Search filters

List of works by Michal Szostak

2-Methyltetrahydrofuran: A Green Solvent for Iron-Catalyzed Cross-Coupling Reactions.

scientific article published in March 2018

A General Method for Two-Step Transamidation of Secondary Amides Using Commercially Available, Air- and Moisture-Stable Palladium/NHC (N-Heterocyclic Carbene) Complexes.

scientific article

An efficient computational model to predict protonation at the amide nitrogen and reactivity along the C-N rotational pathway

scientific article published on April 2015

Barriers to Rotation in ortho-Substituted Tertiary Aromatic Amides: Effect of Chloro-Substitution on Resonance and Distortion

scientific article published on 15 February 2018

Chemistry of Bridged Lactams: Recent Developments

scientific article published on 12 January 2019

Chemistry of bridged lactams and related heterocycles

scientific article

Chemoselective Ketone Synthesis by the Addition of Organometallics to N-Acylazetidines

scientific article published on 29 April 2016

Concise Syntheses of Strychnine and Englerin A: the Power of Reductive Cyclizations Triggered by Samarium Iodide ⬇️

scientific article published on July 20, 2011

Corey-Chaykovsky epoxidation of twisted amides: synthesis and reactivity of bridged spiro-epoxyamines.

scientific article published on September 2009

Decarbonylative Borylation of Amides by Palladium Catalysis

scientific article published on 05 March 2019

Decarbonylative Cyanation of Amides by Palladium Catalysis

scientific article published in June 2017

Decarbonylative Phosphorylation of Amides by Palladium and Nickel Catalysis: The Hirao Cross-Coupling of Amide Derivatives

scientific article published on 14 August 2017

Decarbonylative Phosphorylation of Carboxylic Acids via Redox-Neutral Palladium Catalysis

scientific article published on 04 November 2019

Decarbonylative Suzuki-Miyaura Cross-Coupling of Aroyl Chlorides

scientific article published on 10 August 2020

Decarbonylative cross-coupling of amides

scientific article published on 01 November 2018

Decarbonylative thioetherification by nickel catalysis using air- and moisture-stable nickel precatalysts.

scientific article

Direct synthesis of medium-bridged twisted amides via a transannular cyclization strategy

scientific article published on September 2009

Editorial for "Organometallic Chemistry" Section, in Journal Molecules

scientific article published on 03 July 2020

Efficient Synthesis of Diaryl Ketones by Nickel-Catalyzed Negishi Cross-Coupling of Amides by Carbon-Nitrogen Bond Cleavage at Room Temperature Accelerated by a Solvent Effect.

scientific article

General Method for the Suzuki-Miyaura Cross-Coupling of Primary Amide-Derived Electrophiles Enabled by [Pd(NHC)(cin)Cl] at Room Temperature

scientific article published on 27 November 2017

Graphene oxide catalyzed ketone α-alkylation with alkenes: enhancement of graphene oxide activity by hydrogen bonding

scientific article published on 17 April 2019

Graphene-Catalyzed Direct Friedel-Crafts Alkylation Reactions: Mechanism, Selectivity, and Synthetic Utility

scientific article published on 23 October 2015

Ground-State Distortion in N-Acyl-tert-butyl-carbamates (Boc) and N-Acyl-tosylamides (Ts): Twisted Amides of Relevance to Amide N-C Cross-Coupling

scientific article published on 2 August 2016

Highly Chemoselective Synthesis of Indolizidine Lactams by SmI2 -Induced Umpolung of the Amide Bond via Aminoketyl Radicals: Efficient Entry to Alkaloid Scaffolds.

scientific article

Highly Chemoselective, Transition-Metal-Free Transamidation of Unactivated Amides and Direct Amidation of Alkyl Esters by N-C/O-C Cleavage

scientific article published on 01 July 2019

Highly Selective and Divergent Acyl and Aryl Cross-Couplings of Amides via Ir-Catalyzed C-H Borylation/N-C(O) Activation

scientific article published on 09 July 2020

Highly chemoselective reduction of amides (primary, secondary, tertiary) to alcohols using SmI2/amine/H2O under mild conditions

scientific article

Highly chemoselective ruthenium(ii)-catalyzed direct arylation of cyclic and N,N-dialkyl benzamides with aryl silanes.

