List of works - Laurel Schafer

1,3-N,O-Complexes of late transition metals. Ligands with flexible bonding modes and reaction profiles

scientific article

2-Pyridonate tantalum complexes for the intermolecular hydroaminoalkylation of sterically demanding alkenes

scientific article published on 23 July 2014

2-Pyridonate titanium complexes for chemoselectivity. Accessing intramolecular hydroaminoalkylation over hydroamination

scientific article published on 13 November 2013

A Cyclic Ureate Tantalum Catalyst for Preferential Hydroaminoalkylation with Aliphatic Amines. Mechanistic Insights into Substrate Controlled Reactivity

scientific article published on 07 August 2020

Accessing δ-B–H Coordinated Complexes of Rh(I) and Ir(I) Using Mono- and Dihydroboranes: Cooperative Stabilization by a Phosphoramidate Coligand

Amidate complexes of titanium and zirconium: a new class of tunable precatalysts for the hydroamination of alkynes

scientific article published in October 2003

Amidate-Ligated Complexes of Rhodium(I): A Showcase of Coordination Flexibility

scholarly article by Marcus W. Drover et al published April 2015 in Organometallics

An easy-to-use, regioselective, and robust bis(amidate) titanium hydroamination precatalyst: mechanistic and synthetic investigations toward the preparation of tetrahydroisoquinolines and benzoquinolizine alkaloids.

scientific article published in January 2007

Anti-Markovnikov intermolecular hydroamination: a bis(amidate) titanium precatalyst for the preparation of reactive aldimines

scientific article published on 01 November 2003

Bis(amidate)bis(amido) titanium complex: a regioselective intermolecular alkyne hydroamination catalyst

scientific article published on 21 February 2014

Bis(tert-butylimido)bis(N,O-chelate)tungsten(VI) Complexes: Probing Amidate and Pyridonate Hemilability

scientific article published on 26 April 2017

Broadening the scope of group 4 hydroamination catalysis using a tethered ureate ligand

scientific article published in December 2009

C(sp3 )-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex

scholarly article by Marcus W. Drover et al published 13 February 2017 in European Journal of Inorganic Chemistry

C(sp3 )-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex

scholarly article by Marcus W. Drover et al published 19 May 2017 in European Journal of Inorganic Chemistry

Capturing HBCy2 : Using N,O-Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration

scholarly article by Marcus Drover et al published 5 February 2016 in Angewandte Chemie International Edition

Capturing HBCy2 : Using N,O-Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration

scholarly article by Marcus W. Drover et al published 5 February 2016 in Angewandte Chemie

Catalytic Asymmetric Synthesis of Morpholines. Using Mechanistic Insights To Realize the Enantioselective Synthesis of Piperazines

scientific article published on 26 September 2016

Catalytic Asymmetric Synthesis of Substituted Morpholines and Piperazines ⬇️

scientific article published on October 26, 2012

Catalytic and Atom Economic Csp3 - Csp3 Bond Formation α-to Nitrogen. Alkyl Tantalum Ureates for Hydroaminoalkylation.

scientific article published on 13 January 2018

Chiral neutral zirconium amidate complexes for the asymmetric hydroamination of alkenes

scientific article published on 01 January 2007

Computational and theoretical approaches for mechanistic understanding: general discussion

scientific article published on 01 December 2019

Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(iii) phosphoramidate complex

scientific article published on 23 June 2017

Dynamics of partially miscible polylactide-poly(ε-caprolactone) blends in the presence of cold crystallization

Earth abundant element compounds in homogeneous catalysis

scientific article published on 19 June 2015

Facile access to tuneable Schwartz's reagents: oxidative addition products from the reaction of amide N-H bonds with reduced zirconocene complexes

scientific article published on 03 September 2013

Four-membered heterometallacyclic d⁰ and d¹ complexes of Group 4 metallocenes with amidato ligands

scientific article published on 23 May 2014

Front Cover: C(sp3 )-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex (Eur. J. Inorg. Chem. 20/2017)

scholarly article by Marcus W. Drover et al published 19 May 2017 in European Journal of Inorganic Chemistry

