List of works - Tomoya Miura

A One-Pot Reaction of α-Imino Rhodium Carbenoids and Halohydrins: Access to 2,6-Substituted Dihydro-2H-1,4-oxazines

scientific article published on 13 April 2020

A Reaction of Triazoles with Thioesters to Produce β-Sulfanyl Enamides by Insertion of an Enamine Moiety into the Sulfur-Carbonyl Bond.

scientific article

A syn-Selective Aza-Aldol Reaction of Boron Aza-Enolates Generated from N-Sulfonyl-1,2,3-Triazoles and 9-BBN-H

scientific article published on 03 June 2016

Acyl 1,3-migration in rhodium-catalyzed reactions of acetylenic beta-ketoesters with aryl boronic acids: application to two-carbon-atom ring expansions

scientific article published on 01 November 2005

An efficient method for cyclopentene annulation onto alpha,beta-unsaturated ketones: W(CO)(5)(L)-catalyzed 5-endo-dig cyclization of 6-siloxy-5-en-1-ynes

scientific article published on 01 December 2002

Asymmetric Synthesis and Stereochemical Assignment of 12C/13C Isotopomers

scientific article published on 19 August 2019

Construction of homoallylic alcohols from terminal alkynes and aldehydes with installation of syn-stereochemistry.

scientific article published on 22 April 2014

Copper-catalyzed amination of silyl ketene acetals with N-chloroamines

scientific article published on 02 October 2012

Cyclization reaction of cyano-substituted unsaturated esters prompted by conjugate addition of organoborons

scientific article published on 07 February 2007

Diastereo- and Enantioselective Synthesis of (E)-δ-Boryl-Substituted anti-Homoallylic Alcohols in Two Steps from Terminal Alkynes

scientific article published on 29 August 2019

Direct production of enaminones from terminal alkynes via rhodium-catalyzed reaction of formamides with N-sulfonyl-1,2,3-triazoles

scientific article published on 28 April 2014

Enantioselective Denitrogenative Annulation of 1H-Tetrazoles with Styrenes Catalyzed by Rhodium.

scientific article published on 13 March 2018

Enantioselective Synthesis of (E)-δ-Boryl-Substituted anti-Homoallylic Alcohols Using Palladium and a Chiral Phosphoric Acid.

scientific article

Enantioselective Synthesis of anti-1,2-Oxaborinan-3-enes from Aldehydes and 1,1-Di(boryl)alk-3-enes Using Ruthenium and Chiral Phosphoric Acid Catalysts

scientific article published on 14 July 2017

Enantioselective [2 + 2 + 2] cycloaddition reaction of isocyanates and allenes catalyzed by nickel.

scientific article published on 14 September 2010

Enantioselective synthesis of 3,4-dihydroisoquinolin-1(2H)-ones by nickel-catalyzed denitrogenative annulation of 1,2,3-benzotriazin-4(3H)-ones with allenes

scientific article published on 01 January 2010

Enantioselective synthesis of anti homoallylic alcohols from terminal alkynes and aldehydes based on concomitant use of a cationic iridium complex and a chiral phosphoric acid.

scientific article

Facile synthesis of 2,5-disubstituted thiazoles from terminal alkynes, sulfonyl azides, and thionoesters

scientific article published on 30 April 2015

Formation of carbocycles through sequential carborhodation triggered by addition of organoborons

scientific article published on 24 August 2006

Intramolecular dearomatizing [3 + 2] annulation of α-imino carbenoids with aryl rings furnishing 3,4-fused indole skeletons

scientific article published on 29 January 2014

Intramolecular nucleophilic addition of an organorhodium(I) to a nitrile

scientific article published on 22 April 2005

Ketone synthesis by intramolecular acylation of organorhodium(I) with ester.

scientific article

Nickel-catalysed denitrogenative alkyne insertion reactions of N-sulfonyl-1,2,3-triazoles.

