List of works - Vincenzo Passarelli

A highly efficient Ir-catalyst for the solventless dehydrogenation of formic acid: the key role of an N-heterocyclic olefin

A well-defined NHC-Ir(iii) catalyst for the silylation of aromatic C-H bonds: substrate survey and mechanistic insights

scientific article published on 5 April 2017

An Unprecedented Iridium(III) Catalyst for Stereoselective Dimerisation of Terminal Alkynes

scholarly article by Marco Ciclosi et al published 25 January 2008 in Advanced Synthesis & Catalysis

Bond Activation and Catalysis

Comparative study of [RuClCp(HdmoPTA-κP)(PPh3)][CF3SO3] and the heterobimetallic complexes [RuClCp(PPh3)-μ-dmoPTA-1κP:2κ2N,N′-M(acac-κ2O,O′)2] (M = Co, Ni, Zn; dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)

scientific article published on 21 February 2011

En route to phosphonato iridium(i) complexes: the decisive effect of an intramolecular hydrogen bond

scholarly article by Vincenzo Passarelli et al published 2016 in Dalton Transactions

Experimental and Theoretical Mechanistic Investigation on the Catalytic CO2 Hydrogenation to Formate by a Carboxylate-Functionalized Bis(N-heterocyclic carbene) Zwitterionic Iridium(I) Compound

scholarly article by Raquel Puerta-Oteo et al published 28 August 2017 in Organometallics

Formation of a bridging-imido d6 rhodium compound by nitrene capture. insertion and cycloaddition reactions

scientific article

Intervalent bis(mu-aziridinato)M(II)--M(I) complexes (M=Rh,Ir): delocalized metallo-radicals or delocalized aminyl radicals?

scientific article

Intramolecular C–H Oxidative Addition to Iridium(I) in Complexes Containing a N,N′-Diphosphanosilanediamine Ligand

article

Intramolecular C–H oxidative addition to iridium(i) triggered by trimethyl phosphite in N,N′-diphosphanesilanediamine complexes

article

Ligand Lability Driven by Metal-to-Borane Pseudorotation: A Mechanism for Ligand Exchange

scientific article published on 04 December 2020

Mechanistic Investigation on the Polymerization of Phenylacetylene by 2-Diphenylphosphinopyridine Rhodium(I) Catalysts: Understanding the Role of the Cocatalyst and Alkynyl Intermediates

Mechanistic insights into the tropo-inversion of the biphenyl moiety in chiral bis-amido phosphites and in their palladium(ii) complexes.

scientific article

Metal as Source of Chirality in Octahedral Complexes with Tripodal Tetradentate Ligands

scientific article

Pd(II) complexes of monodentate deoxycholic acid derived binaphthyl diamido phosphites as chiral catalysts in the asymmetric Suzuki-Miyaura cross-coupling

scholarly article by Grazia Iannucci et al published November 2017 in Tetrahedron: Asymmetry

Pentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N-Heterocyclic Carbene Ligands

Perfluorofluorenyl anions and their use as co-catalysts in the zirconocene-promoted polymerization of olefins

Postsynthetic modifications of [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] with Lewis bases: cluster modular tuning

scientific article published on 4 May 2016

Reactivity of NovelN,N′-Diphosphino-Silanediamine-Based Rhodium(I) Derivatives

article

Reversible Activation of Water by an Air- and Moisture-Stable Frustrated Rhodium Nitrogen Lewis Pair

scientific article published on 20 August 2019

Reversible Small-Molecule Interactions with Coordinatively Unsaturated Metal Centers Held in Metallathiaborane Clusters

Rhodium(I)-N-Heterocyclic Carbene Catalyst for Selective Coupling of N-Vinylpyrazoles with Alkynes via C–H Activation

article

Rhodium(III)-Catalyzed Dimerization of Aldehydes to Esters

scholarly article by Cristina Tejel et al published 7 December 2010 in Chemistry—A European Journal

Rhodium–N-Heterocyclic Carbene Catalyzed Hydroalkenylation Reactions with 2-Vinylpyridine and 2-Vinylpyrazine: Preparation of Nitrogen-Bridgehead Heterocycles

Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligands

scientific article published on 30 March 2004

Stabilization of the Hydroperoxido Ligand: A 1κO,2κO′ Dimetallic Coordination Mode

scholarly article by Cristina Tejel et al published 28 February 2008 in Angewandte Chemie International Edition

