List of works - Christian Bruneau

2,2'-Dipyridylamines: more than just sister members of the bipyridine family. Applications and achievements in homogeneous catalysis and photoluminescent materials

scientific article published on 04 July 2019

A direct route to bifunctional aldehyde derivatives via self- and cross-metathesis of unsaturated aldehydes.

scientific article published in January 2009

A new dicoumarinyl ether and two rare furocoumarins from Ruta montana.

scientific article published in February 2003

A straightforward access to guaiazulene derivatives using palladium-catalysed sp2 or sp3 C-H bond functionalisation

scientific article published on 01 June 2013

Alkene metathesis catalysis in ionic liquids with ruthenium allenylidene salts.

scientific article

Autocatalytic Intermolecular versus Intramolecular Deprotonation in CH Bond Activation of Functionalized Arenes by Ruthenium(II) or Palladium(II) Complexes ⬇️

scientific article published on April 17, 2013

C-H Bond Alkylation of Cyclic Amides with Maleimides via a Site-Selective-Determining Six-Membered Ruthenacycle

scientific article published on 09 December 2019

C-H bond functionalization in water catalyzed by carboxylato ruthenium(II) systems

scientific article published on 01 September 2010

Concomitant monoreduction and hydrogenation of unsaturated cyclic imides to lactams catalyzed by ruthenium compounds

scientific article published on 01 March 2005

Cp(η2‐bipy)(MeCN)RuIIPF6 Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic Cp(η2‐bipy)(η3‐allyl)RuIVPF62 Intermediates ⬇️

scientific article published on October 27, 2003

Cross metathesis of unsaturated epoxides for the synthesis of polyfunctional building blocks

scientific article

Cyclobutene ring-opening of bicyclo[4.2.0]octa-1,6-dienes: access to CF3-substituted 5,6,7,8-tetrahydro-1,7-naphthyridines

Dimethyl carbonate: an eco-friendly solvent in ruthenium-catalyzed olefin metathesis transformations.

scientific article

Efficient Domino Hydroformylation/Benzoin Condensation: Highly Selective Synthesis of α-Hydroxy Ketones.

scientific article published on 27 October 2015

Efficient ruthenium-catalyzed synthesis of [3]dendralenes from 1,3-dienic allylic carbonates.

scientific article

Electrophilic activation and cycloisomerization of enynes: a new route to functional cyclopropanes.

scientific article

Ene-yne cross-metathesis with ruthenium carbene catalysts

scientific article published on 4 February 2011

Eta6-mesityl,eta1-imidazolinylidene-carbene-ruthenium(II) complexes: catalytic activity of their allenylidene derivatives in alkene metathesis and cycloisomerisation reactions.

scientific article published in May 2003

Ethenolysis of methyl oleate in room-temperature ionic liquids.

scientific article published in January 2008

Ethenolysis: A Green Catalytic Tool to Cleave Carbon-Carbon Double Bonds.

scientific article published on 30 June 2016

First enantioselective allylic etherification with phenols catalyzed by chiral ruthenium bisoxazoline complexes.

scientific article

Hydride-induced novel cyclization of dienedinitriles leading to multifunctionalized cyclopentadienes

scientific article published on 01 October 2009

Improving sustainability in ene-yne cross-metathesis for transformation of unsaturated fatty esters.

scientific article published on November 2010

Iridium-catalyzed oxidant-free dehydrogenative C-H bond functionalization: selective preparation of N-arylpiperidines through tandem hydrogen transfers

scientific article published on 29 July 2012

Isoquinoline derivatives via stepwise regioselective sp(2) and sp(3) C-H bond functionalizations

scientific article published on 27 March 2012

Metal vinylidenes and allenylidenes in catalysis: applications in anti-Markovnikov additions to terminal alkynes and alkene metathesis

scientific article published on 01 March 2006

Methyl Ricinoleate as Platform Chemical for Simultaneous Production of Fine Chemicals and Polymer Precursors ⬇️

scientific article published on September 25, 2012

N-Heterocyclic carbene-palladium catalysts for the direct arylation of pyrrole derivatives with aryl chlorides.