In Situ Generation of a Regio- and Diastereoselective Hydroaminoalkylation Catalyst Using Commercially Available Starting Materials

scientific article published on 01 November 2017

Intermolecular hydroamination of oxygen-substituted allenes. New routes for the synthesis of N,O-chelated zirconium and titanium amido complexes

scientific article published on 01 July 2011

Intramolecular hydroamination catalysis using trans-N,N′-dibenzylcyclam zirconium complexes

scientific article published in January 2011

Intramolecular hydroamination of unactived olefins with Ti(NMe2)4 as a precatalyst

scientific article published on 01 May 2005

Isocyanate deinsertion from κ1-O amidates: facile access to perfluoroaryl rhodium(i) complexes

scientific article published on 01 December 2015

Isolation of Catalytic Intermediates in Hydroamination Reactions: Insertion of Internal Alkynes into a Zirconium–Amido Bond ⬇️

scientific article published on August 23, 2010

Mechanistic Elucidation of Intramolecular Aminoalkene Hydroamination Catalyzed by a Tethered Bis(ureate) Complex: Evidence for Proton-Assisted C–N Bond Formation at Zirconium ⬇️

scientific article published on 07 September 2011

Mechanistic insight into organic and industrial transformations: general discussion

scientific article published on 01 December 2019

Modular, efficient synthesis of asymmetrically substituted piperazine scaffolds as potent calcium channel blockers ⬇️

scientific article published on April 4, 2013

Mono, bis, and tris(phosphoramidate) titanium complexes: synthesis, structure, and reactivity investigations

scientific article published on 01 July 2019

N,O-Chelating Four-Membered Metallacyclic Titanium(IV) Complexes for Atom-Economic Catalytic Reactions

scientific article published on 6 August 2015

N-Silylenamines as Reactive Intermediates: Hydroamination for the Modular Synthesis of Selectively Substituted Pyridines

article

Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C-H) Agostic Complex.

scientific article published on 21 September 2016

Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C−H) Agostic Complex

scholarly article by D. Dawson Beattie et al published 6 October 2016 in Angewandte Chemie

Oxygenextrusion from amidate ligands to generate terminal TaO units under reducing conditions. How to successfully use amidate ligands in dinitrogen coordination chemistry ⬇️

scientific article published on 07 December 2011

Phosphoramidate tantalum complexes for room-temperature C-H functionalization: hydroaminoalkylation catalysis

scientific article published on 23 July 2013

Phosphoramidate-Assisted Alkyne Activation: Probing the Mechanism of Proton Shuttling in a N,O-Chelated Cp*Ir(III) Complex

Phosphoramidate-Supported Cp*IrIII Aminoborane H2 B=NR2 Complexes: Synthesis, Structure, and Solution Dynamics

scientific article published on 31 March 2016

Physical methods for mechanistic understanding: general discussion

scientific article published on 01 December 2019

Rare-earth amidate complexes. Easily accessed initiators for epsilon-caprolactone ring-opening polymerization

scientific article published on 19 August 2008

Reactivity of an Unsaturated Iridium(III) Phosphoramidate Complex, [Cp*Ir{κ2-N,O}][BArF4]

scholarly article by Marcus W. Drover et al published 22 July 2015 in Organometallics

Redundant CAMTA Transcription Factors Negatively Regulate the Biosynthesis of Salicylic Acid and N-Hydroxypipecolic Acid by Modulating the Expression of SARD1 and CBP60g

scientific article published on 13 November 2019

Regio- and Stereoselective Hydroamination of Alkynes Using an Ammonia Surrogate: Synthesis of N-Silylenamines as Reactive Synthons

scientific article published on 05 April 2018

Selective C-H activation alpha to primary amines. Bridging metallaaziridines for catalytic, intramolecular alpha-alkylation

scientific article published in February 2009

Structure, bonding, and reactivity of Ti and Zr amidate complexes: DFT and X-ray crystallographic studies

scientific article

Synthesis, structure, and reactivity of tris(amidate) mono(amido) and tetrakis(amidate) complexes of group 4 transition metals

scientific article published on 01 November 2013

Ta-Catalyzed Hydroaminoalkylation of Alkenes: Insights into Ligand-Modified Reactivity Using DFT

TaMe3Cl2‐Catalyzed Intermolecular Hydroaminoalkylation: A Simple Complex for Enhanced Reactivity and Expanded Substrate Scope ⬇️

scientific article published on May 17, 2013

Tantallaaziridines: from synthesis to catalytic applications ⬇️

scientific article published on June 25, 2012

Tantalum catalyzed hydroaminoalkylation for the synthesis of α- and β-substituted N-heterocycles

scientific article published on 19 April 2013

Tantalum-amidate complexes for the hydroaminoalkylation of secondary amines: enhanced substrate scope and enantioselective chiral amine synthesis

scientific article published on 01 January 2009

Ti Catalyzed Hydroamination: A Direct Functionalization of Cu Acetylide

article published in 2019

Ti-Catalyzed Hydroamination for the Synthesis of Amine-Containing π-Conjugated Materials

scientific article published on 27 December 2017

Titanium catalysis for the synthesis of fine chemicals - development and trends

scientific article published on 27 August 2020

Titanium pyridonates and amidates: novel catalysts for the synthesis of random copolymers.

