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List of works by Enrique Oñate

(NHC)Palladium Complexes from Hydroxy-Functionalized Imidazolium Salts as Catalyst for the Microwave-Accelerated Fluorine-Free Hiyama Reaction

scientific article published on 20 October 2011

2-Azetidinones as Precursors of Pincer Ligands: Preparation, Structure, and Spectroscopic Properties of CC'N-Osmium Complexes.

scientific article published on 29 October 2015

A Capped Octahedral MHC6 Compound of a Platinum Group Metal

scientific article published on 28 April 2016

Amide-Directed Formation of Five-Coordinate Osmium Alkylidenes from Alkynes

scientific article published on 31 December 2015

Ammonia Borane Dehydrogenation Promoted by a Pincer-Square-Planar Rhodium(I) Monohydride: A Stepwise Hydrogen Transfer from the Substrate to the Catalyst

scientific article published in July 2016

An Entry to Stable Mixed Phosphine-Osmium-NHC Polyhydrides

scientific article published on 04 May 2016

Arene Osmium Complexes with Ethacrynic Acid-Modified Ligands: Synthesis, Characterization, and Evaluation of Intracellular Glutathione S-Transferase Inhibition and Antiproliferative Activity

scholarly article by Gabriele Agonigi et al published 25 March 2016 in Organometallics

Aromatic C−H Bond Activation of 2-Methylpyridine Promoted by an Osmium(VI) Complex: Formation of an η2(N,C)-Pyridyl Derivative

scientific article published on 8 December 2008

Aromatic Osmacyclopropenefuran Bicycles and Their Relevance for the Metal-Mediated Hydration of Functionalized Allenes

scientific article published on 04 October 2016

Aromatic diosmatricyclic nitrogen-containing compounds

scientific article published on 12 August 2008

Assembly of an allenylidene ligand, a terminal alkyne, and an acetonitrile molecule: formation of osmacyclopentapyrrole derivatives

scientific article published on 01 March 2006

Azole Assisted C–H Bond Activation Promoted by an Osmium-Polyhydride: Discerning between N and NH

scientific article published on 5 May 2015

B-H activation and H-H formation: two consecutive heterolytic processes on an osmium-hydrogensulfide bond.

scientific article

Base-Free and Acceptorless Dehydrogenation of Alcohols Catalyzed by an Iridium Complex Stabilized by a N,N,N-Osmaligand

scientific article published on 9 August 2018

Behavior of OsH2Cl2(PiPr3)2in Acetonitrile: The Importance of the Small Details

scientific article published on 9 March 2009

Borinium cations as sigma-B-H ligands in osmium complexes.

scientific article published in April 2010

C(sp2)−H Activation of RCHE−py (E = CH, N) and RCHCHC(O)R‘ Substrates Promoted by a Highly Unsaturated Osmium−Monohydride Complex

scientific article published in March 2005

C-H activations at iridium(I) square-planar complexes promoted by a fifth ligand

scientific article published in December 2005

C-H bond activation and subsequent C-C bond formation promoted by osmium: 2-vinylpyridine-acetylene couplings

scientific article published on 01 April 2006

CCC–Pincer–NHC Osmium Complexes: New Types of Blue-Green Emissive Neutral Compounds for Organic Light-Emitting Devices (OLEDs)

scientific article published on 17 September 2014

Catalytic Cyclization of o-Alkynyl Phenethylamines via Osmacyclopropene Intermediates: Direct Access to Dopaminergic 3-Benzazepines

scientific article published on 14 September 2015

Chelated Assisted Metal-Mediated N–H Bond Activation of β-Lactams: Preparation of Irida-, Rhoda-, Osma-, and Ruthenatrinems

scientific article published in April 2014

Cleavage of both C(sp3)-C(sp2) bonds of alkylidenecyclopropanes: formation of ethylene-osmium-vinylidene complexes.

scientific article published in January 2010

Coordination and Rupture of Methyl C(sp3)−H Bonds in Osmium−Polyhydride Complexes with δ Agostic Interaction

scientific article published in October 2007

Cycloosmathioborane Compounds: Other Manifestations of the Hückel Aromaticity

scientific article published on 30 January 2019

Cβ(sp2)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carbyne, and NH-Tautomerized α-Substituted Pyridine Ligands

scientific article published on 22 September 2008

Cβ−H Activation of Aldehydes Promoted by an Osmium Complex

scientific article published in December 2004

C–H Bond Activation Reactions in Ketones and Aldehydes Promoted by POP-Pincer Osmium and Ruthenium Complexes

scholarly article by Joaquín Alós et al published 24 September 2015 in Organometallics

