List of works - Hendrik Klare

Asymmetric Ring-Closing Metathesis with a Twist

scientific article published on 01 January 2009

Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF3 Does What B(C6 F5 )3 Cannot Do!

scientific article

Brønsted Acid-Promoted Formation of Stabilized Silylium Ions for Catalytic Friedel-Crafts C-H Silylation

scientific article published on 15 June 2016

C(sp3)-F bond activation of CF3-substituted anilines with catalytically generated silicon cations: spectroscopic evidence for a hydride-bridged Ru-S dimer in the catalytic cycle.

scientific article published on 15 January 2013

Catalytic 1,4-selective hydrosilylation of pyridines and benzannulated congeners.

scientific article published in August 2013

Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions

scientific article published on 23 October 2019

Catalytic Friedel-Crafts C-H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes

scientific article published on 28 February 2017

Catalytic dehydrogenative Si-N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base.

scientific article published in February 2013

Characterization of hydrogen-substituted silylium ions in the condensed phase

scientific article published on 01 July 2019

Chiral Recognition with Silicon-Stereogenic Silanes: Remarkable Selectivity Factors in the Kinetic Resolution of Donor-Functionalized Alcohols

scientific article published on 01 January 2007

Cleavage of Unactivated Si−C(sp3 ) Bonds with Reed's Carborane Acids: Formation of Known and Unknown Silylium Ions

scientific article published on 19 June 2018

Cooperative Catalysis at Metal-Sulfur Bonds.

scientific article published on 13 April 2017

Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism

scientific article published on 22 February 2011

Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative SiN Coupling

scientific article published on 27 May 2014

Efficient Biocatalytic Synthesis of Dihalogenated Purine Nucleoside Analogues Applying Thermodynamic Calculations

scientific article published on 19 February 2020

Electrophilic Formylation of Arenes by Silylium Ion Mediated Activation of Carbon Monoxide

scientific article published on 30 May 2018

Friedel-Crafts-Type Intermolecular C-H Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts.

scientific article published on 28 January 2016

Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex

scientific article published on 06 May 2014

Mechanism of the cooperative Si-H bond activation at Ru-S bonds

scientific article published on 18 May 2015

Oxidative Fragmentations and Skeletal Rearrangements of Oxindole Derivatives.

scientific article published on 14 February 2017

Planar Chiral, Ferrocene-Stabilized Silicon Cations.

scientific article published in March 2016

Potassium tert-Butoxide-Catalyzed Dehydrogenative C-H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study.

scientific article published on 12 April 2017

Si-H Bond Activation with Bullock's Cationic Tungsten(II) Catalyst: CO as Cooperating Ligand

scientific article published on 15 November 2019

Silylium ions in catalysis

scientific article published on 19 April 2010

Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes

scientific article published on 17 January 2020

Single-Electron Transfer Reactions in Frustrated and Conventional Silylium Ion/Phosphane Lewis Pairs

scientific article published on 18 October 2018

Taming the Silylium Ion for Low-Temperature Diels-Alder Reactions