scientific article

Titanium pyridonates for the homo- and copolymerization of rac-lactide and ε-caprolactone

scientific article published on 01 July 2015

Toward anti-Markovnikov 1-Alkyne O-Phosphoramidation: Exploiting Metal-Ligand Cooperativity in a 1,3-N,O-Chelated Cp*Ir(III) Complex

scientific article published on 21 June 2016

Understanding Ni(II)-Mediated C(sp)-H Activation: Tertiary Ureas as Model Substrates

scientific article published on 20 September 2018

Vanadium Pyridonate Catalysts: Isolation of Intermediates in the Reductive Coupling of Alcohols

scientific article published on 28 March 2020

Yttrium (amidate) complexes for catalytic C-N bond formation. Rapid, room temperature amidation of aldehydes

scientific article published on 04 May 2012

Zirconium Hydroaminoalkylation. An Alternative Disconnection for the Catalytic Synthesis of α-Arylated Primary Amines

scientific article published on 22 November 2019

Zirconium bis(pyridonate): a modified amidate complex for enhanced substrate scope in aminoalkene cyclohydroamination

scientific article published on 12 October 2009

Zirconium catalyzed alkyne dimerization for selective Z-enyne synthesis ⬇️

scientific article published on 01 November 2012

Zirconium-Catalyzed Hydroaminoalkylation of Alkynes for the Synthesis of Allylic Amines

scientific article published on 28 November 2020

Zirconocene-mediated, high-yielding macrocyclizations of silyl-terminated diynes.

scientific article published in January 2002

List of works by Laurel Schafer

1,3-N,O-Complexes of late transition metals. Ligands with flexible bonding modes and reaction profiles

2-Pyridonate tantalum complexes for the intermolecular hydroaminoalkylation of sterically demanding alkenes

2-Pyridonate titanium complexes for chemoselectivity. Accessing intramolecular hydroaminoalkylation over hydroamination

A Cyclic Ureate Tantalum Catalyst for Preferential Hydroaminoalkylation with Aliphatic Amines. Mechanistic Insights into Substrate Controlled Reactivity

Accessing δ-B–H Coordinated Complexes of Rh(I) and Ir(I) Using Mono- and Dihydroboranes: Cooperative Stabilization by a Phosphoramidate Coligand

Amidate complexes of titanium and zirconium: a new class of tunable precatalysts for the hydroamination of alkynes

Amidate-Ligated Complexes of Rhodium(I): A Showcase of Coordination Flexibility

An easy-to-use, regioselective, and robust bis(amidate) titanium hydroamination precatalyst: mechanistic and synthetic investigations toward the preparation of tetrahydroisoquinolines and benzoquinolizine alkaloids.

Anti-Markovnikov intermolecular hydroamination: a bis(amidate) titanium precatalyst for the preparation of reactive aldimines

Bis(amidate)bis(amido) titanium complex: a regioselective intermolecular alkyne hydroamination catalyst

Bis(tert-butylimido)bis(N,O-chelate)tungsten(VI) Complexes: Probing Amidate and Pyridonate Hemilability

Broadening the scope of group 4 hydroamination catalysis using a tethered ureate ligand

C(sp3 )-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex

C(sp3 )-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex

Capturing HBCy2 : Using N,O-Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration

Capturing HBCy2 : Using N,O-Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration

Catalytic Asymmetric Synthesis of Morpholines. Using Mechanistic Insights To Realize the Enantioselective Synthesis of Piperazines

Catalytic Asymmetric Synthesis of Substituted Morpholines and Piperazines ⬇️

Catalytic and Atom Economic Csp3 - Csp3 Bond Formation α-to Nitrogen. Alkyl Tantalum Ureates for Hydroaminoalkylation.

Chiral neutral zirconium amidate complexes for the asymmetric hydroamination of alkenes

Computational and theoretical approaches for mechanistic understanding: general discussion

Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(iii) phosphoramidate complex

Dynamics of partially miscible polylactide-poly(ε-caprolactone) blends in the presence of cold crystallization

Earth abundant element compounds in homogeneous catalysis

Facile access to tuneable Schwartz's reagents: oxidative addition products from the reaction of amide N-H bonds with reduced zirconocene complexes

Four-membered heterometallacyclic d⁰ and d¹ complexes of Group 4 metallocenes with amidato ligands

Front Cover: C(sp3 )-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex (Eur. J. Inorg. Chem. 20/2017)

In Situ Generation of a Regio- and Diastereoselective Hydroaminoalkylation Catalyst Using Commercially Available Starting Materials

Intermolecular hydroamination of oxygen-substituted allenes. New routes for the synthesis of N,O-chelated zirconium and titanium amido complexes

Intramolecular hydroamination catalysis using trans-N,N′-dibenzylcyclam zirconium complexes

Intramolecular hydroamination of unactived olefins with Ti(NMe2)4 as a precatalyst

Isocyanate deinsertion from κ1-O amidates: facile access to perfluoroaryl rhodium(i) complexes

