List of works - Antonio Otero

A new titanium building block for early-late heterometallic complexes; preparation of a new tetrameric metallomacrocycle by self assembly

scientific article published on 03 April 2006

A pyrimidine thiolate Rh(I) complex: structure, bonding and one-dimensional interactions in solid and in solution

scientific article

A ruthenium(II) complex with bis(3,5-dimethylpyrazol-1-yl)dithioacetate built layer-by-layer on silver and gold surfaces

Activation of a CNXylyl ancillary ligand in the reaction of electron-deficient alkynes with a phosphido niobocene complex

scientific article published on 09 February 2006

Advances in the chemistry of bis-cyclopentadienyl hydride derivatives of niobium and tantalum

scholarly article by Antonio Antiñolo et al published October 1999 in Coordination Chemistry Reviews

Amidinate Aluminium Complexes as Catalysts for Carbon Dioxide Fixation into Cyclic Carbonates

An Efficient and Versatile Lanthanum Heteroscorpionate Catalyst for Carbon Dioxide Fixation into Cyclic Carbonates.

scientific article

An unprecedented hybrid scorpionate/cyclopentadienyl ligand

scientific article published on 01 February 2004

Building Layer-by-Layer a Bis(dithiocarbamato)copper(II) Complex on Au{111} Surfaces

scientific article published on 04 May 2007

C-H bond cleavage and regioselective C-C coupling on a tantalum-bound pincer ligand

scientific article published on 01 October 2010

Catalytic behaviour in the ring-opening polymerisation of organoaluminiums supported by bulky heteroscorpionate ligands

scientific article published on 01 July 2015

Chelating dialkoxide titanium complex: a versatile building block for the construction of heterometallic derivatives

scientific article published on 01 January 2007

Design of new heteroscorpionate ligands and their coordinative ability toward Group 4 transition metals; an efficient synthetic route to obtain enantiopure ligands

scientific article published on 17 July 2006

Direct synthesis of NNN-donor enantiopure scorpionate ligands by an efficient diastereoselective nucleophilic addition to imines

scientific article published on 11 January 2011

Early-late heterobimetallic alkoxides as model systems for late-transition-metal catalysts supported on titania.

scientific article

Enantiopure N,N,O-scorpionate zinc amide and chloride complexes as efficient initiators for the heteroselective ROP of cyclic esters

scientific article published on 01 December 2014

Facile Synthesis of Alkynyl− and Vinylidene−Niobocene Complexes. Unexpected η1-Vinylidene−η2-Alkyne Isomerization

scientific article published in May 2000

First complexes of scandium and yttrium with NNO and NNS heteroscorpionate ligands.

scientific article published in July 2005

Guanidines: from classical approaches to efficient catalytic syntheses.

scientific article published on 14 March 2014

Heteroscorpionate aluminium complexes as chiral building blocks to engineer helical architectures

scientific article published on 01 October 2013

Heteroscorpionate ligands based on bis(pyrazol-1-yl)methane: design and coordination chemistry.

scientific article published on 2 April 2004

Heteroscorpionate magnesium alkyls bearing unprecedented apical σ-C(sp3)-mg bonds: heteroselective ring-opening polymerization of rac-lactide

scientific article

Heteroscorpionate rare-earth initiators for the controlled ring-opening polymerization of cyclic esters

scientific article published on 10 March 2011

Highly thermally stable and robust enantiopure zirconium NNN-scorpionates for the controlled ring-opening polymerization of rac-lactide.

scientific article published on 5 May 2017

Influence of the Counterion on the Synthesis of Cyclic Carbonates Catalyzed by Bifunctional Aluminum Complexes

scientific article published on 08 February 2019

Interaction of ruthenium(III) chloride with bis(3,5-dimethylpyrazol-1-yl)methane oxyanions, potential κ3-N,N,O scorpionates

article published in 2004

Lewis base character of the phosphorus atom in phosphanido-niobocene complexes. Synthesis of new early-early homo- and heterobimetallic entities

scientific article published on 04 February 2011

Ligand-modification effects on the reactivity, solubility, and stability of organometallic tantalum complexes in water

scientific article published on 20 January 2012

Lithium, titanium, and zirconium complexes with novel amidinate scorpionate ligands

scientific article published on 03 February 2007

Mono- and binuclear chiral N,N,O-scorpionate zinc alkyls as efficient initiators for the ROP of rac-lactide.

