List of works - Takahiro Nishimura

Acid-catalyzed chirality-transferring intramolecular Friedel-Crafts cyclization of α-hydroxy-α-alkenylsilanes

scientific article published on 01 July 2019

Asymmetric Alkylation of N-Sulfonylbenzamides with Vinyl Ethers via C-H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes

scientific article published on 17 March 2016

Asymmetric Cyclization of N-Sulfonyl Alkenyl Amides Catalyzed by Iridium/Chiral Diene Complexes

scientific article published on 25 August 2016

Asymmetric Cyclopropanation of Alkenes with Dimethyl Diazomalonate Catalyzed by Chiral Diene–Rhodium Complexes ⬇️

scientific article published on September 24, 2010

Asymmetric addition of dimethylzinc to N-tosylarylimines catalyzed by a rhodium-diene complex toward the synthesis of chiral 1-arylethylamines

scientific article published on 01 March 2006

Asymmetric hydroarylation of vinyl ethers catalyzed by a hydroxoiridium complex: azoles as effective directing groups.

scientific article published on 17 February 2017

Asymmetric synthesis of (triaryl)methylamines by rhodium-catalyzed addition of arylboroxines to cyclic N-sulfonyl ketimines

scientific article published on 08 March 2012

Asymmetric synthesis of beta-alkynyl aldehydes by rhodium-catalyzed conjugate alkynylation

scientific article published on 01 January 2009

Asymmetric synthesis of gem-diaryl substituted cyclic sulfamidates and sulfamides by rhodium-catalyzed arylation of cyclic ketimines

scientific article published on 10 May 2013

Catalytic [3 + 2] annulation of ketimines with alkynes via C-H activation by a cationic iridium(cod) complex

scientific article published on 06 May 2014

Chiral diene-phosphine tridentate ligands for rhodium-catalyzed asymmetric cycloisomerization of 1,6-enynes

scientific article published on 21 June 2011

Chiral tetrafluorobenzobarrelene ligands for the rhodium-catalyzed asymmetric cycloisomerization of oxygen- and nitrogen-bridged 1,6-enynes

scientific article published on 01 February 2010

Chiral tetrafluorobenzobarrelenes as effective ligands for rhodium-catalyzed asymmetric 1,4-addition of arylboroxines to beta,beta-disubstituted alpha,beta-unsaturated ketones

scientific article published on 01 May 2010

Cobalt-catalyzed asymmetric 1,6-addition of (triisopropylsilyl)-acetylene to α,β,γ,δ-unsaturated carbonyl compounds

scientific article published on 09 November 2012

Cobalt-catalyzed asymmetric addition of silylacetylenes to 1,1-disubstituted allenes

scientific article published on 05 September 2013

Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes

scientific article published on 11 May 2012

Cobalt-catalyzed conjugate addition of silylacetylenes to α,β-unsaturated ketones

scientific article published on 10 August 2011

Effect of chiral diene ligands in rhodium-catalyzed asymmetric addition of arylboronic acids to α,β-unsaturated sulfonyl compounds

scientific article published on 29 May 2012

Electronic tuning of chiral diene ligands in iridium-catalyzed asymmetric 1,6-addition of arylboroxines to δ-aryl-α,β,γ,δ-unsaturated ketones

scientific article published on 08 December 2011

Enantioselective 1,4-addition of cyclopropylboronic acid catalyzed by rhodium/chiral diene complexes

scientific article published on 01 May 2015

Enantioselective Synthesis of Chiral Indane Derivatives by Rhodium-Catalyzed Addition of Arylboron Reagents to Substituted Indenes

scientific article published on 09 December 2020

Enantioselective synthesis of 3-substituted dihydrobenzofurans through iridium-catalyzed intramolecular hydroarylation

scientific article published on 05 January 2021

Formation of Carbocycles via a 1,4-Rh Shift Triggered by a Rhodium-Catalyzed Addition of Terminal Alkynes to 3,3-Diarylcyclopropenes

scientific article published on 21 May 2015

Highly selective 1,6-addition of aryl boronic acids to alpha,beta,gamma,delta-unsaturated carbonyl compounds catalyzed by an iridium complex

scientific article published on 01 August 2006

Hydroxoiridium-Catalyzed Hydroalkylation of Terminal Alkenes with Ureas by C(sp3 )-H Bond Activation

scientific article

Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N-Sulfonylbenzamides

scientific article published on 01 November 2017

Hydroxoiridium/Chiral Diene Complexes as Effective Catalysts for Asymmetric Annulation of α-Oxo- and Iminocarboxamides with 1,3-Dienes

scientific article published on 27 July 2015

Hydroxorhodium/chiral diene complexes as effective catalysts for the asymmetric arylation of 3-aryl-3-hydroxyisoindolin-1-ones

scientific article published on 10 January 2013

Iridium-Catalyzed Branch-Selective Hydroarylation of Vinyl Ethers via C-H Bond Activation.