scientific article published on 6 January 2009

Nickel-catalyzed denitrogenative annulation reactions of 1,2,3-benzotriazin-4(3H)-ones with 1,3-dienes and alkenes.

scientific article published on August 2010

Nickel-catalyzed regio- and enantioselective annulation reactions of 1,2,3,4-benzothiatriazine-1,1(2H)-dioxides with allenes

scientific article published on 01 July 2010

Nickel-catalyzed synthesis of 1,3,5-trisubstituted hydantoins from acrylates and isocyanates

scientific article published on 14 June 2011

One-pot procedure for the introduction of three different bonds onto terminal alkynes through N-sulfonyl-1,2,3-triazole intermediates

scientific article published on 25 February 2013

One-pot synthesis of 2,5-dihydropyrroles from terminal alkynes, azides, and propargylic alcohols by relay actions of copper, rhodium, and gold

scientific article published on 24 October 2014

Palladium-catalyzed denitrogenation reaction of 1,2,3-benzotriazin-4(3H)-ones incorporating isocyanides

scientific article published on 14 February 2011

Photocatalyzed ortho-Alkylation of Pyridine N-Oxides through Alkene Cleavage

scientific article published on 6 March 2018

Reactions of iodinated vinylidene complexes generated from 1-iodo-1-alkynes and W(CO)5(thf)

scientific article published on 01 January 2002

Regiocontrolled synthesis of polysubstituted pyrroles starting from terminal alkynes, sulfonyl azides, and allenes

scientific article published on 18 June 2013

Rhodium-Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane

scientific article published on 02 September 2015

Rhodium-catalysed 1,4-addition of diarylindium hydroxides to alpha,beta-unsaturated carbonyl compounds

scientific article published on 13 October 2005

Rhodium-catalysed addition reaction of aryl- and alkenylboronic acids to isocyanates

scientific article published on 01 September 2007

Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

scientific article published on 16 September 2008

Rhodium-catalysed substitutive arylation of cis-allylic diols with arylboroxines

scientific article published on 08 November 2006

Rhodium-catalyzed annulation reactions of 2-cyanophenylboronic acid with alkynes and strained alkenes

scientific article published on 01 July 2005

Rhodium-catalyzed borylative cyclization of 2-alkynylaryl isocyanates with bis(pinacolato)diboron

scientific article published on 11 April 2008

Rhodium-catalyzed cascade reaction of 1,6-enynes involving addition, cyclization, and beta-oxygen elimination

scientific article published on 01 December 2006

Rhodium-catalyzed cyclization of 1,6-enynes triggered by addition of arylboronic acids

scientific article published on 01 February 2005

Rhodium-catalyzed cyclization reaction of 1,6-enynes with arylboronic acids through beta-hydride elimination/hydrorhodation sequence

scientific article published on 01 June 2008

Rhodium-catalyzed reaction of 1-alkenylboronates with aldehydes leading to allylation products

scientific article published on 04 October 2011

Selective 1:2 coupling of aldehydes and allenes with control of regiochemistry

scientific article published on 14 September 2011

Selective Functionalization of Aromatic C(sp2 )-H Bonds in the Presence of Benzylic C(sp3 )-H Bonds by Electron-Deficient Carbenoids Generated from 4-Acyl-1-Sulfonyl-1,2,3-Triazoles.

scientific article published on 6 November 2017

Solvent and ligand partition reaction pathways in nickel-mediated carboxylation of methylenecyclopropanes

scientific article published on 13 January 2006

Stereoselective oxindole synthesis by palladium-catalyzed cyclization reaction of 2-(alkynyl)aryl isocyanates with amides

scientific article published on 01 May 2009

Stereoselective synthesis of 2,3-dihydropyrroles from terminal alkynes, azides, and α,β-unsaturated aldehydes via N-sulfonyl-1,2,3-triazoles

scientific article published on 04 September 2013

Stereoselective synthesis of 3-alkylideneoxindoles by palladium-catalyzed cyclization reaction of 2-(alkynyl)aryl isocyanates with organoboron reagents

scientific article published on 07 October 2008

Stereoselective synthesis of 3-alkylideneoxindoles by rhodium-catalyzed cyclization reaction of 2-alkynylaryl isocyanates with aryl- and alkenylboronic acids

scientific article published on 25 October 2007

Stereoselective synthesis of alpha-allenols by rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids

scientific article published on 01 January 2007

Stereoselective synthesis of syn-configured alpha-allenols by rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids.