scientific article published on 24 February 2017

Highly selective transition-metal-free transamidation of amides and amidation of esters at room temperature

scientific article published in Nature Communications

Highly-chemoselective step-down reduction of carboxylic acids to aromatic hydrocarbons via palladium catalysis

scientific article published on 29 April 2019

Iron-Catalyzed C(sp2)-C(sp3) Cross-Coupling of Aryl Chlorobenzoates with Alkyl Grignard Reagents

scientific article published on 06 January 2020

Iron-Catalyzed C(sp2)-C(sp3) Cross-Coupling of Chlorobenzenesulfonamides with Alkyl Grignard Reagents: Entry to Alkylated Aromatics

scientific article published on 14 January 2019

Iron-Catalyzed C-O Bond Activation: Opportunity for Sustainable Catalysis.

scientific article

Iron-Catalyzed Cross-Coupling in the Synthesis of Pharmaceuticals: In Pursuit of Sustainability.

scientific article published on 19 February 2018

Kinetically Controlled, Highly Chemoselective Acylation of Functionalized Grignard Reagents with Amides by N-C Cleavage

scientific article published on 16 December 2019

Mechanism of SmI2/amine/H2O-promoted chemoselective reductions of carboxylic acid derivatives (esters, acids, and amides) to alcohols

scientific article published on 8 October 2014

Mechanistic Study of SmI2/H2O and SmI2/Amine/H2O-Promoted Chemoselective Reduction of Aromatic Amides (Primary, Secondary, Tertiary) to Alcohols via Aminoketyl Radicals

scientific article published on 22 June 2017

Mechanistic investigation of the selective reduction of Meldrum's acids to β-hydroxy acids using SmI2 and H2O.

scientific article published in August 2014

Metal-Free Transamidation of Secondary Amides by N-C Cleavage

scientific article published on 09 September 2019

Metal-Free Transamidation of Secondary Amides via Selective N-C Cleavage under Mild Conditions.

scientific article published on 14 March 2017

N-Acyl-glutarimides: Effect of Glutarimide Ring on the Structures of Fully Perpendicular Twisted Amides and N-C Bond Cross-Coupling

scientific article published on 06 April 2020

N-Acyl-glutarimides: Resonance and Proton Affinities of Rotationally-Inverted Twisted Amides Relevant to N-C(O) Cross-Coupling

scientific article published on 16 February 2018

N-Acylcarbazoles and N-Acylindoles: Electronically Activated Amides for N-C(O) Cross-Coupling by Nlp to Ar Conjugation Switch

scientific article published on 01 June 2020

N-Acylsaccharins as Amide-Based Arylating Reagents via Chemoselective N-C Cleavage: Pd-Catalyzed Decarbonylative Heck Reaction

scientific article published on 17 November 2016

N-Acylsaccharins: Stable Electrophilic Amide-Based Acyl Transfer Reagents in Pd-Catalyzed Suzuki-Miyaura Coupling via N-C Cleavage

scientific article published on 11 August 2016

N-Acylsuccinimides: twist-controlled, acyl-transfer reagents in Suzuki-Miyaura cross-coupling by N-C amide bond activation.

scientific article published on 17 October 2017

N-Heterocyclic Carbene Complexes in C-H Activation Reactions

scientific article published on 22 January 2020

N-Methylamino Pyrimidyl Amides (MAPA): Highly Reactive, Electronically-Activated Amides in Catalytic N-C(O) Cleavage.

scientific article published on 22 August 2017

Nickel-Catalyzed Diaryl Ketone Synthesis by N-C Cleavage: Direct Negishi Cross-Coupling of Primary Amides by Site-Selective N,N-Di-Boc Activation.

scientific article published on 8 November 2016

On the role of pre- and post-electron-transfer steps in the SmI2 /amine/H(2)O-mediated reduction of esters: new mechanistic insights and kinetic studies

scientific article published on 11 March 2014

P-Doped Porous Carbon as Metal Free Catalysts for Selective Aerobic Oxidation with an Unexpected Mechanism.

scientific article published on 11 January 2016

Palladium-Catalyzed Decarbonylative Borylation of Carboxylic Acids: Tuning Reaction Selectivity by Computation

scientific article published on 21 November 2018

Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of N-Mesylamides by N-C Cleavage: Electronic Effect of the Mesyl Group

scientific article

Palladium-catalyzed Suzuki-Miyaura coupling of amides by carbon-nitrogen cleavage: general strategy for amide N-C bond activation

scientific article published on 11 February 2016

Palladium-catalyzed decarbonylative Suzuki-Miyaura cross-coupling of amides by carbon-nitrogen bond activation

scientific article published on 03 September 2019

Palladium/NHC (NHC = N-Heterocyclic Carbene)-Catalyzed B-Alkyl Suzuki Cross-Coupling of Amides by Selective N-C Bond Cleavage

article

Pd-Catalyzed Suzuki-Miyaura Cross-Coupling of Pentafluorophenyl Esters

Pd-PEPPSI: Pd-NHC Precatalyst for Suzuki-Miyaura Cross-Coupling Reactions of Amides

scientific article published on 27 June 2017

Pd-PEPPSI: a general Pd-NHC precatalyst for Buchwald-Hartwig cross-coupling of esters and amides (transamidation) under the same reaction conditions.

