List of works - Rick L. Danheiser

A New Route to Silyl-substituted Cyclobutenones and Silylketenes

scientific article

A [4 + 4] annulation strategy for the synthesis of eight-membered carbocycles based on intramolecular cycloadditions of conjugated enynes

scientific article published on December 2011

A benzannulation strategy for the synthesis of phenols and heteroaromatic compounds based on the reaction of (trialkylsilyl)vinylketenes with lithium ynolates

scientific article published on January 2008

A general method for the reductive dechlorination of 4,4-dichlorocyclobutenones

scholarly article

A practical method for the synthesis of 2-alkynylpropenals

scientific article

A short and efficient synthesis of the polyacetylene natural product deca-4,6,8-triyn-1-ol

scholarly article

An annulation method for the synthesis of highly substituted polycyclic aromatic and heteroaromatic compounds

article published in 1990

An improved method for the synthesis of .alpha.-diazo ketones

scientific article (publication date: March 1990)

Aza Diels-Alder Reactions of Nitriles, N,N-Dimethylhydrazones, and Oximino Ethers. Application in Formal [2 + 2 + 2] Cycloadditions for the Synthesis of Pyridines

scientific article

Batch and flow photochemical benzannulations based on the reaction of ynamides and diazo ketones. Application to the synthesis of polycyclic aromatic and heteroaromatic compounds

scientific article published on 28 October 2013

Benzannulation via the reaction of ynamides and vinylketenes. application to the synthesis of highly substituted indoles

scientific article published on 03 September 2013

Concerning the Regiochemical Course of the Diels-Alder Reaction in Supercritical Carbon Dioxide

scientific article published on 01 June 1997

Copper-Mediated N-Alkynylation of Carbamates, Ureas, and Sulfonamides. A General Method for the Synthesis of Ynamides ⬇️

scientific article published on October 16, 2003

Cyano Diels−Alder and Cyano Ene Reactions. Applications in a Formal [2 + 2 + 2] Cycloaddition Strategy for the Synthesis of Pyridines ⬇️

scientific article published on September 29, 2010

Efficient total synthesis of (.+-.)-anatoxin a

scientific article published in 1985

Formal Bimolecular [2 + 2 + 2] Cycloaddition Strategy for the Synthesis of Pyridines: Intramolecular Propargylic Ene Reaction/Aza Diels-Alder Reaction Cascades

scientific article published on 24 September 2018

Formal [2 + 2 + 2] cycloaddition strategy based on an intramolecular propargylic ene reaction/Diels-Alder cycloaddition cascade.

scientific article

Furo[2,3- g]thieno[2,3- e]indole: Application of an Ynamide-Based Benzannulation Strategy to the Synthesis of a Tetracyclic Heteroaromatic Compound

scientific article published on 26 September 2018

Improved Conversion and Selectivity of a Diels−Alder Cycloaddition by Use of Emulsions of Carbon Dioxide and Water

scientific article published on 4 February 2006

Intramolecular [4 + 2] Cycloaddition Reactions of Conjugated Ynones. Formation of Polycyclic Furans via the Generation and Rearrangement of Strained Heterocyclic Allenes

scientific article published in 1998

Intramolecular [4 + 2] cycloadditions of benzynes with conjugated enynes, arenynes, and dienes

scientific article

Intramolecular [4 + 2] cycloadditions of iminoacetonitriles: a new class of azadienophiles for hetero Diels-Alder reactions

scientific article

N-tosyl-3-azacyclohexyne. Synthesis and chemistry of a strained cyclic ynamide

scientific article published on 22 October 2014

Palladium catalysed aryl amination reactions in supercritical carbon dioxide

scientific article

Pictet-Spengler reactions in multiphasic supercritical carbon dioxide/CO2-expanded liquid media. In situ generation of carbamates as a strategy for reactions of amines in supercritical carbon dioxide

scientific article published on 4 August 2005

Reaction rates in ultrasonic emulsions of dense carbon dioxide and water

scientific article published on 4 November 2005

Reactions of (trialkylsilyl)vinylketenes with lithium ynolates: a new benzannulation strategy

scientific article

Reproducibility in Chemical Research

scientific article published on 25 August 2016

Ring expansion-annulation strategy for the synthesis of substituted azulenes and oligoazulenes. 2. Synthesis of azulenyl halides, sulfonates, and azulenylmetal compounds and their application in transition-metal-mediated coupling reactions

scientific article published in December 2004

SYNTHESIS OF TERMINAL 1,3-DIYNES VIA SONOGASHIRA COUPLING OF VINYLIDENE CHLORIDE FOLLOWED BY ELIMINATION. PREPARATION OF 1,3-DECADIYNE.