scientific article published on 12 February 2013

New ruthenium metathesis catalysts with chelating indenylidene ligands: synthesis, characterization and reactivity.

scientific article published on 17 February 2012

One-step synthesis of 1-halo-1,3-butadienes via ruthenium-catalysed hydrohalogenative dimerisation of alkynes

scientific article published on 01 November 2012

Palladium-Catalysed Cross-Coupling Reactions Controlled by Noncovalent Zn⋅⋅⋅N Interactions

scientific article published on 3 January 2017

Palladium-Catalyzed Direct Arylation of 5-Chloropyrazoles: A Selective Access to 4-Aryl Pyrazoles

scientific article published on 21 August 2012

Palladium-catalysed direct arylation of thiophenes tolerant to silyl groups

scientific article published on 02 December 2010

Pentamethylcyclopentadienyl-ruthenium catalysts for regio- and enantioselective allylation of nucleophiles

scientific article published on 01 July 2006

Preparation of chiral ruthenium(IV) complexes and applications in regio- and enantioselective allylation of phenols

scientific article published on 18 April 2011

Reactivity of 3-Substituted Fluorobenzenes in Palladium- Catalysed Direct Arylations with Aryl Bromides

article published in 2014

Reactivity of C–H bonds of polychlorobenzenes for palladium-catalysed direct arylations with aryl bromides

Recovery of enlarged olefin metathesis catalysts by nanofiltration in an eco-friendly solvent.

scientific article

Regio- and stereoselective syntheses of piperidine derivatives via ruthenium-catalyzed coupling of propargylic amides and allylic alcohols

scientific article published on 24 May 2012

Ru-Catalyzed Selective C-H Bond Hydroxylation of Cyclic Imides

scientific article published on 25 January 2019

Ruthenium Phosphine-Pyridone Catalyzed Cross-Coupling of Alcohols To form α-Alkylated Ketones

scientific article

Ruthenium catalyzed β-C(sp3)-H functionalization on the 'privileged' piperazine nucleus.

scientific article

Ruthenium(II) and iridium(III) complexes featuring NHC-sulfonate chelate.

scientific article published on 24 September 2015

Ruthenium(II)-Catalyzed C-H (Hetero)Arylation of Alkenylic 1,n-Diazines (n = 2, 3, and 4): Scope, Mechanism, and Application in Tandem Hydrogenations.

scientific article published on 10 January 2018

Ruthenium(II)-catalyzed C-H bond activation and functionalization

scientific article published on 31 August 2012

Ruthenium(IV) complexes featuring P,O-chelating ligands: regioselective substitution directly from allylic alcohols

scientific article published on 01 April 2010

Ruthenium(ii)-catalysed selective C(sp2)-H bond benzoxylation of biologically appealing N-arylisoindolinones

scientific article published on 01 August 2019

Ruthenium-catalysed synthesis of functional conjugated dienes from propargylic carbonates and silyl diazo compounds

scientific article published on 05 February 2013

Ruthenium-catalyzed reductive amination of allylic alcohols

scientific article published on 24 June 2011

Ruthenium-catalyzed selective N ,N-diallylation- and N ,N ,O-triallylation of free amino acids.

scientific article published on 31 July 2009

Ruthenium-catalyzed synthesis of allylic alcohols: boronic acid as a hydroxide source

scientific article published on 01 January 2008

Ruthenium-catalyzed synthesis of functionalized 1,3-dienes

scientific article published on 01 January 2009

Ruthenium-containing phosphinesulfonate chelate for the hydrogenation of aryl ketones

scientific article published on 21 June 2013

Ruthenium–Indenylidene Olefin Metathesis Catalyst with Enhanced Thermal Stability ⬇️

scientific article published on October 25, 2010

Selective and Efficient Iridium Catalyst for the Reductive Amination of Levulinic Acid into Pyrrolidones.

