List of works - Humberto Rodríguez-Solla

A Convenient Samarium-Promoted Synthesis of Aliphatic (E)-Nitroalkenes under Mild Conditions†

scientific article published on 06 June 2007

A Convenient Synthesis of (E)-α,β-Unsaturated Esters with Total Stereoselectivity Promoted by Catalytic Samarium Diiodide

Addition reactions of chloro- or iodomethyllithium to imines. Synthesis of enantiopure aziridines and beta-chloroamines

scientific article published in March 2009

Addition reactions of iodomethyllithium to imines. A direct and efficient synthesis of aziridines and enantiopure amino aziridines

scientific article published on 13 September 2008

An Efficient Catalytic Chromium-Mediated Iodocyclopropanation Reaction: Stereoselective Synthesis of Iodocyclopropanecarboxamides

Asymmetric Construction of Quaternary Stereocenters: Synthesis of Enantiopure Amino Acid-Based Tricyclic α,β-Enones through an ipso-Friedel-Crafts/Michael Addition Cascade

article

Asymmetric conjugate reductions with samarium diiodide: asymmetric synthesis of (2S,3R)- and (2S,3S)-[2-2H,3-2H]-leucine-(S)-phenylalanine dipeptides and (2S,3R)-[2-(2)H,3-2H]-phenylalanine methyl ester.

scientific article published on 17 March 2005

Asymmetric synthesis and applications of beta-amino Weinreb amides: asymmetric synthesis of (S)-coniine.

scientific article

Asymmetric synthesis of 3,4-anti- and 3,4-syn-substituted aminopyrrolidines via lithium amide conjugate addition

scientific article published on 17 May 2007

Aza-Reformatsky Reaction Promoted by Catalytic Samarium Diiodide: Synthesis of β-Amino Esters or Amides

Beta-elimination reactions by using samarium diiodide

scientific article

Chromium-Mediated Stereoselective Synthesis of Carbohydrate-Derived (E)-α,β-Unsaturated Esters or Amides

scientific article published on 07 June 2011

Complete stereospecific cyclopropanation of alpha,beta-unsaturated amides promoted by Sm/CH2I2.

scientific article published in June 2002

CrCl2-promoted stereospecific and stereoselective alkyl- and silylcyclopropanation of alpha,beta-unsaturated amides

scientific article published on 17 April 2008

Diastereoselective conjugate reduction with samarium diiodide: asymmetric synthesis of methyl (2S,3R)-N-acetyl-2-amino-2,3-dideuterio-3-phenylpropionate

scientific article published on 08 September 2004

Direct Aldol Reactions Catalyzed by a Heterogeneous Guanidinium Salt/Proline System under Solvent-Free Conditions‡

scientific article published on 13 May 2011

Efficient Addition Reaction of Bromonitromethane to Aldehydes Catalyzed by NaI: A New Route to 1-Bromo-1-nitroalkan-2-ols under Very Mild Conditions

article

Efficient Nitro-Aldol Reaction Using SmI2: A New Route to Nitro Alcohols under Very Mild Conditions

scientific article published on 01 September 2006

General Preparation of 1-Substituted (E)-1,3-Dienes under Mild Conditions

General, stereoselective synthesis of (Z)-beta,gamma-unsaturated nitriles promoted by samarium diiodide

scientific article published on 23 September 2008

Highly Enantioselective Proline-Catalysed Direct Aldol Reaction of Chloroacetone and Aromatic Aldehydes

scientific article published on 20 March 2012

Highly Stereoselective Halocyclopropanation of α,β-Unsaturated Amides

scholarly article by José M. Concellón et al published September 2009 in Advanced Synthesis & Catalysis

Indium-Mediated Aza-Henry Reaction of Imines: Access to 2-Nitroamines

Lithium amide conjugate addition for the asymmetric synthesis of 3-aminopyrrolidines

scientific article published on 18 May 2006

Metal-Mediated Debromination of gem-Dibromoalkenes under Mild Conditions

Modern Synthetic Methods for the Stereoselective Construction of 1,3-Dienes

scientific article published on 06 January 2021

Ohmic Heating and Ionic Liquids in Combination for the Indium-Promoted Synthesis of 1-Halo Alkenyl Compounds: Applications to Pd-Catalysed Cross-Coupling Reactions