scientific article published on 12 September 2017

Pentafluorophenyl Esters: Highly Chemoselective Ketyl Precursors for the Synthesis of α,α-Dideuterio Alcohols Using SmI2 and D2O as a Deuterium Source

scientific article published on 08 January 2020

Preference of cis-Thioamide Structure in N-Thioacyl-N-methylanilines

scientific article published on 30 November 2020

Proton-coupled electron transfer in the reduction of carbonyls using SmI2-H2O: implications for the reductive coupling of acyl-type ketyl radicals with SmI2-H2O.

scientific article

Proximity effects in nucleophilic addition reactions to medium-bridged twisted lactams: remarkably stable tetrahedral intermediates

scientific article

Redox-Neutral Decarbonylative Cross-Couplings Coming of Age

scientific article published on 07 May 2019

Resonance Destabilization in N-Acylanilines (Anilides): Electronically-Activated Planar Amides of Relevance in N-C(O) Cross-Coupling

scientific article published on 07 June 2017

Reversible Twisting of Primary Amides via Ground State N-C(O) Destabilization: Highly Twisted Rotationally Inverted Acyclic Amides

scientific article published on 14 December 2017

Rh(III)-Catalyzed C-H Amidation of 2-Arylindoles with Dioxazolones: A Route to Indolo[1,2-c]quinazolines

scientific article published on 22 August 2019

Rh-Catalyzed Base-Free Decarbonylative Borylation of Twisted Amides

scientific article published on 30 October 2020

Ruthenium(0)-Catalyzed C-H Arylation of Aromatic Imines under Neutral Conditions: Access to Biaryl Aldehydes

scientific article published on 16 August 2016

Ruthenium(0)-catalyzed hydroarylation of alkynes via ketone-directed C-H functionalization using in situ-generated ruthenium complexes

scientific article published on 14 July 2016

Ruthenium(0)-sequential catalysis for the synthesis of sterically hindered amines by C-H arylation/hydrosilylation

scientific article published on 10 July 2019

Ruthenium(II)-Catalyzed Direct C-H Arylation of Indoles with Arylsilanes in Water.

scientific article published on 28 December 2017

Ruthenium(II)-Catalyzed Ortho-C-H Alkylation of Naphthylamines with Diazo Compounds for Synthesis of 2,2-Disubstituted π-Extended 3-Oxindoles in Water

scientific article published on 19 June 2020

Ruthenium(ii)-catalyzed ortho-C-H arylation of diverse N-heterocycles with aryl silanes by exploiting solvent-controlled N-coordination

scientific article published on 01 June 2017

Sc(OTf)3-catalyzed synthesis of anhydrides from twisted amides.

scientific article published on 8 February 2017

Selective reduction of barbituric acids using SmI2/H2O: synthesis, reactivity, and structural analysis of tetrahedral adducts

scientific article published on 9 October 2013

Selective reductive transformations using samarium diiodide-water ⬇️

scientific article published on August 30, 2011

Stability of medium-bridged twisted amides in aqueous solutions

scientific article

Stereoselective capture of N-acyliminium ions generated from α-hydroxy-N-acylcarbamides: direct synthesis of uracils from barbituric acids enabled by SmI2 reduction

scientific article published on 20 December 2013

Sterically Controlled Pd-Catalyzed Chemoselective Ketone Synthesis via N-C Cleavage in Twisted Amides

scientific article published on 18 August 2015

Sterically Hindered Ketones via Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of Amides by N-C(O) Activation

scientific article published on 17 September 2019

Sterically-controlled intermolecular Friedel-Crafts acylation with twisted amides via selective N-C cleavage under mild conditions

scientific article published on 3 May 2016

Structural Characterization of N-Alkylated Twisted Amides: Consequences for Amide Bond Resonance and N-C Cleavage.

