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List of works by Masahiro Murakami

1,5-Rhodium shift in rearrangement of N-arenesulfonylazetidin-3-ols into benzosultams

scientific article published on 13 December 2013

2-Arylsilacyclobutane as a Latent Carbanion Reacting with CO2

scientific article published on 01 August 2018

A Light/Ketone/Copper System for Carboxylation of Allylic C-H Bonds of Alkenes with CO2.

scientific article published on 21 March 2016

A Reaction of Triazoles with Thioesters to Produce β-Sulfanyl Enamides by Insertion of an Enamine Moiety into the Sulfur-Carbonyl Bond.

scientific article

A new look at boron enolate chemistry: aminative C-C bond formation using diaminoboron enolate with aldehyde.

scientific article published in April 2004

A syn-Selective Aza-Aldol Reaction of Boron Aza-Enolates Generated from N-Sulfonyl-1,2,3-Triazoles and 9-BBN-H

scientific article published on 03 June 2016

Achievements of the Late Professor Teruaki Mukaiyama

scientific article published on 11 December 2020

Acids direct 2-styrylcyclobutanone into two distinctly different reaction pathways

scientific article published on 01 May 2005

Acyl 1,3-migration in rhodium-catalyzed reactions of acetylenic beta-ketoesters with aryl boronic acids: application to two-carbon-atom ring expansions

scientific article published on 01 November 2005

Aminoboranes as "compatible" iminium ion generators in aminative C-C bond formations.

scientific article published in October 2004

Asymmetric Carroll rearrangement of allyl alpha-acetamido-beta-ketocarboxylates catalysed by a chiral palladium complex.

scientific article published on 7 July 2005

Asymmetric synthesis of 3,4-dihydrocoumarins by rhodium-catalyzed reaction of 3-(2-hydroxyphenyl)cyclobutanones

scientific article published on 18 September 2007

Asymmetric synthesis of planar chiral ferrocenes by enantioselective intramolecular C-H arylation of N-(2-haloaryl)ferrocenecarboxamides

scientific article published on 29 September 2014

Atom- and step-economical pathway to chiral benzobicyclo[2.2.2]octenones through carbon-carbon bond cleavage

scientific article published on 27 January 2012

Azulenophenanthrenes from 2,2'-di(arylethynyl)biphenyls through C-C bond cleavage of a benzene ring.

scientific article

Buttressing Salicylaldehydes: A Multipurpose Directing Group for C(sp3 )-H Bond Activation.

scientific article

C1 Oxidation/C2 Reduction Isomerization of Unprotected Aldoses Induced by Light/Ketone

scientific article published on 16 January 2020

Cleavage of C-C and C-Si σ-bonds and their intramolecular exchange.

scientific article published on 14 April 2014

Cleavage of Carbon-Carbon σ-Bonds of Four-Membered Rings

scientific article published on 23 September 2020

Construction of homoallylic alcohols from terminal alkynes and aldehydes with installation of syn-stereochemistry.

scientific article published on 22 April 2014

Construction of tetralin skeletons based on rhodium-catalysed site-selective ring opening of benzocyclobutenols

scientific article published in February 2015

Contrasteric stereochemical dictation of the cyclobutene ring-opening reaction by a vacant boron p orbital.

scientific article

Copper-catalyzed amination of silyl ketene acetals with N-chloroamines

scientific article published on 02 October 2012

Cyclization reaction of cyano-substituted unsaturated esters prompted by conjugate addition of organoborons

scientific article published on 07 February 2007

Diastereo- and Enantioselective Synthesis of (E)-δ-Boryl-Substituted anti-Homoallylic Alcohols in Two Steps from Terminal Alkynes

scientific article published on 29 August 2019

Direct production of enaminones from terminal alkynes via rhodium-catalyzed reaction of formamides with N-sulfonyl-1,2,3-triazoles

scientific article published on 28 April 2014

Dramatic effects of boryl substituents on thermal ring-closing reaction of vinylallenes.

scientific article published in September 2004

Eight-membered ring construction by [4 + 2 + 2] annulation involving beta-carbon elimination.