Isolation of Catalytic Intermediates in Hydroamination Reactions: Insertion of Internal Alkynes into a Zirconium–Amido Bond ⬇️

Mechanistic Elucidation of Intramolecular Aminoalkene Hydroamination Catalyzed by a Tethered Bis(ureate) Complex: Evidence for Proton-Assisted C–N Bond Formation at Zirconium ⬇️

Mechanistic insight into organic and industrial transformations: general discussion

Modular, efficient synthesis of asymmetrically substituted piperazine scaffolds as potent calcium channel blockers ⬇️

Mono, bis, and tris(phosphoramidate) titanium complexes: synthesis, structure, and reactivity investigations

N,O-Chelating Four-Membered Metallacyclic Titanium(IV) Complexes for Atom-Economic Catalytic Reactions

N-Silylenamines as Reactive Intermediates: Hydroamination for the Modular Synthesis of Selectively Substituted Pyridines

Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C-H) Agostic Complex.

Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C−H) Agostic Complex

Oxygenextrusion from amidate ligands to generate terminal TaO units under reducing conditions. How to successfully use amidate ligands in dinitrogen coordination chemistry ⬇️

Phosphoramidate tantalum complexes for room-temperature C-H functionalization: hydroaminoalkylation catalysis

Phosphoramidate-Assisted Alkyne Activation: Probing the Mechanism of Proton Shuttling in a N,O-Chelated Cp*Ir(III) Complex

Phosphoramidate-Supported Cp*IrIII Aminoborane H2 B=NR2 Complexes: Synthesis, Structure, and Solution Dynamics

Physical methods for mechanistic understanding: general discussion

Rare-earth amidate complexes. Easily accessed initiators for epsilon-caprolactone ring-opening polymerization

Reactivity of an Unsaturated Iridium(III) Phosphoramidate Complex, [Cp*Ir{κ2-N,O}][BArF4]

Redundant CAMTA Transcription Factors Negatively Regulate the Biosynthesis of Salicylic Acid and N-Hydroxypipecolic Acid by Modulating the Expression of SARD1 and CBP60g

Regio- and Stereoselective Hydroamination of Alkynes Using an Ammonia Surrogate: Synthesis of N-Silylenamines as Reactive Synthons

Selective C-H activation alpha to primary amines. Bridging metallaaziridines for catalytic, intramolecular alpha-alkylation

Structure, bonding, and reactivity of Ti and Zr amidate complexes: DFT and X-ray crystallographic studies

Synthesis, structure, and reactivity of tris(amidate) mono(amido) and tetrakis(amidate) complexes of group 4 transition metals

Ta-Catalyzed Hydroaminoalkylation of Alkenes: Insights into Ligand-Modified Reactivity Using DFT

TaMe3Cl2‐Catalyzed Intermolecular Hydroaminoalkylation: A Simple Complex for Enhanced Reactivity and Expanded Substrate Scope ⬇️

Tantallaaziridines: from synthesis to catalytic applications ⬇️

Tantalum catalyzed hydroaminoalkylation for the synthesis of α- and β-substituted N-heterocycles

Tantalum-amidate complexes for the hydroaminoalkylation of secondary amines: enhanced substrate scope and enantioselective chiral amine synthesis

Ti Catalyzed Hydroamination: A Direct Functionalization of Cu Acetylide

Ti-Catalyzed Hydroamination for the Synthesis of Amine-Containing π-Conjugated Materials

Titanium catalysis for the synthesis of fine chemicals - development and trends

Titanium pyridonates and amidates: novel catalysts for the synthesis of random copolymers.

Titanium pyridonates for the homo- and copolymerization of rac-lactide and ε-caprolactone

Toward anti-Markovnikov 1-Alkyne O-Phosphoramidation: Exploiting Metal-Ligand Cooperativity in a 1,3-N,O-Chelated Cp*Ir(III) Complex

Understanding Ni(II)-Mediated C(sp)-H Activation: Tertiary Ureas as Model Substrates

Vanadium Pyridonate Catalysts: Isolation of Intermediates in the Reductive Coupling of Alcohols

Yttrium (amidate) complexes for catalytic C-N bond formation. Rapid, room temperature amidation of aldehydes

Zirconium Hydroaminoalkylation. An Alternative Disconnection for the Catalytic Synthesis of α-Arylated Primary Amines

Zirconium bis(pyridonate): a modified amidate complex for enhanced substrate scope in aminoalkene cyclohydroamination

Zirconium catalyzed alkyne dimerization for selective Z-enyne synthesis ⬇️

Zirconium-Catalyzed Hydroaminoalkylation of Alkynes for the Synthesis of Allylic Amines

Zirconocene-mediated, high-yielding macrocyclizations of silyl-terminated diynes.