scientific article published on 8 March 2016

Structural analysis and reactivity of unusual tetrahedral intermediates enabled by SmI2-mediated reduction of barbituric acids: vinylogous N-acyliminium additions to α-hydroxy-N-acyl-carbamides

scientific article published on 24 January 2014

Structural characterization of N-protonated amides: regioselective N-activation of medium-bridged twisted lactams

scientific article

Structures and energetic properties of 4-halobenzamides

scientific article published on 23 October 2018

Structures of Highly Twisted Amides Relevant to Amide N-C Cross-Coupling: Evidence for Ground-State Amide Destabilization.

scientific article

Suzuki-Miyaura Cross-Coupling of N-Acylpyrroles and Pyrazoles: Planar, Electronically Activated Amides in Catalytic N-C Cleavage.

scientific article published on 22 June 2017

Suzuki-Miyaura cross-coupling of amides and esters at room temperature: correlation with barriers to rotation around C-N and C-O bonds.

scientific article published on August 2017

Synthesis and rearrangement of a bridged thioamide

scientific article published on 30 October 2009

Synthesis of Amides by Mild Palladium-Catalyzed Aminocarbonylation of Arylsilanes with Amines Enabled by Copper(II) Fluoride

scientific article published on 19 December 2018

Synthesis of Biaryls through Nickel-Catalyzed Suzuki-Miyaura Coupling of Amides by Carbon-Nitrogen Bond Cleavage.

scientific article

Synthesis of Biaryls via Decarbonylative Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of Carboxylic Acids

scientific article published on 17 August 2019

Synthesis of C6-Substituted Isoquinolino[1,2-b]quinazolines via Rh(III)-Catalyzed C-H Annulation with Sulfoxonium Ylides

scientific article published on 30 January 2020

Synthesis of Nitrogen Heterocycles Using Samarium(II) Iodide

scientific article published on 21 November 2017

Synthesis of biaryl ketones by arylation of Weinreb amides with functionalized Grignard reagents under thermodynamic control vs. kinetic control of N,N-Boc2-amides

scientific article published on 12 May 2020

Synthesis of medium-bridged twisted lactams via cation-pi control of the regiochemistry of the intramolecular Schmidt reaction

scientific article

Synthesis, structural analysis, and reactivity of bridged orthoamides by intramolecular Schmidt reaction

scientific article

The Most Twisted Acyclic Amides: Structures and Reactivity

scientific article published on 10 December 2018

The human Krebs cycle 2-oxoglutarate dehydrogenase complex creates an additional source of superoxide/hydrogen peroxide from 2-oxoadipate as alternative substrate

scientific article

The mitochondrial 2-oxoadipate and 2-oxoglutarate dehydrogenase complexes share their E2 and E3 components for their function and both generate reactive oxygen species

scientific article

Transamidation of Amides and Amidation of Esters by Selective N-C(O)/O-C(O) Cleavage Mediated by Air- and Moisture-Stable Half-Sandwich Nickel(II)-NHC Complexes

scientific article published on 02 January 2021

Transamidation of N-acyl-glutarimides with amines.

scientific article

Transition-Metal-Free Activation of Amides by N-C Bond Cleavage

scientific article published on 13 December 2019

Transition-Metal-Free Esterification of Amides via Selective N-C Cleavage under Mild Conditions

scientific article published on 04 September 2018

Triflamides: Highly Reactive, Electronically Activated N-Sulfonyl Amides in Catalytic N-C(O) Amide Cross-Coupling

scientific article published on 15 February 2019

Tröger's Base Twisted Amides: High Amide Bond Twist and N-/O-Protonation Aptitude

scientific article published on 14 January 2019

Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N-C Amide Bond Activation.

scientific article published on 3 November 2016

Twisted N-Acyl-Hydantoins: Rotationally-Inverted Urea-Imides of Relevance in N-C(O) Cross-Coupling

article

Uncovering the importance of proton donors in TmI2-promoted electron transfer: facile C-N bond cleavage in unactivated amides

scientific article published on 12 June 2013

Well-Defined Palladium(II)–NHC Precatalysts for Cross-Coupling Reactions of Amides and Esters by Selective N–C/O–C Cleavage

scientific article published on 21 September 2018

[Pd(NHC)(acac)Cl]: Well-Defined, Air-Stable, and Readily Available Precatalysts for Suzuki and Buchwald-Hartwig Cross-coupling (Transamidation) of Amides and Esters by N-C/O-C Activation

scientific article published on 16 April 2019

σ N-C Bond Difunctionalization in Bridged Twisted Amides: Sew-and-Cut Activation Approach to Functionalized Isoquinolines.

scientific article published on 24 April 2017

Paulina is supported by:

About Paulina

Help