scientific article published in August 2009

Stereoselective synthesis of trisubstituted alkenylboranes by palladium-catalysed reaction of alkynyltriarylborates with aryl halides

scientific article published on 15 August 2007

Stereospecific reduction of phosphine oxides to phosphines by the use of a methylation reagent and lithium aluminum hydride

scientific article published on 01 January 2001

Synthesis and Reactions of Optically Active Secondary Dialkylphosphine-Boranes

scientific article published on 01 March 2000

Synthesis of 1(2H)-isoquinolones by the nickel-catalyzed denitrogenative alkyne insertion of 1,2,3-benzotriazin-4(3H)-ones

scientific article published on 18 June 2008

Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Tandem Reaction of 2-(Alkynyl)aryl Isocyanates with Benzylic Alcohols ⬇️

scientific article published on October 15, 2010

Synthesis of Elongated Esters from Alkenes

scientific article published on 25 October 2018

Synthesis of Enantiopure C3 -Symmetric Triangular Molecules

scientific article published on 14 February 2017

Synthesis of Penta-2,4-dien-1-imines and 1,2-Dihydropyridines by Rhodium-Catalyzed Reaction of N-Sulfonyl-1,2,3-triazoles with 2-(Siloxy)furans

scientific article published on 28 November 2016

Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes.

scientific article published on 9 May 2011

Synthesis of enaminones by rhodium-catalyzed denitrogenative rearrangement of 1-(N-sulfonyl-1,2,3-triazol-4-yl)alkanols

scientific article published on 15 October 2012

Synthesis of trans-cycloalkenes via enantioselective cyclopropanation and skeletal rearrangement

scientific article published on 31 October 2014

Synthesis of α-amino ketones from terminal alkynes via rhodium-catalyzed denitrogenative hydration of N-sulfonyl-1,2,3-triazoles

scientific article published on 09 December 2011

Synthesis of γ-Boryl-Substituted Homoallylic Alcohols with anti Stereochemistry Based on a Double-Bond Transposition

scientific article published on 21 December 2018

The stereoselective synthesis of α-amino aldols starting from terminal alkynes

scientific article published on 01 September 2014

Useful reactions of silylated propargyltungsten or propargylmolybdenum species

scientific article published on 01 October 2006

Vinylcyclopropanation of olefins via 3-methoxy-1-propenylrhodium(I).

scientific article published in March 2006

W(CO)5(L)-catalyzed endo-selective cyclization of allenyl silyl enol ethers: an efficient method for the cyclopentene annulation onto alpha,beta-unsaturated ketones

scientific article published on 01 May 2003

W(CO)5(L)-catalyzed formal cope rearrangement of allenyl silyl enol ethers

scientific article published on 01 April 2005

List of works by Tomoya Miura

A One-Pot Reaction of α-Imino Rhodium Carbenoids and Halohydrins: Access to 2,6-Substituted Dihydro-2H-1,4-oxazines

A Reaction of Triazoles with Thioesters to Produce β-Sulfanyl Enamides by Insertion of an Enamine Moiety into the Sulfur-Carbonyl Bond.

A syn-Selective Aza-Aldol Reaction of Boron Aza-Enolates Generated from N-Sulfonyl-1,2,3-Triazoles and 9-BBN-H

Acyl 1,3-migration in rhodium-catalyzed reactions of acetylenic beta-ketoesters with aryl boronic acids: application to two-carbon-atom ring expansions

An efficient method for cyclopentene annulation onto alpha,beta-unsaturated ketones: W(CO)(5)(L)-catalyzed 5-endo-dig cyclization of 6-siloxy-5-en-1-ynes

Asymmetric Synthesis and Stereochemical Assignment of 12C/13C Isotopomers

Construction of homoallylic alcohols from terminal alkynes and aldehydes with installation of syn-stereochemistry.