Photoinduced metalation of nonactivated C-Cl bonds with samarium diiodide: synthesis of alkenes with high (Z)-selectivity through beta-elimination reactions

scientific article published on 01 December 2005

Recent synthetic applications of manganese in organic synthesis

scientific article published on January 2008

Samarium-Promoted Asymmetric Aldol-Tishchenko Reaction: Synthesis of Amino Acid-Derived 4-Amino-1,3-diols

scholarly article by Humberto Rodríguez-Solla et al published 5 June 2012 in Advanced Synthesis & Catalysis

Sequential Synthesis of (E)-α,β-Unsaturated Primary Amides with Complete Stereoselectivity†

scientific article published on 01 May 2010

Sequential elimination-cyclopropanation reactions promoted by samarium: highly diastereoselective synthesis of cyclopropylamides.

scientific article

Sequential elimination-reduction reactions promoted by samarium diiodide: synthesis of 2,3-dideuterioesters or -amides

scientific article published on 01 October 2001

Sequential reactions promoted by manganese: completely stereoselective synthesis of (E)-alpha,beta-unsaturated amides, ketones, aldehydes, and carboxylic acids

scientific article published on 21 September 2007

Stereoselective Synthesis of Carbohydrate-Derived N-Sulfonyl Aziridines

Stereoselective synthesis of (Z)-alpha-halo-alpha,beta-unsaturated esters, and amides from aldehydes and trihaloesters or amides promoted by manganese

scientific article published on 21 December 2007

Stereoselective synthesis of (Z)-alpha-haloacrylic acid derivatives, and (Z)-haloallylic alcohols from aldehydes and trihaloesters or amides promoted by Rieke manganese

scientific article published on 18 June 2008

Stereospecific and Stereoselective Alkyl and Silylcyclopropanation of α,β-Unsaturated Amides

article published in 2008

Stereospecific and highly stereoselective cyclopropanation reactions promoted by samarium.

scientific article published on 04 August 2010

Stereospecific cyclopropanation of highly substituted C-C double bonds promoted by CrCl2. Stereoselective synthesis of cyclopropanecarboxamides and cyclopropyl ketones

scientific article published on 13 July 2007

Switching Diastereoselectivity in Proline-Catalyzed Aldol Reactions

scientific article published on 05 November 2012

Synthesis and Synthetic Applications of Samarium Enolates of Unmasked Amides: Efficient Synthesis of 3-Aminoamides and 3-Amino-2-chloroamides

Synthesis and Synthetic Applications of α,β-Dideuterio-α-amino Esters Promoted by Samarium Diiodide

Synthesis and structural characterization of cobalt(II) and copper(II) complexes with N,N-disubstituted-N′-acylthioureas

Synthesis of (E)-alpha,beta-Unsaturated Esters and Amides with Total Selectivity Using Samarium Diiodide We thank the II Plan Regional de Investigación del Principado de Asturias (PB-PGI99-01) and the Ministerio de Educación y Cultura (PB97-1278) fo

scientific article published on 01 August 2000

Synthesis of (E)-alpha,beta-unsaturated amides with high selectivity by using samarium diiodide

scientific article published on 01 July 2001

Synthesis of E-α,β-Unsaturated Ketones with Complete Stereoselectivity via Sequential Aldol-Type/Elimination Reactions Promoted by Samarium Diiodide or Chromium Dichloride

Synthesis of Highly Functionalized Enantiopure Halocyclopropanes Derived from Carbohydrates

Synthesis of Isotopically Labeled (E)-beta,gamma-Unsaturated Esters with Total or High Diastereoselectivity by Using Samarium Diiodide We thank II Plan Regional de Investigación del Principado de Asturias (PB-PGI98-04) and Ministerio de Educación y

scientific article published on 01 October 2001

Synthesis of Sugar-Derived 2-Nitroalkanols via Henry Reaction Promoted by Samarium Diiodide or Indium

scholarly article by Humberto Rodríguez-Solla et al published 8 August 2012 in Synlett

Synthesis of different deuterated carboxylic acids from unsaturated acids promoted by samarium diiodide and D2O

scientific article published on 01 October 2002

Synthesis of enantiopure 2-C-glycosyl-3-nitrochromenes

scientific article published on 9 December 2013

TBD-catalyzed α-sulfenylation of cyclic ketones: desymmetrization of 4-substituted cyclohexanones

TBD/Al2O3: a novel catalytic system for dynamic intermolecular aldol reactions that exhibit complex system behaviour.

