List of works - Raphael G. Raptis

"Systematic Synthesis of a Metal Organic Framework Based on Triangular Cu(3)(μ(3)-OH) Secondary Building Units: From a 0-D Complex, to an 1-D Chain and a 3-D Lattice"

scientific article published on January 2010

2D and 3D alkaline earth metal carboxyphosphonate hybrids: Anti-corrosion coatings for metal surfaces

A 1,3,2-oxazaborolidine dimer derived from (S)-alpha,alpha-diphenylprolinol.

scientific article

A Combined Experimental and Computational Study of the Magnetic Superexchange within a Triangular (μ3-O)-Pyrazolato-FeIII3 Complex

A FeIII /Oxo Cubane Contained in an Octanuclear Complex of T Symmetry That Is Stable Over Five Oxidation States

scientific article published on 01 June 1999

A Redox-Induced Spin-State Cascade in a Mixed-Valent Fe3 (μ3 -O) Triangle

scientific article published on 5 December 2016

A Redox-Induced Spin-State Cascade in a Mixed-Valent Fe3(μ3-O) Triangle

A [Cu3(μ3-O)]-pyrazolate metallacycle with terminal nitrate ligands exhibiting point group symmetry 3

scientific article published on 15 March 2016

A combined experimental and theoretical study of gas sorption on nanoporous silver triazolato metal–organic frameworks

A mixed-valence octanuclear iron-oxo pyrazolate: assessment of electronic delocalization by structural and spectroscopic analysis

scientific article published in December 2008

A novel series of vanadium-sulfite polyoxometalates: synthesis, structural, and physical studies

scientific article

A pyrazolate-supported Fe(3)(mu(3)-O) core: structural, spectroscopic, electrochemical, and magnetic study

scientific article published on 29 November 2007

A robust, porous, cationic silver(i) 3,5-diphenyl-1,2,4-triazolate framework with a uninodal 4(9).6(6) net.

scientific article published on 13 August 2004

A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand

scientific article published on 13 November 2015

Alkaline Earth Metal Organotriphosphonates: Inorganic−Organic Polymeric Hybrids from Dication−Dianion Association

article

Anion Encapsulation by Neutral Supramolecular Assemblies of Cyclic CuII Complexes: A Series of Five Polymerization Isomers,[{cis-CuII(μ-OH)(μ-pz)}n],n=6, 8, 9, 12, and 14

scholarly article by Gellert Mezei et al published 23 January 2004 in Angewandte Chemie International Edition

Bielschowskysin, a gorgonian-derived biologically active diterpene with an unprecedented carbon skeleton.

scientific article published on May 2004

Bipinnatins K-Q, minor cembrane-type diterpenes from the West Indian Gorgonian Pseudopterogorgia kallos: isolation, structure assignment, and evaluation of biological activities.

scientific article

Cadmium(II) Complexes of 4-(4-Pyridyl)Pyrazole: A Case of Two Conformational Supramolecular Isomers Polythreaded in the Same Crystal and a Rare Example of 5-ConnectednovNet

article published in 2008

Coordination polymers of CdII and PbII with croconate show remarkable differences in coordination patterns: a structural and spectroscopic study

scientific article published on 14 June 2019

Corrugated, Sheet-Like Architectures in Layered Alkaline-Earth MetalR,S-Hydroxyphosphonoacetate Frameworks: Applications for Anticorrosion Protection of Metal Surfaces

article by Konstantinos D. Demadis et al published August 2008 in Chemistry of Materials

Crystal structure and conformational analysis of doxorubicin nitrate.

scientific article published on 28 February 2018

Crystal structure of μ6-chlorido-nona-kis-(μ-4-chloro-pyrazolato)bis-μ3-methoxo-hexa-copper(II).

scientific article published on 27 January 2017

Dinuclear gold(III) pyrazolato complexes – Synthesis, structural characterization and transformation to their trinuclear gold(I) and gold(I/III) analogues

article published in 2009

Dolabellane-type diterpenoids with antiprotozoan activity from a southwestern Caribbean gorgonian octocoral of the genus Eunicea ⬇️

scientific article

Double exchange in a mixed-valent octanuclear iron cluster, [Fe8(μ4-O)4(μ-4-Cl-pz)12Cl4](-).

scientific article published on 25 March 2014

Effect of copper-substitution on the structure and nuclearity of Cu(II)-pyrazolates: from trinuclear to tetra-, hexa- and polynuclear complexes