scientific article published on 5 September 2017

Selective ruthenium-catalyzed hydrochlorination of alkynes: one-step synthesis of vinylchlorides

scientific article published on 24 August 2015

Site-Selective Ruthenium-Catalyzed C-H Bond Arylations with Boronic Acids: Exploiting Isoindolinones as a Weak Directing Group

scientific article published on 14 August 2019

Synthesis of heteroarylated polyfluorobiphenyls via palladium-catalyzed sequential sp2 C-H bonds functionalizations

scientific article published on 13 March 2013

Tandem Catalytic Acrylonitrile Cross-Metathesis and Hydrogenation of Nitriles with Ruthenium Catalysts: Direct Access to Linear α,ω-Aminoesters from Renewables

scientific article published on 15 June 2012

Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via π-allylic species ⬇️

scientific article published on May 10, 2012

Unmasking Amides: Ruthenium-Catalyzed Protodecarbonylation of N-Substituted Phthalimide Derivatives

scientific article published on 20 November 2017

Vicinal α,β-functionalizations of amines: cyclization versus dehydrogenative hydrolysis

scientific article published on 18 August 2015

sp3 C-H bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines

scientific article published on 17 June 2011

List of works by Christian Bruneau

2,2'-Dipyridylamines: more than just sister members of the bipyridine family. Applications and achievements in homogeneous catalysis and photoluminescent materials

A direct route to bifunctional aldehyde derivatives via self- and cross-metathesis of unsaturated aldehydes.

A new dicoumarinyl ether and two rare furocoumarins from Ruta montana.

A straightforward access to guaiazulene derivatives using palladium-catalysed sp2 or sp3 C-H bond functionalisation

Alkene metathesis catalysis in ionic liquids with ruthenium allenylidene salts.

Autocatalytic Intermolecular versus Intramolecular Deprotonation in CH Bond Activation of Functionalized Arenes by Ruthenium(II) or Palladium(II) Complexes ⬇️

C-H Bond Alkylation of Cyclic Amides with Maleimides via a Site-Selective-Determining Six-Membered Ruthenacycle

C-H bond functionalization in water catalyzed by carboxylato ruthenium(II) systems

Concomitant monoreduction and hydrogenation of unsaturated cyclic imides to lactams catalyzed by ruthenium compounds

Cp*(η2‐bipy)(MeCN)RuIIPF6 Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic Cp*(η2‐bipy)(η3‐allyl)RuIVPF62 Intermediates ⬇️

Cross metathesis of unsaturated epoxides for the synthesis of polyfunctional building blocks

Cyclobutene ring-opening of bicyclo[4.2.0]octa-1,6-dienes: access to CF3-substituted 5,6,7,8-tetrahydro-1,7-naphthyridines

Dimethyl carbonate: an eco-friendly solvent in ruthenium-catalyzed olefin metathesis transformations.

Efficient Domino Hydroformylation/Benzoin Condensation: Highly Selective Synthesis of α-Hydroxy Ketones.

Efficient ruthenium-catalyzed synthesis of [3]dendralenes from 1,3-dienic allylic carbonates.

Electrophilic activation and cycloisomerization of enynes: a new route to functional cyclopropanes.

Ene-yne cross-metathesis with ruthenium carbene catalysts

Eta6-mesityl,eta1-imidazolinylidene-carbene-ruthenium(II) complexes: catalytic activity of their allenylidene derivatives in alkene metathesis and cycloisomerisation reactions.

Ethenolysis of methyl oleate in room-temperature ionic liquids.

Ethenolysis: A Green Catalytic Tool to Cleave Carbon-Carbon Double Bonds.

First enantioselective allylic etherification with phenols catalyzed by chiral ruthenium bisoxazoline complexes.

Hydride-induced novel cyclization of dienedinitriles leading to multifunctionalized cyclopentadienes

Improving sustainability in ene-yne cross-metathesis for transformation of unsaturated fatty esters.

Iridium-catalyzed oxidant-free dehydrogenative C-H bond functionalization: selective preparation of N-arylpiperidines through tandem hydrogen transfers

Isoquinoline derivatives via stepwise regioselective sp(2) and sp(3) C-H bond functionalizations

Metal vinylidenes and allenylidenes in catalysis: applications in anti-Markovnikov additions to terminal alkynes and alkene metathesis

Methyl Ricinoleate as Platform Chemical for Simultaneous Production of Fine Chemicals and Polymer Precursors ⬇️

N-Heterocyclic carbene-palladium catalysts for the direct arylation of pyrrole derivatives with aryl chlorides.

