Search filters

List of works by Juan A. Casares

14-Electron T-shaped [PdRXL] complexes: evidence or illusion? Mechanistic consequences for the stille reaction and related processes

scientific article published on 01 November 2002

19F NMR in organometallic chemistry

A Chelate with Conformational Memory?

scientific article published on 01 February 1999

A Convenient Quick Synthesis of SnBu2RCl Derivatives

Anionic platinum complexes with 2-pyridylphosphines as ligands for rhodium: synthesis of zwitterionic Pt-Rh organometallic compounds

scientific article

Bimetallic catalysis using transition and Group 11 metals: an emerging tool for C-C coupling and other reactions

scientific article published on 20 January 2012

C-C reductive elimination in palladium complexes, and the role of coupling additives. A DFT study supported by experiment

scientific article published in March 2009

Cationic Intermediates in the Pd-Catalyzed Negishi Coupling. Kinetic and Density Functional Theory Study of Alternative Transmetalation Pathways in the Me–Me Coupling of ZnMe2andtrans-[PdMeCl(PMePh2)2]

scientific article published on 08 August 2011

Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C-AuI Bonds in [AuRL] Complexes

scientific article published on 14 August 2018

Conformational Mobility in Chelated Square-Planar Rh, Ir, Pd, and Pt Complexes

article

Conformational preferences driven by the C-methyl substituent in chelated o-diphenylphosphino-alpha-methyl-N,N-dimethylbenzylamine rhodium complexes

scientific article

Cross Alkyl–Aryl versus Homo Aryl–Aryl Coupling in Palladium-Catalyzed Coupling of Alkyl–Gold(I) and Aryl–Halide

Diamine-catalyzed addition of ZnEt2 to PhC(O)CF3 : two mechanisms and autocatalytic asymmetric enhancement

scientific article published on 15 September 2014

Dramatic mechanistic switch in Sn/Au(I) group exchanges: transmetalation vs. oxidative addition.

scientific article published in March 2016

Efficient rhodium catalysts for the hydrogenolysis of thiophenic molecules in homogeneous phase

Efficient silylformylation of alkynes catalyzed by rhodium complexes with P,N donor ligands

Enthalpy of ligand substitution in cis organopalladium complexes with monodentate ligands

scientific article published on 27 August 2009

In Situ Generation of ArCu from CuF2 Makes Coupling of Bulky Aryl Silanes Feasible and Highly Efficient

scientific article published on 19 February 2016

Insertion of iridium into C-H and C-S bonds of 2,5-dimethylthiophene 2-methylbenzothiophene and 4,6-dimethyldibenzothiophene

scholarly article by Claudio Bianchini et al published August 1997 in Journal of Organometallic Chemistry

Insights into the mechanism of the Negishi reaction: ZnRX versus ZnR2 reagents

scientific article

Mechanism of the Uncatalyzed Dissociative Cis-Trans Isomerization of Bis(pentafluorophenyl)bis(tetrahydrothiophene): A Refinement

scientific article published on 01 August 1998

Metal Activation of Dibenzo[b,d]thiophene. Reactivity of the C-S Insertion Product [MeC(CH2PPh2)3]IrH(.eta.2(C,S)-C12H8S)

Neutral and Cationic Complexes with P-Bonded 2-Pyridylphosphines as N-Donor Ligands toward Rhodium. Electrical Charge vs Steric Hindrance on the Conformational Control

scientific article published on 01 August 2006

Observation of a Hidden Intermediate in the Stille Reaction. Study of the Reversal of the Transmetalation Step

scientific article published on 18 July 2008

Observation of a Slow Dissociative Process in Palladium(II) Complexes

scholarly article by Juan A. Casares et al published June 1995 in Organometallics

Organometallic Nucleophiles and Pd: What Makes ZnMe2 Different? Is Au Like Zn?

Palladium Catalysts for Norbornene Polymerization. A Study by NMR and Calorimetric Methods

Rhodium Complexes with the Chelating and Binucleating Ligands P(CH2CH2Py)nPh3-n(Py = 2-Pyridyl;n= 1, 2): Structures and Fluxional Behavior

scientific article published on 01 February 2000

Speciation of ZnMe2, ZnMeCl, and ZnCl2 in Tetrahydrofuran (THF), and Its Influence on Mechanism Calculations of Catalytic Processes

Stable Nickel Catalysts for Fast Norbornene Polymerization: Tuning Reactivity

scholarly article by Juan A. Casares et al published October 2005 in European Journal of Inorganic Chemistry

Stille Coupling of Alkynyl Stannane and Aryl Iodide, a Many-Pathways Reaction: The Importance of Isomerization

article published in 2011

Stille coupling involving bulky groups feasible with gold cocatalyst

scientific article published on 22 January 2013

Strong Metallophilic Interactions in the Palladium Arylation by Gold Aryls

scientific article published on 04 April 2012

Study of the Replacement of Weak Ligands on Square-Planar Organometallic Nickel(II) Complexes. Organo-Nickel Aquacomplexes

scientific article published on 01 February 2007

The Negishi Catalysis: Full Study of the Complications in the Transmetalation Step and Consequences for the Coupling Products

The decisive role of ligand metathesis in Au/Pd bimetallic catalysis

scientific article published on 11 July 2013

Paulina is supported by:

About Paulina

Help