Effect of pyrazole-substitution on the structure and nuclearity of Cu(II)-pyrazolato complexes

Electronic structure and magnetic properties of a trigonal prismatic Cu(II)6 cluster.

scientific article published on 26 June 2009

Experimental and Theoretical Mössbauer Study of an Extended Family of [Fe8(μ4-O)4(μ-4-R-px)12X4] Clusters

article

First structural characterization of a delocalized, mixed-valent, triangular Cu37+ species: chemical and electrochemical oxidation of a CuII3(mu3-O) pyrazolate and electronic structure of the oxidation product.

scientific article

Interactions between H-bonded [CuII3(μ3-OH)] triangles; a combined magnetic susceptibility and EPR study

scientific article published on 01 June 2018

Isolation and characterization of kallosin A, a novel rearranged pseudopterane diterpenoid from the Caribbean sea plume Pseudopterogorgia kallos (Bielschowsky).

scientific article

Isolation and structure of providencin: a highly oxygenated diterpene possessing a unique bicyclo[12.2.0]hexadecane ring system from the sea plume Pseudopterogorgia kallos.

scientific article published on July 2003

Magnetic resonance imaging contrast enhancement in vitro and in vivo by octanuclear iron-oxo cluster-based agents

scientific article published on 26 June 2018

Metal tetraphosphonate "wires" and their corrosion inhibiting passive films

scientific article

Metal−Organotetraphosphonate Inorganic−Organic Hybrids: Crystal Structure and Anticorrosion Effects of Zinc Hexamethylenediaminetetrakis(methylenephosphonate) on Carbon Steels

article

New terpenoid constituents from Eunicea pinta

scientific article published on 01 September 2002

Nitrite Reduction by Trinuclear Copper Pyrazolate Complexes: An Example of a Catalytic, Synthetic Polynuclear NO Releasing System

scientific article published on 15 May 2019

Oxidation of gold(i) pyrazolates by aqua regia. X-Ray crystal structures of the first examples of trinuclear AuIII3 and AuIAuIII2 pyrazolato complexes

Palladium Nanostructures and Nanoparticles from Molecular Precursors on Highly Ordered Pyrolytic Graphite

scientific article published on 01 November 2006

Phosphonopolycarboxylates as Chemical Additives for Calcite Scale Dissolution and Metallic Corrosion Inhibition Based on a Calcium-Phosphonotricarboxylate Organic−Inorganic Hybrid

article

Pyrazole-4-sulfonate networks of alkali and alkaline-earth metals. Effect of cation size, charge, H-bonding and aromatic interactions on the three-dimensional supramolecular architecture

article by Gellert Mezei et al published 2003 in New Journal of Chemistry

Relaying Isomerism from Ligands to Metal Complexes: Synthesis and Structures of Four Isomeric Binary Silver(I) 3,5-Dibutyl-1,2,4-triazolates

Remarkably selective NH4+ binding and fluorescence sensing by tripodal tris(pyrazolyl) receptors derived from 1,3,5-triethylbenzene: structural and theoretical insights on the role of ion pairing

Selective CO2 Adsorption on Metal-Organic Frameworks Based on Trinuclear Cu3-Pyrazolato Complexes: An Experimental and Computational Study

article

Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo11V7}: [MoVI11VV5VIV2O52(μ9-SO3)]7−

Spin relaxation in a ferromagnetically coupled triangular Cu3 complex

Spin-glass behavior of a hierarchically-organized, hybrid microporous material, based on an extended framework of octanuclear iron-oxo units.

scientific article published in February 2015

Spontaneous Resolution by Crystallization of an Octanuclear Iron(III) Complex Using Only Racemic Reagents

scientific article published on 17 April 2019

Stepwise, ring-closure synthesis and characterization of a homoleptic palladium(II)-pyrazolato cyclic trimer

scientific article

Structural and 57Fe-Mössbauer characterization of mononuclear ferrous and ferric pyrazole complexes

Structural and Photophysical Characterisation offac-[Tricarbonyl(chloro)(5,6-epoxy-1,10-phenanthroline)rhenium(I)]

scholarly article by Angel A. Martí et al published 10 November 2004 in European Journal of Inorganic Chemistry

Structural architectures of charge-assisted, hydrogen-bonded, 2D layered amine⋯tetraphosphonate and zinc⋯tetraphosphonate ionic materials

article by Konstantinos D. Demadis et al published October 2009 in Polyhedron

Substituent Effects on the Supramolecular Aggregation of AgI-Pyrazolato Trimers

Supramolecular assembly of trimeric gold(I) pyrazolates through aurophilic attractions.

