List of works - Claude Y Legault

CalcUS: An Open-Source Quantum Chemistry Web Platform

scientific article published in 2022

Catalytic asymmetric hydrogenation of N-iminopyridinium ylides: expedient approach to enantioenriched substituted piperidine derivatives.

scientific article published in June 2005

Catalytic enantioselective α-tosyloxylation of ketones using iodoaryloxazoline catalysts: insights on the stereoinduction process

scientific article published on 12 December 2012

Complexation promoted additions to N-benzoyliminopyridinium ylides. A novel and highly regioselective approach to polysubstituted piperidines.

scientific article

Copper-catalyzed O-arylation of N-protected 1,2-aminoalcohols using functionalized trivalent organobismuth reagents

scientific article published on 01 February 2015

Denitrogenative Hydrotrifluoromethylation of Benzaldehyde Hydrazones: Synthesis of (2,2,2-Trifluoroethyl)arenes

scientific article published on 07 August 2019

Diazirines as potent electrophilic nitrogen sources: application to the synthesis of pyrazoles

scientific article published on 30 December 2013

Enabling nucleophilic substitution reactions of activated alkyl fluorides through hydrogen bonding.

scientific article published on 24 April 2013

Enantioselective Iodine(III)-Mediated Synthesis of α-Tosyloxy Ketones: Breaking the Selectivity Barrier.

scientific article published on 17 September 2015

Experimental and Theoretical Quantification of the Lewis Acidity of Iodine(III) Species.

scientific article

Formal intramolecular (4 + 1)-cycloaddition of dialkoxycarbenes: control of the stereoselectivity and a mechanistic portrait

scientific article published on 23 March 2012

Highly efficient synthesis of O-(2,4-dinitrophenyl)hydroxylamine. Application to the synthesis of substituted N-benzoyliminopyridinium ylides.

scientific article published in September 2003

Iodine(III)-Mediated Contraction of 3,4-Dihydropyranones: Access to Polysubstituted γ-Butyrolactones

scientific article published on 24 June 2019

Iodine(III)-Mediated Oxidative Hydrolysis of Haloalkenes: Access to α-Halo Ketones by a Release-and-Catch Mechanism.

scientific article published on 17 December 2015

Lewis Acidity Scale of Diaryliodonium Ions toward Oxygen, Nitrogen, and Halogen Lewis Bases

scientific article published on 03 March 2020

Mechanistic insights on the iodine(III)-mediated α-oxidation of ketones

scientific article published on 26 June 2015

Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes

scientific article published on 17 December 2015

Origin of chemoselectivity in N-heterocyclic carbene catalyzed cross-benzoin reactions: DFT and experimental insights.

scientific article published on 18 March 2015

Origins of differences in reactivities of alkenes, alkynes, and allenes in [Rh(CO)2Cl]2-catalyzed (5 + 2) cycloaddition reactions with vinylcyclopropanes

scientific article published on 2 February 2008

Photocatalytic degradation of carbamazepine and three derivatives using TiO₂ and ZnO: effect of pH, ionic strength, and natural organic matter.

scientific article published on 11 January 2014

Structure and reactivity of a new anionic N-heterocyclic carbene silver(I) complex

scientific article published on 01 July 2005

Study of the Reactivity of [Hydroxy(tosyloxy)iodo]benzene Toward Enol Esters to Access α-Tosyloxy Ketones

scientific article published on 22 June 2015

Synthesis and characterization of combined cross-linked laccase and tyrosinase aggregates transforming acetaminophen as a model phenolic compound in wastewaters.

scientific article

The Acid-Free Cyclopropanol-Minisci Reaction Reveals the Catalytic Role of Silver-Pyridine Complexes

scientific article published on 19 January 2018

Theoretical bond dissociation energies of halo-heterocycles: trends and relationships to regioselectivity in palladium-catalyzed cross-coupling reactions

scientific article published on May 2009

Tunable Approach for the Stereoselective Synthesis of 1-C-Diethylphosphono(difluoromethyl) Iminosugars as Glycosyl Phosphate Mimics

scientific article

List of works by Claude Y Legault

CalcUS: An Open-Source Quantum Chemistry Web Platform

Catalytic asymmetric hydrogenation of N-iminopyridinium ylides: expedient approach to enantioenriched substituted piperidine derivatives.

Catalytic enantioselective α-tosyloxylation of ketones using iodoaryloxazoline catalysts: insights on the stereoinduction process

Complexation promoted additions to N-benzoyliminopyridinium ylides. A novel and highly regioselective approach to polysubstituted piperidines.

Copper-catalyzed O-arylation of N-protected 1,2-aminoalcohols using functionalized trivalent organobismuth reagents

Denitrogenative Hydrotrifluoromethylation of Benzaldehyde Hydrazones: Synthesis of (2,2,2-Trifluoroethyl)arenes

Diazirines as potent electrophilic nitrogen sources: application to the synthesis of pyrazoles

Enabling nucleophilic substitution reactions of activated alkyl fluorides through hydrogen bonding.

Enantioselective Iodine(III)-Mediated Synthesis of α-Tosyloxy Ketones: Breaking the Selectivity Barrier.

Experimental and Theoretical Quantification of the Lewis Acidity of Iodine(III) Species.

Formal intramolecular (4 + 1)-cycloaddition of dialkoxycarbenes: control of the stereoselectivity and a mechanistic portrait

Highly efficient synthesis of O-(2,4-dinitrophenyl)hydroxylamine. Application to the synthesis of substituted N-benzoyliminopyridinium ylides.

Iodine(III)-Mediated Contraction of 3,4-Dihydropyranones: Access to Polysubstituted γ-Butyrolactones

Iodine(III)-Mediated Oxidative Hydrolysis of Haloalkenes: Access to α-Halo Ketones by a Release-and-Catch Mechanism.

Lewis Acidity Scale of Diaryliodonium Ions toward Oxygen, Nitrogen, and Halogen Lewis Bases

Mechanistic insights on the iodine(III)-mediated α-oxidation of ketones

Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes

Origin of chemoselectivity in N-heterocyclic carbene catalyzed cross-benzoin reactions: DFT and experimental insights.

Origins of differences in reactivities of alkenes, alkynes, and allenes in [Rh(CO)2Cl]2-catalyzed (5 + 2) cycloaddition reactions with vinylcyclopropanes

Photocatalytic degradation of carbamazepine and three derivatives using TiO₂ and ZnO: effect of pH, ionic strength, and natural organic matter.

Structure and reactivity of a new anionic N-heterocyclic carbene silver(I) complex

Study of the Reactivity of [Hydroxy(tosyloxy)iodo]benzene Toward Enol Esters to Access α-Tosyloxy Ketones

Synthesis and characterization of combined cross-linked laccase and tyrosinase aggregates transforming acetaminophen as a model phenolic compound in wastewaters.

The Acid-Free Cyclopropanol-Minisci Reaction Reveals the Catalytic Role of Silver-Pyridine Complexes

Theoretical bond dissociation energies of halo-heterocycles: trends and relationships to regioselectivity in palladium-catalyzed cross-coupling reactions

Tunable Approach for the Stereoselective Synthesis of 1-C-Diethylphosphono(difluoromethyl) Iminosugars as Glycosyl Phosphate Mimics