminate anion and a B(C6F5)3 adduct anion

scientific article published on 03 November 2011

Isolation of Labile Pseudohalogen NSO Species

scientific article published on 13 April 2016

Isolation of a labile homoleptic diazenium cation.

scientific article published on 14 February 2014

Lewis Acid Catalyzed Synthesis of Cyanidophosphates

scientific article published on 5 February 2016

Lewis acid assisted methyl/chlorine exchange in silylated hydrazinochlorophosphanes

scientific article published on 22 February 2011

Lewis-acid-assisted methyl exchange reactions in silylated aminodichloroarsanes

scientific article

Low temperature isolation of a dinuclear silver complex of the cyclotetraphosphane [ClP(μ-PMes*)]2

scientific article published on 01 January 2016

Low-Temperature Isolation of the Bicyclic Phosphinophosphonium Salt [Mes*2 P4 Cl][GaCl4 ]

scientific article published on 17 April 2015

Low-temperature isolation of an azidophosphenium cation

scientific article published on 04 May 2012

Mercury azides and the azide of Millon's base.

scientific article published on 26 August 2013

Metal-Free Activation of Hydrogen, Carbon Dioxide, and Ammonia by the Open-Shell Singlet Biradicaloid [P(μ-NTer)]2.

scientific article published in September 2016

Mg(I) Halide vs. Magnesium Metal: Differences in Reaction Energy and Reactivity Monitored in Reduction Processes of P-Cl Bonds

scientific article published on 27 November 2018

Molecular E(CN)3 (E=Sb, Bi) Species Synthesized from Ionic Liquids as Solvates.

scientific article published on 23 August 2016

Molecular relaxation processes in a MOF-5 structure revealed by broadband dielectric spectroscopy: signature of phenylene ring fluctuations

scientific article published on October 2010

Molecular vibration spectroscopy studies on novel trinuclear rhodium-7-hydride complexes of the general type {[Rh(PP*)X]3(μ(2-X)3(μ3-X)}(BF4)2 (X = H, D)

scientific article published on 21 June 2012

Mono-, di-, and tricoordinated phosphorus attached to a N-N unit: an experimental and theoretical study

scientific article

NSCl(2)(-): Thiazyl Dichloride-An Aza Analogue of Thionyl Dichloride A.S. thanks Prof. Dr. T. M. Klapötke (LMU München) for his generous support and Prof. Dr. R. D. Harcourt (Melbourne University) for many helpful discussions. We thank Prof. Dr. W.

scientific article published on 01 May 2001

New P-N cage compounds generated by small-molecule activation

scientific article published on 25 February 2014

Nitro(nitroso)cyanomethanides

scientific article published on 01 June 2005

Nitrosyl Azide, N4O, an Intrinsically Unstable Oxide of Nitrogen

scholarly article by Axel Schulz et al published November 1993 in Angewandte Chemie International Edition

Nonlinear, Resonance-Stabilized Pseudohalides: From Alkali Methanides to Ionic Liquids of Methanides

On Silylated Oxonium and Sulfonium Ions and Their Interaction with Weakly Coordinating Borate Anions

scientific article published on 24 January 2020

On the Staudinger Reaction of SP(N3)3 with PPh3 and(Me3Si)2N–(Me3Si)N–PPh2

On the behaviour of biradicaloid [P(μ-NTer)]2 towards Lewis acids and bases

scientific article published on 18 April 2016

On the synthesis and reactivity of highly labile pseudohalogen phosphenium ions

scientific article

P-P σ-bond activation by gold(I) coordination.

scientific article published in January 2015

Parahydrogen-induced polarization with a metal-free P-P biradicaloid

scientific article published on 01 March 2019

Preparation and Characterization of a Ligand-Stabilized Trimethylphosphane Dication

Preparation and characterization of [CF3SO3(SiMe3)2]+[B(C6F5)4]-

scientific article published on 14 April 2010

Preparation of N(SeCl)2+X–(X = SbCl6or FeCl4), F3CCSeNSeCCF3+SbCl6–, F3CCSeNSeCCF3, F3CCSeNSeCCF3and F3CCSeSeC(CF3)C(CF3)SeSeCCF3. Electron diffraction study of F3CCSeSeCCF3and crystal structure of the eight-membered heterocycle F3CCSeSeC(CF3)C(C

Pseudohalide HCN aggregate ions: [N3(HCN)3]-, [OCN(HCN)3]-, [SCN(HCN)2]- and [P(CN·HCN)2]-

scientific article published on 18 September 2020

Pseudohalonium ions: [Me3Si-X-SiMe3]+ (X=CN, OCN, SCN, and NNN).

scientific article published in June 2010

Reactions of group 4 metallocene alkyne complexes with carbodiimides: experimental and theoretical studies of the structure and bonding of five-membered hetero-metallacycloallenes

scientific article published on 17 March 2011

Reactions of titanocene bis(trimethylsilyl)acetylene complexes with carbodiimides: an experimental and theoretical study of complexation versus C-N bond activation

scientific article published on 18 September 2012

Reduction of dichloro(diaza-phospha)stibanes - isolation of a donor-stabilized distibenium dication

scientific article published on 24 August 2015

Reversible switching between housane and cyclopentanediyl isomers: an isonitrile-catalysed thermal reverse reaction

scientific article published on 01 September 2020

S2 N3+ : An Aromatic SN Cation with an N3 Unit

scientific article published on 01 September 2001

Salts and ionic liquids of resonance stabilized amides.

scientific article published in October 2009

Salts of HCN-Cyanide-Aggregates: [CN(HCN)n]- (n = 2 - 3)

scientific article published on 06 February 2020

Selective hydroformylation of olefins over the rhodium supported large porous metal–organic framework MIL-101