scientific article published on 5 May 2015

Iridium-Catalyzed Hydroarylation of Conjugated Dienes via π-Allyliridium Intermediates.

scientific article published on 11 January 2018

Iridium-Catalyzed Regio- and Enantioselective Hydroarylation of Alkenyl Ethers by Olefin Isomerization.

scientific article published on 13 April 2017

Iridium-catalyzed [3 + 2] annulation of 1,3-dienes with ortho-carbonylated phenylboronic acids. A catalytic process involving regioselective 1,2-addition

scientific article published on 26 May 2007

Iridium-catalyzed [3 + 2] annulation of cyclic N-sulfonyl ketimines with 1,3-dienes via C-H activation

scientific article published on 31 January 2013

Iridium-catalyzed annulation of salicylimines with 1,3-dienes

scientific article published on 18 June 2014

Iridium-catalyzed asymmetric [3+2] annulation of aromatic ketimines with alkynes via C-H activation: unexpected inversion of the enantioselectivity induced by protic acids

scientific article published on 07 April 2016

Iridium-catalyzed asymmetric cyclization of alkenoic acids leading to γ-lactones

scientific article published on 01 September 2015

Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes providing nitriles.

scientific article published in June 2005

Iridium/chiral diene-catalyzed asymmetric 1,6-addition of arylboroxines to alpha,beta,gamma,delta-unsaturated carbonyl compounds

scientific article published on 01 June 2010

Kinetic studies prove high catalytic activity of a diene-rhodium complex in 1,4-addition of phenylboronic acid to alpha,beta-unsaturated ketones

scientific article published on 01 November 2006

Oxovanadium complex-catalyzed aerobic oxidation of propargylic alcohols

scientific article

Palladium(II)-Catalyzed Oxidation of Alcohols to Aldehydes and Ketones by Molecular Oxygen

scientific article published on 01 September 1999

Palladium-catalysed asymmetric arylation of tert-cyclobutanols via enantioselective C-C bond cleavage

scientific article published on 01 January 2002

Palladium-catalyzed asymmetric arylation, vinylation, and allenylation of tert-cyclobutanols via enantioselective C-C bond cleavage.

scientific article

Palladium-catalyzed oxidative alkynylation of alkenes via C-C bond bleavage under oxygen atmosphere.

scientific article published in August 2003

Palladium-catalyzed transformation of cyclobutanone O-benzoyloximes to nitriles via C-C bond cleavage.

scientific article

Rhodium-catalyzed aryl transfer from trisubstituted aryl methanols to alpha,beta-unsaturated carbonyl compounds

scientific article published on 01 January 2007

Rhodium-catalyzed aryl- and alkylation-oligomerization of alkynoates with organoboron reagents giving salicylates.

scientific article published on 17 February 2010

Rhodium-catalyzed asymmetric addition of arylboronic acids to 2H-chromenes leading to 3-arylchromane derivatives

scientific article published on 01 October 2019

Rhodium-catalyzed asymmetric addition of arylboronic acids to beta-phthaliminoacrylate esters toward the synthesis of beta-amino acids

scientific article published on 01 January 2010

Rhodium-catalyzed asymmetric addition of arylboronic acids to cyclic N-sulfonyl ketimines towards the synthesis of α,α-diaryl-α-amino acid derivatives

scientific article published on 01 May 2015

Rhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate esters

scientific article published on 17 August 2011

Rhodium-catalyzed asymmetric conjugate alkynylation of enones with alkynylsilanols

scientific article published on 01 August 2009

Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes.

scientific article published on 18 August 2010

Rhodium-catalyzed asymmetric cyclodimerization of oxa- and azabicyclic alkenes

scientific article published on 01 February 2007

Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes.

scientific article

Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids.

scientific article published in March 2006

Rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols: synthetic equivalent to asymmetric conjugate alkynylation of enones

scientific article published on 27 October 2007

Rhodium-catalyzed asymmetric ring-opening alkynylation of azabenzonorbornadienes

scientific article published on 19 August 2008

Rhodium-catalyzed enantioselective 1,6-addition of arylboronic acids to enynamides: asymmetric synthesis of axially chiral allenylsilanes

scientific article published on 01 September 2010

Rhodium-catalyzed rearrangement of aryl bis(alkynyl) carbinols to 3-alkynyl-1-indanones

scientific article published on 01 January 2008

Ruthenium/chloride catalytic system for conjugate addition of terminal alkynes to acrylate esters.