scientific article published in February 2006

Enantioface-selective palladium-catalyzed silaboration of allenes via double asymmetric induction.

scientific article published in September 2003

Enantioselective C-C bond cleavage creating chiral quaternary carbon centers.

scientific article

Enantioselective Construction of 3-Hydroxypiperidine Scaffolds by Sequential Action of Light and Rhodium upon N-Allylglyoxylamides

scientific article published on 07 May 2015

Enantioselective Denitrogenative Annulation of 1H-Tetrazoles with Styrenes Catalyzed by Rhodium.

scientific article published on 13 March 2018

Enantioselective Synthesis of (E)-δ-Boryl-Substituted anti-Homoallylic Alcohols Using Palladium and a Chiral Phosphoric Acid.

scientific article

Enantioselective Synthesis of anti-1,2-Oxaborinan-3-enes from Aldehydes and 1,1-Di(boryl)alk-3-enes Using Ruthenium and Chiral Phosphoric Acid Catalysts

scientific article published on 14 July 2017

Enantioselective [2 + 2 + 2] cycloaddition reaction of isocyanates and allenes catalyzed by nickel.

scientific article published on 14 September 2010

Enantioselective insertion of a carbenoid carbon into a C-C bond to expand cyclobutanols to cyclopentanols

scientific article published on 7 May 2014

Enantioselective synthesis of 3,4-dihydroisoquinolin-1(2H)-ones by nickel-catalyzed denitrogenative annulation of 1,2,3-benzotriazin-4(3H)-ones with allenes

scientific article published on 01 January 2010

Enantioselective synthesis of anti homoallylic alcohols from terminal alkynes and aldehydes based on concomitant use of a cationic iridium complex and a chiral phosphoric acid.

scientific article

Facile synthesis of 2,5-disubstituted thiazoles from terminal alkynes, sulfonyl azides, and thionoesters

scientific article published on 30 April 2015

Formation of carbocycles through sequential carborhodation triggered by addition of organoborons

scientific article published on 24 August 2006

Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes

scientific article published on 02 July 2011

Gold-catalysed intramolecular trans-allylsilylation of alkynes forming 3-allyl-1-silaindenes.

scientific article published on 20 May 2008

Intramolecular dearomatizing [3 + 2] annulation of α-imino carbenoids with aryl rings furnishing 3,4-fused indole skeletons

scientific article published on 29 January 2014

Intramolecular nucleophilic addition of an organorhodium(I) to a nitrile

scientific article published on 22 April 2005

Intramolecular σ-bond metathesis between carbon-carbon and silicon-silicon bonds

scientific article published on 31 May 2012

Iterative approach to oligo(arylenevinylene)s containing tetrasubstituted vinylene units

scientific article published on 01 July 2010

Ketone synthesis by intramolecular acylation of organorhodium(I) with ester.

scientific article

Light-driven carboxylation of o-alkylphenyl ketones with CO2

scientific article published on 29 October 2015

Light/Palladium-Promoted Benzylic C-H Acylation Using a Benzoyl Group as the Photo-Directing Group

scientific article published on 14 January 2019

Metal-catalysed cleavage of carbon–carbon bonds ⬇️

scientific article published on October 18, 2010

Molybdenum-catalyzed ring-closing metathesis of allenynes

scientific article published on 01 September 2005

New catalyzed three-component cycloadditions for the synthesis of eight-membered carbocycles

scientific article published on 01 February 2003

Nickel-catalysed denitrogenative alkyne insertion reactions of N-sulfonyl-1,2,3-triazoles.

scientific article published on 6 January 2009

Nickel-catalysed intramolecular alkene insertion into cyclobutanones

scientific article published on 20 September 2006

Nickel-catalyzed denitrogenative annulation reactions of 1,2,3-benzotriazin-4(3H)-ones with 1,3-dienes and alkenes.

scientific article published on August 2010

Nickel-catalyzed intermolecular alkyne insertion into cyclobutanones.

