List of works - Gabriel Dos Passos Gomes

CO2 or SO2: Should It Stay, or Should It Go?

scientific article published on 29 April 2019

Changing the path of least resistance, or access to endo-dig products via a sequence of three exo-trig transition states: electronic effects in homoallyic ring expansion cascades of alkenyl isonitriles.

scientific article

Combining Traceless Directing Groups with Hybridization Control of Radical Reactivity: From Skipped Enynes to Defect-Free Hexagonal Frameworks.

scientific article

Coupling N-H Deprotonation, C-H Activation, and Oxidation: Metal-Free C(sp3)-H Aminations with Unprotected Anilines.

scientific article published on 16 October 2017

Coupling Radical Homoallylic Expansions with C-C Fragmentations for the Synthesis of Heteroaromatics: Quinolines from Reactions of o-Alkenylarylisonitriles with Aryl, Alkyl, and Perfluoroalkyl Radicals

scientific article published on 30 March 2017

Data-science driven autonomous process optimization

scholarly article published 3 November 2020

Data-science driven autonomous process optimization

scientific article published on 3 November 2020

Data-science driven autonomous process optimization

scientific article published on 2 November 2020

Drawing Catalytic Power from Charge Separation: Stereoelectronic and Zwitterionic Assistance in the Au(I)-Catalyzed Bergman Cyclization

scientific article

Electronic Donation or Steric Contraction: A Spectroscopic and Structural Analysis of Medium-Sized Constrained Rings for Potential Long-Range Hyperconjugation

scientific article published on 06 August 2019

Erratum: Organocatalyzed synthesis of fluorinated poly(aryl thioethers).

scientific article published on 13 November 2017

Five Roads That Converge at the Cyclic Peroxy-Criegee Intermediates: BF3-Catalyzed Synthesis of β-Hydroperoxy-β-peroxylactones

Interrupted Bayer-Villiger Rearrangement: Building A Stereoelectronic Trap for the Criegee Intermediate.

scientific article published on 31 January 2018

Isonitriles as Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy in Radical Additions

article

Machine Learning Reactivity in the Chemical Space Surrounding Vaska's Complex

scholarly article published 27 November 2019

Machine Learning Reactivity in the Chemical Space Surrounding Vaska's Complex

scientific article published on 27 November 2019

Machine learning dihydrogen activation in the chemical space surrounding Vaska's complex

scientific article published on 07 April 2020

Organocatalyzed synthesis of fluorinated poly(aryl thioethers).

scientific article published on August 2017

Oxidative Rearrangement of MIDA (<i>N</i>-Methyliminodiacetic Acid) Boronates: Mechanistic Insights and Synthetic Applications

scientific article published on 06 January 2021

Ozone-Free Synthesis of Ozonides: Assembling Bicyclic Structures from 1,5-Diketones and Hydrogen Peroxide.

scientific article

Regioselective One-Pot Synthesis of Triptycenes via Triple-Cycloadditions of Arynes to Ynolates.

scientific article published on 28 December 2016

Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy of Functional Groups

scientific article published on 11 November 2016

Stereoelectronic Control in the Ozone-Free Synthesis of Ozonides.

scientific article published on 5 April 2017

Stereoelectronic Influence of a "Spectator" Propargylic Substituent Can Override Aromaticity Effects in Radical Peri-Cyclizations en Route to Expanded Polyaromatics

scientific article published on 04 February 2019

Stereoelectronic Interactions as a Probe for the Existence of the Intramolecular α-Effect.

scientific article published on 12 July 2017

Substituent effects on stereoselectivity of dihalocarbene reactions with cyclohexadiene and on the reactivity of bis-dihalocyclopropanes in electrophilic nitrations en route to pyrimidine N-oxides.

scientific article published on 2 November 2017

Traceless Directing Groups in Radical Cascades: From Oligoalkynes to Fused Helicenes without Tethered Initiators

scientific article published on 13 January 2015

Twofold π-Extension of Polyarenes via Double and Triple Radical Alkyne peri-Annulations: Radical Cascades Converging on the Same Aromatic Core

scientific article published on 04 April 2020

List of works by Gabriel Dos Passos Gomes

CO2 or SO2: Should It Stay, or Should It Go?

Changing the path of least resistance, or access to endo-dig products via a sequence of three exo-trig transition states: electronic effects in homoallyic ring expansion cascades of alkenyl isonitriles.

Combining Traceless Directing Groups with Hybridization Control of Radical Reactivity: From Skipped Enynes to Defect-Free Hexagonal Frameworks.

Coupling N-H Deprotonation, C-H Activation, and Oxidation: Metal-Free C(sp3)-H Aminations with Unprotected Anilines.

Coupling Radical Homoallylic Expansions with C-C Fragmentations for the Synthesis of Heteroaromatics: Quinolines from Reactions of o-Alkenylarylisonitriles with Aryl, Alkyl, and Perfluoroalkyl Radicals

Data-science driven autonomous process optimization

Data-science driven autonomous process optimization

Data-science driven autonomous process optimization

Drawing Catalytic Power from Charge Separation: Stereoelectronic and Zwitterionic Assistance in the Au(I)-Catalyzed Bergman Cyclization

Electronic Donation or Steric Contraction: A Spectroscopic and Structural Analysis of Medium-Sized Constrained Rings for Potential Long-Range Hyperconjugation

Erratum: Organocatalyzed synthesis of fluorinated poly(aryl thioethers).

Five Roads That Converge at the Cyclic Peroxy-Criegee Intermediates: BF3-Catalyzed Synthesis of β-Hydroperoxy-β-peroxylactones

Interrupted Bayer-Villiger Rearrangement: Building A Stereoelectronic Trap for the Criegee Intermediate.

Isonitriles as Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy in Radical Additions

Machine Learning Reactivity in the Chemical Space Surrounding Vaska's Complex

Machine Learning Reactivity in the Chemical Space Surrounding Vaska's Complex

Machine learning dihydrogen activation in the chemical space surrounding Vaska's complex

Organocatalyzed synthesis of fluorinated poly(aryl thioethers).

Oxidative Rearrangement of MIDA (<i>N</i>-Methyliminodiacetic Acid) Boronates: Mechanistic Insights and Synthetic Applications

Ozone-Free Synthesis of Ozonides: Assembling Bicyclic Structures from 1,5-Diketones and Hydrogen Peroxide.

Regioselective One-Pot Synthesis of Triptycenes via Triple-Cycloadditions of Arynes to Ynolates.

Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy of Functional Groups

Stereoelectronic Control in the Ozone-Free Synthesis of Ozonides.

Stereoelectronic Influence of a "Spectator" Propargylic Substituent Can Override Aromaticity Effects in Radical Peri-Cyclizations en Route to Expanded Polyaromatics

Stereoelectronic Interactions as a Probe for the Existence of the Intramolecular α-Effect.

Substituent effects on stereoselectivity of dihalocarbene reactions with cyclohexadiene and on the reactivity of bis-dihalocyclopropanes in electrophilic nitrations en route to pyrimidine N-oxides.

Traceless Directing Groups in Radical Cascades: From Oligoalkynes to Fused Helicenes without Tethered Initiators

Twofold π-Extension of Polyarenes via Double and Triple Radical Alkyne peri-Annulations: Radical Cascades Converging on the Same Aromatic Core