List of works - Ulf-Peter Apfel

A dinuclear porphyrin-macrocycle as efficient catalyst for the hydrogen evolution reaction

scientific article published on 27 October 2020

Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases

scientific article published on 19 July 2017

Aging-Associated Enzyme Human Clock-1: Substrate-Mediated Reduction of the Diiron Center for 5-Demethoxyubiquinone Hydroxylation ⬇️

scientific article published on March 20, 2013

Bio-inspired design: bulk iron-nickel sulfide allows for efficient solvent-dependent CO2 reduction

scientific article published on 06 November 2018

Bioinspired reactivity and coordination chemistry

scientific article published on 01 May 2019

Chalcogenide substitution in the [2Fe] cluster of [FeFe]-hydrogenases conserves high enzymatic activity.

scientific article published on 27 November 2017

Cobalt–metalloid alloys for electrochemical oxidation of 5-hydroxymethylfurfural as an alternative anode reaction in lieu of oxygen evolution during water splitting.

scientific article

Differential Protonation at the Catalytic Six-Iron Cofactor of [FeFe]-Hydrogenases Revealed by 57Fe Nuclear Resonance X-ray Scattering and Quantum Mechanics/Molecular Mechanics Analyses

scientific article published on 25 February 2019

Efficient Activation of the Greenhouse Gas CO2 ⬇️

scientific article published on April 13, 2011

Electrochemical Investigations of the Mechanism of Assembly of the Active-Site H-Cluster of [FeFe]-Hydrogenases.

scientific article published on 24 October 2016

Electronic and molecular structure relations in diiron compounds mimicking the [FeFe]-hydrogenase active site studied by X-ray spectroscopy and quantum chemistry

scientific article published on 14 September 2017

From Enzymes to Functional Materials-Towards Activation of Small Molecules.

scientific article published on 17 August 2017

How [FeFe]-Hydrogenase Facilitates Bidirectional Proton Transfer

scientific article published on 15 October 2019

Insights from 125Te and 57Fe nuclear resonance vibrational spectroscopy: a [4Fe-4Te] cluster from two points of view

scientific article published on 24 June 2019

Interplay between CN- Ligands and the Secondary Coordination Sphere of the H-Cluster in [FeFe]-Hydrogenases.

scientific article published on 27 November 2017

Interplay of Spin Crossover and Coordination-Induced Spin State Switch for Iron Bis(pyrazolyl)methanes in Solution

scientific article published on 01 October 2020

Koordinationschemie und Bioanorganik

Local surface structure and composition control the hydrogen evolution reaction on iron nickel sulfides

scientific article published on 26 January 2018

Loss of Specific Active-Site Iron Atoms in Oxygen-Exposed [FeFe]-Hydrogenase Determined by Detailed X-ray Structure Analyses

scientific article published on 25 October 2019

Modulation of the CO2 fixation in dinickel azacryptands.

scientific article published on 21 February 2017

Organometallic Fe-Fe Interactions: Beyond Common Metal-Metal Bonds and Inverse Mixed-Valent Charge Transfer.

scientific article

Preparation and Characterization of Homologous Diiron Dithiolato, Diselenato, and Ditellurato Complexes: [FeFe]-Hydrogenase Models

Proton-Coupled Reduction of the Catalytic [4Fe-4S] Cluster in [FeFe]-Hydrogenases

scientific article published on 26 October 2017

Protonation/reduction dynamics at the [4Fe-4S] cluster of the hydrogen-forming cofactor in [FeFe]-hydrogenases

scientific article

Seleno-analogues of pentlandites (Fe4.5Ni4.5S8-YSeY, Y = 1-6): tuning bulk Fe/Ni sulphoselenides for hydrogen evolution

scientific article published on 01 July 2019

Shedding Light on Proton and Electron Dynamics in [FeFe] Hydrogenases

scientific article published on 16 March 2020

Spectroscopic and reactivity differences in metal complexes derived from sulfur containing Triphos homologs

scientific article published on 01 October 2017

Spectroscopical Investigations on the Redox Chemistry of [FeFe]-Hydrogenases in the Presence of Carbon Monoxide

scientific article published on 09 July 2018

Spontaneous Si-C bond cleavage in (TriphosSi)-nickel complexes

scientific article published on 22 December 2016

Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO2 reduction and enhanced proton reduction

scientific article published on 01 May 2019

Synthetic approaches to artificial photosynthesis: general discussion

scientific article published on 01 July 2019

[FeFe]-Hydrogenases: maturation and reactivity of enzymatic systems and overview of biomimetic models

scientific article published on 11 December 2020

[FeFe]-Hydrogenases: recent developments and future perspectives.