scientific article published in January 2003

Synthesis and Characterization of Linear Trinuclear Pd, Co, and Pd/Co Pyrazolate Complexes

Synthesis and characterization of palladium and palladium-cobalt nanoparticles on Vulcan XC-72R for the oxygen reduction reaction

scientific article published on 05 November 2013

Synthesis of 8-(1,2,3-triazol-1-yl)-7-deazapurine nucleosides by azide-alkyne click reactions and direct C-H bond functionalization

scientific article published on 19 August 2016

Synthesis of pyrazole (hemi)aminals via the cleavage of saturated aliphatic ether C–O bonds in the presence of ferric halides

Synthesis, characterization, and study of octanuclear iron-oxo clusters containing a redox-active Fe4O4-cubane core.

scientific article published on 14 December 2007

Synthesis, structure and properties of tetrameric gold(I) 3,5-di-tert-butyl–pyrazolate

The spectroelectrochemical, magnetic, and structural characterization of reduced hexaazatriphenylenehexacarbonitrile, HAT(CN)6

Thermal Reduction of Pd Molecular Cluster Precursors at Highly Ordered Pyrolytic Graphite Surfaces

scientific article published on 01 September 2004

Three new multinuclear motifs in Cu(II)-pyrazolate chemistry

article published in 2012

Towards ionic liquids with tailored magnetic properties: bmim+ salts of ferro- and antiferromagnetic Cu triangles

scientific article

Tri-, deca- and dodecanuclear Co(III)-pyrazolate metallacycles

scientific article published on 12 March 2010

Triangular, ferromagnetically-coupled CuII 3-pyrazolato complexes as possible models of particulate methane monooxygenase (pMMO).

scientific article published in September 2003

Trigonal prismatic Cu(I) and Ag(I) pyrazolato nanocage hosts: encapsulation of S8 and hydrocarbon guests

scientific article published on 12 September 2013

Trigonal-prismatic CuII6-pyrazolato cages: structural and electrochemical study, evidence of charge delocalisation

article

Trinuclear, Antiferromagnetically Coupled CuIIComplex with an EPR Spectrum of Mononuclear CuII: Effect of Alcoholic Solvents

Tuning of the [Cu3(mu-O)]4+/5+ redox couple: spectroscopic evidence of charge delocalization in the mixed-valent [Cu3(mu-O)]5+ species

scientific article

Uracil Nucleosides with Reactive Group at C5 Position: 5-(1-Halo-2-sulfonylvinyl)uridine Analogues

scientific article published in 2016

Water-Soluble Derivatives of Octanuclear Iron-Oxo-Pyrazolato Complexes; An Experimental and Computational Study

scientific article

pH – Specific synthesis, spectroscopic, and structural characterization of an assembly of species between Co(II) and N,N-bis(phosphonomethyl)glycine. Gaining insight into metal-ion phosphonate interactions in aqueous Co(II)–organophosphonate syst

List of works by Raphael G. Raptis

"Systematic Synthesis of a Metal Organic Framework Based on Triangular Cu(3)(μ(3)-OH) Secondary Building Units: From a 0-D Complex, to an 1-D Chain and a 3-D Lattice"

2D and 3D alkaline earth metal carboxyphosphonate hybrids: Anti-corrosion coatings for metal surfaces

A 1,3,2-oxazaborolidine dimer derived from (S)-alpha,alpha-diphenylprolinol.

A Combined Experimental and Computational Study of the Magnetic Superexchange within a Triangular (μ3-O)-Pyrazolato-FeIII3 Complex

A FeIII /Oxo Cubane Contained in an Octanuclear Complex of T Symmetry That Is Stable Over Five Oxidation States

A Redox-Induced Spin-State Cascade in a Mixed-Valent Fe3 (μ3 -O) Triangle

A Redox-Induced Spin-State Cascade in a Mixed-Valent Fe3(μ3-O) Triangle

A [Cu3(μ3-O)]-pyrazolate metallacycle with terminal nitrate ligands exhibiting point group symmetry 3

A combined experimental and theoretical study of gas sorption on nanoporous silver triazolato metal–organic frameworks

A mixed-valence octanuclear iron-oxo pyrazolate: assessment of electronic delocalization by structural and spectroscopic analysis

A novel series of vanadium-sulfite polyoxometalates: synthesis, structural, and physical studies

A pyrazolate-supported Fe(3)(mu(3)-O) core: structural, spectroscopic, electrochemical, and magnetic study

A robust, porous, cationic silver(i) 3,5-diphenyl-1,2,4-triazolate framework with a uninodal 4(9).6(6) net.