scientific article published on 10 May 2004

Selective H/D Exchange at Vinyl and Methylidene Groups with D2O Catalyzed by an Iridium Complex

scientific article published on 13 July 2016

Sodium tetraarylborates as effective nucleophiles in rhodium/diene-catalyzed 1,4-addition to beta,beta-disubstituted alpha,beta-unsaturated ketones: catalytic asymmetric construction of quaternary carbon stereocenters

scientific article published on 01 September 2009

Stereoselective hydroacylation of bicyclic alkenes with 2-hydroxybenzaldehydes catalyzed by hydroxoiridium/diene complexes

scientific article published on 03 August 2015

Steric tuning of silylacetylenes and chiral phosphine ligands for rhodium-catalyzed asymmetric conjugate alkynylation of enones

scientific article published on 16 January 2008

The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes

scientific article published on 17 August 2009

Vanadium-catalyzed sulfenylation of indoles and 2-naphthols with thiols under molecular oxygen

scientific article

List of works by Takahiro Nishimura

Acid-catalyzed chirality-transferring intramolecular Friedel-Crafts cyclization of α-hydroxy-α-alkenylsilanes

Asymmetric Alkylation of N-Sulfonylbenzamides with Vinyl Ethers via C-H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes

Asymmetric Cyclization of N-Sulfonyl Alkenyl Amides Catalyzed by Iridium/Chiral Diene Complexes

Asymmetric Cyclopropanation of Alkenes with Dimethyl Diazomalonate Catalyzed by Chiral Diene–Rhodium Complexes ⬇️

Asymmetric addition of dimethylzinc to N-tosylarylimines catalyzed by a rhodium-diene complex toward the synthesis of chiral 1-arylethylamines

Asymmetric hydroarylation of vinyl ethers catalyzed by a hydroxoiridium complex: azoles as effective directing groups.

Asymmetric synthesis of (triaryl)methylamines by rhodium-catalyzed addition of arylboroxines to cyclic N-sulfonyl ketimines

Asymmetric synthesis of beta-alkynyl aldehydes by rhodium-catalyzed conjugate alkynylation

Asymmetric synthesis of gem-diaryl substituted cyclic sulfamidates and sulfamides by rhodium-catalyzed arylation of cyclic ketimines

Catalytic [3 + 2] annulation of ketimines with alkynes via C-H activation by a cationic iridium(cod) complex

Chiral diene-phosphine tridentate ligands for rhodium-catalyzed asymmetric cycloisomerization of 1,6-enynes

Chiral tetrafluorobenzobarrelene ligands for the rhodium-catalyzed asymmetric cycloisomerization of oxygen- and nitrogen-bridged 1,6-enynes

Chiral tetrafluorobenzobarrelenes as effective ligands for rhodium-catalyzed asymmetric 1,4-addition of arylboroxines to beta,beta-disubstituted alpha,beta-unsaturated ketones

Cobalt-catalyzed asymmetric 1,6-addition of (triisopropylsilyl)-acetylene to α,β,γ,δ-unsaturated carbonyl compounds

Cobalt-catalyzed asymmetric addition of silylacetylenes to 1,1-disubstituted allenes

Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes

Cobalt-catalyzed conjugate addition of silylacetylenes to α,β-unsaturated ketones

Effect of chiral diene ligands in rhodium-catalyzed asymmetric addition of arylboronic acids to α,β-unsaturated sulfonyl compounds

Electronic tuning of chiral diene ligands in iridium-catalyzed asymmetric 1,6-addition of arylboroxines to δ-aryl-α,β,γ,δ-unsaturated ketones

Enantioselective 1,4-addition of cyclopropylboronic acid catalyzed by rhodium/chiral diene complexes

Enantioselective Synthesis of Chiral Indane Derivatives by Rhodium-Catalyzed Addition of Arylboron Reagents to Substituted Indenes

Enantioselective synthesis of 3-substituted dihydrobenzofurans through iridium-catalyzed intramolecular hydroarylation

Formation of Carbocycles via a 1,4-Rh Shift Triggered by a Rhodium-Catalyzed Addition of Terminal Alkynes to 3,3-Diarylcyclopropenes

Highly selective 1,6-addition of aryl boronic acids to alpha,beta,gamma,delta-unsaturated carbonyl compounds catalyzed by an iridium complex

Hydroxoiridium-Catalyzed Hydroalkylation of Terminal Alkenes with Ureas by C(sp3 )-H Bond Activation

Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N-Sulfonylbenzamides

Hydroxoiridium/Chiral Diene Complexes as Effective Catalysts for Asymmetric Annulation of α-Oxo- and Iminocarboxamides with 1,3-Dienes

Hydroxorhodium/chiral diene complexes as effective catalysts for the asymmetric arylation of 3-aryl-3-hydroxyisoindolin-1-ones

Iridium-Catalyzed Branch-Selective Hydroarylation of Vinyl Ethers via C-H Bond Activation.

