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List of works by Ramón Macías

A DFT and crystallographic reinvestigation of the [L2RuC2B7H9] and [L3RuC2B7H9] ‘hypercloso’ and closo systems

Addition to Brønsted Acid/Base Driven Chemistry with Rhodathiaboranes: A Labile {SB9H9}-Thiodecaborane Fragment System

article

Alkene hydrogenation on an 11-vertex rhodathiaborane with full cluster participation

scientific article

Alkyne-Promoted H2Loss in a Metallaborane:Nido-to-ClosoCluster Transformation and sp CH Bond Oxidative Addition

article

An iridaborane reaction cycle driven by PMe3 and BH3.THF: synthesis and characterization of [Cp*IrB3H7(PMe3)] and [Cp*IrB2H6(PMe3)]

scientific article published on 01 October 2002

Brønsted Acid/Base Driven Chemistry with Rhodathiaboranes: A Labile {SB9H9}–Thiadecaborane Fragment System

Chemistry of 11-vertex rhodathiaboranes: reactions with monodentate phosphines

scientific article published on 24 May 2011

Decaborane Thiols as Building Blocks for Self-Assembled Monolayers on Metal Surfaces

scientific article published on 9 January 2012

Decaborane anion tautomerism: ion pairing and proton transfer control.

scientific article published on 12 April 2018

Effects of metal-centre orbital control on cluster character and electron distribution between borane and hydrocarbon ligands; significance of the structures of [μ-9,10-(SMe)-8,8-(PPh3)2-nido-8,7-IrSB 9H9] and [μ-9,10-(SMe)-8-(η4-C5Me5H)- nido-8,7

scientific article published in 1997

Eleven- and twelve-vertex polyhedral metalladithiaborane chemistry. Novel compounds from the arachno-[S2B9H10]–anion: [(PPh3)3H2IrS2B9H10], [(PPh3)2HIrS2B9H9] and [(PPh3)2HRhS2B8H8]

scientific article published in 1994

Facile two-electron reduction of a closo-rhodathiadecaborane

scientific article published on 23 August 2012

From Imidazole toward Imidazolium Salts and N-Heterocyclic Carbene Ligands: Electronic and Geometrical Redistribution

scientific article published on 10 April 2017

Heterolytic H2 activation on a carbene-ligated rhodathiaborane promoted by isonido-nido cage opening

scientific article published on 01 October 2013

Isonitrile ligand effects on small-molecule-sequestering in bimetalladodecaborane clusters

scientific article published in December 2013

Ligand Lability Driven by Metal-to-Borane Pseudorotation: A Mechanism for Ligand Exchange

scientific article published on 04 December 2020

Macropolyhedral Nickelaboranes from the Metal-Assisted Fusion of KB9H14

scientific article published on 09 September 2019

Metallaborane Reactivity. A Stoichiometric Mechanism for the Insertion of Two Alkynes into an Iridaborane Framework via a Disposable Molybdenum Chaperone

scientific article published on 24 February 2007

Modification of [8,8,8-(H)(PPh3)2-9-(Py)-nido-8,7-RhSB9H9], Py = NC5H5, with Monodentate Phosphines: Reactivity and Mechanistic Insights

Molybdenum-mediated alkyne incorporation into an iridaborane framework--release of the iridacarborane from the molybdenum coordination sphere through a dissociative equilibrium

scientific article published on 01 March 2006

NH3-promoted ligand lability in eleven-vertex rhodathiaboranes

scientific article

New Iridathiaboranes with ReversibleIsonido↔NidoCluster Flexibility

scientific article published on 01 August 2010

Phosphine-boranes as bidentate ligands: formation of [8,8-eta(2)-(eta(2)-(BH(3)).dppm)-nido-8,7-RhSB(9)H(10)] and [9,9-eta(2)-(eta(2)-(BH(3)).dppm)-nido-9,7,8-RhC(2)B(8)H(11)] from [8,8-(eta(2)-dppm)-8-(eta(1)-dppm)-nido-8,7-RhSB(9)H(10)] and [9,9-(

scientific article published on 01 November 2002

Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB(9)} and {PtCB(9)} metallaheteroboranes

scientific article published in May 2007

Polyhedral metallathiaborane chemistry: Synthesis and characterisation of metallathiaboranes based on the twelve-vertex icosahedral closo-{MSB10H10} unit, where M is Rh or Ir

scientific article published in February 2008

Postsynthetic modifications of [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] with Lewis bases: cluster modular tuning

scientific article published on 4 May 2016

Proton-assisted hydrogen activation on polyhedral cations

scientific article published on 10 February 2013

Reactions of 11-vertex rhodathiaboranes with HCl: synthesis and reactivity of new Cl-ligated clusters

scientific article

Reversible Capture of Small Molecules On Bimetallaborane Clusters: Synthesis, Structural Characterization, and Photophysical Aspects

scientific article published on 21 July 2011

Reversible Ethylene Dihydrogen Mediated 11-Vertexnido→closo→nidoConversion in a Metallathiaborane Cluster

scientific article published on 25 January 2008

Reversible Small-Molecule Interactions with Coordinatively Unsaturated Metal Centers Held in Metallathiaborane Clusters

Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η2-C2H4)(PPh3)RhSB8H7(PPh3)]

scientific article published on 01 March 2015

Square-planar rhodium(I) complexes partnered with [arachno-6-SB(9)H(12)]- : a route toward the synthesis of new rhodathiaboranes and organometallic/thiaborane salts

scientific article

Synthesis and characterization of dicarboranylmethylammonium polyoxometallates

scientific article published in 2010

Synthesis and characterization of new 10- and 12-vertex CO-ligated metallathiaboranes

Ten-vertex polyhedral azametallaborane chemistry: a unique nido-6,9 to nido-6,8-cluster isomerization

scientific article published on 15 July 2008

Ten-vertex rhodadithiaborane chemistry:.

scientific article

Twelve-vertex polyhedral carbaborane chemistry. Isostructural cations and anions: The ‘globule–globule’ salt [H3NCH2C2B10H11][H3CCH2CB11H11]

scientific article published in March 2006

Unusual cationic rhodathiaboranes: synthesis and characterization of [8,8,8-(H)(PR3)2-9-(Py)-nido-8,7-RhSB9H10]+and [1,3-μ-(H)-1,1-(PR3)2-3-(Py)-isonido-1,2-RhSB9H8]+

scientific article published on 01 April 2014

[1,1-(η2-dppe)-3-(NC5H5)-closo-1,2-RhSB9H8]: conformational lability and reactivity with H2 upon protonation

scientific article published on 01 May 2015

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