scientific article published in May 2005

Nickel-catalyzed regio- and enantioselective annulation reactions of 1,2,3,4-benzothiatriazine-1,1(2H)-dioxides with allenes

scientific article published on 01 July 2010

Nickel-catalyzed synthesis of 1,3,5-trisubstituted hydantoins from acrylates and isocyanates

scientific article published on 14 June 2011

One-pot procedure for the introduction of three different bonds onto terminal alkynes through N-sulfonyl-1,2,3-triazole intermediates

scientific article published on 25 February 2013

One-pot synthesis of 2,5-dihydropyrroles from terminal alkynes, azides, and propargylic alcohols by relay actions of copper, rhodium, and gold

scientific article published on 24 October 2014

Organometallic chemistry: A shortcut to molecular complexity

scientific article published in March 2017

Palladium- and nickel-catalyzed intramolecular cyanoboration of alkynes.

scientific article

Palladium-Catalyzed Intermolecular Exchange between C-C and C-Si σ-Bonds.

scientific article published on 24 August 2017

Palladium-Catalyzed Intramolecular Insertion of Alkenes into the Carbon-Nitrogen Bond of β-Lactams

scientific article published on 01 July 2015

Palladium-catalyzed addition of cyanoboranes to alkynes: regio- and stereoselective synthesis of alpha,beta-unsaturated beta-boryl nitriles.

scientific article published in April 2005

Palladium-catalyzed denitrogenation reaction of 1,2,3-benzotriazin-4(3H)-ones incorporating isocyanides

scientific article published on 14 February 2011

Palladium-catalyzed sequential carbon-carbon bond cleavage/formation producing arylated benzolactones.

scientific article published on 28 October 2008

Photocatalyzed ortho-Alkylation of Pyridine N-Oxides through Alkene Cleavage

scientific article published on 6 March 2018

Photoinduced Cyclization of (o-Alkylbenzoyl)phosphonates to Benzocyclobutenols.

scientific article published on 23 May 2017

Potential of Metal-Catalyzed C-C Single Bond Cleavage for Organic Synthesis.

scientific article published on 11 October 2016

Pyridine-directed palladium-catalyzed phosphonation of C(sp2)-H bonds

scientific article published on 23 July 2013

Reactivity change of cyclobutanols towards isocyanates: rhodium favors C-carbamoylation over O-carbamoylation.

scientific article published on 17 September 2013

Regiocontrolled synthesis of polysubstituted pyrroles starting from terminal alkynes, sulfonyl azides, and allenes

scientific article published on 18 June 2013

Rhodium-Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane

scientific article published on 02 September 2015

Rhodium-catalysed 1,4-addition of diarylindium hydroxides to alpha,beta-unsaturated carbonyl compounds

scientific article published on 13 October 2005

Rhodium-catalysed addition reaction of aryl- and alkenylboronic acids to isocyanates

scientific article published on 01 September 2007

Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

scientific article published on 16 September 2008

Rhodium-catalysed substitutive arylation of cis-allylic diols with arylboroxines

scientific article published on 08 November 2006

Rhodium-catalyzed addition/ring-opening reaction of arylboronic acids with cyclobutanones.

scientific article

Rhodium-catalyzed annulation reactions of 2-cyanophenylboronic acid with alkynes and strained alkenes

scientific article published on 01 July 2005

Rhodium-catalyzed borylative cyclization of 2-alkynylaryl isocyanates with bis(pinacolato)diboron

scientific article published on 11 April 2008

Rhodium-catalyzed carbonylation of spiropentanes

scientific article published on 03 October 2007

Rhodium-catalyzed cascade reaction of 1,6-enynes involving addition, cyclization, and beta-oxygen elimination

scientific article published on 01 December 2006

Rhodium-catalyzed cyclization of 1,6-enynes triggered by addition of arylboronic acids

scientific article published on 01 February 2005

Rhodium-catalyzed cyclization reaction of 1,6-enynes with arylboronic acids through beta-hydride elimination/hydrorhodation sequence

scientific article published on 01 June 2008

Rhodium-catalyzed reaction of 1-alkenylboronates with aldehydes leading to allylation products

scientific article published on 04 October 2011

Rhodium-catalyzed ring opening of benzocyclobutenols with site-selectivity complementary to thermal ring opening.