scientific article published on 25 October 2017

New Niobocene Alkyne Complexes: Synthesis and Characterization of Neutral and Cationic Niobium Complexes with Functionalized Alkynes. X-ray Crystal Structure of [Nb(η5-C5H4SiMe3)2(Cl)(η2(C,C)-R1C⋮CR2)] (R1= C⋮CPh, R2= Ph (2b); R1= CH2CHC(CH3)2,

scientific article published in March 1999

New achiral and chiral NNE heteroscorpionate ligands. Synthesis of homoleptic lithium complexes as well as halide and alkyl scandium and yttrium complexes.

scientific article published on 18 November 2009

New complexes of zirconium(IV) and hafnium(IV) with heteroscorpionate ligands and the hydrolysis of such complexes to give a zirconium cluster

scientific article published on 01 February 2004

Niobocene Alkyne Complexes: Synthesis and Characterization of Neutral and Cationic d2Metal Alkyne Derivatives. X-ray Crystal Structure of [Nb(η5-C5H4SiMe3)2(η2(C,C)-HC⋮CPh)(CH2Ph)]

article published in 1997

Nitric oxide binding and photodelivery based on ruthenium(II) complexes of 4-arylazo-3,5-dimethylpyrazole

scientific article

On the search for NNO-donor enantiopure scorpionate ligands and their coordination to group 4 metals.

scientific article published in June 2009

One-Component Aluminum(heteroscorpionate) Catalysts for the Formation of Cyclic Carbonates from Epoxides and Carbon Dioxide

scientific article

Organo-Aluminum and Zinc Acetamidinates: Preparation, Coordination Ability, and Ring-Opening Polymerization Processes of Cyclic Esters

scientific article published on 13 September 2018

Oxo- and imido-alkoxide vanadium complexes as precatalysts for the guanylation of aromatic amines

scientific article published on 07 June 2010

Preparation of new monoanionic "scorpionate" ligands: synthesis and structural characterization of titanium(IV) complexes bearing this class of ligand

scientific article published on 01 October 2002

Preparation, X-ray crystal and electronic structure of the novel raft cluster [NbAuH2{C5H4(SiMe3)}2]3

Reactions of alkynes with phosphido niobocenes: a combined experimental and theoretical study.

scientific article published on 11 January 2010

Reactivity of a Super-Electron-Rich Olefin Derived from Cyclam

Ruthenium Complexes of the Scorpionate Ligand Bis(3,5-dimethylpyrazol-1-yl)dithioacetate and the Effect of Nitric Oxide Coordination

Straightforward generation of helical chirality driven by a versatile heteroscorpionate ligand: self-assembly of a metal helicate by using CH-pi interactions

scientific article published on 01 August 2010

Study of the Coordination Modes of Hybrid NNCp Cyclopentadienyl/Scorpionate Ligands in Ir Compounds

scientific article published on 12 December 2018

Synthesis and Characterization of Palladium(II) Complexes with New Polydentate Nitrogen Ligands. Dynamic Behavior Involving Pd-N Bond Rupture. X-ray Molecular Structure of [{Pd(eta(3)-C(4)H(7))}(2)(Me-BPzTO)](4-MeC(6)H(4)SO(3)) [Me-BPzTO = 4,6-Bis(4

scientific article published on 01 December 1998

Synthesis and Characterization of the Stable Cationic d2 Metal Acetylene Complexes [Nb(.eta.5-C5H4SiMe3)2(.eta.2(C,C)-RC.tplbond.CR')(NCMe)]+. X-ray Crystal Structures of [Nb(.eta.5-C5H4SiMe3)2(.eta.2(C,C)-MeO2CC.tplbond.CMe)(NCMe)][BPh4] and [(.eta.

