List of works - Takeo Sakai

A convergent strategy for the synthesis of polycyclic ethers by using oxiranyl anions

scientific article published on 06 October 2011

Acceleration of Acid-Catalyzed Hydrolysis in a Biphasic System by Sodium Tetracyanocyclopentadienides

scientific article published on 01 January 2016

Asymmetric construction of quaternary carbon centers by sequential conjugate addition of lithium amide and in situ alkylation: utility in the synthesis of (-)-aspidospermidine

scientific article published on 01 February 2009

Asymmetric synthesis of intermediates for otamixaban and premafloxacin by the chiral ligand-controlled asymmetric conjugate addition of a lithium amide

scientific article published on 01 June 2006

Aza Diels-Alder Reactions of Nitriles, N,N-Dimethylhydrazones, and Oximino Ethers. Application in Formal [2 + 2 + 2] Cycloadditions for the Synthesis of Pyridines

scientific article

CAr-O Rotamers in 3,3'-Disubstituted BINOL Esters.

scientific article

Chiral ligand-controlled asymmetric conjugate addition of lithium amides to enoates

scientific article published on 01 March 2003

Convergent Synthesis of Fused Ring Systems in Large Polycyclic Ethers.

scientific article published in January 2017

Correction to "Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide"

scientific article published on 26 December 2017

Cyano Diels−Alder and Cyano Ene Reactions. Applications in a Formal [2 + 2 + 2] Cycloaddition Strategy for the Synthesis of Pyridines ⬇️

scientific article published on September 29, 2010

Divergent synthesis of trans-fused polycyclic ethers by a convergent oxiranyl anion strategy

scientific article published on 05 December 2012

Formal [2 + 2 + 2] cycloaddition strategy based on an intramolecular propargylic ene reaction/Diels-Alder cycloaddition cascade.

scientific article

General entry to asymmetric one-pot [N + 2 + n] cyclization for the synthesis of three- to seven-membered azacycloalkanes

scientific article published on 20 August 2012

Ion-Pair Extraction of Quaternary Ammoniums Using Tetracyanocyclopentadienides and Synthetic Application for Complex Ammoniums

scientific article published on 12 April 2019

Mechanism of the regio- and diastereoselective ring expansion reaction using trimethylsilyldiazomethane

scientific article published on 17 August 2012

Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide

scientific article published on 30 November 2017

N-Allyl-N-tert-butyldimethylsilylamine for chiral ligand-controlled asymmetric conjugate addition to tert-butyl alkenoates.

scientific article

Synthesis of functionalized tetracyanocyclopentadienides from tetracyanothiophene and sulfones.

scientific article published on 16 October 2013

Synthesis of the GHIJKL Fragment of Gymnocin-B

scientific article published on 22 August 2019

Synthesis of the KLMN Fragment of Gymnocin-A from the FGH Fragment.

scientific article

Synthesis of the KLMN fragment of gymnocin-A using oxiranyl anion convergent methodology.

scientific article published on 9 April 2014

Total Synthesis of Brevisamide Using an Oxiranyl Anion Strategy.

scientific article published on 8 April 2016

Total Synthesis of Gymnocin-A.

scientific article published in November 2015

Total synthesis of (-)-kopsinine by an asymmetric one-pot [n+2+3] cyclization

scientific article published on 21 August 2012

List of works by Takeo Sakai

A convergent strategy for the synthesis of polycyclic ethers by using oxiranyl anions

Acceleration of Acid-Catalyzed Hydrolysis in a Biphasic System by Sodium Tetracyanocyclopentadienides

Asymmetric construction of quaternary carbon centers by sequential conjugate addition of lithium amide and in situ alkylation: utility in the synthesis of (-)-aspidospermidine

Asymmetric synthesis of intermediates for otamixaban and premafloxacin by the chiral ligand-controlled asymmetric conjugate addition of a lithium amide

Aza Diels-Alder Reactions of Nitriles, N,N-Dimethylhydrazones, and Oximino Ethers. Application in Formal [2 + 2 + 2] Cycloadditions for the Synthesis of Pyridines

CAr-O Rotamers in 3,3'-Disubstituted BINOL Esters.

Chiral ligand-controlled asymmetric conjugate addition of lithium amides to enoates

Convergent Synthesis of Fused Ring Systems in Large Polycyclic Ethers.

Correction to "Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide"

Cyano Diels−Alder and Cyano Ene Reactions. Applications in a Formal [2 + 2 + 2] Cycloaddition Strategy for the Synthesis of Pyridines ⬇️

Divergent synthesis of trans-fused polycyclic ethers by a convergent oxiranyl anion strategy

Formal [2 + 2 + 2] cycloaddition strategy based on an intramolecular propargylic ene reaction/Diels-Alder cycloaddition cascade.

General entry to asymmetric one-pot [N + 2 + n] cyclization for the synthesis of three- to seven-membered azacycloalkanes

Ion-Pair Extraction of Quaternary Ammoniums Using Tetracyanocyclopentadienides and Synthetic Application for Complex Ammoniums

Mechanism of the regio- and diastereoselective ring expansion reaction using trimethylsilyldiazomethane

Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide

N-Allyl-N-tert-butyldimethylsilylamine for chiral ligand-controlled asymmetric conjugate addition to tert-butyl alkenoates.

Synthesis of functionalized tetracyanocyclopentadienides from tetracyanothiophene and sulfones.

Synthesis of the GHIJKL Fragment of Gymnocin-B

Synthesis of the KLMN Fragment of Gymnocin-A from the FGH Fragment.

Synthesis of the KLMN fragment of gymnocin-A using oxiranyl anion convergent methodology.

Total Synthesis of Brevisamide Using an Oxiranyl Anion Strategy.

Total Synthesis of Gymnocin-A.

Total synthesis of (-)-kopsinine by an asymmetric one-pot [n+2+3] cyclization