C−C Bond Activation of the NHC Ligand of an Osmium−Amido Complex

scientific article published on 25 October 2010

Dehydrative cyclization of alkynals: vinylidene complexes with the Cβ incorporated into unsaturated five- or six-membered rings

scientific article published on 02 August 2011

Dehydrogenation of Formic Acid Promoted by a Trihydride-Hydroxo-Osmium(IV) Complex: Kinetics and Mechanism

scholarly article by Miguel A. Esteruelas et al published 22 October 2018 in ACS Catalysis

Dihydride versus Elongated Dihydrogen in [H2Os(κ2-O2CCH3)L(PiPr3)2]+Complexes: Influence of the L Ligand

scientific article published in March 2002

Dioxygen activation by an osmium-dihydride: preparation and characterization of a d4 square-planar complex

scientific article published on 01 November 2003

Direct Access to POP-Type Osmium(II) and Osmium(IV) Complexes: Osmium a Promising Alternative to Ruthenium for the Synthesis of Imines from Alcohols and Amines

scientific article published on 9 May 2011

Direct C-H Borylation of Arenes Catalyzed by Saturated Hydride-Boryl-Iridium-POP Complexes: Kinetic Analysis of the Elemental Steps

scientific article published on 19 May 2020

Displacement of Phenyl and Styryl Ligands by Benzophenone Imine and 2-Vinylpyridine on Ruthenium and Osmium

scientific article published in June 2006

Electronic Communication in Binuclear Osmium- and Iridium-Polyhydrides

scientific article published on 5 February 2021

Elongated Dihydrogen versus Compressed Dihydride in Osmium Complexes.

scientific article

Elongated σ-Borane versus σ-Borane in Pincer–POP–Osmium Complexes

scholarly article by Miguel A. Esteruelas et al published 13 June 2017 in Organometallics

Evidence for a Bis(Elongated σ)-Dihydrideborate Coordinated to Osmium.

scientific article published on 2 April 2018

Formation of Unusual Iridabenzene and Metallanaphthalene Containing Electron-Withdrawing Substituents

scientific article published on 01 August 2003

From tetrahydroborate- to aminoborylvinylidene-osmium complexes via alkynyl-aminoboryl intermediates

scientific article published on 27 January 2011

Homo- and hetero-binuclear complexes containing the anion [Rh(C5Me5){PO(OMe)2}2(pyrazolate)]–as ligand. Crystal structure of [(C5Me5)Rh{µ-PO(OMe)2}2(µ-C3H3N2)-Ru(C6H6)]ClO4·CH2Cl2

Hydride-alkenylcarbyne to alkenylcarbene transformation in bisphosphine-osmium complexes.

scientific article published in August 2005

Influence of the Anion of the Salt Used on the Coordination Mode of an N-Heterocyclic Carbene Ligand to Osmium

scientific article published in December 2007

Insertion of Unsaturated C-C Bonds into the O-H Bond of an Iridium(III)-Hydroxo Complex: Formation of Phosphorescent Emitters with an Asymmetrical β-Diketonate Ligand

scientific article published on 15 October 2020

Iridium-Promoted B-B Bond Activation: Preparation and X-ray Diffraction Analysis of a mer-Tris(boryl) Complex

scientific article published on 27 March 2019

Kinetic Analysis and Sequencing of Si-H and C-H Bond Activation Reactions: Direct Silylation of Arenes Catalyzed by an Iridium-Polyhydride

scientific article published on 30 October 2020

Mechanistic Insight into the Facilitation of β-Lactam Fragmentation through Metal Assistance

Monocationic trihydride and dicationic dihydride-dihydrogen and bis(dihydrogen) osmium complexes containing cyclic and acyclic triamine ligands: influence of the N-Os-N angles on the hydrogen-hydrogen interactions.