Synthesis and characterization of complexes containing Ti-O-Si moieties. Catalytic activity in olefin epoxidation

scientific article published on 10 January 2007

Synthesis and structural characterization of amido scorpionate rare earth metals complexes

scientific article published on 01 July 2014

Synthesis of Cyclic Carbonates Catalysed by Aluminium Heteroscorpionate Complexes.

scientific article published in June 2015

Synthesis of new heteroscorpionate iridium(i) and iridium(iii) complexes

scientific article published on 01 April 2015

Synthesis, structural characterization and catalytic evaluation of the ring-opening polymerization of discrete five-coordinate alkyl aluminium complexes

scientific article published on 08 February 2013

Synthesis, structures and ring-opening polymerization studies of new zinc chloride and amide complexes supported by amidinate heteroscorpionate ligands.

scientific article published on 11 August 2009

Versatile organoaluminium catalysts based on heteroscorpionate ligands for the preparation of polyesters

scientific article published on 01 June 2018

Versatile scorpionates and new developments in the denticity changes of NNCp hybrid scorpionate/cyclopentadienyl ligands in Sc and Y compounds: from kappa1-Neta5-Cp to kappa2-NNeta5-Cp.

scientific article published on 30 April 2008

List of works by Antonio Otero

A new titanium building block for early-late heterometallic complexes; preparation of a new tetrameric metallomacrocycle by self assembly

A pyrimidine thiolate Rh(I) complex: structure, bonding and one-dimensional interactions in solid and in solution

A ruthenium(II) complex with bis(3,5-dimethylpyrazol-1-yl)dithioacetate built layer-by-layer on silver and gold surfaces

Activation of a CNXylyl ancillary ligand in the reaction of electron-deficient alkynes with a phosphido niobocene complex

Advances in the chemistry of bis-cyclopentadienyl hydride derivatives of niobium and tantalum

Amidinate Aluminium Complexes as Catalysts for Carbon Dioxide Fixation into Cyclic Carbonates

An Efficient and Versatile Lanthanum Heteroscorpionate Catalyst for Carbon Dioxide Fixation into Cyclic Carbonates.

An unprecedented hybrid scorpionate/cyclopentadienyl ligand

Building Layer-by-Layer a Bis(dithiocarbamato)copper(II) Complex on Au{111} Surfaces

C-H bond cleavage and regioselective C-C coupling on a tantalum-bound pincer ligand

Catalytic behaviour in the ring-opening polymerisation of organoaluminiums supported by bulky heteroscorpionate ligands

Chelating dialkoxide titanium complex: a versatile building block for the construction of heterometallic derivatives

Design of new heteroscorpionate ligands and their coordinative ability toward Group 4 transition metals; an efficient synthetic route to obtain enantiopure ligands

Direct synthesis of NNN-donor enantiopure scorpionate ligands by an efficient diastereoselective nucleophilic addition to imines

Early-late heterobimetallic alkoxides as model systems for late-transition-metal catalysts supported on titania.

Enantiopure N,N,O-scorpionate zinc amide and chloride complexes as efficient initiators for the heteroselective ROP of cyclic esters

Facile Synthesis of Alkynyl− and Vinylidene−Niobocene Complexes. Unexpected η1-Vinylidene−η2-Alkyne Isomerization

First complexes of scandium and yttrium with NNO and NNS heteroscorpionate ligands.

Guanidines: from classical approaches to efficient catalytic syntheses.

Heteroscorpionate aluminium complexes as chiral building blocks to engineer helical architectures

Heteroscorpionate ligands based on bis(pyrazol-1-yl)methane: design and coordination chemistry.

Heteroscorpionate magnesium alkyls bearing unprecedented apical σ-C(sp3)-mg bonds: heteroselective ring-opening polymerization of rac-lactide

Heteroscorpionate rare-earth initiators for the controlled ring-opening polymerization of cyclic esters

Highly thermally stable and robust enantiopure zirconium NNN-scorpionates for the controlled ring-opening polymerization of rac-lactide.

Influence of the Counterion on the Synthesis of Cyclic Carbonates Catalyzed by Bifunctional Aluminum Complexes

Interaction of ruthenium(III) chloride with bis(3,5-dimethylpyrazol-1-yl)methane oxyanions, potential κ3-N,N,O scorpionates

Lewis base character of the phosphorus atom in phosphanido-niobocene complexes. Synthesis of new early-early homo- and heterobimetallic entities

Ligand-modification effects on the reactivity, solubility, and stability of organometallic tantalum complexes in water

Lithium, titanium, and zirconium complexes with novel amidinate scorpionate ligands

Mono- and binuclear chiral N,N,O-scorpionate zinc alkyls as efficient initiators for the ROP of rac-lactide.