scientific article

SYNTHESIS OF YNAMIDES BY N-ALKYNYLATION OF AMINE DERIVATIVES. PREPARATION OF N-ALLYL-N-(METHOXYCARBONYL)-1,3-DECADIYNYLAMINE.

scientific article

Scope and stereochemical course of the (trimethylsilyl)cyclopentene annulation ⬇️

scholarly article

Stereoselective synthesis of highly substituted cyclopentenones through [4+1] annulations of trialkylsilyl vinyl ketenes with alpha-benzotriazolyl organolithium compounds

scientific article

Synthesis of 2-indanones via [4 + 1] annulation reactions of (trialkylsilyl)arylketenes

scientific article published on 01 July 2002

Synthesis of 2-iodoynamides and regioselective [2+2] cycloadditions with ketene

scientific article

Synthesis of 3-cyclopentenols by alkoxy-accelerated vinylcyclopropane rearrangement

article

Synthesis of Highly Substituted Pyridines via [4 + 2] Cycloadditions of Vinylallenes and Sulfonyl Cyanides

scientific article published on 12 December 2019

Synthesis of Highly Substituted Quinolines via a Tandem Ynamide Benzannulation/Iodocyclization Strategy

scientific article published on 10 August 2015

Synthesis of amides and lactams in supercritical carbon dioxide

scientific article published in December 2009

Synthesis of highly substituted indolines and indoles via intramolecular [4 + 2] cycloaddition of ynamides and conjugated enynes

scientific article

Synthesis of polycyclic benzofused nitrogen heterocycles via a tandem ynamide benzannulation/ring-closing metathesis strategy. Application in a formal total synthesis of (+)-FR900482

scientific article

Total synthesis of quinolizidine alkaloid (-)-217A. Application of iminoacetonitrile cycloadditions in organic synthesis

scientific article

Trialkylsilyloxyalkynes: Synthesis and aromatic annulation reactions

scholarly article

Tropylium Tetrafluoroborate

Ultrasonic Emulsification of Liquid, Near-Critical Carbon Dioxide−Water Biphasic Mixtures for Acceleration of a Hydrolysis Reaction

scientific article published in July 2003

Why nature eschews the concerted [2 + 2 + 2] cycloaddition of a nonconjugated cyanodiyne. Computational study of a pyridine synthesis involving an ene-Diels-Alder-bimolecular hydrogen-transfer mechanism

scientific article published on 25 January 2012

[2+2] Cycloaddition of ketenes with ynamides. A general method for the synthesis of 3-aminocyclobutenone derivatives

scientific article

List of works by Rick L. Danheiser

A New Route to Silyl-substituted Cyclobutenones and Silylketenes

A [4 + 4] annulation strategy for the synthesis of eight-membered carbocycles based on intramolecular cycloadditions of conjugated enynes

A benzannulation strategy for the synthesis of phenols and heteroaromatic compounds based on the reaction of (trialkylsilyl)vinylketenes with lithium ynolates

A general method for the reductive dechlorination of 4,4-dichlorocyclobutenones

A practical method for the synthesis of 2-alkynylpropenals

A short and efficient synthesis of the polyacetylene natural product deca-4,6,8-triyn-1-ol

An annulation method for the synthesis of highly substituted polycyclic aromatic and heteroaromatic compounds

An improved method for the synthesis of .alpha.-diazo ketones

Aza Diels-Alder Reactions of Nitriles, N,N-Dimethylhydrazones, and Oximino Ethers. Application in Formal [2 + 2 + 2] Cycloadditions for the Synthesis of Pyridines

Batch and flow photochemical benzannulations based on the reaction of ynamides and diazo ketones. Application to the synthesis of polycyclic aromatic and heteroaromatic compounds

Benzannulation via the reaction of ynamides and vinylketenes. application to the synthesis of highly substituted indoles

Concerning the Regiochemical Course of the Diels-Alder Reaction in Supercritical Carbon Dioxide

Copper-Mediated N-Alkynylation of Carbamates, Ureas, and Sulfonamides. A General Method for the Synthesis of Ynamides ⬇️

Cyano Diels−Alder and Cyano Ene Reactions. Applications in a Formal [2 + 2 + 2] Cycloaddition Strategy for the Synthesis of Pyridines ⬇️

Efficient total synthesis of (.+-.)-anatoxin a

Formal Bimolecular [2 + 2 + 2] Cycloaddition Strategy for the Synthesis of Pyridines: Intramolecular Propargylic Ene Reaction/Aza Diels-Alder Reaction Cascades

Formal [2 + 2 + 2] cycloaddition strategy based on an intramolecular propargylic ene reaction/Diels-Alder cycloaddition cascade.