New ruthenium metathesis catalysts with chelating indenylidene ligands: synthesis, characterization and reactivity.

One-step synthesis of 1-halo-1,3-butadienes via ruthenium-catalysed hydrohalogenative dimerisation of alkynes

Palladium-Catalysed Cross-Coupling Reactions Controlled by Noncovalent Zn⋅⋅⋅N Interactions

Palladium-Catalyzed Direct Arylation of 5-Chloropyrazoles: A Selective Access to 4-Aryl Pyrazoles

Palladium-catalysed direct arylation of thiophenes tolerant to silyl groups

Pentamethylcyclopentadienyl-ruthenium catalysts for regio- and enantioselective allylation of nucleophiles

Preparation of chiral ruthenium(IV) complexes and applications in regio- and enantioselective allylation of phenols

Reactivity of 3-Substituted Fluorobenzenes in Palladium- Catalysed Direct Arylations with Aryl Bromides

Reactivity of C–H bonds of polychlorobenzenes for palladium-catalysed direct arylations with aryl bromides

Recovery of enlarged olefin metathesis catalysts by nanofiltration in an eco-friendly solvent.

Regio- and stereoselective syntheses of piperidine derivatives via ruthenium-catalyzed coupling of propargylic amides and allylic alcohols

Ru-Catalyzed Selective C-H Bond Hydroxylation of Cyclic Imides

Ruthenium Phosphine-Pyridone Catalyzed Cross-Coupling of Alcohols To form α-Alkylated Ketones

Ruthenium catalyzed β-C(sp3)-H functionalization on the 'privileged' piperazine nucleus.

Ruthenium(II) and iridium(III) complexes featuring NHC-sulfonate chelate.

Ruthenium(II)-Catalyzed C-H (Hetero)Arylation of Alkenylic 1,n-Diazines (n = 2, 3, and 4): Scope, Mechanism, and Application in Tandem Hydrogenations.

Ruthenium(II)-catalyzed C-H bond activation and functionalization

Ruthenium(IV) complexes featuring P,O-chelating ligands: regioselective substitution directly from allylic alcohols

Ruthenium(ii)-catalysed selective C(sp2)-H bond benzoxylation of biologically appealing N-arylisoindolinones

Ruthenium-catalysed synthesis of functional conjugated dienes from propargylic carbonates and silyl diazo compounds

Ruthenium-catalyzed reductive amination of allylic alcohols

Ruthenium-catalyzed selective N ,N-diallylation- and N ,N ,O-triallylation of free amino acids.

Ruthenium-catalyzed synthesis of allylic alcohols: boronic acid as a hydroxide source

Ruthenium-catalyzed synthesis of functionalized 1,3-dienes

Ruthenium-containing phosphinesulfonate chelate for the hydrogenation of aryl ketones

Ruthenium–Indenylidene Olefin Metathesis Catalyst with Enhanced Thermal Stability ⬇️

Selective and Efficient Iridium Catalyst for the Reductive Amination of Levulinic Acid into Pyrrolidones.

Selective ruthenium-catalyzed hydrochlorination of alkynes: one-step synthesis of vinylchlorides

Site-Selective Ruthenium-Catalyzed C-H Bond Arylations with Boronic Acids: Exploiting Isoindolinones as a Weak Directing Group

Synthesis of heteroarylated polyfluorobiphenyls via palladium-catalyzed sequential sp2 C-H bonds functionalizations

Tandem Catalytic Acrylonitrile Cross-Metathesis and Hydrogenation of Nitriles with Ruthenium Catalysts: Direct Access to Linear α,ω-Aminoesters from Renewables

Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via π-allylic species ⬇️

Unmasking Amides: Ruthenium-Catalyzed Protodecarbonylation of N-Substituted Phthalimide Derivatives

Vicinal α,β-functionalizations of amines: cyclization versus dehydrogenative hydrolysis

sp3 C-H bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines

Cp(η2‐bipy)(MeCN)RuIIPF6 Catalysts for Regioselective Allylic Substitution and Characterization of Dicationic Cp(η2‐bipy)(η3‐allyl)RuIVPF62 Intermediates ⬇️