scientific article published in March 2009

Multiple C−H Bond Activation of Phenyl-Substituted Pyrimidines and Triazines Promoted by an Osmium Polyhydride: Formation of Osmapolycycles with Three, Five, and Eight Fused Rings

scientific article published on 22 February 2010

N-h and N-C bond activation of pyrimidinic nucleobases and nucleosides promoted by an osmium polyhydride

scientific article published on 09 May 2012

NH-Tautomerization of Quinolines and 2-Methylpyridine Promoted by a Hydride-Iridium(III) Complex: Importance of the Hydride Ligand

scientific article published on 13 April 2009

Nazarov type cyclization on an osmium-dienylcarbene complex

scientific article published on 01 February 2009

One-Pot Dehydrogenative Addition of Isopropyl to Alkynes Promoted by Osmium: Formation of γ-(η3-Allyl)-α-Alkenylphosphine Derivatives Starting from a Dihydride−Dihydrogen−Triisopropylphosphine Complex

scientific article published in April 2007

Osmium Hydride Acetylacetonate Complexes and Their Application in Acceptorless Dehydrogenative Coupling of Alcohols and Amines and for the Dehydrogenation of Cyclic Amines

scientific article published on 3 August 2017

Osmium NHC Complexes from Alcohol-Functionalized Imidazoles and Imidazolium Salts

scientific article published on 28 March 2011

Osmium(II) Complexes Containing a Dianionic CCCC-Donor Tetradentate Ligand

scientific article published on 30 November 2016

Osmium-Catalyzed Allylic Alkylation

scholarly article by Miguel A. Esteruelas et al published 13 October 2008 in Organometallics

Osmium-Centered Oxetylidene: Formation and Cleavage

scholarly article by María Batuecas et al published 28 November 2012 in Organometallics

Osmium−Allenylidene Complexes Containing an N-Heterocyclic Carbene Ligand

scientific article published in February 2008

Oxidative Addition of Group 14 Element Hydrido Compounds to OsH(2)(eta(2)-CH(2)=CHEt)(CO)(P(i)Pr(3))(2): Synthesis and Characterization of the First Trihydrido-Silyl, Trihydrido-Germyl, and Trihydrido-Stannyl Derivatives of Osmium(IV)

scientific article published on 01 February 1996

POP-pincer osmium-polyhydrides: head-to-head (Z)-dimerization of terminal alkynes

scientific article published on 26 April 2013

POP-pincer ruthenium complexes: d(6) counterparts of osmium d(4) species.

scientific article published on 9 January 2014

Phosphorescent Iridium(III) Complexes with a Dianionic C,C',N,N'-Tetradentate Ligand

scientific article published on 28 August 2020

Preparation and Photophysical Properties of Bis(tridentate) Iridium(III) Emitters: Pincer Coordination of 2,6-Di(2-pyridyl)phenyl

scientific article published on 02 March 2020

Preparation and characterization of novel Os-diolefin dimers: new entry to Os-cyclooctadiene complexes

scientific article published on 01 December 2006

Preparation of Half-Sandwich Osmium-Allyl Complexes by Consecutive C−C Bond Formation and C−H Bond Activation Reactions

scientific article published in January 2006

Preparation of Phosphorescent Iridium(III) Complexes with a Dianionic C,C,C,C-Tetradentate Ligand

scientific article published on 14 March 2018

Preparation of Phosphorescent Osmium(IV) Complexes with N,N′,C- and C,N,C′-Pincer Ligands

scientific article published on 18 April 2017

Preparation of Tris-Heteroleptic Iridium(III) Complexes Containing a Cyclometalated Aryl-N-Heterocyclic Carbene Ligand

scientific article published on 23 August 2018

Preparation, Spectroscopic Characterization, X-ray Structure, and Theoretical Investigation of Hydride−, Dihydrogen−, and Acetone−OsTp Complexes: A Hydridotris(pyrazolyl)borate−Cyclopentadienyl Comparison

scientific article published in August 2007

Reaction of a Cationic Osmium(IV) Dihydride with Ethylene: Formation and Structure of the Novel Tetraethylene Dimer Complex [{(PiPr3)(η2-C2H4)2Os}2(μ-OH)2(μ-O2CCH3)]BF4

scientific article published in August 2000

Reactions of New Osmium−Dihydride Complexes with Terminal Alkynes: Metallacyclopropene versus Metal−Carbyne. Influence of the Alkyne Substituent

scholarly article by María L. Buil et al published November 1999 in Organometallics