A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand

Alkaline Earth Metal Organotriphosphonates: Inorganic−Organic Polymeric Hybrids from Dication−Dianion Association

Anion Encapsulation by Neutral Supramolecular Assemblies of Cyclic CuII Complexes: A Series of Five Polymerization Isomers,[{cis-CuII(μ-OH)(μ-pz)}n],n=6, 8, 9, 12, and 14

Bielschowskysin, a gorgonian-derived biologically active diterpene with an unprecedented carbon skeleton.

Bipinnatins K-Q, minor cembrane-type diterpenes from the West Indian Gorgonian Pseudopterogorgia kallos: isolation, structure assignment, and evaluation of biological activities.

Cadmium(II) Complexes of 4-(4-Pyridyl)Pyrazole: A Case of Two Conformational Supramolecular Isomers Polythreaded in the Same Crystal and a Rare Example of 5-ConnectednovNet

Coordination polymers of CdII and PbII with croconate show remarkable differences in coordination patterns: a structural and spectroscopic study

Corrugated, Sheet-Like Architectures in Layered Alkaline-Earth MetalR,S-Hydroxyphosphonoacetate Frameworks: Applications for Anticorrosion Protection of Metal Surfaces

Crystal structure and conformational analysis of doxorubicin nitrate.

Crystal structure of μ6-chlorido-nona-kis-(μ-4-chloro-pyrazolato)bis-μ3-methoxo-hexa-copper(II).

Dinuclear gold(III) pyrazolato complexes – Synthesis, structural characterization and transformation to their trinuclear gold(I) and gold(I/III) analogues

Dolabellane-type diterpenoids with antiprotozoan activity from a southwestern Caribbean gorgonian octocoral of the genus Eunicea ⬇️

Double exchange in a mixed-valent octanuclear iron cluster, [Fe8(μ4-O)4(μ-4-Cl-pz)12Cl4](-).

Effect of copper-substitution on the structure and nuclearity of Cu(II)-pyrazolates: from trinuclear to tetra-, hexa- and polynuclear complexes

Effect of pyrazole-substitution on the structure and nuclearity of Cu(II)-pyrazolato complexes

Electronic structure and magnetic properties of a trigonal prismatic Cu(II)6 cluster.

Experimental and Theoretical Mössbauer Study of an Extended Family of [Fe8(μ4-O)4(μ-4-R-px)12X4] Clusters

First structural characterization of a delocalized, mixed-valent, triangular Cu37+ species: chemical and electrochemical oxidation of a CuII3(mu3-O) pyrazolate and electronic structure of the oxidation product.

Interactions between H-bonded [CuII3(μ3-OH)] triangles; a combined magnetic susceptibility and EPR study

Isolation and characterization of kallosin A, a novel rearranged pseudopterane diterpenoid from the Caribbean sea plume Pseudopterogorgia kallos (Bielschowsky).

Isolation and structure of providencin: a highly oxygenated diterpene possessing a unique bicyclo[12.2.0]hexadecane ring system from the sea plume Pseudopterogorgia kallos.

Magnetic resonance imaging contrast enhancement in vitro and in vivo by octanuclear iron-oxo cluster-based agents

Metal tetraphosphonate "wires" and their corrosion inhibiting passive films

Metal−Organotetraphosphonate Inorganic−Organic Hybrids: Crystal Structure and Anticorrosion Effects of Zinc Hexamethylenediaminetetrakis(methylenephosphonate) on Carbon Steels

New terpenoid constituents from Eunicea pinta

Nitrite Reduction by Trinuclear Copper Pyrazolate Complexes: An Example of a Catalytic, Synthetic Polynuclear NO Releasing System

Oxidation of gold(i) pyrazolates by aqua regia. X-Ray crystal structures of the first examples of trinuclear AuIII3 and AuIAuIII2 pyrazolato complexes

Palladium Nanostructures and Nanoparticles from Molecular Precursors on Highly Ordered Pyrolytic Graphite

Phosphonopolycarboxylates as Chemical Additives for Calcite Scale Dissolution and Metallic Corrosion Inhibition Based on a Calcium-Phosphonotricarboxylate Organic−Inorganic Hybrid