scientific article

Temperature-Controlled Stereodivergent Synthesis of 2,2'-Biflavanones Promoted by Samarium Diiodide

scientific article published on 13 September 2019

The first cyclopropanation reaction of unmasked alpha,beta-unsaturated carboxylic acids: direct and complete stereospecific synthesis of cyclopropanecarboxylic acids promoted by Sm/CHI3

scientific article published on 19 June 2007

The first sequential reaction promoted by manganese: complete stereoselective synthesis of (E)-alpha,beta-unsaturated esters from 2,2-dichloroesters and aldehydes

scientific article published on 15 May 2007

The use of samarium or sodium iodide salts as an alternative for the aza-Henry reaction

Total regioselective transformation of aromatic aziridine 2-carboxamides into 2-aminoamides promoted by active manganese

scientific article published in April 2010

Totally selective synthesis of enantiopure (3S,5S)- and (3R,5R)-4-amino-3,5-dihydroxypiperidines from aminodiepoxides derived from serine

scientific article published on 4 July 2008

Unctuous ZrO2 nanoparticles with improved functional attributes as lubricant additives

scientific article published on 16 October 2017

List of works by Humberto Rodríguez-Solla

A Convenient Samarium-Promoted Synthesis of Aliphatic (E)-Nitroalkenes under Mild Conditions†

A Convenient Synthesis of (E)-α,β-Unsaturated Esters with Total Stereoselectivity Promoted by Catalytic Samarium Diiodide

Addition reactions of chloro- or iodomethyllithium to imines. Synthesis of enantiopure aziridines and beta-chloroamines

Addition reactions of iodomethyllithium to imines. A direct and efficient synthesis of aziridines and enantiopure amino aziridines

An Efficient Catalytic Chromium-Mediated Iodocyclopropanation Reaction: Stereoselective Synthesis of Iodocyclopropanecarboxamides

Asymmetric Construction of Quaternary Stereocenters: Synthesis of Enantiopure Amino Acid-Based Tricyclic α,β-Enones through an ipso-Friedel-Crafts/Michael Addition Cascade

Asymmetric conjugate reductions with samarium diiodide: asymmetric synthesis of (2S,3R)- and (2S,3S)-[2-2H,3-2H]-leucine-(S)-phenylalanine dipeptides and (2S,3R)-[2-(2)H,3-2H]-phenylalanine methyl ester.

Asymmetric synthesis and applications of beta-amino Weinreb amides: asymmetric synthesis of (S)-coniine.

Asymmetric synthesis of 3,4-anti- and 3,4-syn-substituted aminopyrrolidines via lithium amide conjugate addition

Aza-Reformatsky Reaction Promoted by Catalytic Samarium Diiodide: Synthesis of β-Amino Esters or Amides

Beta-elimination reactions by using samarium diiodide

Chromium-Mediated Stereoselective Synthesis of Carbohydrate-Derived (E)-α,β-Unsaturated Esters or Amides

Complete stereospecific cyclopropanation of alpha,beta-unsaturated amides promoted by Sm/CH2I2.

CrCl2-promoted stereospecific and stereoselective alkyl- and silylcyclopropanation of alpha,beta-unsaturated amides

Diastereoselective conjugate reduction with samarium diiodide: asymmetric synthesis of methyl (2S,3R)-N-acetyl-2-amino-2,3-dideuterio-3-phenylpropionate

Direct Aldol Reactions Catalyzed by a Heterogeneous Guanidinium Salt/Proline System under Solvent-Free Conditions‡

Efficient Addition Reaction of Bromonitromethane to Aldehydes Catalyzed by NaI: A New Route to 1-Bromo-1-nitroalkan-2-ols under Very Mild Conditions

Efficient Nitro-Aldol Reaction Using SmI2: A New Route to Nitro Alcohols under Very Mild Conditions

General Preparation of 1-Substituted (E)-1,3-Dienes under Mild Conditions

General, stereoselective synthesis of (Z)-beta,gamma-unsaturated nitriles promoted by samarium diiodide

Highly Enantioselective Proline-Catalysed Direct Aldol Reaction of Chloroacetone and Aromatic Aldehydes

Highly Stereoselective Halocyclopropanation of α,β-Unsaturated Amides

Indium-Mediated Aza-Henry Reaction of Imines: Access to 2-Nitroamines

Lithium amide conjugate addition for the asymmetric synthesis of 3-aminopyrrolidines

Metal-Mediated Debromination of gem-Dibromoalkenes under Mild Conditions

Modern Synthetic Methods for the Stereoselective Construction of 1,3-Dienes

Ohmic Heating and Ionic Liquids in Combination for the Indium-Promoted Synthesis of 1-Halo Alkenyl Compounds: Applications to Pd-Catalysed Cross-Coupling Reactions

Photoinduced metalation of nonactivated C-Cl bonds with samarium diiodide: synthesis of alkenes with high (Z)-selectivity through beta-elimination reactions

Recent synthetic applications of manganese in organic synthesis

Samarium-Promoted Asymmetric Aldol-Tishchenko Reaction: Synthesis of Amino Acid-Derived 4-Amino-1,3-diols

Sequential Synthesis of (E)-α,β-Unsaturated Primary Amides with Complete Stereoselectivity†

Sequential elimination-cyclopropanation reactions promoted by samarium: highly diastereoselective synthesis of cyclopropylamides.