Stereospecific control of the metal-centred chirality of rhodium(iii) and iridium(iii) complexes bearing tetradentate CNN'P ligands

scientific article published on 26 May 2017

Structure and protonation of the bis-ethylene adduct [Pt(μ-PBut2)(η2-CH2CH2)]2. Pt–H–P agostic interaction and proton scrambling

Synproportionation reactions between copper(II) trihalogenoacetates Cu(CX3CO2)2, X = F, Cl or Br, and copper in the presence of carbon monoxide

Synthesis and reactivity of the novel hydride derivative RhHCl(TIMP(3)) (HTIMP(3) = tris[1-(diphenylphosphino)-3-methyl-1H-indol-2-yl]methane).

scientific article published on 9 February 2009

Synthesis and structural characterization of iron(II) derivatives of heterocyclic tridentate amines

article published in 2003

Synthesis, characterization, and reactivity of manganese(II) and iron(II) trifluoroacetates. Crystal and molecular structure of two linkage isomers of polynuclear [Mn(CF 3 COO) 2 (THF) 2 ] n

scholarly article by Fausto Calderazzo et al published 2001 in Canadian Journal of Chemistry

Synthesis, reactivity and structures of mono- and dihaloacetato complexes of copper(I) and copper(II)

Synthesis, spectroscopy and electrochemistry of new 4-(4-acetyl-5- substituted-4, 5-dihydro-1, 3,4-oxodiazol-2-yl)methoxy)-2H-chromen-2-ones as a novel class of potential antibacterial and antioxidant derivatives

article by N. Hamdi et al published June 2011 in Comptes Rendus Chimie

Synthesis, variable temperature NMR investigations and solid state characterization of novel octafluorofluorene compounds

article published in 2009

Temperature Dual Enantioselective Control in a Rhodium-Catalyzed Michael-Type Friedel-Crafts Reaction: A Mechanistic Explanation.

scientific article published on 27 June 2016

The Ligating Ability of Functionalised Diaminodimethylsilanes towards Zirconium(IV)

scholarly article by Vincenzo Passarelli et al published April 2004 in European Journal of Inorganic Chemistry

The Stepwise Reaction of Rhodium and Iridium Complexes of formula [MCl2(κ4C,N,N',P-L)] with Silver Cations: A Case of trans-Influence and Chiral Self-Recognition

scientific article

Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum framework

Unsymmetrically Substituted Dimethyldiaminosilanes as Ligands towards Zirconium(IV)

scholarly article by Vincenzo Passarelli & Pierino Zanella published November 2004 in European Journal of Inorganic Chemistry

Zwitterionic Rhodium and Iridium Complexes Based on a Carboxylate Bridge-Functionalized Bis-N-heterocyclic Carbene Ligand: Synthesis, Structure, Dynamic Behavior, and Reactivity.

scientific article published on 6 April 2018

List of works by Vincenzo Passarelli

A highly efficient Ir-catalyst for the solventless dehydrogenation of formic acid: the key role of an N-heterocyclic olefin

A well-defined NHC-Ir(iii) catalyst for the silylation of aromatic C-H bonds: substrate survey and mechanistic insights

An Unprecedented Iridium(III) Catalyst for Stereoselective Dimerisation of Terminal Alkynes

Bond Activation and Catalysis

Comparative study of [RuClCp(HdmoPTA-κP)(PPh3)][CF3SO3] and the heterobimetallic complexes [RuClCp(PPh3)-μ-dmoPTA-1κP:2κ2N,N′-M(acac-κ2O,O′)2] (M = Co, Ni, Zn; dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)

En route to phosphonato iridium(i) complexes: the decisive effect of an intramolecular hydrogen bond

Experimental and Theoretical Mechanistic Investigation on the Catalytic CO2 Hydrogenation to Formate by a Carboxylate-Functionalized Bis(N-heterocyclic carbene) Zwitterionic Iridium(I) Compound

Formation of a bridging-imido d6 rhodium compound by nitrene capture. insertion and cycloaddition reactions

Intervalent bis(mu-aziridinato)M(II)--M(I) complexes (M=Rh,Ir): delocalized metallo-radicals or delocalized aminyl radicals?

