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List of works by Apparao Draksharapu

A Non-Heme Iron Photocatalyst for Light-Driven Aerobic Oxidation of Methanol

scientific article published on 15 January 2018

A Non-Heme Iron Photocatalyst for Light-Driven Aerobic Oxidation of Methanol

Acid pKa Dependence in O-O Bond Heterolysis of a Nonheme FeIII-OOH Intermediate To Form a Potent FeV═O Oxidant with Heme Compound I-Like Reactivity

scientific article published on 26 September 2019

Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds.

scientific article

An Electrochemical and Raman Spectroscopy Study of the Surface Behaviour of Mononuclear Ruthenium and Osmium Polypyridyl Complexes Based on Pyridyl- and Thiophene-Based Linkers

scholarly article by Yvonne Halpin et al published 17 June 2013 in European Journal of Inorganic Chemistry

Binding of copper(II) polypyridyl complexes to DNA and consequences for DNA-based asymmetric catalysis

scientific article published on February 2015

Characterisation of the interactions between substrate, copper(II) complex and DNA and their role in rate acceleration in DNA-based asymmetric catalysis

scientific article published in February 2015

Conflicting Role of Water in the Activation of H2O2 and the Formation and Reactivity of Non-Heme Fe(III)-OOH and Fe(III)-O-Fe(III) Complexes at Room Temperature

scientific article published on 13 April 2016

Crystallographic Evidence for a Sterically Induced Ferryl Tilt in a Non-Heme Oxoiron(IV) Complex that Makes it a Better Oxidant

Crystallographic Evidence for a Sterically Induced Ferryl Tilt in a Non-Heme Oxoiron(IV) Complex that Makes it a Better Oxidant

scientific article published on 28 June 2018

Dinuclear compounds without a metal–metal bond. Dirhodium(III,III) carboxamidates

Direct photochemical activation of non-heme Fe(iv)[double bond, length as m-dash]O complexes

scientific article

Facile Conversion of syn -[FeIV (O)(TMC)]2+ into the anti Isomer via Meunier's Oxo-Hydroxo Tautomerism Mechanism

scientific article published on 17 January 2019

Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III)

scholarly article by Apparao Draksharapu et al published 27 June 2017 in Angewandte Chemie

Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III).

scientific article published on 9 June 2017

H2O2 Oxidation by FeIII–OOH Intermediates and Its Effect on Catalytic Efficiency

scientific article published on 6 September 2018

Identification and spectroscopic characterization of nonheme iron(III) hypochlorite intermediates.

scientific article published on 6 February 2015

Ligand exchange and spin state equilibria of Fe(II)(N4Py) and related complexes in aqueous media

scientific article published on 23 December 2011

NMR Reveals That a Highly Reactive Nonheme FeIV =O Complex Retains Its Six-Coordinate Geometry and S=1 State in Solution

scientific article published on 27 June 2019

Novel artificial metalloenzymes by in vivo incorporation of metal-binding unnatural amino acids.

scientific article published on 9 October 2014

Off-line reaction monitoring of the oxidation of alkenes in water using drop coating deposition Raman (DCDR) spectroscopy.

scientific article

On the Lewis Acidity of the Oxoiron(IV) Unit in a Tetramethylcyclam Complex

scientific article published on 2 December 2017

Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases

scientific article published on 7 December 2017

Photo-induced oxidation of [Fe(II)(N4Py)CH3CN] and related complexes.

scientific article published in November 2012

Rapid Hydrogen and Oxygen Atom Transfer by a High-Valent Nickel-Oxygen Species

scientific article published on 6 September 2016

Reactivity of a Nickel(II) Bis(amidate) Complex with meta-Chloroperbenzoic Acid: Formation of a Potent Oxidizing Species

scientific article published on 25 August 2015

Reinvestigating 2,5-di(pyridin-2-yl)pyrazine ruthenium complexes: selective deuteration and Raman spectroscopy as tools to probe ground and excited-state electronic structure in homo- and heterobimetallic complexes

scientific article published on 18 August 2011

Sc (or HClO) Activation of a Nonheme Fe-OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene

scientific article published on 17 April 2018

Sc3+-Promoted O-O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O2 to Generate a Complex with an FeIV2(μ-O)2 Core

scientific article published on 19 February 2020

Spectroscopic Analyses on Reaction Intermediates Formed during Chlorination of Alkanes with NaOCl Catalyzed by a Nickel Complex

scientific article published on 5 November 2015

Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-oxo Intermediate

scientific article published on 20 February 2018

Spectroscopic and Reactivity Comparisons between Nonheme Oxoiron(IV) and Oxoiron(V) Species Bearing the Same Ancillary Ligand

scientific article published on 11 September 2019

Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units

scientific article

Spectroscopic characterization of a Ru( iii )-OCl intermediate: a structural mimic of haloperoxidase enzymes ⬇️

scientific article published in 2022

Spectroscopy, photophysics and structural dynamics in metal‐centred species, some recent investigations: from spin‐crossover complexes and oxygen activation to photocatalysis

article

Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

scientific article published in February 2014

Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex

scientific article published on 5 June 2017

Unexpected reversible pyrazine based methylation in a Ru(ii) complex bearing a pyrazin-2′-yl-1,2,4-triazolato ligand and its effect on acid/base and photophysical properties

scientific article published on 04 December 2012

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