Sequential elimination-reduction reactions promoted by samarium diiodide: synthesis of 2,3-dideuterioesters or -amides

Sequential reactions promoted by manganese: completely stereoselective synthesis of (E)-alpha,beta-unsaturated amides, ketones, aldehydes, and carboxylic acids

Stereoselective Synthesis of Carbohydrate-Derived N-Sulfonyl Aziridines

Stereoselective synthesis of (Z)-alpha-halo-alpha,beta-unsaturated esters, and amides from aldehydes and trihaloesters or amides promoted by manganese

Stereoselective synthesis of (Z)-alpha-haloacrylic acid derivatives, and (Z)-haloallylic alcohols from aldehydes and trihaloesters or amides promoted by Rieke manganese

Stereospecific and Stereoselective Alkyl and Silylcyclopropanation of α,β-Unsaturated Amides

Stereospecific and highly stereoselective cyclopropanation reactions promoted by samarium.

Stereospecific cyclopropanation of highly substituted C-C double bonds promoted by CrCl2. Stereoselective synthesis of cyclopropanecarboxamides and cyclopropyl ketones

Switching Diastereoselectivity in Proline-Catalyzed Aldol Reactions

Synthesis and Synthetic Applications of Samarium Enolates of Unmasked Amides: Efficient Synthesis of 3-Aminoamides and 3-Amino-2-chloroamides

Synthesis and Synthetic Applications of α,β-Dideuterio-α-amino Esters Promoted by Samarium Diiodide

Synthesis and structural characterization of cobalt(II) and copper(II) complexes with N,N-disubstituted-N′-acylthioureas

Synthesis of (E)-alpha,beta-Unsaturated Esters and Amides with Total Selectivity Using Samarium Diiodide We thank the II Plan Regional de Investigación del Principado de Asturias (PB-PGI99-01) and the Ministerio de Educación y Cultura (PB97-1278) fo

Synthesis of (E)-alpha,beta-unsaturated amides with high selectivity by using samarium diiodide

Synthesis of E-α,β-Unsaturated Ketones with Complete Stereoselectivity via Sequential Aldol-Type/Elimination Reactions Promoted by Samarium Diiodide or Chromium Dichloride

Synthesis of Highly Functionalized Enantiopure Halocyclopropanes Derived from Carbohydrates

Synthesis of Isotopically Labeled (E)-beta,gamma-Unsaturated Esters with Total or High Diastereoselectivity by Using Samarium Diiodide We thank II Plan Regional de Investigación del Principado de Asturias (PB-PGI98-04) and Ministerio de Educación y

Synthesis of Sugar-Derived 2-Nitroalkanols via Henry Reaction Promoted by Samarium Diiodide or Indium

Synthesis of different deuterated carboxylic acids from unsaturated acids promoted by samarium diiodide and D2O

Synthesis of enantiopure 2-C-glycosyl-3-nitrochromenes

TBD-catalyzed α-sulfenylation of cyclic ketones: desymmetrization of 4-substituted cyclohexanones

TBD/Al2O3: a novel catalytic system for dynamic intermolecular aldol reactions that exhibit complex system behaviour.

Temperature-Controlled Stereodivergent Synthesis of 2,2'-Biflavanones Promoted by Samarium Diiodide

The first cyclopropanation reaction of unmasked alpha,beta-unsaturated carboxylic acids: direct and complete stereospecific synthesis of cyclopropanecarboxylic acids promoted by Sm/CHI3

The first sequential reaction promoted by manganese: complete stereoselective synthesis of (E)-alpha,beta-unsaturated esters from 2,2-dichloroesters and aldehydes

The use of samarium or sodium iodide salts as an alternative for the aza-Henry reaction

Total regioselective transformation of aromatic aziridine 2-carboxamides into 2-aminoamides promoted by active manganese

Totally selective synthesis of enantiopure (3S,5S)- and (3R,5R)-4-amino-3,5-dihydroxypiperidines from aminodiepoxides derived from serine

Unctuous ZrO2 nanoparticles with improved functional attributes as lubricant additives