scientific article published on 4 May 2018

List of works by Ulf-Peter Apfel

A dinuclear porphyrin-macrocycle as efficient catalyst for the hydrogen evolution reaction

Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases

Aging-Associated Enzyme Human Clock-1: Substrate-Mediated Reduction of the Diiron Center for 5-Demethoxyubiquinone Hydroxylation ⬇️

Bio-inspired design: bulk iron-nickel sulfide allows for efficient solvent-dependent CO2 reduction

Bioinspired reactivity and coordination chemistry

Chalcogenide substitution in the [2Fe] cluster of [FeFe]-hydrogenases conserves high enzymatic activity.

Cobalt–metalloid alloys for electrochemical oxidation of 5-hydroxymethylfurfural as an alternative anode reaction in lieu of oxygen evolution during water splitting.

Differential Protonation at the Catalytic Six-Iron Cofactor of [FeFe]-Hydrogenases Revealed by 57Fe Nuclear Resonance X-ray Scattering and Quantum Mechanics/Molecular Mechanics Analyses

Efficient Activation of the Greenhouse Gas CO2 ⬇️

Electrochemical Investigations of the Mechanism of Assembly of the Active-Site H-Cluster of [FeFe]-Hydrogenases.

Electronic and molecular structure relations in diiron compounds mimicking the [FeFe]-hydrogenase active site studied by X-ray spectroscopy and quantum chemistry

From Enzymes to Functional Materials-Towards Activation of Small Molecules.

How [FeFe]-Hydrogenase Facilitates Bidirectional Proton Transfer

Insights from 125Te and 57Fe nuclear resonance vibrational spectroscopy: a [4Fe-4Te] cluster from two points of view

Interplay between CN- Ligands and the Secondary Coordination Sphere of the H-Cluster in [FeFe]-Hydrogenases.

Interplay of Spin Crossover and Coordination-Induced Spin State Switch for Iron Bis(pyrazolyl)methanes in Solution

Koordinationschemie und Bioanorganik

Local surface structure and composition control the hydrogen evolution reaction on iron nickel sulfides

Loss of Specific Active-Site Iron Atoms in Oxygen-Exposed [FeFe]-Hydrogenase Determined by Detailed X-ray Structure Analyses

Modulation of the CO2 fixation in dinickel azacryptands.

Organometallic Fe-Fe Interactions: Beyond Common Metal-Metal Bonds and Inverse Mixed-Valent Charge Transfer.

Preparation and Characterization of Homologous Diiron Dithiolato, Diselenato, and Ditellurato Complexes: [FeFe]-Hydrogenase Models

Proton-Coupled Reduction of the Catalytic [4Fe-4S] Cluster in [FeFe]-Hydrogenases

Protonation/reduction dynamics at the [4Fe-4S] cluster of the hydrogen-forming cofactor in [FeFe]-hydrogenases

Seleno-analogues of pentlandites (Fe4.5Ni4.5S8-YSeY, Y = 1-6): tuning bulk Fe/Ni sulphoselenides for hydrogen evolution

Shedding Light on Proton and Electron Dynamics in [FeFe] Hydrogenases

Spectroscopic and reactivity differences in metal complexes derived from sulfur containing Triphos homologs

Spectroscopical Investigations on the Redox Chemistry of [FeFe]-Hydrogenases in the Presence of Carbon Monoxide

Spontaneous Si-C bond cleavage in (TriphosSi)-nickel complexes

Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO2 reduction and enhanced proton reduction

Synthetic approaches to artificial photosynthesis: general discussion

[FeFe]-Hydrogenases: maturation and reactivity of enzymatic systems and overview of biomimetic models

[FeFe]-Hydrogenases: recent developments and future perspectives.

{1,1′-(Dimethylsilylene)bis[methanechalcogenolato]}diiron Complexes [2Fe2E(Si)] (E=S, Se, Te) - [FeFe] Hydrogenase Models