Copper-catalyzed amination of silyl ketene acetals with N-chloroamines

Cyclization reaction of cyano-substituted unsaturated esters prompted by conjugate addition of organoborons

Diastereo- and Enantioselective Synthesis of (E)-δ-Boryl-Substituted anti-Homoallylic Alcohols in Two Steps from Terminal Alkynes

Direct production of enaminones from terminal alkynes via rhodium-catalyzed reaction of formamides with N-sulfonyl-1,2,3-triazoles

Enantioselective Denitrogenative Annulation of 1H-Tetrazoles with Styrenes Catalyzed by Rhodium.

Enantioselective Synthesis of (E)-δ-Boryl-Substituted anti-Homoallylic Alcohols Using Palladium and a Chiral Phosphoric Acid.

Enantioselective Synthesis of anti-1,2-Oxaborinan-3-enes from Aldehydes and 1,1-Di(boryl)alk-3-enes Using Ruthenium and Chiral Phosphoric Acid Catalysts

Enantioselective [2 + 2 + 2] cycloaddition reaction of isocyanates and allenes catalyzed by nickel.

Enantioselective synthesis of 3,4-dihydroisoquinolin-1(2H)-ones by nickel-catalyzed denitrogenative annulation of 1,2,3-benzotriazin-4(3H)-ones with allenes

Enantioselective synthesis of anti homoallylic alcohols from terminal alkynes and aldehydes based on concomitant use of a cationic iridium complex and a chiral phosphoric acid.

Facile synthesis of 2,5-disubstituted thiazoles from terminal alkynes, sulfonyl azides, and thionoesters

Formation of carbocycles through sequential carborhodation triggered by addition of organoborons

Intramolecular dearomatizing [3 + 2] annulation of α-imino carbenoids with aryl rings furnishing 3,4-fused indole skeletons

Intramolecular nucleophilic addition of an organorhodium(I) to a nitrile

Ketone synthesis by intramolecular acylation of organorhodium(I) with ester.

Nickel-catalysed denitrogenative alkyne insertion reactions of N-sulfonyl-1,2,3-triazoles.

Nickel-catalyzed denitrogenative annulation reactions of 1,2,3-benzotriazin-4(3H)-ones with 1,3-dienes and alkenes.

Nickel-catalyzed regio- and enantioselective annulation reactions of 1,2,3,4-benzothiatriazine-1,1(2H)-dioxides with allenes

Nickel-catalyzed synthesis of 1,3,5-trisubstituted hydantoins from acrylates and isocyanates

One-pot procedure for the introduction of three different bonds onto terminal alkynes through N-sulfonyl-1,2,3-triazole intermediates

One-pot synthesis of 2,5-dihydropyrroles from terminal alkynes, azides, and propargylic alcohols by relay actions of copper, rhodium, and gold

Palladium-catalyzed denitrogenation reaction of 1,2,3-benzotriazin-4(3H)-ones incorporating isocyanides

Photocatalyzed ortho-Alkylation of Pyridine N-Oxides through Alkene Cleavage

Reactions of iodinated vinylidene complexes generated from 1-iodo-1-alkynes and W(CO)5(thf)

Regiocontrolled synthesis of polysubstituted pyrroles starting from terminal alkynes, sulfonyl azides, and allenes

Rhodium-Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane

Rhodium-catalysed 1,4-addition of diarylindium hydroxides to alpha,beta-unsaturated carbonyl compounds

Rhodium-catalysed addition reaction of aryl- and alkenylboronic acids to isocyanates

Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

Rhodium-catalysed substitutive arylation of cis-allylic diols with arylboroxines

Rhodium-catalyzed annulation reactions of 2-cyanophenylboronic acid with alkynes and strained alkenes