Silylium-arene adducts: an experimental and theoretical study.

scientific article published on 6 December 2011

Solid state structure of Bi(N3)3, Bi(N3)3·solvates and the structural dynamics in the [Bi(N3)6]3- anion

scientific article published on 09 May 2013

Stabilized transient R2PN species

scientific article published on 13 February 2013

Stable heterocyclopentane-1,3-diyls

scientific article published on 21 January 2015

Structure and bonding in silver halides. A quantum chemical study of the monomers: Ag(2)X, AgX, AgX(2), and AgX(3) (X = F, Cl, Br, I)

scientific article

Structure and bonding of novel acyclic bisaminoarsenium cations

scientific article published on 17 June 2013

Studies of the Reaction Behavior of Nitryl Compounds Towards Azides: Evidence for Tetranitrogen Dioxide, N4O2

article

Synthesis and Characterization of Silylated Phosphonium [P(OSiMe3)4]+ and Phosphate [O2P(OSiMe3)2]- Salts

scientific article published on 09 July 2018

Synthesis and Structure of Bismuth-Nitrogen Cage Compounds and Heterocubanes: [Cl-Bi(μ3-N-TMP)]4: A Dimer of a 1,3-Dichloro-cyclo-dibismadiazane

scientific article published on 17 January 2020

Synthesis and structure of monomeric, trimeric, and mixed phenylcyanamides.

scientific article

Synthesis of 1,3-dichloro-cyclo-1,3-diphosphadiazanes from silylated amino(dichloro)phosphanes

scientific article

Synthesis of Heavy Cyclodipnictadiphosphanes [ClE(μ-P-Ter)]2 [E = P, As, Sb, or Bi; Ter = 2,6-bis(2,4,6-trimethylphenyl)phenyl].

scientific article

Synthesis of Sterically Demanding Secondary Phosphides and Diphosphanes and Their Utilization in Small-Molecule Activation

scientific article published on 01 September 2020

Synthesis of a Molecule with Four Different Adjacent Pnictogens.

scientific article

Synthesis of blue imino(pentafluorophenyl)phosphane.

scientific article published on 25 May 2011

Synthesis of elusive chloropnictenium ions.

scientific article published on 17 March 2015

Synthesis of mono-, di-, and triaminobismuthanes and observation of C-C coupling of aromatic systems with bismuth(III) chloride

scientific article published on 25 February 2016

Synthesis of sterically encumbered 2,4-bis-m-terphenyl-1,3-dichloro-2,4-cyclo-dipnictadiazanes [m-TerNPnCl](2), (Pn = P, As).

scientific article published on 15 September 2010

Synthesis, Characterization, and Crystal Structure of 1,3-Dipentafluorophenyl-2,2,2,4,4,4-hexazido-1,3-diaza-2,4-diphosphetidine

Synthesis, structure, and bonding of weakly coordinating anions based on CN adducts.

scientific article published in July 2009

Synthesis, structure, and reactivity of diazene adducts: isolation of iso-diazene stabilized as a borane adduct.

scientific article published on 24 July 2014

Synthetic strategies to bicyclic tetraphosphanes using P1, P2 and P4 building blocks

scientific article published on 04 September 2015

Tetracyanido(difluorido)phosphates M(+) [PF2 (CN)4 ](.).

scientific article published on 20 February 2015

Tetrazarsoles--a new class of binary arsenic-nitrogen heterocycles

scientific article published on 01 January 2008

Tetrazastannoles versus distannadiazanes - a question of the tin(ii) source

scientific article published on 01 December 2018

The dianion of 5-cyanoiminotetrazoline: C2N62-.

scientific article published in August 2005

The elusive cyanoformate: an unusual cyanide shuttle.

scientific article published on 2 July 2014

The reactivity of silylated amino(dichloro)phosphanes in the presence of silver salts.

scientific article published on 21 February 2014

The software defined implantable modular platform (STELLA) for preclinical deep brain stimulation research in rodents

scientific article published on 20 September 2021

Theoretical Evidence for Two New Intermediate Xenon Species: Xenon Azide Fluoride, FXe(N(3)), and Xenon Isocyanate Fluoride, FXe(NCO)

scientific article published on 01 April 1997

Theoretical evidence of the stabilization of an unusual four-membered metallacycloallene by a transition-metal fragment

scientific article published on 23 April 2012

Trapping of Brønsted acids with a phosphorus-centered biradicaloid - synthesis of hydrogen pseudohalide addition products

scientific article published on 28 September 2020

Trapping of transient, heavy pnictogen-centred biradicals

scientific article published on 01 March 2018

Tunable Cyclopentane-1,3-diyls Generated by Insertion of Isonitriles into Diphosphadiazanediyls

scientific article

Vaporization and formation enthalpies of 1-alkyl-3-methylimidazolium tricyanomethanides.

scientific article published on 21 September 2011

Vibrational frequencies of the isoelectronic tetrahedral species GeF4 and AsF4+. Comparison of experimental data with results from ab initio and density functional theory

Zwitterionic and biradicaloid heteroatomic cyclopentane derivatives containing different group 15 elements.

scientific article published on 27 October 2015

[Cp2Ti(III)(NCy)2C-Ti(III)Cp2]: a transient titanocene carbene complex?

scientific article published on 01 November 2010

[E(μ-NBbp)]2 (E = P, As) - group 15 biradicals synthesized from acyclic precursors

scientific article published on 01 July 2019

[Me3SiN(PPh3)-ICN]: a new labile donor-acceptor complex.

scientific article

[P(μ-NTer)]2: a biradicaloid that is stable at high temperature

scientific article published on 19 August 2011

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