Reactions of an Osmium(IV)-Hydroxo Complex with Amino-Boranes: Formation of Boroxide Derivatives

scholarly article by Antonio Antiñolo et al published 21 November 2018 in Organometallics

Redox Isomerization of Allylic Alcohols Catalyzed by Osmium and Ruthenium Complexes Containing a Cyclopentadienyl Ligand with a Pendant Amine or Phosphoramidite Group: X-ray Structure of an η3-1-Hydroxyallyl-Metal-Hydride Intermediate

scholarly article by María Batuecas et al published 10 May 2010 in Organometallics

Reduction and C(sp2)−H Bond Activation of Ketones Promoted by a Cyclopentadienyl-Osmium- Dihydride-Dihydrogen Complex

scientific article published in November 2005

Reduction of Benzonitriles via Osmium-Azavinylidene Intermediates Bearing Nucleophilic and Electrophilic Centers

scientific article published on 19 June 2019

Ruthenium Hydroxycarbenes as Key Intermediates in Cycloisomerization and Decarbonylative Cyclization of Terminal Alkynals

Ruthenium-catalyzed (2 + 2) intramolecular cycloaddition of allenenes

scientific article published on 28 April 2011

Sequential and selective hydrogenation of the C(alpha)-C(beta) and M-C(alpha) double bonds of an allenylidene ligand coordinated to osmium: new reaction patterns between an allenylidene complex and alcohols

scientific article published on 20 June 2007

Sequential protonation and methylation of a hydride-osmium complex containing a cyclopentadienyl ligand with a pendant amine group.

scientific article published in May 2005

Seven-Coordinate Dihydrido Complex OsH2(κ2-O2CCH3){κ1-OC(O)CH3}(PiPr3)2as Precursor of New Organometallic Compounds Containing Unsaturated η1-Carbon Ligands

scientific article published in September 1998

Square-Planar Alkylidyne-Osmium and Five-Coordinate Alkylidene-Osmium Complexes: Controlling the Transformation from Hydride-Alkylidyne to Alkylidene

scientific article published on 21 July 2016

Stoichiometric and Catalytic Deuteration of Pyridine and Methylpyridines by H/D Exchange with Benzene-d6Promoted by an Unsaturated Osmium Tetrahydride Species

scientific article published on 13 July 2009

Synthesis of Hydrido−Vinylidene and Hydrido−Carbyne Osmium Complexes Containing Pyrazole: New Examples of N−H···Y (Y = N, F, Cl) Hydrogen Bonds

scientific article published in August 1999

The Allenylidene Complex [Ru(η5-C5H5)(CCCPh2)(CO)(PiPr3)]BF4as a Precursor of Novel Pyrido[1,2-a]pyrimidinyl and 1,3-Thiazinyl Complexes

scientific article published in October 2000

The Dihydride−Osmium(IV) Complex [OsH2(κ2-O2CCH3)(H2O)(PiPr3)2]BF4 as a Precursor for Carbon−Carbon Coupling Reactions

scientific article published in November 2000

Thermally Activated Site Exchange and Quantum Exchange Coupling Processes in Unsymmetrical Trihydride Osmium Compounds

scientific article published on 01 April 1999

Tuning the Nature and Formation of Bis(dihydrogen)–Osmium Species

scientific article published on 30 January 2018

Understanding the formation of N-H tautomers from alpha-substituted pyridines: tautomerization of 2-ethylpyridine promoted by osmium

scientific article published on 16 August 2007

[H(EtOH)2][{OsCl(η4-COD)}2(μ-H)(μ-Cl)2] as an Intermediate for the Preparation of [OsCl2(COD)]xand Its Activity as an Ionic Hydrogenation and Etherification Catalyst

mer, fac, and Bidentate Coordination of an Alkyl-POP Ligand in the Chemistry of Nonclassical Osmium Hydrides.

scientific article

β-Borylalkenyl Z–E Isomerization in Rhodium-Mediated Diboration of Nonfunctionalized Internal Alkynes

scientific article published on 14 June 2018

η1 -Arene Complexes as Intermediates in the Preparation of Molecular Phosphorescent Iridium(III) Complexes.

scientific article published on 12 September 2017

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