Intramolecular C–H Oxidative Addition to Iridium(I) in Complexes Containing a N,N′-Diphosphanosilanediamine Ligand

Intramolecular C–H oxidative addition to iridium(i) triggered by trimethyl phosphite in N,N′-diphosphanesilanediamine complexes

Ligand Lability Driven by Metal-to-Borane Pseudorotation: A Mechanism for Ligand Exchange

Mechanistic Investigation on the Polymerization of Phenylacetylene by 2-Diphenylphosphinopyridine Rhodium(I) Catalysts: Understanding the Role of the Cocatalyst and Alkynyl Intermediates

Mechanistic insights into the tropo-inversion of the biphenyl moiety in chiral bis-amido phosphites and in their palladium(ii) complexes.

Metal as Source of Chirality in Octahedral Complexes with Tripodal Tetradentate Ligands

Pd(II) complexes of monodentate deoxycholic acid derived binaphthyl diamido phosphites as chiral catalysts in the asymmetric Suzuki-Miyaura cross-coupling

Pentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N-Heterocyclic Carbene Ligands

Perfluorofluorenyl anions and their use as co-catalysts in the zirconocene-promoted polymerization of olefins

Postsynthetic modifications of [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] with Lewis bases: cluster modular tuning

Reactivity of NovelN,N′-Diphosphino-Silanediamine-Based Rhodium(I) Derivatives

Reversible Activation of Water by an Air- and Moisture-Stable Frustrated Rhodium Nitrogen Lewis Pair

Reversible Small-Molecule Interactions with Coordinatively Unsaturated Metal Centers Held in Metallathiaborane Clusters

Rhodium(I)-N-Heterocyclic Carbene Catalyst for Selective Coupling of N-Vinylpyrazoles with Alkynes via C–H Activation

Rhodium(III)-Catalyzed Dimerization of Aldehydes to Esters

Rhodium–N-Heterocyclic Carbene Catalyzed Hydroalkenylation Reactions with 2-Vinylpyridine and 2-Vinylpyrazine: Preparation of Nitrogen-Bridgehead Heterocycles

Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligands

Stabilization of the Hydroperoxido Ligand: A 1κO,2κO′ Dimetallic Coordination Mode

Stereospecific control of the metal-centred chirality of rhodium(iii) and iridium(iii) complexes bearing tetradentate CNN'P ligands

Structure and protonation of the bis-ethylene adduct [Pt(μ-PBut2)(η2-CH2CH2)]2. Pt–H–P agostic interaction and proton scrambling

Synproportionation reactions between copper(II) trihalogenoacetates Cu(CX3CO2)2, X = F, Cl or Br, and copper in the presence of carbon monoxide

Synthesis and reactivity of the novel hydride derivative RhHCl(TIMP(3)) (HTIMP(3) = tris[1-(diphenylphosphino)-3-methyl-1H-indol-2-yl]methane).

Synthesis and structural characterization of iron(II) derivatives of heterocyclic tridentate amines

Synthesis, characterization, and reactivity of manganese(II) and iron(II) trifluoroacetates. Crystal and molecular structure of two linkage isomers of polynuclear [Mn(CF 3 COO) 2 (THF) 2 ] n

Synthesis, reactivity and structures of mono- and dihaloacetato complexes of copper(I) and copper(II)

Synthesis, spectroscopy and electrochemistry of new 4-(4-acetyl-5- substituted-4, 5-dihydro-1, 3,4-oxodiazol-2-yl)methoxy)-2H-chromen-2-ones as a novel class of potential antibacterial and antioxidant derivatives

Synthesis, variable temperature NMR investigations and solid state characterization of novel octafluorofluorene compounds

Temperature Dual Enantioselective Control in a Rhodium-Catalyzed Michael-Type Friedel-Crafts Reaction: A Mechanistic Explanation.

The Ligating Ability of Functionalised Diaminodimethylsilanes towards Zirconium(IV)

The Stepwise Reaction of Rhodium and Iridium Complexes of formula [MCl2(κ4C,N,N',P-L)] with Silver Cations: A Case of trans-Influence and Chiral Self-Recognition

Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum framework

Unsymmetrically Substituted Dimethyldiaminosilanes as Ligands towards Zirconium(IV)

Zwitterionic Rhodium and Iridium Complexes Based on a Carboxylate Bridge-Functionalized Bis-N-heterocyclic Carbene Ligand: Synthesis, Structure, Dynamic Behavior, and Reactivity.