Rhodium-catalyzed borylative cyclization of 2-alkynylaryl isocyanates with bis(pinacolato)diboron

Rhodium-catalyzed cascade reaction of 1,6-enynes involving addition, cyclization, and beta-oxygen elimination

Rhodium-catalyzed cyclization of 1,6-enynes triggered by addition of arylboronic acids

Rhodium-catalyzed cyclization reaction of 1,6-enynes with arylboronic acids through beta-hydride elimination/hydrorhodation sequence

Rhodium-catalyzed reaction of 1-alkenylboronates with aldehydes leading to allylation products

Selective 1:2 coupling of aldehydes and allenes with control of regiochemistry

Selective Functionalization of Aromatic C(sp2 )-H Bonds in the Presence of Benzylic C(sp3 )-H Bonds by Electron-Deficient Carbenoids Generated from 4-Acyl-1-Sulfonyl-1,2,3-Triazoles.

Solvent and ligand partition reaction pathways in nickel-mediated carboxylation of methylenecyclopropanes

Stereoselective oxindole synthesis by palladium-catalyzed cyclization reaction of 2-(alkynyl)aryl isocyanates with amides

Stereoselective synthesis of 2,3-dihydropyrroles from terminal alkynes, azides, and α,β-unsaturated aldehydes via N-sulfonyl-1,2,3-triazoles

Stereoselective synthesis of 3-alkylideneoxindoles by palladium-catalyzed cyclization reaction of 2-(alkynyl)aryl isocyanates with organoboron reagents

Stereoselective synthesis of 3-alkylideneoxindoles by rhodium-catalyzed cyclization reaction of 2-alkynylaryl isocyanates with aryl- and alkenylboronic acids

Stereoselective synthesis of alpha-allenols by rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids

Stereoselective synthesis of syn-configured alpha-allenols by rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids.

Stereoselective synthesis of trisubstituted alkenylboranes by palladium-catalysed reaction of alkynyltriarylborates with aryl halides

Stereospecific reduction of phosphine oxides to phosphines by the use of a methylation reagent and lithium aluminum hydride

Synthesis and Reactions of Optically Active Secondary Dialkylphosphine-Boranes

Synthesis of 1(2H)-isoquinolones by the nickel-catalyzed denitrogenative alkyne insertion of 1,2,3-benzotriazin-4(3H)-ones

Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Tandem Reaction of 2-(Alkynyl)aryl Isocyanates with Benzylic Alcohols ⬇️

Synthesis of Elongated Esters from Alkenes

Synthesis of Enantiopure C3 -Symmetric Triangular Molecules

Synthesis of Penta-2,4-dien-1-imines and 1,2-Dihydropyridines by Rhodium-Catalyzed Reaction of N-Sulfonyl-1,2,3-triazoles with 2-(Siloxy)furans

Synthesis of cross-conjugated trienes by rhodium-catalyzed dimerization of monosubstituted allenes.

Synthesis of enaminones by rhodium-catalyzed denitrogenative rearrangement of 1-(N-sulfonyl-1,2,3-triazol-4-yl)alkanols

Synthesis of trans-cycloalkenes via enantioselective cyclopropanation and skeletal rearrangement

Synthesis of α-amino ketones from terminal alkynes via rhodium-catalyzed denitrogenative hydration of N-sulfonyl-1,2,3-triazoles

Synthesis of γ-Boryl-Substituted Homoallylic Alcohols with anti Stereochemistry Based on a Double-Bond Transposition

The stereoselective synthesis of α-amino aldols starting from terminal alkynes

Useful reactions of silylated propargyltungsten or propargylmolybdenum species

Vinylcyclopropanation of olefins via 3-methoxy-1-propenylrhodium(I).

W(CO)5(L)-catalyzed endo-selective cyclization of allenyl silyl enol ethers: an efficient method for the cyclopentene annulation onto alpha,beta-unsaturated ketones

W(CO)5(L)-catalyzed formal cope rearrangement of allenyl silyl enol ethers