Iridium-Catalyzed Hydroarylation of Conjugated Dienes via π-Allyliridium Intermediates.

Iridium-Catalyzed Regio- and Enantioselective Hydroarylation of Alkenyl Ethers by Olefin Isomerization.

Iridium-catalyzed [3 + 2] annulation of 1,3-dienes with ortho-carbonylated phenylboronic acids. A catalytic process involving regioselective 1,2-addition

Iridium-catalyzed [3 + 2] annulation of cyclic N-sulfonyl ketimines with 1,3-dienes via C-H activation

Iridium-catalyzed annulation of salicylimines with 1,3-dienes

Iridium-catalyzed asymmetric [3+2] annulation of aromatic ketimines with alkynes via C-H activation: unexpected inversion of the enantioselectivity induced by protic acids

Iridium-catalyzed asymmetric cyclization of alkenoic acids leading to γ-lactones

Iridium-catalyzed ring cleavage reaction of cyclobutanone O-benzoyloximes providing nitriles.

Iridium/chiral diene-catalyzed asymmetric 1,6-addition of arylboroxines to alpha,beta,gamma,delta-unsaturated carbonyl compounds

Kinetic studies prove high catalytic activity of a diene-rhodium complex in 1,4-addition of phenylboronic acid to alpha,beta-unsaturated ketones

Oxovanadium complex-catalyzed aerobic oxidation of propargylic alcohols

Palladium(II)-Catalyzed Oxidation of Alcohols to Aldehydes and Ketones by Molecular Oxygen

Palladium-catalysed asymmetric arylation of tert-cyclobutanols via enantioselective C-C bond cleavage

Palladium-catalyzed asymmetric arylation, vinylation, and allenylation of tert-cyclobutanols via enantioselective C-C bond cleavage.

Palladium-catalyzed oxidative alkynylation of alkenes via C-C bond bleavage under oxygen atmosphere.

Palladium-catalyzed transformation of cyclobutanone O-benzoyloximes to nitriles via C-C bond cleavage.

Rhodium-catalyzed aryl transfer from trisubstituted aryl methanols to alpha,beta-unsaturated carbonyl compounds

Rhodium-catalyzed aryl- and alkylation-oligomerization of alkynoates with organoboron reagents giving salicylates.

Rhodium-catalyzed asymmetric addition of arylboronic acids to 2H-chromenes leading to 3-arylchromane derivatives

Rhodium-catalyzed asymmetric addition of arylboronic acids to beta-phthaliminoacrylate esters toward the synthesis of beta-amino acids

Rhodium-catalyzed asymmetric addition of arylboronic acids to cyclic N-sulfonyl ketimines towards the synthesis of α,α-diaryl-α-amino acid derivatives

Rhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate esters

Rhodium-catalyzed asymmetric conjugate alkynylation of enones with alkynylsilanols

Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes.

Rhodium-catalyzed asymmetric cyclodimerization of oxa- and azabicyclic alkenes

Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes.

Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids.

Rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols: synthetic equivalent to asymmetric conjugate alkynylation of enones

Rhodium-catalyzed asymmetric ring-opening alkynylation of azabenzonorbornadienes

Rhodium-catalyzed enantioselective 1,6-addition of arylboronic acids to enynamides: asymmetric synthesis of axially chiral allenylsilanes

Rhodium-catalyzed rearrangement of aryl bis(alkynyl) carbinols to 3-alkynyl-1-indanones

Ruthenium/chloride catalytic system for conjugate addition of terminal alkynes to acrylate esters.

Selective H/D Exchange at Vinyl and Methylidene Groups with D2O Catalyzed by an Iridium Complex

Sodium tetraarylborates as effective nucleophiles in rhodium/diene-catalyzed 1,4-addition to beta,beta-disubstituted alpha,beta-unsaturated ketones: catalytic asymmetric construction of quaternary carbon stereocenters

Stereoselective hydroacylation of bicyclic alkenes with 2-hydroxybenzaldehydes catalyzed by hydroxoiridium/diene complexes

Steric tuning of silylacetylenes and chiral phosphine ligands for rhodium-catalyzed asymmetric conjugate alkynylation of enones

The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes

Vanadium-catalyzed sulfenylation of indoles and 2-naphthols with thiols under molecular oxygen