scientific article published on 11 October 2012

Rhodium‐catalyzed restructuring of carbon frameworks ⬇️

scientific article published on 01 October 2010

Ruthenium-Catalyzed Cycloisomerization of 2,2'-Diethynylbiphenyls Involving Cleavage of a Carbon-Carbon Triple Bond.

scientific article published on 10 December 2015

Ruthenium-Mediated Regio- and Stereoselective Alkenylation of Pyridine ⬇️

scientific article published on April 23, 2003

Ruthenium-catalysed double trans-hydrosilylation of 1,4-diarylbuta-1,3-diynes leading to 2,5-diarylsiloles

scientific article published on 05 April 2007

Ruthenium-catalyzed trans-hydrogermylation of alkynes: formation of 2,5-disubstituted germoles through double trans-hydrogermylation of 1,3-diynes

scientific article published on 01 March 2010

Selective 1:2 coupling of aldehydes and allenes with control of regiochemistry

scientific article published on 14 September 2011

Selective Functionalization of Aromatic C(sp2 )-H Bonds in the Presence of Benzylic C(sp3 )-H Bonds by Electron-Deficient Carbenoids Generated from 4-Acyl-1-Sulfonyl-1,2,3-Triazoles.

scientific article published on 6 November 2017

Solar-driven incorporation of carbon dioxide into α-amino ketones

scientific article published on 06 November 2012

Solvent and ligand partition reaction pathways in nickel-mediated carboxylation of methylenecyclopropanes

scientific article published on 13 January 2006

Special issue celebrating 40 years of the Mukaiyama aldol reaction: introductory remarks

scientific article published in February 2014

Stereoselective oxindole synthesis by palladium-catalyzed cyclization reaction of 2-(alkynyl)aryl isocyanates with amides

scientific article published on 01 May 2009

Stereoselective restructuring of 3-arylcyclobutanols into 1-indanols by sequential breaking and formation of carbon-carbon bonds

scientific article published on 01 December 2009

Stereoselective synthesis of (E)-(trisubstituted alkenyl)borinic esters: stereochemistry reversed by ligand in the palladium-catalyzed reaction of alkynylborates with aryl halides

scientific article published on 01 December 2009

Stereoselective synthesis of 2,3-dihydropyrroles from terminal alkynes, azides, and α,β-unsaturated aldehydes via N-sulfonyl-1,2,3-triazoles

scientific article published on 04 September 2013

Stereoselective synthesis of 3-alkylideneoxindoles by palladium-catalyzed cyclization reaction of 2-(alkynyl)aryl isocyanates with organoboron reagents

scientific article published on 07 October 2008

Stereoselective synthesis of 3-alkylideneoxindoles by rhodium-catalyzed cyclization reaction of 2-alkynylaryl isocyanates with aryl- and alkenylboronic acids

scientific article published on 25 October 2007

Stereoselective synthesis of alpha-allenols by rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids

scientific article published on 01 January 2007

Stereoselective synthesis of syn-configured alpha-allenols by rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids.

scientific article published in August 2009

Stereoselective synthesis of trisubstituted alkenylboranes by palladium-catalysed reaction of alkynyltriarylborates with aryl halides

scientific article published on 15 August 2007

Stereospecific ring expansion from orthocyclophanes with central chirality to metacyclophanes with planar chirality

scientific article published on 01 January 2014

Studies on the thermal ring-opening reactions of cis-3,4-bis(organosilyl)cyclobutenes

scientific article published on 14 April 2007

Substituent effect of group 14 elements on the ring-opening reaction of cyclobutene.