Pyrazole-4-sulfonate networks of alkali and alkaline-earth metals. Effect of cation size, charge, H-bonding and aromatic interactions on the three-dimensional supramolecular architecture

Relaying Isomerism from Ligands to Metal Complexes: Synthesis and Structures of Four Isomeric Binary Silver(I) 3,5-Dibutyl-1,2,4-triazolates

Remarkably selective NH4+ binding and fluorescence sensing by tripodal tris(pyrazolyl) receptors derived from 1,3,5-triethylbenzene: structural and theoretical insights on the role of ion pairing

Selective CO2 Adsorption on Metal-Organic Frameworks Based on Trinuclear Cu3-Pyrazolato Complexes: An Experimental and Computational Study

Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo11V7}: [MoVI11VV5VIV2O52(μ9-SO3)]7−

Spin relaxation in a ferromagnetically coupled triangular Cu3 complex

Spin-glass behavior of a hierarchically-organized, hybrid microporous material, based on an extended framework of octanuclear iron-oxo units.

Spontaneous Resolution by Crystallization of an Octanuclear Iron(III) Complex Using Only Racemic Reagents

Stepwise, ring-closure synthesis and characterization of a homoleptic palladium(II)-pyrazolato cyclic trimer

Structural and 57Fe-Mössbauer characterization of mononuclear ferrous and ferric pyrazole complexes

Structural and Photophysical Characterisation offac-[Tricarbonyl(chloro)(5,6-epoxy-1,10-phenanthroline)rhenium(I)]

Structural architectures of charge-assisted, hydrogen-bonded, 2D layered amine⋯tetraphosphonate and zinc⋯tetraphosphonate ionic materials

Substituent Effects on the Supramolecular Aggregation of AgI-Pyrazolato Trimers

Supramolecular assembly of trimeric gold(I) pyrazolates through aurophilic attractions.

Synthesis and Characterization of Linear Trinuclear Pd, Co, and Pd/Co Pyrazolate Complexes

Synthesis and characterization of palladium and palladium-cobalt nanoparticles on Vulcan XC-72R for the oxygen reduction reaction

Synthesis of 8-(1,2,3-triazol-1-yl)-7-deazapurine nucleosides by azide-alkyne click reactions and direct C-H bond functionalization

Synthesis of pyrazole (hemi)aminals via the cleavage of saturated aliphatic ether C–O bonds in the presence of ferric halides

Synthesis, characterization, and study of octanuclear iron-oxo clusters containing a redox-active Fe4O4-cubane core.

Synthesis, structure and properties of tetrameric gold(I) 3,5-di-tert-butyl–pyrazolate

The spectroelectrochemical, magnetic, and structural characterization of reduced hexaazatriphenylenehexacarbonitrile, HAT(CN)6

Thermal Reduction of Pd Molecular Cluster Precursors at Highly Ordered Pyrolytic Graphite Surfaces

Three new multinuclear motifs in Cu(II)-pyrazolate chemistry

Towards ionic liquids with tailored magnetic properties: bmim+ salts of ferro- and antiferromagnetic Cu triangles

Tri-, deca- and dodecanuclear Co(III)-pyrazolate metallacycles

Triangular, ferromagnetically-coupled CuII 3-pyrazolato complexes as possible models of particulate methane monooxygenase (pMMO).

Trigonal prismatic Cu(I) and Ag(I) pyrazolato nanocage hosts: encapsulation of S8 and hydrocarbon guests

Trigonal-prismatic CuII6-pyrazolato cages: structural and electrochemical study, evidence of charge delocalisation

Trinuclear, Antiferromagnetically Coupled CuIIComplex with an EPR Spectrum of Mononuclear CuII: Effect of Alcoholic Solvents

Tuning of the [Cu3(mu-O)]4+/5+ redox couple: spectroscopic evidence of charge delocalization in the mixed-valent [Cu3(mu-O)]5+ species

Uracil Nucleosides with Reactive Group at C5 Position: 5-(1-Halo-2-sulfonylvinyl)uridine Analogues

Water-Soluble Derivatives of Octanuclear Iron-Oxo-Pyrazolato Complexes; An Experimental and Computational Study

pH – Specific synthesis, spectroscopic, and structural characterization of an assembly of species between Co(II) and N,N-bis(phosphonomethyl)glycine. Gaining insight into metal-ion phosphonate interactions in aqueous Co(II)–organophosphonate syst