Furo[2,3- g]thieno[2,3- e]indole: Application of an Ynamide-Based Benzannulation Strategy to the Synthesis of a Tetracyclic Heteroaromatic Compound

Improved Conversion and Selectivity of a Diels−Alder Cycloaddition by Use of Emulsions of Carbon Dioxide and Water

Intramolecular [4 + 2] Cycloaddition Reactions of Conjugated Ynones. Formation of Polycyclic Furans via the Generation and Rearrangement of Strained Heterocyclic Allenes

Intramolecular [4 + 2] cycloadditions of benzynes with conjugated enynes, arenynes, and dienes

Intramolecular [4 + 2] cycloadditions of iminoacetonitriles: a new class of azadienophiles for hetero Diels-Alder reactions

N-tosyl-3-azacyclohexyne. Synthesis and chemistry of a strained cyclic ynamide

Palladium catalysed aryl amination reactions in supercritical carbon dioxide

Pictet-Spengler reactions in multiphasic supercritical carbon dioxide/CO2-expanded liquid media. In situ generation of carbamates as a strategy for reactions of amines in supercritical carbon dioxide

Reaction rates in ultrasonic emulsions of dense carbon dioxide and water

Reactions of (trialkylsilyl)vinylketenes with lithium ynolates: a new benzannulation strategy

Reproducibility in Chemical Research

Ring expansion-annulation strategy for the synthesis of substituted azulenes and oligoazulenes. 2. Synthesis of azulenyl halides, sulfonates, and azulenylmetal compounds and their application in transition-metal-mediated coupling reactions

SYNTHESIS OF TERMINAL 1,3-DIYNES VIA SONOGASHIRA COUPLING OF VINYLIDENE CHLORIDE FOLLOWED BY ELIMINATION. PREPARATION OF 1,3-DECADIYNE.

SYNTHESIS OF YNAMIDES BY N-ALKYNYLATION OF AMINE DERIVATIVES. PREPARATION OF N-ALLYL-N-(METHOXYCARBONYL)-1,3-DECADIYNYLAMINE.

Scope and stereochemical course of the (trimethylsilyl)cyclopentene annulation ⬇️

Stereoselective synthesis of highly substituted cyclopentenones through [4+1] annulations of trialkylsilyl vinyl ketenes with alpha-benzotriazolyl organolithium compounds

Synthesis of 2-indanones via [4 + 1] annulation reactions of (trialkylsilyl)arylketenes

Synthesis of 2-iodoynamides and regioselective [2+2] cycloadditions with ketene

Synthesis of 3-cyclopentenols by alkoxy-accelerated vinylcyclopropane rearrangement

Synthesis of Highly Substituted Pyridines via [4 + 2] Cycloadditions of Vinylallenes and Sulfonyl Cyanides

Synthesis of Highly Substituted Quinolines via a Tandem Ynamide Benzannulation/Iodocyclization Strategy

Synthesis of amides and lactams in supercritical carbon dioxide

Synthesis of highly substituted indolines and indoles via intramolecular [4 + 2] cycloaddition of ynamides and conjugated enynes

Synthesis of polycyclic benzofused nitrogen heterocycles via a tandem ynamide benzannulation/ring-closing metathesis strategy. Application in a formal total synthesis of (+)-FR900482

Total synthesis of quinolizidine alkaloid (-)-217A. Application of iminoacetonitrile cycloadditions in organic synthesis

Trialkylsilyloxyalkynes: Synthesis and aromatic annulation reactions

Tropylium Tetrafluoroborate

Ultrasonic Emulsification of Liquid, Near-Critical Carbon Dioxide−Water Biphasic Mixtures for Acceleration of a Hydrolysis Reaction

Why nature eschews the concerted [2 + 2 + 2] cycloaddition of a nonconjugated cyanodiyne. Computational study of a pyridine synthesis involving an ene-Diels-Alder-bimolecular hydrogen-transfer mechanism

[2+2] Cycloaddition of ketenes with ynamides. A general method for the synthesis of 3-aminocyclobutenone derivatives