scientific article published on 28 July 2010

Synthesis of 1(2H)-isoquinolones by the nickel-catalyzed denitrogenative alkyne insertion of 1,2,3-benzotriazin-4(3H)-ones

scientific article published on 18 June 2008

Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Tandem Reaction of 2-(Alkynyl)aryl Isocyanates with Benzylic Alcohols ⬇️

scientific article published on October 15, 2010

Synthesis of 3,3-disubstituted α-tetralones by rhodium-catalysed reaction of 1-(2-haloaryl)cyclobutanols

scientific article published on 11 January 2012

Synthesis of Elongated Esters from Alkenes

scientific article published on 25 October 2018

Synthesis of Enantiopure C3 -Symmetric Triangular Molecules

scientific article published on 14 February 2017

Synthesis of Fused and Linked Benzofurans from 2-Alkynylphenol Derivatives through Rhodium(I)-catalyzed Domino-type Addition Reactions

scientific article published on 01 December 2018

Synthesis of Penta-2,4-dien-1-imines and 1,2-Dihydropyridines by Rhodium-Catalyzed Reaction of N-Sulfonyl-1,2,3-triazoles with 2-(Siloxy)furans

scientific article published on 28 November 2016

Synthesis of Pyridine−Borane Complexes via Electrophilic Aromatic Borylation ⬇️

scientific article published on November 23, 2010

Synthesis of Tofisopam by Way of Photoinduced CO2 Fixation

scientific article published on 28 November 2019

Synthesis of acylphosphonates by a palladium-catalyzed phosphonocarbonylation reaction of aryl iodides with phosphites

scientific article

Synthesis of alpha-keto esters by the rhodium-catalysed reaction of cyanoformate with arylboronic acids

scientific article published on 26 April 2007

Synthesis of amine-borane intramolecular complexes through palladium-catalyzed rearrangement of ammonioalkynyltriarylborates

scientific article published on 14 February 2008

Synthesis of chiral N-heterocyclic carbene ligands with rigid backbones and application to the palladium-catalyzed enantioselective intramolecular α-arylation of amides

scientific article published on 08 March 2011

Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes.

scientific article published on 9 May 2011

Synthesis of enaminones by rhodium-catalyzed denitrogenative rearrangement of 1-(N-sulfonyl-1,2,3-triazol-4-yl)alkanols

scientific article published on 15 October 2012

Synthesis of enantiopure dehydropiperidinones from α-amino acids and alkynes via azetidin-3-ones

scientific article published on 17 July 2012

Synthesis of pyridine-N-oxide-borane intramolecular complexes by palladium-catalyzed reaction of 2-bromopyridine-N-oxides with alkynyltriarylborates

scientific article published on 23 May 2011

Synthesis of seven-membered-ring ketones by arylative ring expansion of alkyne-substituted cyclobutanones

scientific article published on 01 July 2005

Synthesis of silafluorenes by iridium-catalyzed [2 + 2 + 2] cycloaddition of silicon-bridged diynes with alkynes

scientific article published on 01 January 2007

Synthesis of tertiary propargylamines by sequential reactions of in situ generated thioiminium salts with organolithium and -magnesium reagents.

scientific article

Synthesis of trans-cycloalkenes via enantioselective cyclopropanation and skeletal rearrangement

scientific article published on 31 October 2014

Synthesis of α-amino ketones from terminal alkynes via rhodium-catalyzed denitrogenative hydration of N-sulfonyl-1,2,3-triazoles

scientific article published on 09 December 2011

Synthesis of γ-Boryl-Substituted Homoallylic Alcohols with anti Stereochemistry Based on a Double-Bond Transposition

scientific article published on 21 December 2018

Synthetic Approach to Benzocyclobutenones Using Visible Light and a Phosphonate Auxiliary

scientific article published on 08 February 2018

The Mukaiyama aldol reaction: 40 years of continuous development.

scientific article published on 23 July 2013

The stereoselective synthesis of α-amino aldols starting from terminal alkynes

scientific article published on 01 September 2014

Theoretical and experimental studies on the thermal ring-opening reaction of cyclobutene having a stannyl substituent at the 3-position.

scientific article

Vinylcyclopropanation of olefins via 3-methoxy-1-propenylrhodium(I).

scientific article published in March 2006

sp3-sp2 vs sp3-sp3 C-C site selectivity in Rh-catalyzed ring opening of benzocyclobutenol: a DFT study.

scientific article published on 16 December 2013

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