New Niobocene Alkyne Complexes: Synthesis and Characterization of Neutral and Cationic Niobium Complexes with Functionalized Alkynes. X-ray Crystal Structure of [Nb(η5-C5H4SiMe3)2(Cl)(η2(C,C)-R1C⋮CR2)] (R1= C⋮CPh, R2= Ph (2b); R1= CH2CHC(CH3)2,

New achiral and chiral NNE heteroscorpionate ligands. Synthesis of homoleptic lithium complexes as well as halide and alkyl scandium and yttrium complexes.

New complexes of zirconium(IV) and hafnium(IV) with heteroscorpionate ligands and the hydrolysis of such complexes to give a zirconium cluster

Niobocene Alkyne Complexes: Synthesis and Characterization of Neutral and Cationic d2Metal Alkyne Derivatives. X-ray Crystal Structure of [Nb(η5-C5H4SiMe3)2(η2(C,C)-HC⋮CPh)(CH2Ph)]

Nitric oxide binding and photodelivery based on ruthenium(II) complexes of 4-arylazo-3,5-dimethylpyrazole

On the search for NNO-donor enantiopure scorpionate ligands and their coordination to group 4 metals.

One-Component Aluminum(heteroscorpionate) Catalysts for the Formation of Cyclic Carbonates from Epoxides and Carbon Dioxide

Organo-Aluminum and Zinc Acetamidinates: Preparation, Coordination Ability, and Ring-Opening Polymerization Processes of Cyclic Esters

Oxo- and imido-alkoxide vanadium complexes as precatalysts for the guanylation of aromatic amines

Preparation of new monoanionic "scorpionate" ligands: synthesis and structural characterization of titanium(IV) complexes bearing this class of ligand

Preparation, X-ray crystal and electronic structure of the novel raft cluster [NbAuH2{C5H4(SiMe3)}2]3

Reactions of alkynes with phosphido niobocenes: a combined experimental and theoretical study.

Reactivity of a Super-Electron-Rich Olefin Derived from Cyclam

Ruthenium Complexes of the Scorpionate Ligand Bis(3,5-dimethylpyrazol-1-yl)dithioacetate and the Effect of Nitric Oxide Coordination

Straightforward generation of helical chirality driven by a versatile heteroscorpionate ligand: self-assembly of a metal helicate by using CH-pi interactions

Study of the Coordination Modes of Hybrid NNCp Cyclopentadienyl/Scorpionate Ligands in Ir Compounds

Synthesis and Characterization of Palladium(II) Complexes with New Polydentate Nitrogen Ligands. Dynamic Behavior Involving Pd-N Bond Rupture. X-ray Molecular Structure of [{Pd(eta(3)-C(4)H(7))}(2)(Me-BPzTO)](4-MeC(6)H(4)SO(3)) [Me-BPzTO = 4,6-Bis(4

Synthesis and Characterization of the Stable Cationic d2 Metal Acetylene Complexes [Nb(.eta.5-C5H4SiMe3)2(.eta.2(C,C)-RC.tplbond.CR')(NCMe)]+. X-ray Crystal Structures of [Nb(.eta.5-C5H4SiMe3)2(.eta.2(C,C)-MeO2CC.tplbond.CMe)(NCMe)][BPh4] and [(.eta.

Synthesis and characterization of complexes containing Ti-O-Si moieties. Catalytic activity in olefin epoxidation

Synthesis and structural characterization of amido scorpionate rare earth metals complexes

Synthesis of Cyclic Carbonates Catalysed by Aluminium Heteroscorpionate Complexes.

Synthesis of new heteroscorpionate iridium(i) and iridium(iii) complexes

Synthesis, structural characterization and catalytic evaluation of the ring-opening polymerization of discrete five-coordinate alkyl aluminium complexes

Synthesis, structures and ring-opening polymerization studies of new zinc chloride and amide complexes supported by amidinate heteroscorpionate ligands.

Versatile organoaluminium catalysts based on heteroscorpionate ligands for the preparation of polyesters

Versatile scorpionates and new developments in the denticity changes of NNCp hybrid scorpionate/cyclopentadienyl ligands in Sc and Y compounds: from kappa1-Neta5-Cp to kappa2-NNeta5-Cp.